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31. 发明授权

US5962610A Ethylene fluoro-containing copolymers 失效
标题翻译：含乙烯含氟共聚物
公开(公告)号：US5962610A
公开(公告)日：1999-10-05
申请号：US888286
申请日：1997-07-03
申请人： Julio A. Abusleme , Vincenzo Arcella , Giambattista Besana
发明人： Julio A. Abusleme , Vincenzo Arcella , Giambattista Besana
IPC分类号： C08J5/18 , C08F2/00 , C08F210/02 , C08F214/18 , C08F214/24 , C08F214/26
CPC分类号： C08F214/186 , C08F210/02
摘要： Ethylene fluoro-containing copolymers of the ECTFE and ETFE type, optionally in the presence of a third comonomer in amount comprised between 0.1 and 10% by moles, having a viscosity between 10.sup.2 and 10.sup.5 Pa.sec with shear rates of 1 sec.sup.-1 measured at the temperature of about 30.degree. C. higher than the second melting temperature, and having a rheologic curve in the diagram shear viscosity/shear-rate with a slope higher than 200, calculated as ratio between the viscosity in Pa.sec and the shear-rate in sec.sup.-1 in the shear-rate range comprised between 1 and 10 sec.sup.-1, and having a processability zone with shear-rate values higher than 10 s.sup.-1.
摘要翻译： ECTFE和ETFE型的含乙烯基氟的共聚物，任选地在第三共聚单体存在下，其量为0.1至10摩尔％，其粘度为102至105Pa·s，剪切速率为1秒-1 在比第二熔融温度高约30℃的温度下，在图中具有斜率高于200的剪切粘度/剪切速率的流变曲线，以Pa.sec中的粘度与剪切力之比计算 - 在剪切速率范围为1至10秒-1的sec-1范围内，并具有剪切速率值高于10s-1的加工性区域。

32. 发明授权

US5688838A Process for preparing hydrogen-containing fluoropolymers by suspension (co)polymerization 失效
标题翻译：通过悬浮（共）聚合制备含氢含氟聚合物的方法
公开(公告)号：US5688838A
公开(公告)日：1997-11-18
申请号：US508926
申请日：1995-07-28
申请人： Julio A. Abusleme , Pier Antonio Guarda , Ralph De Pasquale
发明人： Julio A. Abusleme , Pier Antonio Guarda , Ralph De Pasquale
IPC分类号： C08F14/24 , C08F2/18 , C08F2/48 , C08F2/50 , C08F14/00 , C08F14/18 , C08F14/26 , C08F210/02 , C08F2/46
CPC分类号： C08F14/18 , C08F210/02
摘要： Process for preparing hydrogen-containing fluoropolymers, wherein the corresponding olefinic monomers are (co) polymerized in an organic suspending medium in the presence of a radical photoinitiator and of ultraviolet-visible radiation at a temperature of from -60.degree. C. to +30.degree. C. Hydrogen-containing fluoropolymers are thus obtained having high second melting temperature and high maximum operating temperature, using as initiators non-hazardous products, which can be easily handled and kept also at room temperature.
摘要翻译：制备含氢含氟聚合物的方法，其中相应的烯属单体在有机悬浮介质中在自由基光引发剂的存在下和在-60℃至+ 30℃的温度下进行紫外 - 可见辐射（共）聚合因此，使用具有高的第二熔解温度和高的最高工作温度的含氢的含氟聚合物作为引发剂非危险产品，其可以容易地在室温下处理和保存。

