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31. 发明授权

US5298579A Olefin polymerization process 失效
标题翻译：烯烃聚合工艺
公开(公告)号：US5298579A
公开(公告)日：1994-03-29
申请号：US976194
申请日：1992-11-13
申请人： Raymond E. Hoff , Leonard V. Cribbs
发明人： Raymond E. Hoff , Leonard V. Cribbs
IPC分类号： C08F4/609 , C08F10/00 , C08J9/00
CPC分类号： C08F10/00 , Y10S526/904 , Y10S526/943
摘要： A method of using a catalyst with a suitable cocatalyst in the polymerization or copolymerization of 1-olefins are disclosed. The catalyst is prepared by: a) contacting a Group IIA organometallic compound, like 2-methylpentanoxymagnesium chloride, or a Group III organometallic compound, like triethylaluminum, or a combination thereof, with a porous or nonporous biodegradable substrate having active surface hydroxyl groups, like cellulose, to provide a modified biodegradable substrate; then b) contacting the modified biodegradable substrate with a transition metal compound, such as a transition metal halide or alkoxide, like titanium tetrachloride or vanadium (V) trichloride oxide, to form discrete catalyst particles. The catalyst particles are used in conjunction with a suitable cocatalyst, like triethylaluminum, in the homopolymerization or copolymerization of 1-olefins. During polymerization, porous biodegradable catalyst particles are fragmented into small solid particles that are trapped within polymer. The fragmented catalyst particles are allowed to remain within the polymer; do not adversely affect the physical or esthetic properties of the polymer or articles made therefrom; and serve as biodegradable sites that facilitate environmental degradation of the polymer.
摘要翻译：公开了在1-烯烃的聚合或共聚中使用具有合适助催化剂的催化剂的方法。该催化剂通过以下方法制备：a）使IIA族有机金属化合物如2-甲基戊氧基氯化镁或III族有机金属化合物如三乙基铝或其组合与具有活性表面羟基的多孔或无孔可生物降解底物接触，如纤维素，以提供改性的可生物降解底物; 然后b）使改性的可生物降解底物与过渡金属化合物如过渡金属卤化物或醇盐如四氯化钛或钒（V）三氯化氧接触，以形成离散的催化剂颗粒。催化剂颗粒与合适的助催化剂如三乙基铝一起用于1-烯烃的均聚或共聚。在聚合过程中，多孔可生物降解的催化剂颗粒被分散在被聚集在聚合物内的小固体颗粒中。使碎裂的催化剂颗粒保留在聚合物内; 不会对聚合物或由其制成的制品的物理或美学性质产生不利影响; 并且用作促进聚合物环境降解的可生物降解位点。

32. 发明授权

US5283049A Minimizing coking problems in tubular process furnaces 失效
标题翻译：最小化管状加工炉中的焦化问题
公开(公告)号：US5283049A
公开(公告)日：1994-02-01
申请号：US900880
申请日：1992-06-18
申请人： Joseph H. Fluder , Richard A. Benson , Julio A. Peguero
发明人： Joseph H. Fluder , Richard A. Benson , Julio A. Peguero
IPC分类号： B01J19/00 , C01B3/24 , C10G9/16 , F28D7/00
CPC分类号： C01B3/24 , B01J19/0026 , C10G9/16
摘要： A closed tube extension or deadleg is included below the vertical tube of a hydrocarbon pyrolysis furnace. The deadleg passively collects spall coke particles to avoid plugging of the tube or its hydrocarbon inlet. Inspection or cleaning devices can be inserted through the deadleg into the tube and blocked tubes can be cleared. Pressurized steam and/or air can be injected through the deadleg to accelerate decoking of individual tubes.
摘要翻译：在碳氢化合物热解炉的垂直管下面包括一个封闭的管延伸部分或死鱼杆。尸体被动地收集散粒焦炭颗粒，以避免管或其碳氢化合物入口堵塞。检查或清洁装置可以插入管内，并可将被堵塞的管子清除。加压的蒸汽和/或空气可以通过该死板注入，以加速单个管的脱焦。

