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31. 发明授权

US4705553A Method of reducing plant growth height using phenylalkylmorpholines 失效
标题翻译：使用苯基吗啉降低植物生长高度的方法
公开(公告)号：US4705553A
公开(公告)日：1987-11-10
申请号：US015542
申请日：1987-02-13
申请人： Ernst Buschmann , Walter Himmele , Heinz Eckhardt , Hansgeorg Ernst , Wilhelm Rademacher , Johann Jung
发明人： Ernst Buschmann , Walter Himmele , Heinz Eckhardt , Hansgeorg Ernst , Wilhelm Rademacher , Johann Jung
IPC分类号： C07D295/02 , A01N33/08 , A01N35/04 , A01N43/40 , A01N43/84 , C07C17/26 , C07C43/225 , C07C45/74 , C07C47/232 , C07D207/06 , C07D211/14 , C07D223/04 , C07D265/30 , C07D279/12 , C07D295/03 , C07D295/073 , C07D295/096
CPC分类号： C07C17/2632 , A01N33/08 , A01N35/04 , A01N43/40 , A01N43/84 , C07C17/16 , C07C17/269 , C07C22/04 , C07C25/02 , C07C43/225 , C07C45/74 , C07C47/232 , C07C49/80 , C07D295/03 , C07D295/073 , C07D295/096
摘要： Novel phenylalkylcycloamines, their preparation, agents containing these compounds, and methods for regulating plant growth.
摘要翻译：新型苯基烷基环胺，其制备方法，含这些化合物的试剂，以及调节植物生长的方法。

32. 发明授权

US4550182A Preparation of .alpha.-tocopherol 失效
标题翻译： α-生育酚的制备
公开(公告)号：US4550182A
公开(公告)日：1985-10-29
申请号：US588374
申请日：1984-03-12
申请人： Hansgeorg Ernst , Henning-Peter Gehrken , Joachim Paust
发明人： Hansgeorg Ernst , Henning-Peter Gehrken , Joachim Paust
IPC分类号： C07D317/60 , B01J31/16 , C07B61/00 , C07D311/72
CPC分类号： C07D311/72
摘要： A process for the preparation of .alpha.-tocopherol of the formula I ##STR1## by reacting a chroman derivative with a C.sub.14 -Grignard reagent using a di-alkali metal tetrahalocuprate catalyst in a Schlosser-Fouquet reaction, wherein a chroman derivative of the general formula II ##STR2## where Y is a leaving group, especially Br, is used and is reacted, at from -70.degree. to 0.degree. C., first with a solution of about 1 equivalent of a Grignard compound of the general formula IIIX--Mg--R (III)where X is Cl, Br or I and R is straight-chain or branched alkyl of 1 to 14 carbon atoms, preferably methyl, ethyl or ##STR3## and then with a solution of a Grignard reagent of the formula IIIa ##STR4## in an ether solvent and a solution of a di-alkali metal tetrahalocuprate in an ether solvent. The novel process simplifies the preparation of 2RS,4'RS,8'RS-, 2R,4'RS,8'RS- or 2R,4'R,8'R-.alpha.-tocopherol by reacting a chroman structural unit, containing a C.sub.2 side-chain in the 2-position, with the corresponding C.sub.14 -Grignard compound.
摘要翻译：通过在Schlosser-Fouquet反应中使用二碱金属四卤代硼酸催化剂使苯并二氢吡喃衍生物与C14-格氏试剂反应制备式I的α-生育酚的方法，其中将使用其中Y为离去基团，特别是Br的通式II（II），并且在-70℃至0℃下反应，首先用约1当量的Grignard化合物通式III X-Mg-R（III）其中X为Cl，Br或I，R为1至14个碳原子的直链或支链烷基，优选为甲基，乙基或者“ 式IIIa的格利雅试剂（IIIa）在醚溶剂中和二碱金属四卤代硼酸酯在醚溶剂中的溶液。该新方法简化了2RS，4'RS，8'RS-，2R，4'RS，8'RS-或2R，4'R，8'R-α-生育酚的制备，通过使色结构单元反应， 2-位的C2侧链与相应的C14-格利雅化合物。

