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    • 33. 发明申请
    • SILICON FILM AND LITHIUM SECONDARY BATTERY
    • 硅胶片和锂二次电池
    • US20120244441A1
    • 2012-09-27
    • US13514893
    • 2010-12-10
    • Suguru NodaShingo MorokumaTaketsugu Yamamoto
    • Suguru NodaShingo MorokumaTaketsugu Yamamoto
    • C01B33/02B32B5/06C23C16/24C23C16/30B32B15/04H01M4/38B82Y30/00
    • H01M10/052C23C14/14C23C14/541H01G11/06H01G11/24H01G11/28H01M4/0421H01M4/134H01M4/1395Y02E60/13Y02T10/7011Y02T10/7022Y10T428/249921
    • Provided are a silicon film which can give an electrode suitable for use in high-capacity lithium secondary batteries, and a process for easily producing the silicon film. The silicon film comprises a columnar aggregate which is an aggregate of columnar structures made of Si or a Si compound. The silicon film may be a film wherein the diameter of the columnar structures is from 10 nm to 100 nm and the film thickness is from 0.2 μm to 100 μm. In the process for preparing a silicon film on a substrate by vapor deposition using a vapor deposition source made of Si or a Si compound, the temperature of the vapor deposition source is 1700 K or higher, the temperature of the substrate is lower than that of the vapor deposition source, and the temperature difference between the vapor deposition source and the substrate is 700 K or larger. In the process for preparing the silicon film, the distance (D) between the vapor deposition source and the substrate is shorter than the minimum diameter (P) of the substrate, the minimum diameter (P) being determined by viewing the substrate from the perpendicular direction. Also provided are an electrode comprising the silicon film, and a lithium secondary battery comprising the electrode as a negative electrode.
    • 提供一种能够提供适用于大容量锂二次电池的电极的硅膜,以及容易制造硅膜的方法。 硅膜包括柱状聚集体,其是由Si或Si化合物制成的柱状结构的聚集体。 硅膜可以是其中柱状结构的直径为10nm至100nm并且膜厚度为0.2μm至100μm的膜。 在通过使用由Si或Si化合物制成的气相沉积源通过气相沉积在衬底上制备硅膜的方法中,气相沉积源的温度为1700K或更高,衬底的温度低于 蒸镀源和蒸镀源与基板的温度差为700K以上。 在制备硅膜的过程中,蒸镀源与衬底之间的距离(D)比衬底的最小直径(P)短,最小直径(P)通过从垂直方向观察衬底来确定 方向。 还提供了包括硅膜的电极和包含该电极作为负电极的锂二次电池。
    • 35. 发明申请
    • SODIUM-MANGANESE MIXED METAL OXIDE, PRODUCTION METHOD THEREOF AND SODIUM SECONDARY BATTERY
    • 氧化锰 - 锰锰混合金属氧化物,其生产方法和钠二次电池
    • US20100266900A1
    • 2010-10-21
    • US12743971
    • 2008-11-17
    • Masami MakideraTaketsugu YamamotoSatoru Kuze
    • Masami MakideraTaketsugu YamamotoSatoru Kuze
    • H01M4/50H01M4/88
    • H01M10/054C01G45/1228C01P2002/72C01P2002/76C01P2006/40H01M2/1653H01M2/1686H01M4/505
    • Disclosed is a mixed metal oxide which is reduced in the amount of scarce metal used therein, while having excellent performance as a positive electrode active material for secondary batteries. Also disclosed are a positive electrode for sodium secondary batteries having excellent performance, and a sodium secondary battery. Specifically disclosed is a method for producing a sodium-manganese complex metal oxide which is characterized by comprising a step for calcining a material, which contains sodium carbonate (Na2CO3) and dimanganese trioxide (Mn2O3) in such amounts that the molar ratio of sodium to manganese (Na/Mn) is not less than 0.4 but not more than 0.7, at a temperature of not less than 850° C. Also specifically disclosed are a sodium-manganese complex metal oxide produced by the method, a positive electrode for sodium secondary batteries which contains such a sodium-manganese complex metal oxide, and a sodium secondary battery.
    • 公开了一种混合金属氧化物,其中使用的稀有金属的量减少,同时具有作为二次电池的正极活性物质的优异的性能。 还公开了具有优异性能的钠二次电池用正极和钠二次电池。 具体公开了一种钠锰复合金属氧化物的制造方法,其特征在于,包括使含有碳酸钠(Na 2 CO 3)和三氧化二锰(Mn 2 O 3)的物质煅烧的工序,使得钠与锰的摩尔比 (Na / Mn)在不低于850℃的温度下不小于0.4但不大于0.7。还具体公开了通过该方法生产的钠锰复合金属氧化物,钠二次电池用正极 其含有这样的钠锰复合金属氧化物和钠二次电池。