33. 发明授权

US5266627A Hydrolyzable silane copolymer compositions resistant to premature crosslinking and process 失效
标题翻译：耐水解性硅烷共聚物组合物耐过早交联和工艺
公开(公告)号：US5266627A
公开(公告)日：1993-11-30
申请号：US914375
申请日：1992-07-15
申请人： Craig C. Meverden , Robert L. Silverman
发明人： Craig C. Meverden , Robert L. Silverman
IPC分类号： C08K3/00 , C08K3/04 , C08K3/22 , C08L43/04 , C08K5/09 , C08F230/08
CPC分类号： C08K3/22 , C08K3/0033 , C08K3/04 , C08L43/04
摘要： Filled, pelletized silane copolymer compositions resistant to premature crosslinking during compounding and storage but which are readily hydrolyzed and undergo cure in the presence of silanol condensation catalyst are provided. The compositions comprise random copolymers of ethylene an vinyltriethoxysilane with relatively high levels of particulate fillers, such as carbon black, alumina trihydrate and the like, dispersed therein. The invention also relates to a method of crosslinking these compositions by combining the filled silane copolymer composition with a second component containing a silanol condensation.
摘要翻译：提供了在混合和储存期间耐过早交联但在硅烷醇缩合催化剂存在下易于水解和经历固化的填充的，造粒的硅烷共聚物组合物。组合物包含乙烯，乙烯基三乙氧基硅烷与分散在其中的相对高含量的颗粒填料如炭黑，三水合氧化铝等的无规共聚物。本发明还涉及通过将填充的硅烷共聚物组合物与含有硅烷醇缩合物的第二组分组合来交联这些组合物的方法。

34. 发明授权

US5237097A Catalytic carbonylation process 失效
标题翻译：催化羰基化工艺
公开(公告)号：US5237097A
公开(公告)日：1993-08-17
申请号：US994819
申请日：1992-12-22
申请人： David W. Smith , Ronnie M. Hanes
发明人： David W. Smith , Ronnie M. Hanes
IPC分类号： C07C51/12 , C07C51/14 , C07C67/36 , C07C67/38
CPC分类号： C07C51/12
摘要： A process is disclosed for the carbonylation of an organic compound selected from the group consisting of an olefin, an alcohol, an acid and an ester. In this process the organic compound is reacted with carbon monoxide in the presence of a Group VIII metal-containing catalyst. The liquid carbonylation product solution of this reaction is conveyed to a separation zone maintained at a lower total pressure than is the pressure in the reaction zone. Simultaneously with the conveyance of the liquid product solution to the separation zone is the introduction therein of a carbon monoxide-containing gaseous stream, the carbon monoxide therein contributing a partial pressure of up to 30 psia of the total pressure in said separation zone. A portion of the liquid carbonylation product solution is flashed and removed from the separation zone. The unflashed liquid carbonylation product solution is recycled back into the reaction zone.
摘要翻译：公开了用于羰基化选自烯烃，醇，酸和酯的有机化合物的方法。在该方法中，有机化合物与一氧化碳在含Ⅷ族金属的催化剂存在下反应。将该反应的液体羰基化产物溶液输送到保持在比反应区中的压力更低的总压力的分离区。在将液体产物溶液输送到分离区的同时，其中引入含一氧化碳气体物流，其中的一氧化碳在所述分离区域中提供高达30psia的总压力的分压。一部分液体羰基化产物溶液被闪蒸并从分离区除去。未闪蒸的液体羰基化产物溶液循环回到反应区。

35. 发明授权

US5225469A Flame retardant polymeric compositions 失效
公开(公告)号：US5225469A
公开(公告)日：1993-07-06
申请号：US921617
申请日：1992-08-03
申请人： Melvin F. Maringer , James W. Biggs
发明人： Melvin F. Maringer , James W. Biggs
IPC分类号： C08K3/22 , C08K5/5419 , C08L23/08 , H01B3/44
CPC分类号： H01B3/441 , C08K3/22 , C08K5/5419 , C08L23/0853 , C08L2201/02 , C08L23/0869 , C08L2312/00
摘要： The present invention relates to improved polymeric compositions based on ethylene-vinyl ester and ethylene-alkyl acrylate copolymers which can be crosslinked to provide insulation coatings for wire and cable products. The copolymer compositions contain a hydrated inorganic filler, an alkoxysilane, an antioxidant and a polymeric processing additive. Organic peroxides are preferably employed to facilitate crosslinking. An improved method for providing the improved compositions and electrical conductors coated with the crosslinkable polymeric compositions are also provided by the invention.

