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    • 31. 发明授权
    • Azolyloxy-carboxylic acid n-oxy-amide compounds
    • 芳氧基 - 羧酸正氧化酰胺化合物
    • US4408055A
    • 1983-10-04
    • US204147
    • 1980-11-05
    • Heinz ForsterFritz MaurerVolker MuesLudwig EueRobert R. Schmidt
    • Heinz ForsterFritz MaurerVolker MuesLudwig EueRobert R. Schmidt
    • A01N43/72A01N43/74A01N43/76A01N43/78A01N43/82A01N43/824A01N43/836C07C233/05C07C233/06C07C233/07C07C235/06C07C239/14C07C239/20C07C275/64C07C291/04C07D261/12C07D263/58C07D271/06C07D271/07C07D277/20C07D277/34C07D277/56C07D277/68C07D285/08C07D285/12C07D285/125C07D285/13C07D283/02C07D269/02C07D271/00C07D285/02
    • C07D271/07A01N43/74A01N43/82C07C275/64C07C291/04C07D261/12C07D277/34C07D277/56C07D277/68C07D285/08C07D285/125C07D285/13
    • Azolyloxy-carboxylic acid N-oxy-amide compound of the formula ##STR1## wherein R is a five-membered hetero-aromatic monocyclic radical which contains an oxygen atom or a sulphur atom and in addition 1 to 3 nitrogen atoms and which is optionally substituted by halogen, cyano, nitro, amino, alkylamino, arylamino, dialkylamino, alkylcarbonylamino, alkylcarbonyl, carboxyl, alkoxycarbonyl, carbamoyl, alkylaminocarbonyl, dialkylaminocarbonyl, arylaminocarbonyl (which is optionally substituted by halogen, nitro or alkyl), aryl (which is optionally substituted by halogen, cyano, nitro, alkyl or alkoxy), by a radical which is optionally substituted by halogen and is selected from aralkyl, alkoxy, alkenoxy, alkynoxy, alkoxycarbonylalkoxy, aralkoxy, aryloxy, alkylthio, alkenylthio, alkoxycarbonylalkylthio, aralkylthio, arylthio, alkylsulphinyl, alkylsulphonyl, alkyl, alkenyl, alkynyl, alkoxyalkyl, aralkoxyalkyl, aryloxyalkyl, alkylthioalkyl, alkylsulphinylalkyl, alkylsulphonylalkyl, arylthioalkyl, arylsulphinylalkyl, arylsulphonylalkyl, carboxyalkyl, and alkoxycarbonylalkyl, or by optionally substituted aminocarbonylalkyl, cyanoalkyl or cycloalkyl, or which is optionally benzo-fused, the benzo radical optionally being substituted by halogen, alkyl, halogenoalkyl, alkoxy, halogenoalkoxy, alkylthio, halogenoalkylthio, amino, alkylamino, dialkylamino, nitro, cyano, alkoxycarbonyl or optionally halogen-substituted alkylenedioxy,R.sup.1 is hydrogen or alkyl, andR.sup.2 and R.sup.3 are individually selected from optionally substituted radicals selected from the group consisting of alkyl, alkenyl, alkynyl, cycloalkyl, aralkyl, aryl orR.sup.2 and R.sup.3 taken together represent alkyleneare effective herbicides.