33. 发明授权

US08492579B2 Method for producing astaxanthin dimethyldisuccinate 有权
标题翻译：虾青素二甲基琥珀酸盐的制备方法
公开(公告)号：US08492579B2
公开(公告)日：2013-07-23
申请号：US13021173
申请日：2011-02-04
申请人： Hansgeorg Ernst , Walter Dobler , Andreas Keller , Klaus Henrich
发明人： Hansgeorg Ernst , Walter Dobler , Andreas Keller , Klaus Henrich
IPC分类号： C07C403/24
CPC分类号： C07C403/24 , C07C2601/16
摘要： The present invention relates to an improved method for producing all-E astaxanthin dimethyldisuccinate of the formula I.
摘要翻译：本发明涉及一种生产式I的全-E虾青素二甲基丁二酸酯的改进方法。

34. 发明授权

US07378558B2 Method for producing carotenoids 失效
标题翻译：生产类胡萝卜素的方法
公开(公告)号：US07378558B2
公开(公告)日：2008-05-27
申请号：US10532207
申请日：2003-11-17
申请人： Hansgeorg Ernst , Klaus Henrich , Andreas Keller
发明人： Hansgeorg Ernst , Klaus Henrich , Andreas Keller
IPC分类号： C07C45/68 , C07C49/543 , C07C43/03 , C07C35/18 , C07C69/73
CPC分类号： C07C403/24 , C07C1/34 , C07C43/15 , C07C67/343 , C07C69/734 , C07C11/21
摘要： A process for preparing carotenoids, in which the process includes reacting a dialkoxy dialdehyde in a double Wittig condensation with a phosphonium salt of or in a double Wittig-Horner condensation with a phosphonate. The carotenoids include, for example, β-carotene, zeaxanthin, canthaxanthin, astaxathin, lycopene and croceptin, which are useful as nutraceuticals, food colorants, and feed additives.
摘要翻译：一种制备类胡萝卜素的方法，其中该方法包括使双维t嗪缩合中的二烷氧基二醛与双维维特 - 霍纳缩合的鏻盐与膦酸酯反应。类胡萝卜素包括例如β-胡萝卜素，玉米黄质，角黄素，虾青素，番茄红素和croceptin，其可用作营养制品，食品着色剂和饲料添加剂。

35. 发明申请

US20070244344A1 Method for Producing 2,7-Dimethyl-Octa-2,4,6-Trienedial 有权
标题翻译： 2,7-二甲基 - 八甲基-2,4,6-三烯酸的生产方法
公开(公告)号：US20070244344A1
公开(公告)日：2007-10-18
申请号：US10588683
申请日：2005-02-04
申请人： Hansgeorg Ernst , Klaus Henrich , Andreas Keller
发明人： Hansgeorg Ernst , Klaus Henrich , Andreas Keller
IPC分类号： C07C45/45
CPC分类号： C07C45/515 , C07C41/54 , C07C45/65 , C07C47/277 , C07C47/21 , C07C43/315
摘要： The present invention relates to an improved process for preparing 2,7-dimethylocta-2,4,6-trienedial of the formula I, by a) double enol ether condensation of a butenedial bisacetal of the formula II with an enol ether of the formula III, in the presence of a Lewis acid catalyst to give a condensation product of the formula IV, where the radicals R1 and R2 in formulae II to IV are independently of one another C1-C6-alkyl; b) hydrolysis of the acetal groups of IV by adding an aqueous acid to form the dialdehyde of the formula V; d) crystallization of I from the reaction mixture, Wherein process steps a) to d) are carried out in the presence of an inert, water-immiscible organic solvent.
摘要翻译：本发明涉及通过以下方式制备式I的2,7-二甲基辛-2,4,6-三烯酸的改进方法：a）式Ⅱ的丁二醛双缩醛与式II的烯醇醚的双烯醇醚缩合 III，在路易斯酸催化剂的存在下，得到式IV的缩合产物，其中式II至IV中的基团R 1和R 2与式另一个C 1 -C 6 - 烷基; b）通过加入酸水溶液来水解IV的缩醛基以形成式V的二醛; d）从反应混合物中结晶I，其中方法步骤a）至d）在惰性的与水不混溶的有机溶剂的存在下进行。