33. 发明授权

US5646223A Perfluorodioxoles, the preparation process thereof, and homopolymers and copolymers therefrom 失效
标题翻译：全氟二恶烷，其制备方法及其均聚物和共聚物
公开(公告)号：US5646223A
公开(公告)日：1997-07-08
申请号：US694509
申请日：1996-08-07
申请人： Walter Navarrini , Vito Tortelli , Pasqua Colaianna , Julio A. Abusleme
发明人： Walter Navarrini , Vito Tortelli , Pasqua Colaianna , Julio A. Abusleme
IPC分类号： C07D317/42 , C08F34/00 , C08F34/02 , C08F134/02 , C08F214/26 , C08F234/02 , C10M107/24 , C10N50/10 , C08F16/24
CPC分类号： C07D317/42 , C08F214/262 , C08F2438/01
摘要： The invention relates to new thermoprocessable copolymers of tetrafluoroethylene constituted by perfluoromethylvinylether (0.5-13% by weight), a fluorinated dioxole (0.05-3%) and tetrafluoroethylene (difference to 100%), particularly useful for coating electric cables by melt extrusion. It relates also to new perfluorodioxoles of formula ##STR1## wherein R.sub.F is a C.sub.1 -C.sub.5 perfluoroalkyl radical; X.sub.1 and X.sub.2 are, independently from each other, F or CF.sub.3 ; and their homopolymers and copolymers, in particular thermoprocessable copolymers as defined above.
摘要翻译：本发明涉及由全氟甲基乙烯基醚（0.5-13重量％），氟化二氧杂环戊烯（0.05-3％）和四氟乙烯（差异至100％）构成的四氟乙烯的新型热可加工共聚物，特别适用于通过熔融挤出涂覆电缆。它还涉及式为“IMAGE”的新的全氟二恶烷，其中RF是C1-C5全氟烷基; X 1和X 2彼此独立地为F或CF 3; 和它们的均聚物和共聚物，特别是如上定义的热可加工共聚物。

34. 发明授权

US5434229A Radical (co)polymerization process of fluorinated olefinic monomers 失效
标题翻译：氟化烯烃单体的自由基（共）聚合方法
公开(公告)号：US5434229A
公开(公告)日：1995-07-18
申请号：US200224
申请日：1994-02-23
申请人： Julio A. Abusleme , Guglielmo Gregorio
发明人： Julio A. Abusleme , Guglielmo Gregorio
IPC分类号： C08F2/38 , C08F2/22 , C08F14/18 , C08F214/18 , C08F2/18
CPC分类号： C08F14/18
摘要： Branched aliphatic hydrocarbons, having from 6 to 25 carbon atoms and a ratio between the number of methyl groups and the number of carbon atoms higher than 0.5, are used in radical (co)polymerization processes of fluorinated olefinic monomers, optionally in association with non-fluorinated olefins, both in suspension and in aqueous emulsion. Such hydrocarbons are characterized, in the usual reaction conditions, by a chain transfer effect practically absent.
摘要翻译：具有6至25个碳原子的分支脂族烃和甲基数和高于0.5的碳原子数之间的比例用于氟化烯烃单体的自由基（共）聚合方法中，任选地与非 - 氟化烯烃，均为悬浮液和水性乳液。这些烃在通常的反应条件下通过实际上不存在的链转移效应来表征。

35. 发明授权

US09701766B2 Hydrophilic vinylidene fluoride polymers 有权
公开(公告)号：US09701766B2
公开(公告)日：2017-07-11
申请号：US13995454
申请日：2011-12-13
申请人： Julio A. Abusleme , Roberto Biancardi , Fabien Roblot , Anna Maria Bertasa , Giulio Brinati
发明人： Julio A. Abusleme , Roberto Biancardi , Fabien Roblot , Anna Maria Bertasa , Giulio Brinati
IPC分类号： C08F14/22 , B01D71/32 , B01D71/78 , C08F214/22 , C08F251/02 , C08F290/02 , C08F290/10 , C08F8/00
CPC分类号： C08F14/22 , B01D71/32 , B01D71/78 , B01D2323/38 , C08F8/00 , C08F214/225 , C08F251/02 , C08F290/02 , C08F290/10 , C08F214/22
摘要： The present invention pertains to a process for the manufacture of a grafted fluorinated polymer comprising at least one grafted side chain comprising one or more glycosidic recurring units [polymer (F)], said process comprising polymerizing: vinylidene fluoride (VDF), optionally, one or more other fluorinated monomers [monomers (F)], and optionally, one or more (meth)acrylic monomers [monomers (MA)], in the presence of at least one polysaccharide derivative [derivative (P)], said polysaccharide derivative having a dynamic viscosity of less than 15 mPa×s, as measured according to ASTM D445 at 20° C. in an aqueous solution at a concentration of 2% by weight, and by further providing novel polymers (F) as defined above.