    • 具有下式的酰氧基 - 羧酸N-氧化 - 酰胺化合物(I)其中R是含有氧原子或硫原子的5元杂芳族单环基团,另外还含有1至3个氮原子, 烷基氨基,烷基羰基,羧基,烷氧基羰基,氨基甲酰基,烷基氨基羰基,二烷基氨基羰基,芳基氨基羰基(其任选被卤素,硝基或烷基取代),芳基(其是 任选地被卤素,氰基,硝基,烷基或烷氧基取代),其任选被卤素取代的基团,并且选自芳烷基,烷氧基,烯氧基,炔氧基,烷氧基羰基烷氧基,芳烷氧基,芳氧基,烷硫基,烯硫基,烷氧基羰基烷硫基,芳烷硫基, ,烷基亚磺酰基,烷基磺酰基,烷基,烯基,炔基,烷氧基烷基,芳烷氧基烷基,芳氧基烷基,烷硫基烷基,烷基亚磺酰基烷基,烷基磺酰基烷基,芳硫基 芳基亚磺酰基烷基,芳基磺酰基烷基,羧基烷基和烷氧基羰基烷基,或任选取代的氨基羰基烷基,氰基烷基或环烷基,或任选苯并稠合,任选被卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基, 氨基,烷基氨基,二烷基氨基,硝基,氰基,烷氧基羰基或任选卤素取代的亚烷基二氧基,R 1是氢或烷基,R 2和R 3分别选自任选取代的基团,其选自烷基,烯基,炔基,环烷基, ,芳基或R2和R3一起代表亚烷基是有效的除草剂。
    • 32. 发明授权
    • 1-Acyloxymethyl-4,5-dichloro-imidazole derivatives and their use as
herbicides
    • 1-酰氧基甲基-4,5-二氯 - 咪唑衍生物及其作为除草剂的用途
    • US4187101A
    • 1980-02-05
    • US946252
    • 1978-09-27
    • Florin SengKlaus SasseGunther BeckLudwig EueRobert R. Schmidt
    • Florin SengKlaus SasseGunther BeckLudwig EueRobert R. Schmidt
    • A01N43/50C07D233/68C07D233/90C07D487/14A01N9/22
    • C07D487/14A01N43/50C07D233/68C07D233/90
    • 1-Acyloxymethyl-4,5-dichloro-imidazole-2-carboxylic acid derivatives of the formula ##STR1## in which X represents trifluoromethyl, cyano or a group ##STR2## in which R.sup.1 represents a saturated or unsaturated aliphatic radical, which can be carrying one or more substituents selected from halogen, alkoxy with 1 to 6 carbon atoms and alkylmercapto with 1 to 6 carbon atoms, R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group, R.sup.3 represents alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl each with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents selected from alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms, phenyl (which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, trifluoromethyl and alkoxy with 1 to 4 carbon atoms), furyl or thienyl, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms and trifluoromethyl or, R.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atoms form an optionally substituted 5-membered to 7-membered heterocyclic ring in which 1 to 3 ring members may be selected from oxygen, sulfur and nitrogen, and R represents alkyl with 1 to 6 carbon atoms, plant protective compositions containing the same as active ingredients together with diluents, and methods for protecting plants by applying such novel 1-acyloxymethyl-4,5-dichloro-imidazole-2-carboxylic acid derivatives to a plant or its habitat.
    • 其中X表示三氟甲基,氰基或其中R 1表示饱和或不饱和脂肪族基团的基团,其中X表示三氟甲基,氰基或者其中R 1表示饱和或不饱和脂肪族基团的基团的1-芳氧基甲基-4,5-二氯 - 咪唑-2-羧酸衍生物, 其可以携带一个或多个选自卤素,具有1至6个碳原子的烷氧基和具有1至6个碳原子的烷基巯基的取代基,R 2表示氢,具有1至8个碳原子的烷基,具有至多8个碳原子的烯基或甲酰基 基团,R 3表示具有1至8个碳原子的烷基或各自具有至多8个碳原子的烯基或炔基,这些烷基,烯基和炔基中的每一个可以携带一个或多个选自具有1至4个碳原子的烷氧基的取代基 原子,具有1至4个碳原子的烷基巯基,苯基(其可任选地携带一个或多个选自卤素,具有1至4个碳原子的烷基,三氟甲基和具有1至4个碳原子的烷氧基)的取代基,呋喃基或噻吩基,或表示环烷基 与5到 任选被具有1至6个碳原子的烷基取代的环中的7个碳原子,或表示可以任选携带一个或多个选自卤素,具有1至4个碳原子的烷基,具有1至4个碳原子的烷氧基的取代基的苯基, 具有1至4个碳原子的烷基巯基和三氟甲基,或者R 2和R 3与相邻的氮原子一起形成任选取代的5元至7元杂环,其中1至3个环成员可以选自氧,硫和氮, R表示具有1-6个碳原子的烷基,含有与活性成分一起含有稀释剂的植物保护组合物,以及通过应用这种新颖的1-酰氧基甲基-4,5-二氯 - 咪唑-2-羧酸衍生物保护植物的方法 到植物或其栖息地。
    • 33. 发明授权
    • 4,5-Dichloro-imidazole derivatives and their use as herbicides
    • US4185991A
    • 1980-01-29
    • US945288
    • 1978-09-25
    • Klaus SasseGunther BeckLudwig EueRobert R. Schmidt
    • Klaus SasseGunther BeckLudwig EueRobert R. Schmidt
    • A01N43/50C07D233/68C07D233/90C07D487/14A01N9/22
    • C07D487/14A01N43/50C07D233/68C07D233/90