36. 发明授权

US5219930A Process for converting vinyl alcohol polymers to poly(keto-esters) therefrom 失效
标题翻译：将乙烯醇聚合物转化成聚（乙酸酯）的方法
公开(公告)号：US5219930A
公开(公告)日：1993-06-15
申请号：US6568
申请日：1993-01-21
申请人： Biau-Hung Chang , Jack Kwiatek , Thomas S. Brima
发明人： Biau-Hung Chang , Jack Kwiatek , Thomas S. Brima
IPC分类号： C08F8/06
CPC分类号： C08F8/06 , C08F2810/50
摘要： Processes for converting vinyl alcohol polymers to poly(keto-esters) and the novel products obtained therefrom are disclosed. The process involves reacting a vinyl alcohol polymer, such as PVA or EVOH, with an organic peroxyacid oxidizing agent in an inert liquid medium at a temperature from -20.degree. C. to 150.degree. C. to convert the secondary hydroxyl groups of the vinyl alcohol polymer to carbonyl and oxycarbonyl groups. In another aspect of the invention, the vinyl alcohol copolymer is first reacted with an oxidizing agent capable of converting the secondary hydroxyl groups to carbonyl but not to oxycarbonyl and then subsequently oxidized using a peroxyacid to form oxycarbonyl. The poly(keto-esters) comprised of carbonyl units, oxycarbonyl units, hydroxyl-containing units and units which are primarily hydrocarbons in nature are photodegradable and biodegradable.
摘要翻译：公开了将乙烯醇聚合物转化成聚（酮 - 酯）的方法和由其获得的新产品。该方法包括使乙烯醇聚合物如PVA或EVOH与有机过氧酸氧化剂在惰性液体介质中在-20℃至150℃的温度下反应，以将乙烯醇的仲羟基聚合物与羰基和氧羰基。在本发明的另一方面，乙烯醇共聚物首先与能够将仲羟基转化成羰基而不是氧羰基的氧化剂反应，然后用过氧酸氧化形成氧羰基。由羰基单元，氧羰基单元，含羟基单元和主要是烃类的单元组成的聚（酮 - 酯）是可光降解的和可生物降解的。

37. 发明授权

US5212266A Propylene polymerization method 失效
标题翻译：丙烯聚合法
公开(公告)号：US5212266A
公开(公告)日：1993-05-18
申请号：US865799
申请日：1992-03-30
申请人： Charles K. Buehler , Cindy S. Senger , Kenneth W. Johnson
发明人： Charles K. Buehler , Cindy S. Senger , Kenneth W. Johnson
IPC分类号： C08F4/652 , C08F2/50 , C08F4/60 , C08F4/64 , C08F4/649 , C08F10/00 , C08F10/06 , C08F110/06
CPC分类号： C08F10/00 , C08F2/50 , C08F110/06
摘要： A catalyst component useful in propylene polymerization in combination with a dialkyl aluminum halide cocatalyst comprises the product of reaction of TiCl.sub.3 which is substantially free of extraneous halide with a selected electron donor compound which is dissolved in a liquid hydrocarbon solvent in which the TiCl.sub.3 is dispersed. The electron donor compound is selected from certain organic acid esters, hindered phenolic compounds and silyl esters.The catalyst of the invention provides increased activity, molecular weight control, increased isotacticity of propylene polymer products and prevents catalyst feed line pluggage, among other advantages.
摘要翻译：用于丙烯聚合的二烷基卤化铝助催化剂的催化剂组分包括基本上不含外来卤化物的TiCl 3与溶解在其中分散有TiCl 3的液态烃溶剂中的选定电子给体化合物的反应产物。电子给体化合物选自某些有机酸酯，受阻酚化合物和甲硅烷基酯。本发明的催化剂提供了增加的活性，分子量控制，增加的丙烯聚合物产物的全同立构规整度，并且防止了催化剂进料线插入物以及其它优点。