36. 发明申请

US20070004925A1 Method for the production of phytofluene 失效
公开(公告)号：US20070004925A1
公开(公告)日：2007-01-04
申请号：US10595503
申请日：2004-10-15
申请人： Hansgeorg Ernst , Klaus Henrich
发明人： Hansgeorg Ernst , Klaus Henrich
IPC分类号： C07D319/06
CPC分类号： C07C45/60 , C07C1/34 , C07C45/515 , C07C45/59 , C07C11/21 , C07C47/21
摘要： The invention relates to a process for preparing phytofluene of the formula I, where a) a phosphonium salt of the formula II is condensed with an aldehyde of the formula III in a Wittig reaction to give an acetal of the formula IV b) the condensation product of the formula IV is subjected to an acid-catalyzed acetal hydrolysis to give the aldehyde of the formula V c) and V is condensed in a further Wittig reaction with a phosphonium salt of the formula VI to give phytofluene where the radicals R1, R2 and R7, and X− and Y− have the meaning sated in the description.

37. 发明申请

US20060106257A1 Method for producing carotenoids 失效
标题翻译：生产类胡萝卜素的方法
公开(公告)号：US20060106257A1
公开(公告)日：2006-05-18
申请号：US10532207
申请日：2003-11-17
申请人： Hansgeorg Ernst , Klaus Henrich , Andreas Keller
发明人： Hansgeorg Ernst , Klaus Henrich , Andreas Keller
IPC分类号： C07C45/45
CPC分类号： C07C403/24 , C07C1/34 , C07C43/15 , C07C67/343 , C07C69/734 , C07C11/21
摘要： A process for preparing carotenoids, in which the process includes reacting a dialkoxy dialdehyde in a double Wittig condensation with a phosphonium salt of or in a double Wittig-Horner condensation with a phosphonate. The carotenoids include, for example, β-carotene, zeaxanthin, canthaxanthin, astaxathin, lycopene and croceptin, which are useful as nutraceuticals, food colorants, and feed additives.
摘要翻译：一种制备类胡萝卜素的方法，其中该方法包括使双维t嗪缩合中的二烷氧基二醛与双维维特 - 霍纳缩合的鏻盐与膦酸酯反应。类胡萝卜素包括例如β-胡萝卜素，玉米黄质，角黄素，虾青素，番茄红素和croceptin，其可用作营养制品，食品着色剂和饲料添加剂。

38. 发明申请

US20050165078A1 Method for the production of chiral imidazolidin-2-ones 失效
标题翻译：制备手性咪唑烷-2-酮的方法
公开(公告)号：US20050165078A1
公开(公告)日：2005-07-28
申请号：US10510439
申请日：2003-04-08
申请人： Hansgeorg Ernst , Jurgen Koppenhofer , Daniela Klein
发明人： Hansgeorg Ernst , Jurgen Koppenhofer , Daniela Klein
IPC分类号： C07D233/34 , C07B53/00 , C07B61/00 , C07D233/00 , A61K31/4178 , A61K31/4168 , C07D233/04 , C07D47/02
CPC分类号： C07D233/00
摘要： The invention relates to a process for preparing chiral imidazolidin-2-ones of the formula I in which R1 is C1-C8-alkyl, cyclohexyl, phenyl, a C1-C6-alkyl-, halo-, nitro-, C1-C6-alkoxy-, C1-C6-alkylmercapto- or CF3-substituted phenyl radical, naphthyl or a C1-C6-alkyl-, halo-, nitro-, C1-C6-alkoxy- or CF3-substituted naphthyl radical, R2 is C1-C8-alkyl, C2-C8-alkenyl, cyclohexyl, phenyl or a phenyl-C1-C6-alkyl radical which may be substituted by a nitro, C1-C6-alkoxy, methylenedioxy or CF3 radical, and R3 is C1-C12-alkyl, C2-C8-alkenyl, cyclohexyl, phenyl or a C1-C6-alkyl-, halo-, nitro-, C1-C6-alkoxy-, methylenedioxy-, dialkylamino- or CF3-substituted phenyl radical, by reacting a compound of the formula II or the salt thereof in which R1, R2 and R3 have the abovementioned meaning, with urea in the presence of an involatile ammonium salt, wherein the reaction is carried out in the presence of an aprotic polar organic solvent.
摘要翻译：本发明涉及一种制备其中R 1是C 1 -C 8 - 的式I的手性咪唑烷-2-酮的方法，烷基，环己基，苯基，C 1 -C 6 - 烷基 - ，卤代 - ，硝基 - ，C 1 -C 3 - C 6 - 烷氧基 - ，C 1 -C 6 - 烷基巯基或CF 3 - 取代的苯基，萘基或C C 1 -C 6 - 烷基 - ，卤代 - ，硝基 - ，C 1 -C 6 - 烷氧基 - 或CF 3 - 取代的萘基，R 2是C 1 -C 8 - 烷基，C _{和R 3具有上述含义，在非挥发性铵盐存在下用脲进行反应，其中反应在非质子极性有机溶剂的存在下进行。}

