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31. 发明授权

US5474638A Method of using aqueous polymer dispersions as lamination adhesives for glossy films 失效
标题翻译：使用聚合物水分散体作为光泽膜的层压粘合剂的方法
公开(公告)号：US5474638A
公开(公告)日：1995-12-12
申请号：US201266
申请日：1994-02-24
申请人： Klaus Kohlhammer , Wilfried Huster , Walter Dobler
发明人： Klaus Kohlhammer , Wilfried Huster , Walter Dobler
IPC分类号： B32B27/00 , B32B7/12 , C08F28/00 , C08F220/10 , C08F220/12 , C08F220/26 , C08F220/28 , C08F228/02 , C08J5/12 , C09J133/04 , C09J133/06 , C09J133/08 , C09J129/02
CPC分类号： B32B7/12 , C09J133/06
摘要： The invention relates to a method of using aqueous polymer dispersions based on acrylate-methacrylate copolymers as lamination adhesives for heat sealed glossy films, where the aqueous polymer dispersions have a solids content of from 20 to 65% by weight, the copolymer has a glass transition temperature of from -35.degree. to -10.degree. C., a K value of from 40 to 100 and a mean particle size of less than 200 nm, and the copolymer is obtainable by free-radical emulsion polymerization of:a) from 50 to 80 parts by weight of one or more comonomers from the group consisting of alkyl acrylates of alcohols having 2 to 10 carbon atoms,b) from 10 to 25 parts by weight of one or more comonomers from the group consisting of alkyl methacrylates of alcohols having 1 to 10 carbon atoms, andc1) from 0 to 10 parts by weight of one or more vinyl-aromatic comonomers,c2) from 0.1 to 4.0 parts by weight of one or more .alpha.,.beta.-unsaturated, monoolefinic carboxylic acids,c3) from 0 to 4.0 parts by weight of one or more .alpha..beta.-unsaturated, monoolefinic carboxamides,c4) from 0 to 8 parts by weight of one or more comonomers from the group consisting of hydroxyalkyl (meth)acrylates made from esters of acrylic acid or methacrylic acid and diols having 2 to 10 carbon atoms, andc5) from 0.1 to 4.0 parts by weight of one or more .alpha..beta.-unsaturated, monoolefinic compounds containing sulfonyl or sulfonate groups.
摘要翻译：本发明涉及使用基于丙烯酸酯 - 甲基丙烯酸酯共聚物的水性聚合物分散体作为热密封光泽膜的层压粘合剂的方法，其中聚合物水分散体的固体含量为20-65重量％，该共聚物具有玻璃化转变温度为-35〜-10℃，K值为40〜100，平均粒径小于200nm，共聚物可通过自由基乳液聚合得到：a）从50〜 80重量份由具有2至10个碳原子的醇的丙烯酸烷基酯组成的组中的一种或多种共聚单体，b）10至25重量份的一种或多种共聚单体，其由具有1个至少10个碳原子，和c1）0至10重量份的一种或多种乙烯基芳族共聚单体，c2）0.1至4.0份重量的一种或多种α，β-不饱和单烯烃羧酸，c3） 0〜4.0份重量 t的一种或多种αβ-不饱和单烯烃甲酰胺，c4）0至8份重量的一种或多种由丙烯酸或甲基丙烯酸的酯和二醇制成的（甲基）丙烯酸羟烷基酯的共聚单体，其具有2 至10个碳原子，和c5）0.1至4.0重量份的一种或多种含有磺酰基或磺酸酯基团的α不饱和单烯烃化合物。