38. 发明授权

US5207971A Extrusion of wrinkle-free blown film from high modulus resin 失效
标题翻译：从高模量树脂挤出无皱吹塑薄膜
公开(公告)号：US5207971A
公开(公告)日：1993-05-04
申请号：US832254
申请日：1992-02-07
申请人： Richard J. Volungis
发明人： Richard J. Volungis
IPC分类号： B29C47/88
CPC分类号： B29C47/8835 , B29C47/0026 , B29K2029/04 , B29K2067/00 , B29K2067/006 , B29K2995/0046
摘要： An improved blown-film extrusion process with particular application for high modulus thermoplastic resins. A cylinder is mounted above the cooling air ring. The film bubble passes through this cylinder, which has a diameter approximating the final diameter of the bubble. The frost line remains at or slightly higher than the top of the cylinder, leaving a small gap between the top of the cylinder bubble. The improvement enhances bubble cooling and stability and results in wrinkle-free film.
摘要翻译：改进的吹塑薄膜挤出方法，特别适用于高模量热塑性树脂。气缸安装在冷却环的上方。膜泡通过该圆筒，其直径接近气泡的最终直径。霜冻线保持在或稍高于圆柱体的顶部，在气泡的顶部之间留下小的间隙。该改进增强了气泡冷却和稳定性并导致无皱纹膜。

39. 发明授权

US5198400A Mixed chromium catalysts and polymerizations utilizing same 失效
标题翻译：混合铬催化剂和利用其的聚合
公开(公告)号：US5198400A
公开(公告)日：1993-03-30
申请号：US675378
申请日：1991-03-26
申请人： Stanley J. Katzen , Thomas J. Pullukat , Michael W. Lynch , Louis J. Rekers
发明人： Stanley J. Katzen , Thomas J. Pullukat , Michael W. Lynch , Louis J. Rekers
IPC分类号： C08F4/06 , C08F4/24 , C08F4/648 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00 , C08F110/02 , C08F2410/04
摘要： Mixed catalyst compositions comprised of a first supported chromium-containing catalyst component and a second supported chromium-containing catalyst component and which additionally have one or more metallic or non-metallic catalytic agents associated therewith are provided. The additional metallic or non-metallic elements associated with the catalyst components can be aluminum, titanium, zirconium, boron, phosphorous or combinations thereof. The pore volume of the silica supports used for the first and second catalyst components differs by at least 0.3 cc/g. The mixed catalyst compositions of the invention are useful for the preparation of polyolefins. They are particularly useful of polymerization of ethylene in particle form polymerizations to produce high density polyethylene blow molding resins having good processability and physical properties. The improved particle form polymerization process and products obtained thereby using the above-described mixed catalyst compositions are also described.
摘要翻译：提供由第一负载的含铬催化剂组分和第二负载的含铬催化剂组分组成的并且另外具有与其相关的一种或多种金属或非金属催化剂的混合催化剂组合物。与催化剂组分相关的另外的金属或非金属元素可以是铝，钛，锆，硼，磷或它们的组合。用于第一和第二催化剂组分的二氧化硅载体的孔体积至少为0.3cc / g。本发明的混合催化剂组合物可用于制备聚烯烃。它们特别可用于以颗粒形式聚合的乙烯聚合，以生产具有良好加工性能和物理性能的高密度聚乙烯吹塑树脂。还描述了改进的颗粒形式聚合方法和由此使用上述混合催化剂组合物获得的产物。

40. 发明授权

US5191004A Flame retardant crosslinkable polymeric compositions having improved processability 失效
标题翻译：阻燃可交联聚合物组合物具有改善的加工性能
公开(公告)号：US5191004A
公开(公告)日：1993-03-02
申请号：US674824
申请日：1991-03-22
申请人： Melvin F. Maringer , James W. Biggs
发明人： Melvin F. Maringer , James W. Biggs
IPC分类号： C08K3/22 , C08K5/5419 , C08L23/08 , H01B3/44
CPC分类号： H01B3/441 , C08K3/22 , C08K5/5419 , C08L23/0853 , C08L2201/02 , C08L2203/202 , C08L23/0869 , C08L2312/00
摘要： The invention relates to improved flame retardant crosslinkable compositions useful as insulation coatings for wire and cable based on ethylene-vinyl ester and ethylene-alkyl acrylate copolymers. The compositions contain a hydrated inorganic filler, an alkoxysilane, an antioxidant and a hydrocarbon processing oil. Organic peroxides are preferably employed to facilitate crosslinking. A method for providing the improved flame retardant crosslinkable compositions and electrical conductors coated therewith are also provided.
摘要翻译：本发明涉及可用作基于乙烯 - 乙烯基酯和乙烯 - 丙烯酸烷基酯共聚物的电线和电缆绝缘涂层的改进的阻燃交联组合物。组合物含有水合无机填料，烷氧基硅烷，抗氧化剂和烃加工油。有机过氧化物优选用于促进交联。还提供了用于提供改进的阻燃剂可交联组合物和涂覆其的电导体的方法。

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