36. 发明申请

US20090203830A1 Thermoplastic Fluoropolymer Composition 有权
标题翻译：热塑性氟聚合物组合物
公开(公告)号：US20090203830A1
公开(公告)日：2009-08-13
申请号：US11995428
申请日：2006-06-27
申请人： Julio A. Abusleme , Giulio Brinati , Pier Antonio Guarda
发明人： Julio A. Abusleme , Giulio Brinati , Pier Antonio Guarda
IPC分类号： C08L27/20 , C08L27/14 , C08L27/18
CPC分类号： C08L27/16 , C08L27/18 , C08L71/00 , C08L2205/02 , C08L2205/03 , C08L2666/02 , C08L2666/14
摘要： The invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic partially fluorinated fluoropolymer having a melt flow index (MFI) of less than 10 g/10 min. as measured according to ASTM D-1238 under a piston load of 5 kg polymer A; from 0.05 to 5% by weight of A at least one (per)fluoropolyether, polymer B; and from 0 to 10% by weight of A of at least one per(halo)fluoropolymer polymer C. The addition of a (per)fluoropolyether B and, optionally, of a per(halo) fluoropolymer C advantageously enables improvement of rheological behavior of thermoplastic partially fluorinated fluoropolymer A, making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency. Still objects of the inventions are the process for manufacturing said thermoplastic fluoropolymer composition and the articles thereof.
摘要翻译：本发明涉及一种热塑性含氟聚合物组合物，其包含：至少一种热塑性部分氟化含氟聚合物，其熔体流动指数（MFI）小于10g / 10min。根据ASTM D-1238在5kg聚合物A的活塞负载下测量; 0.05至5重量％的A至少一个（全）氟聚醚，聚合物B; 和0至10重量％的至少一个每（卤素）含氟聚合物C的A。加入（全）氟聚醚B和任选的全（卤）氟聚合物C有利地可以改善流变行为热塑性部分氟化氟聚合物A，使得在较不严格的条件下可能的处理并产生具有突出的表面方面和良好的均匀性和一致性的最终部件。本发明的另一个目的是制造所述热塑性含氟聚合物组合物及其制品的方法。

37. 发明申请

US20080161481A1 Thermoplastic Fluoropolymer Composition 有权
标题翻译：热塑性氟聚合物组合物
公开(公告)号：US20080161481A1
公开(公告)日：2008-07-03
申请号：US11912250
申请日：2006-04-25
申请人： Julio A. Abusleme , Claudia Manzoni , Giambattista Besana
发明人： Julio A. Abusleme , Claudia Manzoni , Giambattista Besana
IPC分类号： C08L27/12 , C08L27/16 , C08L27/18
CPC分类号： C08L27/12 , C08L27/16 , C08L27/18 , C08L2205/02 , C08L2666/04
摘要： The invention pertains to a multi-phase thermoplastic fluoropolymer composition, comprising a thermoplastic fluoropolymer and discrete domains of melt-processable perfluoropolymer, to the articles therefrom and to a process for manufacturing thermoplastic fluoropolymer compositions. The multi-phase thermoplastic fluoropolymer composition comprises: —at least one thermoplastic fluoropolymer (A); and —from 0.1 to 10% by weight of (A) of at least one melt-processible perfluoropolymer (B), and is characterized in that the polymer (B) is present in the composition in phase-separated domains in a continuous phase mainly comprising (A), at least 75% by volume of said domains having maximal dimension not exceeding 1 μm. The process of the invention comprises mixing: (i) a thermoplastic fluoropolymer (A); (ii) a melt-processible perfluoropolymer (B) under the form of particles having an average primary particle size not exceeding 300 nm; (iii) and optionally other additives or filling materials.
摘要翻译：本发明涉及一种多相热塑性含氟聚合物组合物，其包含热塑性氟聚合物和可熔融加工的全氟聚合物的离散区域，以及其制备方法以及制造热塑性含氟聚合物组合物的方法。多相热塑性含氟聚合物组合物包含： - 至少一种热塑性含氟聚合物（A）; 和（A）0.1至10重量％的至少一种可熔融加工的全氟聚合物（B），其特征在于聚合物（B）主要以连续相存在于相分离区域中的组合物中包含（A），至少75体积％的所述结构域的最大尺寸不超过1μm。本发明的方法包括混合：（i）热塑性含氟聚合物（A）; （ii）具有平均一次粒径不超过300nm的颗粒形式的可熔融加工的全氟聚合物（B）; （iii）和任选的其它添加剂或填充材料。