32. 发明授权

US5112723A Photosensitive recording element 失效
标题翻译：感光记录元素
公开(公告)号：US5112723A
公开(公告)日：1992-05-12
申请号：US476939
申请日：1990-02-08
申请人： Wolfgang Huemmer , Walter Dobler , Dieter Littmann
发明人： Wolfgang Huemmer , Walter Dobler , Dieter Littmann
IPC分类号： G03F7/004 , G03F7/027 , G03F7/031 , G03F7/032
CPC分类号： G03F7/027 , G03F7/032
摘要： In a photosensitive recording element which contains at least one photopolymerizable recording layer (B) consisting ofb.sub.1) at least one partially of virtually completely hydrolyzed poly(vinyl alkanecarboxylate) and/or at least one partially or virtually completely hydrolyzed vinyl alkanecarboxylate/alkylene oxide graft copolymer as a binder,b.sub.2) at least one photopolymerization initiator,b.sub.3) at least one photopolymerizable olefinically unsaturated compound (monomer) which is compatible with the binder (b.sub.1), and/or photopolymerizable olefinically unsaturated radicals which are bonded as side radicals and/or terminal radicals to the binder (b.sub.1), andb.sub.4) at least two assistants, at least one of the said assistants (b.sub.4) has been selected from the group consisting ofb.sub.41) the isoalloxazines and the alloxazines, and at least one of the other assistants has been selected from the group consisting ofb.sub.42) the potassium salt of N-nitrosocyclohexylhydroxlamine, N-nitrosodiphenylamine and hydroquinone monomethyl ether,the amounts used of the assistants (b.sub.41) and (b.sub.42) being from 0.01 to 6% by weight, based on the total weight of the photopolymerizable recording layer (B), and the weight ratio (b.sub.41) : B.sub.42) being from 1:2 to 1:1,000.
摘要翻译：在含有至少一种可光聚合记录层（B）的光敏记录元件中，所述光致聚合记录层（B）由b1）至少部分实质上完全水解的聚（乙烯基链烷羧酸酯）和/或至少一种部分或几乎完全水解的乙烯基烷羧酸酯/烯化氧接枝共聚物作为粘合剂，b2）至少一种光聚合引发剂，b3）与粘合剂（b1）相容的至少一种可光聚合的烯属不饱和化合物（单体）和/或可光聚合的烯属不饱和基团作为侧基键合和/ 或末端基团，和b4）至少两种助剂，所述助剂（b4）中的至少一种选自b41）异卤代氮杂和氧氟烷，并且至少一种其他助剂选自b42）N-亚硝基环己基羟胺的钾盐，N-亚硝基二苯胺和水解剂（b41）和（b42）的助剂（b41）和（b42）所用的量为0.01-6重量％，基于可光聚合记录层（B）的总重量和重量比（b41）：B42）从1：2到1：1,000。

33. 发明授权

US5009753A Preparation of dihydroxydiones 失效
标题翻译：二羟基二糖的制备
公开(公告)号：US5009753A
公开(公告)日：1991-04-23
申请号：US423224
申请日：1989-10-18
申请人： Dieter Hermeling , Rainer Becker , Walter Dobler
发明人： Dieter Hermeling , Rainer Becker , Walter Dobler
IPC分类号： C07C49/17 , C25B3/10
CPC分类号： C07C49/17 , C25B3/10
摘要： Dihydroxydiones of the general formulaR--CO--CH(OH)--CH(OH)--CO--R Iwhere R is alkyl, are prepared by a process in which an aldehyde of the general formula ##STR1## where R has the abovementioned meaning, is subjected to electrolysis in a water-containing electrolyte which has a pH of less than 7.
摘要翻译：其中R为烷基的通式为R-CO-CH（OH）-CH（OH）-CO-R I的二羟基二糖是通过其中R具有上述通式的醛的方法制备的意思是在pH小于7的含水电解液中进行电解。

34. 发明授权

US07264696B2 Dividing-wall column with feed in whole or in part in the vaporous state and/or side stream take off in whole or in part in the vaporous state 有权
标题翻译：全部或部分进料在蒸发态和/或侧流中的分隔壁塔全部或部分脱气
公开(公告)号：US07264696B2
公开(公告)日：2007-09-04
申请号：US11384370
申请日：2006-03-21
申请人： Gerd Kaibel , Christian Miller , Katrin Klaβ , Alois Kindler , Werner Aquila , Walter Dobler , Klaus Breuer , Achim Pommer , Thomas Dirnsteiner
发明人： Gerd Kaibel , Christian Miller , Katrin Klaβ , Alois Kindler , Werner Aquila , Walter Dobler , Klaus Breuer , Achim Pommer , Thomas Dirnsteiner
IPC分类号： B01D3/42
CPC分类号： B01D3/141 , B01D3/14 , Y10S203/11 , Y10S203/20
摘要： A dividing-wall column having a dividing wall which is essentially disposed along the long direction of the column is proposed, which divides the column interior into a feed part, a take off part, an upper shared column part and a lower shared column part, with feed in whole or in part in the vaporous state of a mixture to be separated between the upper region of the feed part and the lower region of the feed part and/or side stream take off in whole or in part in the vaporous state between the upper region of the take off part and the lower region of the take off part, where if feed is in whole or in part in the vaporous state the cross-sectional area of the upper region of the feed part is increased by plane-parallel displacement of the dividing wall toward the upper region of the take off part, and/or if the side stream take off is in whole or in part in the vaporous state, the cross-sectional area of the lower region of the take off part is increased by displacement of the dividing wall toward the lower region of the feed part, in such a manner that the F factor is substantially the same in all column regions.
摘要翻译：提出了具有分隔壁的分隔壁，该分隔壁基本上沿着塔的长方向设置，其将塔内部分为进料部分，脱落部分，上共享塔部分和下共享塔部分，在进料部分的上部区域和进料部分的下部区域和/或侧馏分之间在蒸气状态下的全部或部分蒸气状态下的进料全部或部分地在蒸气状态之间分离，取出部分的上部区域和脱落部分的下部区域，如果进料全部或部分处于气态，则进料部分的上部区域的横截面面积被平面平行地增加分流壁向脱气部的上部区域的位移，和/或侧流的脱落全部或部分处于蒸发状态，脱落部的下部区域的截面积为由分界位移增加壁朝向馈送部分的下部区域，使得F因子在所有列区域中基本相同。

