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31. 发明授权

US5892076A Allyl containing metal complexes and olefin polymerization process 失效
标题翻译：含烯丙基的金属络合物和烯烃聚合方法
公开(公告)号：US5892076A
公开(公告)日：1999-04-06
申请号：US815913
申请日：1997-03-11
申请人： Peter N. Nickias
发明人： Peter N. Nickias
IPC分类号： C07F17/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/659 , C08F10/00 , C07F7/00 , C07F7/28
CPC分类号： C08F10/00 , C07F17/00 , C08F4/619 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65912 , Y10S526/943
摘要： Metal complexes useful as olefin polymerization catalysts corresponding to the formula: ##STR1## or a dimer, solvated adduct, chelated derivative or mixture thereof, wherein:Q is a cyclic group or Y*, that is bound to M by means of a delocalized .pi.-bond, said group containing up to 50 nonhydrogen atoms;M is a metal of Group 3, 4 or the Lanthanide series of the Periodic Table of the Elements;Z is a covalently bound, divalent substituent of up to 50 non-hydrogen atoms having the formula, --(ER.sub.2).sub.m --, wherein E independently each occurrence is carbon, silicon or germanium, R independently each occurrence is selected from the group consisting of hydrocarbyl, hydrocarbyloxy, silyl, and germyl of up to 20 atoms other than hydrogen, and m is an integer from 1 to 3;Y* is an allyl or a hydrocarbyl-, silyl- or germyl-substituted allyl group containing up to 20 nonhydrogen atoms bonded to Z and bonded via an .eta..sup.3 -.pi. bond to M;L is a neutral confugated diene ligand having up to 20 non-hydrogen atoms;X" independently each occurrence is a monovalent, anionic moiety selected from hydride, halo, hydrocarbyl, silyl, germyl, hydrocarbyloxy, amide, siloxy, halohydrocarbyl, halosilyl, silylhydrocarbyl, and aminohydrocarbyl having up to 20 non-hydrogen atoms, or two X" groups together form a divalent hydrocarbadiyl group;n is a number from 0 to 3; andp is an inteaer from 0 to 2.
摘要翻译：可用作对应于下式的烯烃聚合催化剂的金属络合物：或其二聚物，溶剂化加合物，螯合衍生物或其混合物，其中：Q是环状基团或Y *，其通过离域pI 所述基团含有多达50个非氢原子; M是元素周期表第3,4族金属或镧系元素; Z是具有式 - （ER 2）m - 的多达50个非氢原子的共价结合的二价取代基，其中E独立地每次出现为碳，硅或锗，R各自独立地选自烃基，烃氧基，甲硅烷基和除氢以外的至多20个原子的甲锗烷基，m是1至3的整数; Y *是含有至多20个非氢原子的烯丙基或烃基 - 甲硅烷基或甲锗烷基取代的烯丙基，其与Z键合并通过η3键连接至M; L是具有至多20个非氢原子的中性配位二烯配体; X“独立地是选自氢化物，卤素，烃基，甲硅烷基，甲硅烷基，烃氧基，酰胺，甲硅烷氧基，卤代烃基，卤代甲硅烷基，甲硅烷基烃基和具有至多20个非氢原子的氨基烃基的一价阴离子部分，或两个X 一起形成二价烃基; n是从0到3的数字; 并且p是从0到2的内部。

