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    • 3. 发明申请
    • SODIUM SECONDARY BATTERY
    • 钠二次电池
    • US20110003191A1
    • 2011-01-06
    • US12865987
    • 2009-02-03
    • Satoru KuzeMasami MakideraTaketsugu Yamamoto
    • Satoru KuzeMasami MakideraTaketsugu Yamamoto
    • H01M4/50H01M4/52H01M2/14
    • H01M2/1686C01G45/1228C01G51/50C01P2006/40H01M2/1653H01M4/505H01M4/525H01M4/587H01M10/054
    • The present invention provides a sodium secondary battery having a superior cycling performance as compared with conventional techniques. A sodium secondary battery of the present invention comprises a positive electrode comprising a mixed metal oxide which comprises Na and M1 wherein M1 represents two or more elements selected from the group consisting of Mn, Fe, Co and Ni, with an Na:M1 molar ratio being a:1 wherein a is a value falling within the range of more than 0.5 and less than 1, a negative electrode comprising a carbonaceous material capable of storing and releasing Na ions, and an electrolyte. Further, the sodium secondary battery of the present invention may comprise a separator, and the separator may be a separator comprising a porous laminated film in which a heat-resistant porous layer comprising a heat-resistant resin and a porous film comprising a thermoplastic resin are stacked each other.
    • 本发明提供了与常规技术相比具有优异的循环性能的钠二次电池。 本发明的钠二次电池包括含有包含Na和M1的混合金属氧化物的正极,其中M1表示选自Mn,Fe,Co和Ni中的两种或更多种元素,Na:M1摩尔比 其中a是大于0.5且小于1的范围的值,包含能够储存和释放Na离子的碳质材料的负极和电解质。 此外,本发明的钠二次电池可以包括隔膜,隔板可以是包括多孔层压膜的隔板,其中包含耐热树脂的耐热多孔层和包含热塑性树脂的多孔膜是 彼此堆叠
    • 6. 发明申请
    • MIXED METAL OXIDE AND SODIUM SECONDARY BATTERY
    • 混合金属氧化物和钠二次电池
    • US20100323232A1
    • 2010-12-23
    • US12865976
    • 2009-02-03
    • Satoru KuzeMasami MakideraTaketsugu Yamamoto
    • Satoru KuzeMasami MakideraTaketsugu Yamamoto
    • H01M2/14H01M4/40H01M4/505H01M4/485H01M10/054
    • H01M4/525H01M2/1653H01M2/1686H01M4/505H01M10/054H01M10/54Y02W30/84
    • The present invention provides a sodium secondary battery capable of reducing the amount of lithium used, and ensuring a larger discharge capacity maintenance rate when having repeated a charge and discharge, as compared with conventional techniques; and a mixed metal oxide usable as the positive electrode active material therefor. A mixed metal oxide of the present invention comprises Na and M1 wherein M1 represents three or more elements selected from the group consisting of Mn, Fe, Co and Ni with an Na:M1 molar ratio being a:1 wherein a is a value falling within the range of more than 0.5 and less than 1. Also, a mixed metal oxide of the present invention is represented by the following formula (1): NaaM1O2  (1) wherein M1 and a each have the same meaning as above.The positive electrode active material for secondary batteries of the present invention comprises the mixed metal oxide above.