35. 发明申请

US20070167655A1 Method for the production of tetrahydrogeranylacetone 失效
标题翻译：四氢笨花丙酮生产方法
公开(公告)号：US20070167655A1
公开(公告)日：2007-07-19
申请号：US10596335
申请日：2004-12-10
申请人： Walter Dobler , Nicolaus Bahr , Alois Kindler , Christian Miller , Axel Salden
发明人： Walter Dobler , Nicolaus Bahr , Alois Kindler , Christian Miller , Axel Salden
IPC分类号： C07C45/45
CPC分类号： C07D473/34 , C07C45/62 , C07C45/74 , C07D231/12 , C07D231/14 , C07D231/16 , C07D231/18 , C07D231/38 , C07D231/56 , C07D233/56 , C07D235/06 , C07D249/12 , C07D257/04 , C07D401/12 , C07D403/12 , C07D409/04 , C07C49/04 , C07C49/203
摘要： The present invention relates to a process for preparing tetrahydrogeranylacetone (tetrahydropseudoionone) by aldol condensation of citral with acetone and subsequent hydrogenation. The invention further relates to the use of thus obtained tetrahydro-geranylacetone for preparing phytol, isophytol, tocopherol and/or tocopherol derivatives. In addition, the invention relates to processes for preparing tocopherols and/or tocopherol derivatives.
摘要翻译：本发明涉及通过柠檬醛与丙酮的醛醇缩合并随后氢化制备四氢胆烷丙酮（tetrahydropseudoionone）的方法。本发明还涉及如此得到的四氢 - 香叶基丙酮用于制备植物醇，异植醇，生育酚和/或生育酚衍生物的用途。此外，本发明涉及制备生育酚和/或生育酚衍生物的方法。

36. 发明申请

US20070098838A1 Injection molding machine for producing shaped plastic parts, preferably plastic cups 审中-公开
标题翻译：用于生产成型塑料部件的注塑机，优选塑料杯
公开(公告)号：US20070098838A1
公开(公告)日：2007-05-03
申请号：US11549144
申请日：2006-10-13
申请人： Walter Dobler
发明人： Walter Dobler
IPC分类号： B29C45/42
CPC分类号： B29C45/1769 , B29C45/14008 , B29C45/2673 , B29C45/32 , B29C45/42 , B29C2045/14049 , B29C2045/14918 , B29L2031/7132
摘要： An injection molding machine for producing shaped plastic parts has at least one injection mold and at least one removal unit with which shaped plastic parts are removed from the at least one injection mold. The shaped plastic parts are put down in a controlled way while the at least one injection mold is in a closed position. At least one putting-down unit is provided and the at least one removal unit transfers the shaped plastic parts to the at least one putting-down unit. The putting-down unit places the shaped plastic parts into at least one receptacle.
摘要翻译：一种用于生产成形塑料部件的注射成型机具有至少一个注射模具和至少一个移除单元，通过该至少一个移除单元，从至少一个注射模具移除成形塑料部件。成形的塑料部件以受控的方式放置，同时至少一个注射模具处于关闭位置。提供至少一个压下单元，并且所述至少一个移除单元将成形的塑料部件传送到至少一个放下单元。压制单元将成形塑料部件放置在至少一个容器中。

