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    • 6. 发明授权
    • Halogenoalkoxy-phenylsulphonylisothioureidoazine herbicidal agents
    • 卤代烷氧基 - 苯基磺酰基异硫脲酰肼类除草剂
    • US4911752A
    • 1990-03-27
    • US170613
    • 1988-03-15
    • Christa FestKlaus-Helmut MullerTheodor PfisterHans-Jochem RiebelHans-Joachim SantelRobert R. Schmidt
    • Christa FestKlaus-Helmut MullerTheodor PfisterHans-Jochem RiebelHans-Joachim SantelRobert R. Schmidt
    • C07D239/42A01N47/42C07D239/47C07D239/52C07D251/16C07D251/22C07D251/46
    • A01N47/42
    • A method of combating unwanted vegetation which comprises applying to such vegetation or to a locus from which it is desired to exclude such vegetation a herbicidally effective amount of a halogenoalkoxyphenylsulphonylisothioureidoazine of the formula ##STR1## in which R.sup.1 represents halogeno-C.sub.1 -C.sub.4 -alkoxy,R.sup.2 represents hydrogen, halogen, hydroxyl, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -halogenoalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -halogenoalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -halogenoalkylthio, amino, C.sub.1 -C.sub.4 -alkylamino or di-(C.sub.1 -C.sub.4 -alkyl)amino,X represents nitrogen or a --CH-- grouping,Y represents nitrogen or a --CR.sup.4 -- grouping,whereinR.sup.4 represents hydrogen, halogen, cyano, C.sub.1 -C.sub.4 -alkyl, formyl, C.sub.1 -C.sub.4 -alkyl-carbonyl or C.sub.1 -C.sub.4 -alkoxy-carbonyl, andZ represents nitrogen or a --CR.sup.5 -- grouping,whereinR.sup.5 represents hydrogen, halogen, hydroxyl, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylamino or di-(C.sub.1 -C.sub.4 -alkyl)-amino, andR.sup.3 represents C.sub.1 -C.sub.10 -alkyl (which is optionally substituted by fluorine, chlorine, bromine, cyano, C.sub.1 -C.sub.4 -alkoxy, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, aminocarbonyl, C.sub.1 -C.sub.4 -alkylaminocarbonyl or di-(C.sub.1 -C.sub.4 -alkyl)-amino-carbonyl), or represents C.sub.2 -C.sub.6 -alkenyl (which is optionally substituted by fluorine, chlorine and/or bromine) or C.sub.2 -C.sub.6 -alkinyl, or represents phenyl-C.sub.1 -C.sub.2 -alkyl (which is optionally substituted in the phenyl part by fluorine, chlorine, bromine, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxy-carbonyl).
    • 一种防治不想要的植物的方法,其包括施用于这样的植被或希望从其排除这些植被的场所,除草有效量的式“IMAGE”的卤代烷氧基苯基磺酰基异硫脲基,其中R 1表示卤代-C 1 -C 4烷氧基, R2代表氢,卤素,羟基,C1-C4烷基,C1-C4-卤代烷基,C1-C4-烷氧基,C1-C4-卤代烷氧基,C1-C4-烷硫基,C1-C4-卤代烷硫基,氨基,C1-C4- 烷基氨基或二(C1-C4烷基)氨基,X表示氮或-CH-基,Y表示氮或-CR4-基团,其中R4表示氢,卤素,氰基,C1-C4-烷基,甲酰基, C 1 -C 4烷基 - 羰基或C 1 -C 4 - 烷氧基羰基,Z表示氮或-CR 5 - 基团,其中R 5表示氢,卤素,羟基,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基, C 1 -C 4 - 烷基氨基或二 - (C 1 -C 4 - 烷基) - 氨基,R 3表示C 1 -C 10 - 烷基(其任选被氟,氯,溴,氰基, C 1 -C 4 - 烷氧基,羧基,C 1 -C 4 - 烷氧基羰基,氨基羰基,C 1 -C 4 - 烷基氨基羰基或二 - (C 1 -C 4 - 烷基) - 氨基 - 羰基),或表示C 2 -C 6 - 链烯基(其任选被 氟,氯和/或溴)或C 2 -C 6 - 炔基,或代表苯基-C 1 -C 2 - 烷基(其在苯基部分被氟,氯,溴,硝基,氰基,C 1 -C 4烷基, C 1 -C 4 - 烷氧基或C 1 -C 4烷氧羰基)。
    • 8. 发明授权
    • 3-substituted
1-(2-halogenoalkoxy-benzenesulphonyl)-3-heteroaryl-(thio)ureas
    • 3-取代的1-(2-卤代烷氧基 - 苯磺酰基)-3-杂芳基 - (硫代)脲
    • US4780126A