    • 本发明提供一种能够减少所使用的锂的量的钠二次电池,并且与现有的技术相比,能够在重复进行充放电时确保更大的放电容量维持率。 和可用作其的正极活性物质的混合金属氧化物。 本发明的混合金属氧化物包含Na和M1,其中M1表示选自Mn,Fe,Co和Ni中的三种或更多种元素,Na:M1摩尔比为a:1,其中a为落入 范围大于0.5且小于1.此外,本发明的混合金属氧化物由下式(1)表示:NaaM1O2(1)其中M1和a各自具有与上述相同的含义。 本发明的二次电池用正极活性物质包含上述复合金属氧化物。
    • 7. 发明申请
    • MIXED METAL OXIDE AND SODIUM SECONDARY BATTERY
    • 混合金属氧化物和钠二次电池
    • US20110003192A1
    • 2011-01-06
    • US12865993
    • 2009-02-03
    • Satoru KuzeMasami MakideraTaketsugu Yamamoto
    • Satoru KuzeMasami MakideraTaketsugu Yamamoto
    • H01M2/16H01M4/88
    • H01M10/054C01G49/0072C01G53/50C01P2002/72H01M2/1653H01M2/1686H01M4/505H01M4/525H01M4/5825H01M10/4235Y02E60/122
    • The present invention provides a sodium secondary battery capable of reducing the amount used of a scarce metal element such as lithium and cobalt and moreover, ensuring a larger discharge capacity after repeating charge/discharge as compared with conventional techniques, and a mixed metal oxide usable as the positive electrode active material therefor. The mixed metal oxide of the present invention comprises Na, Mn and M1 wherein M1 is Fe or Ni, with a Na:Mn:M1 molar ratio being a:(1-b):b wherein a is a value falling within the range of more than 0.5 and less than 1, and b is a value falling within the range of from 0.001 to 0.5. Another mixed metal oxide of the present invention is a mixed metal oxide represented by the following formula (1): NaaMn1-bM1bO2 (1) wherein M1, a and b each have the same meaning as above. The positive electrode active material for sodium secondary batteries of the present invention comprises the mixed metal oxide above.
    • 本发明提供一种钠二次电池,其能够减少诸如锂和钴之类的稀有金属元素的使用量,此外,与常规技术相比,确保了重复充电/放电后的放电容量更大,并且可用作 正极活性物质。 本发明的混合金属氧化物包括Na,Mn和M1,其中M1是Fe或Ni,Na:Mn:M1的摩尔比为a:(1-b):b其中a是落在 大于0.5且小于1,b为0.001至0.5的范围内的值。 本发明的另一种混合金属氧化物是由下式(1)表示的混合金属氧化物:NaaMn1-bM1bO2(1)其中M1,a和b各自具有与上述相同的含义。 本发明的钠二次电池用正极活性物质包含上述混合金属氧化物。
    • 10. 发明申请
    • SODIUM-MANGANESE MIXED METAL OXIDE, PRODUCTION METHOD THEREOF AND SODIUM SECONDARY BATTERY
    • 氧化锰 - 锰锰混合金属氧化物,其生产方法和钠二次电池
    • US20100266900A1
    • 2010-10-21
    • US12743971
    • 2008-11-17
    • Masami MakideraTaketsugu YamamotoSatoru Kuze
    • Masami MakideraTaketsugu YamamotoSatoru Kuze
    • H01M4/50H01M4/88
    • H01M10/054C01G45/1228C01P2002/72C01P2002/76C01P2006/40H01M2/1653H01M2/1686H01M4/505
    • Disclosed is a mixed metal oxide which is reduced in the amount of scarce metal used therein, while having excellent performance as a positive electrode active material for secondary batteries. Also disclosed are a positive electrode for sodium secondary batteries having excellent performance, and a sodium secondary battery. Specifically disclosed is a method for producing a sodium-manganese complex metal oxide which is characterized by comprising a step for calcining a material, which contains sodium carbonate (Na2CO3) and dimanganese trioxide (Mn2O3) in such amounts that the molar ratio of sodium to manganese (Na/Mn) is not less than 0.4 but not more than 0.7, at a temperature of not less than 850° C. Also specifically disclosed are a sodium-manganese complex metal oxide produced by the method, a positive electrode for sodium secondary batteries which contains such a sodium-manganese complex metal oxide, and a sodium secondary battery.
    • 公开了一种混合金属氧化物,其中使用的稀有金属的量减少,同时具有作为二次电池的正极活性物质的优异的性能。 还公开了具有优异性能的钠二次电池用正极和钠二次电池。 具体公开了一种钠锰复合金属氧化物的制造方法,其特征在于,包括使含有碳酸钠(Na 2 CO 3)和三氧化二锰(Mn 2 O 3)的物质煅烧的工序,使得钠与锰的摩尔比 (Na / Mn)在不低于850℃的温度下不小于0.4但不大于0.7。还具体公开了通过该方法生产的钠锰复合金属氧化物,钠二次电池用正极 其含有这样的钠锰复合金属氧化物和钠二次电池。