37. 发明授权

US07141698B2 Continuous process for producing pseudoionones and ionones 有权
标题翻译：连续生产假阳离子和紫罗兰酮的方法
公开(公告)号：US07141698B2
公开(公告)日：2006-11-28
申请号：US10533969
申请日：2003-10-28
申请人： Walter Dobler , Nicolaus Bahr , Klaus Breuer , Alois Kindler
发明人： Walter Dobler , Nicolaus Bahr , Klaus Breuer , Alois Kindler
IPC分类号： C07C45/72
CPC分类号： C07C403/16 , C07C45/54 , C07C2601/14 , C07C2601/16 , C07C49/203
摘要： The invention relates to a continuous process for producing pseudoionones of general formulas (I) and (I′) as well as isomers thereof, whereby: R1 represents CH3 or (a); R2 and R3 represent hydrogen, CH3 or C2H5, and; R4 and R5 represent hydrogen or CH3. These pseudoionones are produced by reacting an aldehyde of formula (II) with an excess of a ketone of general formula (III), whereby R1, R2 and R3 have the aforementioned meanings, in the presence of water and alkali hydroxide at an increased temperature and in a homogeneous solution. The inventive process is characterized in that: a) the intermixing of the homogeneous solution consisting of aldehyde, ketone and aqueous alkali lye occurs at a temperature ranging from 10 to 120° C.; b) the undissolved water and alkali hydroxide contained in the reaction mixture are subsequently separated out; c) while avoiding back mixing, the homogeneous reaction mixture is then guided through a reactor, which permits a residence time ranging from 2 to 300 minutes, at a temperature that is 10 to 120° C. higher than the boiling point of the lowest-boiling component and under a vapor pressure p ranging from 106 to 107 Pa; d) the reaction mixture is cooled by expansion; e) ketone is removed from the reaction mixture using vapor flowing in the opposite direction and; f) the raw product is dried and rid from excessive aldehyde and secondary components via a rectification column
摘要翻译：本发明涉及用于生产通式（I）和（I'）的假阳离子及其异构体的连续方法，其中：R 1表示CH 3或（一个）; R 2和R 3代表氢，CH 3或C 2 H 5，，和 R 4和R 5代表氢或CH 3。这些假性离子是通过使式（II）的醛与过量的通式（III）的酮反应制得的，其中R 1，R 2和R 2 在水和碱金属氢氧化物的存在下，在升高的温度下和均匀的溶液中具有上述含义。本发明的方法的特征在于：a）由醛，酮和碱性碱液组成的均匀溶液的混合在10至120℃的温度下进行; b）随后将反应混合物中所含的未溶解的水和氢氧化碱分离出来; c）同时避免反混合，然后将均匀的反应混合物引导通过反应器，其允许停留时间为2至300分钟，温度高于最低浓度的沸点为10至120℃，沸腾成分，并且在10 -6至10 7 Pa范围内的蒸汽压力p; d）反应混合物通过膨胀冷却; e）使用沿相反方向流动的蒸汽从反应混合物中除去酮; f）将原料干燥并通过精馏塔除去过量的醛和次要组分

38. 发明申请

US20060211898A1 Method for the production of tetrahydrogeranylacetone 有权
标题翻译：四氢笨花丙酮生产方法
公开(公告)号：US20060211898A1
公开(公告)日：2006-09-21
申请号：US10519684
申请日：2003-07-14
申请人： Hans-Georg Goebbel , Gerd Kaibel , Christian Miller , Walter Dobler , Thomas Dirnsteiner , Thilo Hahn , Klaus Breuer , Werner Aquila
发明人： Hans-Georg Goebbel , Gerd Kaibel , Christian Miller , Walter Dobler , Thomas Dirnsteiner , Thilo Hahn , Klaus Breuer , Werner Aquila
IPC分类号： C07C11/00
CPC分类号： C07C45/62 , C07C49/04
摘要： A process is described for preparing tetrahydrogeranylacetone in which pseudoionone, geranylacetone and/or dihydrogeranylacetone in a liquid phase, in which particles of a catalyst which is capable of preferentially hydrogenating carbon-carbon double bonds over carbon-oxygen double bonds are suspended, is conducted through a device which inhibits the transport of the catalyst particles in the presence of a hydrogen-containing gas.
摘要翻译：描述了一种制备四氢ger anyl anyl A A is ger ger ger through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through 在含氢气体的存在下抑制催化剂颗粒的输送的装置。