    • 1988-10-25
    • US060187
    • 1987-06-09
    • Hans-Joachim DiehrChrista FestRolf KirstenJoachim KluthKlaus-Helmut MullerTheodor PfisterUwe PriesnitzHans-Jochem RiebelWolfgang RoyHans-Joachim SantelRobert R. SchmidtLudwig EueErnst Kysela
    • Hans-Joachim DiehrChrista FestRolf KirstenJoachim KluthKlaus-Helmut MullerTheodor PfisterUwe PriesnitzHans-Jochem RiebelWolfgang RoyHans-Joachim SantelRobert R. SchmidtLudwig EueErnst Kysela
    • A01N47/36C07C311/65C07C331/32C07D521/00C07D251/42A01N43/66C07D251/46
    • C07D521/00A01N47/36C07C311/65C07C331/32
    • 3-Substituted 1-(2-halogenoalkoxy-benzenesulphonyl)-3-heteroaryl-(thio)urea herbicides of the formula ##STR1## in which (A)R is CF.sub.3,Q is O,R.sup.1 is CH.sub.3, C.sub.2 H.sub.5, C.sub.3 H.sub.7 -n, C.sub.3 H.sub.7 -i, CH.sub.2 --CH.dbd.CH.sub.2, CH.sub.2 --C.tbd.CH or CH.sub.2 --C.sub.6 H.sub.5,R.sup.2 is CH.sub.3, OCH.sub.3, OC.sub.2 H.sub.5, SCH.sub.3, NH--CH.sub.3 or NH--C.sub.2 H.sub.5,X is N,Y is N andZ is C--CH.sub.3, C--C.sub.2 H.sub.5, C--OCH.sub.3 or C--OC.sub.2 H.sub.5 ; or(B)R is CF.sub.3,Q is O,R.sup.1 is CH.sub.3, C.sub.2 H.sub.5, C.sub.3 H.sub.7 -n, C.sub.3 H.sub.7 -i, CH.sub.2 --CH.dbd.CH.sub.2, CH.sub.2 --C.tbd.CH or CH.sub.2 --C.sub.6 H.sub.5,R.sup.2 is CH.sub.3, OCH.sub.3 or OC.sub.2 H.sub.5,X is N,Y is C--H andZ is C--C.sub.2 H.sub.5, C--OCH.sub.3 or C--OC.sub.2 H.sub.5 ; or(C)R is CH.sub.2 --CH.sub.2 Cl,Q is O,R.sup.1 is CH.sub.3, C.sub.2 H.sub.5, C.sub.3 H.sub.7 -n, C.sub.3 H.sub.7 -i, CH.sub.2 --CH.dbd.CH.sub.2, CH.sub.2 --C.tbd.CH or CH.sub.2 --C.sub.6 H.sub.5,R.sup.2 is CH.sub.3, OCH.sub.3, OC.sub.2 H.sub.5, SCH.sub.3, NH--CH.sub.3 or NH--C.sub.2 H.sub.5,X is N,Y is N andZ is C--CH.sub.3, C--C.sub.2 H.sub.5, C--OCH.sub.3 or C--OC.sub.2 H.sub.5 ; or(D)R is CH.sub.2 --CH.sub.2 Cl,Q is O,R.sup.1 is CH.sub.3, C.sub.2 H.sub.5, C.sub.3 H.sub.7 -n, C.sub.3 H.sub.7 -i, CH.sub.2 --CH.dbd.CH.sub.2, CH.sub.2 --C.tbd.CH or CH.sub.2 --C.sub.6 H.sub.5,R.sup.2 is CH.sub.3, OCH.sub.3 or OC.sub.2 H.sub.5,X is N,Y is C--H andZ is C--CH.sub.3, C--C.sub.2 H.sub.5, C--OCH.sub.3 or C--OC.sub.2 H.sub.5 ; or(E)R is CHF.sub.2,Q is O,R.sup.1 is CH.sub.3,R.sup.2 is CH.sub.3,X is N,Y is N andZ is C--CH.sub.3,or a salt thereof with a metal or basic organic nitrogen compound.
    • (A)R为CF 3,Q为O,R 1为CH 3,C 2 H 5,C 3 H 7 -n的3-取代的1-(2-卤代烷氧基 - 苯磺酰基)-3-杂芳基 - (硫代)脲除草剂 ,C 3 H 7 -i,CH 2 -CH = CH 2,CH 2 -C 3 CH 2或CH 2 -C 6 H 5,R 2是CH 3,OCH 3,OC 2 H 5,SCH 3,NH-CH 3或NH-C 2 H 5,X是N,Y是N,Z是C -CH 3,C-C 2 H 5,C-OCH 3或C-OC 2 H 5; 或(B)R是CF 3,Q是O,R 1是CH 3,C 2 H 5,C 3 H 7-n,C 3 H 7-i,CH 2 -CH = CH 2,CH 2 -C 3 CH 2或CH 2 -C 6 H 5,R 2是CH 3,OCH 3或OC 2 H 5, X是N,Y是CH,Z是C-C 2 H 5,C-OCH 3或C-OC 2 H 5; 或(C)R是CH 2 -CH 2 Cl,Q是O,R 1是CH 3,C 2 H 5,C 3 H 7-n,C 3 H 7 -i,CH 2 -CH = CH 2,CH 2 -C 3 CH 2或CH 2 -C 6 H 5,R 2是CH 3,OCH 3, OC2H5,SCH3,NH-CH3或NH-C2H5,X是N,Y是N,Z是C-CH3,C-C2H5,C-OCH3或C-OC2H5; 或(D)R是CH 2 -CH 2 Cl,Q是O,R 1是CH 3,C 2 H 5,C 3 H 7-n,C 3 H 7 -i,CH 2 -CH = CH 2,CH 2 -C 3 CH 2或CH 2 -C 6 H 5,R 2是CH 3,OCH 3或 OC2H5,X是N,Y是CH,Z是C-CH3,C-C2H5,C-OCH3或C-OC2H5; 或(E)R是CHF 2,Q是O,R 1是CH 3,R 2是CH 3,X是N,Y是N,Z是C-CH 3,或其与金属或碱性有机氮化合物的盐。