    • A 4,5-dichloro-imidazole derivative of the formula ##STR1## in which X represents trifluoromethyl, cyano or a ##STR2## or ##STR3## in which R.sup.1 represents a saturated or unsaturated aliphatic radical, which can be carrying one or more substituents selected from halogen, alkoxy with 1 to 6 carbon atoms and alkylmercapto with 1 to 6 carbon atoms,R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group,R.sup.3 represents hydrogen, alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl each with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents selected from alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms, phenyl (which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, trifluoromethyl and alkoxy with 1 to 4 carbon atoms), furyl or thienyl, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms and trifluoromethyl, orR.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atom form an optionally substituted 5-membered to 7-membered heterocyclic ring in which 1 to 3 ring members may be selected from oxygen, sulphur and nitrogen, andR represents alkyl with 1 to 12 carbon atoms or alkenyl or alkynyl each with up to 12 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents selected from halogen, alkoxy with 1 to 6 carbon atoms, alkylmercapto with 1 to 6 carbon atoms, cycloalkyl with 5 to 7 carbon atoms in the ring and phenyl (which itself optionally carries one or more substituents selected from alkyl with 1 to 6 carbon atoms, alkoxy with 1 to 6 carbon atoms, halogen and trifluoromethyl), or represents cycloalkyl with 5 to 7 carbon atoms in the ring or represents a phenyl radical which is at least disubstituted; and the use of such novel 4,5-dichloro-imidazole derivatives as plant protection agents especially as a herbicide, plant growth regulant, insecticide or acaricide.
    • 34. 发明授权
    • 1-Acyloxymethyl-4,5-dichloro-imidazole-2-carboxylic acid derivatives and
their use as plant protection agents
    • 1-氧代甲基-4,5-二氯 - 咪唑-2-羧酸衍生物及其作为植物保护剂的用途
    • US4177055A
    • 1979-12-04
    • US835093
    • 1977-09-21
    • Florin SengKlaus SasseGunther BeckLudwig EueRobert R. Schmidt
    • Florin SengKlaus SasseGunther BeckLudwig EueRobert R. Schmidt
    • A01N43/50C07D233/68C07D233/90C07D487/14A01N9/22
    • C07D487/14A01N43/50C07D233/68C07D233/90
    • Novel 1-acyloxymethyl-4,5-dichloro-imidazole-2-carboxylic acid derivatives of the formula ##STR1## in which X represents trifluoromethyl, cyano or a group ##STR2## in which R.sup.1 represents an optionally substituted saturated or unsaturated aliphatic radical, R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group, R.sup.3 represents alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl each with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents, or R.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atom form an optionally substituted 5- to 7-membered heterocyclic ring in which 1 to 3 ring members may be selected from oxygen, sulfur and nitrogen, and R represents alkyl with 1 to 6 carbon atoms, plant protective compositions containing the same as active ingredients together with diluents, and methods for protecting plants by applying such novel 1-acyloxymethyl-4,5-dichloro-imidazole-2-carboxylic acid derivatives to a plant or its habitat.