38. 发明授权

US06706351B2 Multilayer composition comprising fluoropolymers and hydrogenated polymers 有权
标题翻译：包含含氟聚合物和氢化聚合物的多层组合物
公开(公告)号：US06706351B2
公开(公告)日：2004-03-16
申请号：US09951580
申请日：2001-09-14
申请人： Julio A. Abusleme , Claudia Manzoni
发明人： Julio A. Abusleme , Claudia Manzoni
IPC分类号： B32B108
CPC分类号： B32B27/28 , B32B1/08 , F16L2011/047 , Y10T428/1393 , Y10T428/31504 , Y10T428/31507 , Y10T428/31511 , Y10T428/3154 , Y10T428/31551 , Y10T428/31721 , Y10T428/31786 , Y10T428/31855 , Y10T428/31931 , Y10T428/31935 , Y10T428/31938 , Y10T428/31971
摘要： A multilayer composition comprising: A) a first layer based on copolymers of ethylene (E) with tetrafluoroethylene (TFE) and/or chorotrifluoroethylene (CTFE); B) a second intermediate layer comprising thermoprocessable copolymers of ethylene (E) with tetrafluoroethylene (TFE) and/or chorotrifluoroethylene (CTFE) modified with acrylic monomers; C) a third layer based on hydrogenated polymers; said multilayer composition containing in layer B) and/or in layer C) one or more crosslinking agents.
摘要翻译：一种多层组合物，包括：A）基于乙烯（E）与四氟乙烯（TFE）和/或三氟氯乙烯（CTFE）的共聚物的第一层; B）包含乙烯（E）与四氟乙烯（TFE）的热可加工共聚物的第二中间层，和/或丙烯酸单体改性的三氟乙烯（CTFE）; C）基于氢化聚合物的第三层; 所述多层组合物含有层B）和/或层C）一种或多种交联剂。

39. 发明授权

US06673866B2 Thermoplastic compositions of fluoropolymers 失效
标题翻译：含氟聚合物的热塑性组合物
公开(公告)号：US06673866B2
公开(公告)日：2004-01-06
申请号：US09962353
申请日：2001-09-26
申请人： Mikhail Zolotnitsky , Julio A. Abusleme
发明人： Mikhail Zolotnitsky , Julio A. Abusleme
IPC分类号： C08F2712
CPC分类号： C08L27/12 , C08K3/016 , C08K5/0016 , C08L2205/02 , C08L2666/04
摘要： A polymer composition formed by: I) fluoropolymers selected from one or more of the following: copolymers based on ethylene, TFE and/or CTFE modified with hydrogenated monomers, or blends of these fluoropolymers with PCTFE; said fluoropolymers and/or the corresponding blends optionally mixed with hydrogenated plasticizers; II) one or more inorganic fire-retardants, treated and not with dispersing agents; III) one or more crosslinking agents; IV) optional additives.
摘要翻译：通过以下方法形成的聚合物组合物：I）选自以下一种或多种的含氟聚合物：基于乙烯的共聚物，用氢化单体改性的TFE和/或CTFE，或这些含氟聚合物与PCTFE的共混物; 所述含氟聚合物和/或相应的共混物任选地与氢化增塑剂混合; II）一种或多种无机阻燃剂，经处理而不与分散剂混合; III）一种或多种交联剂; IV）任选的添加剂。

40. 发明授权

US06566442B2 Thermoplastic fluorinated polymers 失效
公开(公告)号：US06566442B2
公开(公告)日：2003-05-20
申请号：US10151954
申请日：2002-05-22
申请人： Julio A. Abusleme , Claudia Manzoni
发明人： Julio A. Abusleme , Claudia Manzoni
IPC分类号： C08F2712
CPC分类号： C08L27/12 , C08L2205/02 , C08L2666/04
摘要： A composition comprising a polymer mixture A of polymers formed by: (a) from 10 to 70% by moles of ethylene (E), (b) from 30 to 90%, by moles of a fluorinated monomer selected from tetrafluoroethylene (TFE), chlorotrifluoroethylene (CTFE), or mixtures thereof, (c) from 0.1 to 30% by moles, with respect to the total amount of monomers (a) and (b), of one or more acrylic monomers; characterized in that the polymer mixture A comprises polymer fractions having a different content of the acrylic comonomer such that the elastic modulus at 23° C. (ASTM D1708) of said polymer mixture A is lower than at least 10% of the elastic modulus of a polymer formed by monomers a), b) and c) wherein the polymer fractions have substantially an equal content of the acrylic comonomer.

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