39. 发明授权

US06747177B2 Process for the preparation of meso-zeaxanthin 失效
标题翻译：内消旋玉米黄质的制备方法
公开(公告)号：US06747177B2
公开(公告)日：2004-06-08
申请号：US10619423
申请日：2003-07-16
申请人： Hansgeorg Ernst , Klaus Henrich , Klaus Ditrich
发明人： Hansgeorg Ernst , Klaus Henrich , Klaus Ditrich
IPC分类号： C07C3508
CPC分类号： C07C403/24 , C07B2200/07 , C07C29/74 , C07C35/18 , C07C69/65 , C07C2601/14 , Y02P20/55 , C07C35/26
摘要： A process for the preparation of optically pure acetylenediols of the formulae R-I and S-I and their further reaction to give meso-zeaxanthin are described.
摘要翻译：描述了制备式R-I和S-1的光学纯乙炔二醇的方法及其进一步反应得到内消旋 - 玉米黄质的方法。

40. 发明授权

US06740774B1 Preparation of N-acylamino acid esters and N-acylamino acetals 失效
标题翻译： N-酰基氨基酸酯和N-酰基氨基缩醛的制备
公开(公告)号：US06740774B1
公开(公告)日：2004-05-25
申请号：US09639681
申请日：2000-08-16
申请人： Joachim Paust , Hansgeorg Ernst , Reinhard Kaczmarek , Hagen Jaedicke
发明人： Joachim Paust , Hansgeorg Ernst , Reinhard Kaczmarek , Hagen Jaedicke
IPC分类号： C07C22900
CPC分类号： C07C231/08 , C07C233/18 , C07C233/47
摘要： A process for preparing N-acyl derivatives of the formula I, in which the substituents independently of one another have the following meanings: X is CH(OR3)2, COOR3; R1 is hydrogen, C1-C12-alkyl, aryl, unsubstituted or substituted; R2 is hydrogen, C1-C12-alkyl, aryl, unsubstituted or substituted; R3 is C1-C12-alkyl, which comprises reacting a carboxamide R1—CONH2 of the formula II with a glyoxal monoacetal derivative of the formula III, in the presence of a carboxylic acid R4—COOH of the formula IV where R4=C1-C12-alkyl, where the substituents R1 to R3 are as defined above, is described.
摘要翻译：制备式I的N-酰基衍生物的方法，其中取代基彼此独立地具有以下含义：X是CH（OR 3）2，COOR 3; R 1是氢，C 1 C 12 - 烷基，芳基，未取代或取代的; R 2是氢，C 1 -C 12 - 烷基，芳基，未取代或取代的; R 3是C 1 -C 12烷基，其包括使羧酰胺R 1， -CONH 2与式III的乙二醛单缩醛衍生物在式IV的羧酸R 4 -COOH的存在下反应，其中R 4 = C 1 -C 12 - 烷基，其中取代基R' 1> -R 3如上所定义。

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