    • 具有式(I)的新颖的1-酰氧基甲基-4,5-二氯 - 咪唑-2-羧酸衍生物,其中X表示三氟甲基,氰基或基团,其中R 1表示任选取代的饱和或不饱和的 脂族基团,R 2表示氢,具有1至8个碳原子的烷基,具有至多8个碳原子的烯基或甲酰基,R 3表示具有1至8个碳原子的烷基或具有至多8个碳原子的链烯基或炔基, 这些烷基,烯基和炔基中的每一个可以携带一个或多个取代基,或代表环中具有5至7个碳原子的环烷基,其任选被具有1至6个碳原子的烷基取代,或表示可以任选携带的苯基 一个或多个取代基,或者R 2和R 3与相邻的氮原子结合形成任选取代的5至7元杂环,其中1至3个环成员可以选自氧,硫和氮,R代表a1 具有1至6个碳原子的烷基,含有与活性成分一起的稀释剂的植物保护性组合物,以及通过将这种新颖的1-酰氧基甲基-4,5-二氯 - 咪唑-2-羧酸衍生物施用于植物来保护植物的方法 或其栖息地。
    • 40. 发明授权
    • Azolyloxy-carboxylic acid amide compounds and herbicidal compositions
    • 芳氧基 - 羧酸酰胺化合物和除草组合物
    • US4756741A
    • 1988-07-12
    • US819200
    • 1986-01-15
    • Heinz ForsterWolfgang HoferVolker MuesLudwig EueRobert R. Schmidt
    • Heinz ForsterWolfgang HoferVolker MuesLudwig EueRobert R. Schmidt
    • A01N43/72A01N43/76A01N43/78A01N43/80A01N43/82A01N43/824A01N43/832A01N43/836A01N43/84A01N43/86A01N43/90C07D261/12C07D261/18C07D263/38C07D265/38C07D271/06C07D271/10C07D275/02C07D277/16C07D277/20C07D277/34C07D277/36C07D277/56C07D285/08C07D285/10C07D285/12C07D285/125C07D285/13C07D295/185C07D413/12C07D417/12C07D491/113
    • C07D295/185A01N43/80A01N43/82A01N43/90C07D277/34C07D277/56
    • Azolyloxy-carboxylic acid amides of the formula ##STR1## wherein R is a five-membered hetero-aromatic monocyclic radical which contains an oxygen atom or a sulfur atom and 1 to 3 nitrogen atoms; orR is said monocyclic radical substituted by halogen, nitro, cyano, amino, alkylamino, dialkylamino, arylamino, alkylcarbonylamino, alkylcarbonyl, carboxyl, alkoxycarbonyl, carbamoyl, alkylaminocarbonyl, dialkylaminocarbonyl, arylaminocarbonyl substituted arylaminocarbonyl wherein the substituents are halogen, nitro or alkyl, aryl, substituted aryl wherein the substituents are halogen, nitro, cyano, alkyl, halogenoalkyl or alkoxy, aralkyl, haloaralkyl, alkoxy, halo-alkoxy, alkenoxy, alkynoxy, alkoxycarbonylalkoxy, aralkoxy or aryloxy, optionally halogen-substituted alkylthio, alkenylthio, alkynylthio, alkoxycarbonylalkylthio, aralkylthio, arylthio, alkylsulphinyl or alkylsulphonyl, optionally halogen-substituted alkyl, alkenyl, alkynyl, alkoxyalkyl, aralkoxyalkyl, aryloxyalkyl, alkylthioalkyl, alkylsulphinylalkyl, alkylsulphonylalkyl, arylthioalkyl, arylsulphinylalkyl, arylsulphonylalkyl, carboxyalkyl, alkoxycarbonylalkyl, optionally substituted aminocarbonylalkyl, cyanoalkyl or cycloalkyl,R.sup.1 is hydrogen or alkyl andR.sup.2 and R.sup.3 are individually selected from hydrogen, optionally substituted alkyl, alkenyl, alkynyl, aralkyl, cycloalkyl or aryl, or a nitrogen-containing heterocyclic radical, orR.sup.2 and R.sup.3, together with the nitrogen atom to which they are bonded, represent an optionally substituted, optionally partially unsaturated and optionally benzo-fused monocyclic or bicyclic radical which optionally contains one or more further hetero-atoms; are effective herbicides.
    • 式(I)的酰氧基 - 羧酸酰胺其中R是含有氧原子或硫原子和1-3个氮原子的五元杂芳族单环基团; 或R是被卤素,硝基,氰基,氨基,烷基氨基,二烷基氨基,芳基氨基,烷基羰基氨基,烷基羰基,羧基,烷氧基羰基,氨基甲酰基,烷基氨基羰基,二烷基氨基羰基,芳基氨基羰基取代的芳基氨基羰基取代的单环基团,其中取代基是卤素,硝基或烷基,芳基 其中取代基为卤素,硝基,氰基,烷基,卤代烷基或烷氧基,芳烷基,卤代烷基,烷氧基,卤代烷氧基,链烯氧基,炔氧基,烷氧羰基烷氧基,芳烷氧基或芳氧基,任选卤素取代的烷硫基,烯硫基,炔硫基,烷氧羰基烷硫基 ,芳烷硫基,芳硫基,烷基亚磺酰基或烷基磺酰基,任选卤素取代的烷基,烯基,炔基,烷氧基烷基,芳烷氧基烷基,芳氧基烷基,烷硫基烷基,烷基亚磺酰基烷基,烷基磺酰基烷基,芳硫基烷基,芳基亚磺酰基烷基,芳基磺酰基烷基,羧基烷基,烷氧基羰基烷基,任选取代的氨基羰基烷基,氰基烷基或环 烷基,R 1是氢或烷基,R 2和R 3分别选自氢,任选取代的烷基,烯基,炔基,芳烷基,环烷基或芳基或含氮杂环基,或者R 2和R 3与氮原子一起 它们被键合,表示任选地被任意取代的,任选地部分不饱和的和任选地苯并稠合的单环或双环基,其任选地含有一个或多个另外的杂原子; 是有效的除草剂。