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    • 32. 发明授权
    • Preparation process of cinnamate ester
    • 肉桂酸酯的制备方法
    • US5179224A
    • 1993-01-12
    • US769481
    • 1991-10-01
    • Usaji TakakiYoshihiro YamamotoToshio MatsuhisaIsamu SudoShinobu Aoki
    • Usaji TakakiYoshihiro YamamotoToshio MatsuhisaIsamu SudoShinobu Aoki
    • C07C69/618
    • C07C69/618Y02P20/584
    • Disclosed herein is a process for preparing a corresponding cinnamate ester by reacting a styrene compound, carbon monoxide, an alcohol and oxygen by the use of (1) metallic palladium or a compound thereof, (2) a copper compound, (3) a compound of at least one metal selected from Groups 4A, 5A, 7A, 8A (the iron group only) and 2B in the Periodic Table and (4) a halogen compound as a catalyst which comprises treating the catalyst components recovered from the reaction liquid after completion of the reaction with an oxidizing agent in the presence of an organic acid to regenerate their catalytic activity, using the resulting catalyst components again in the reaction as a catalyst and repeating the foregoing procedure.The regenerated catalyst is recovered in catalytic activity to the extent of that of a fresh catalyst and thus gives a high reaction performance in the subsequent reaction. Thus, the catalyst containing expensive metal can be used circulatively.
    • 本文公开了通过使用(1)金属钯或其化合物使苯乙烯化合物,一氧化碳,醇和氧反应制备相应的肉桂酸酯的方法,(2)铜化合物,(3)化合物 的选自4A,5A,7A,8A(仅铁族)和2B中的至少一种金属,以及(4)作为催化剂的卤素化合物,其包括在完成后处理从反应液中回收的催化剂成分 在有机酸存在下与氧化剂反应以再生其催化活性,在反应中再次使用所得催化剂组分作为催化剂,并重复上述步骤。 再生催化剂的催化活性回收到新鲜催化剂的催化活性,因此在随后的反应中得到高的反应性能。 因此,可以循环使用含有贵金属的催化剂。