39. 发明申请

US20050070733A1 Supported metal oxides as catalysts for aldol condensations 失效
标题翻译：负载金属氧化物作为醛醇缩合的催化剂
公开(公告)号：US20050070733A1
公开(公告)日：2005-03-31
申请号：US10497597
申请日：2002-12-02
申请人： Marcus Sigl , Christian Miller , Walter Dobler , Mathias Haake
发明人： Marcus Sigl , Christian Miller , Walter Dobler , Mathias Haake
IPC分类号： B01D3/26 , B01D3/00 , B01J8/00 , B01J8/02 , B01J8/04 , B01J8/12 , B01J19/24 , B01J19/32 , B01J21/04 , B01J23/10 , B01J23/92 , B01J35/02 , B01J38/64 , B01J38/66 , C07B41/06 , C07B61/00 , C07C45/72 , C07C45/74 , C07C49/203 , C07C67/293 , B01J23/00 , C07C45/68
CPC分类号： B01J19/32 , B01D3/009 , B01J8/003 , B01J8/0292 , B01J8/12 , B01J19/249 , B01J21/04 , B01J23/10 , B01J23/92 , B01J35/026 , B01J2219/2453 , B01J2219/2459 , B01J2219/2471 , B01J2219/2481 , B01J2219/2497 , B01J2219/3221 , B01J2219/32217 , B01J2219/32227 , B01J2219/32237 , B01J2219/32258 , B01J2219/32262 , B01J2219/32408 , B01J2219/32466 , B01J2219/326 , C07C45/72 , C07C45/74 , Y02P20/127 , Y02P20/584 , C07C49/203
摘要： A supported catalyst is proposed comprising one or more metal oxides as active component on a catalyst support for carrying out an aldol condensation, with the catalyst support being γ-aluminum oxide, the active component comprising one or more oxides of the elements having atomic numbers 39 or from 57 to 71 and the concentration of the active component being in the range from 5 to 12% by weight, based on the weight of the catalyst support.
摘要翻译：提出了一种负载催化剂，其包含一种或多种金属氧化物作为用于进行醛醇缩合的催化剂载体上的活性组分，催化剂载体是γ-氧化铝，活性组分包含一种或多种原子序数为39的元素的氧化物或57至71，活性组分的浓度为5至12重量％，基于催化剂载体的重量。

40. 发明授权

US06559259B2 Compositions containing addition polymers prepared using crosslinkable protective colloids 失效
标题翻译：含有使用可交联保护胶体制备的加成聚合物的组合物
公开(公告)号：US06559259B2
公开(公告)日：2003-05-06
申请号：US09939992
申请日：2001-08-27
申请人： Klaus Kohlhammer , Gerhard Koegler , Monika Rockinger , Walter Dobler
发明人： Klaus Kohlhammer , Gerhard Koegler , Monika Rockinger , Walter Dobler
IPC分类号： C08F1230
CPC分类号： C04B40/0042 , C04B2103/0057 , C08F2/24 , D21H17/39 , C04B24/163 , C04B24/26
摘要： A water-soluble, crosslinkable protective colloid is provided having a molecular weight of least than 500,000 comprising: a) 20 to 959 by weight of monomer units containing sulphonic acid or sulphonate groups, b) 4 to 800 by weight of monomer units containing N-methylol or N-alkoxymethyl groups, and c) 0.1 to 20% by weight of hydrophobic monomer units such as water insoluble ethylenically unsaturated compounds and the hydrophobic end groups of initiator radicals or regulator molecules. Optionally, up to 50% by weight of the monomer units containing sulphonic acid or sulphonate groups can be replaced by monomer units containing carboxyl groups or monomer units containing amide groups.
摘要翻译：提供分子量小于500,000的水溶性可交联保护胶体，其包含：a）20至959重量份含有磺酸或磺酸酯基团的单体单元，b）4至800重量份含有N- 羟甲基或N-烷氧基甲基，和c）0.1至20重量％的疏水性单体单元如水不溶性烯属不饱和化合物和引发剂基团或调节剂分子的疏水端基。任选地，含有磺酸或磺酸盐基团的多至50重量％的单体单元可以被含有羧基的单体单元或含有酰胺基团的单体单元代替。

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