32. 发明授权

US5854362A Supported biscyclopentadienyl metal complexes 失效
标题翻译：负载双环戊二烯基金属配合物
公开(公告)号：US5854362A
公开(公告)日：1998-12-29
申请号：US570261
申请日：1995-12-11
申请人： Peter N. Nickias , Lee Spencer
发明人： Peter N. Nickias , Lee Spencer
IPC分类号： C07F17/00 , C08F4/645 , C08F4/659 , C08F10/00 , C08F210/16
CPC分类号： C07F17/00 , C08F10/00 , C08F210/16 , C08F4/65908 , C08F4/65916 , Y10S526/943
摘要： Metal complexes corresponding to the formula: ##STR1## wherein: L independently each occurrence is a delocalized, .pi.-bonded group that is bound to M, containing up to 50 nonhydrogen atoms; M is a metal of Group 3, 4 or the Lanthanide series of the Periodic Table of the Elements; Z is a covalently bound, divalent substituent of up to 50 non-hydrogen atoms having the formula, --(ER.sub.2).sub.m --, wherein E independently each occurrence is carbon, silicon or germanium, R independently each occurrence is selected from the group consisting of C.sub.1-20 hydrocarbyl, and C.sub.1-20 hydrocarbyloxy, with the proviso that in at least one occurrence R is C.sub.1-20 hydrocarbyloxy, and m is an integer from 1 to 3; X' is a neutral Lewis base ligand having up to 20 non-hydrogen atoms; X" independently each occurrence is a monovalent, anionic moiety selected from hydride, halo, hydrocarbyl, silyl, germyl, hydrocarbyloxy, amide, siloxy, halohydrocarbyl, halosilyl, silylhydrocarbyl, and aminohydrocarbyl having up to 20 non-hydrogen atoms, or two X" groups together form a divalent hydrocarbadiyl or neutral hydrocarbon group; n is a number from 0 to 3; and p is an integer from 0 to 2.
摘要翻译：对应于下式的金属络合物：其中：L独立地每次发生是与Mg结合的离域的π键合基团，其含有至多50个非氢原子; M是元素周期表第3,4族金属或镧系元素; Z是具有式 - （ER 2）m - 的多达50个非氢原子的共价结合的二价取代基，其中E独立地每次出现为碳，硅或锗，R各自独立地选自 C 1-20烃基和C 1-20烃氧基，条件是在至少一个出现中R是C 1-20烃氧基，m是1至3的整数; X'是具有至多20个非氢原子的中性路易斯碱配体; X“独立地是选自氢化物，卤素，烃基，甲硅烷基，甲硅烷基，烃氧基，酰胺，甲硅烷氧基，卤代烃基，卤代甲硅烷基，甲硅烷基烃基和具有至多20个非氢原子的氨基烃基的一价阴离子部分，或两个X “一起形成二价烃基或中性烃基; n是从0到3的数字; p为0〜2的整数。

33. 发明授权

US5688880A Readily supportable metal complexes 失效
标题翻译：易于支持的金属配合物
公开(公告)号：US5688880A
公开(公告)日：1997-11-18
申请号：US570262
申请日：1995-12-11
申请人： Lee Spencer , Peter N. Nickias
发明人： Lee Spencer , Peter N. Nickias
IPC分类号： C07F17/00 , C08F4/619 , C08F4/6192 , C08F4/643 , C08F10/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/61908 , C08F4/61916 , C08F4/6192 , Y10S526/943
摘要： Metal complexes useful as olefin polymerization catalysts corresponding to the formula: ##STR1## wherein: L is a delocalized, .pi.-bonded group that is bound to M, containing up to 50 nonhydrogen atoms; M is a metal of Group 3, 4 or the Lanthanide series of the Periodic Table of the Elements; Z is a covalently bound, divalent substituent of up to 50 non-hydrogen atoms having the formula, --(ER.sub.2).sub.m --, wherein E independently each occurrence is carbon, silicon or germanium, R independently each occurrence is selected from the group consisting of C.sub.1-20 hydrocarbyl, and C.sub.1-20 hydrocarbyloxy, with the proviso that in at least one occurrence R is C.sub.1-20 hydrocarbyloxy, and m is an integer from 1 to 3; Y is a divalent ligand group comprising nitrogen, phosphorus, oxygen or sulfur, said Y containing up to 20 nonhydrogen atoms; X' is a neutral Lewis base ligand having up to 20 non-hydrogen atoms; X" independently each occurrence is a monovalent, anionic moiety selected from hydride, halo, hydrocarbyl, silyl, germyl, hydrocarbyloxy, amide, siloxy, halohydrocarbyl, halosilyl, silylhydrocarbyl, and aminohydrocarbyl having up to 20 non-hydrogen atoms, or two X" groups together form a divalent hydrocarbadiyl group; n is a number from 0 to 3; and p is an integer from 0 to 2.
摘要翻译：可用作对应于下式的烯烃聚合催化剂的金属络合物：其中：L是与M结合的离域的π键合基，其含有至多50个非氢原子; M是元素周期表第3,4族金属或镧系元素; Z是具有式 - （ER 2）m - 的多达50个非氢原子的共价结合的二价取代基，其中E独立地每次出现为碳，硅或锗，R各自独立地选自 C 1-20烃基和C 1-20烃氧基，条件是在至少一个出现中R是C 1-20烃氧基，m是1至3的整数; Y是包含氮，磷，氧或硫的二价配体基团，所述Y含有至多20个非氢原子; X'是具有至多20个非氢原子的中性路易斯碱配体; X“独立地是选自氢化物，卤素，烃基，甲硅烷基，甲硅烷基，烃氧基，酰胺，甲硅烷氧基，卤代烃基，卤代甲硅烷基，甲硅烷基烃基和具有至多20个非氢原子的氨基烃基的一价阴离子部分，或两个X 一起形成二价烃基; n是从0到3的数字; p为0〜2的整数。

34. 发明授权

US5347024A Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation 失效
标题翻译：通过路易斯酸制备加成聚合催化剂减轻金属中心氧化
公开(公告)号：US5347024A
公开(公告)日：1994-09-13
申请号：US34434
申请日：1993-03-19
申请人： Peter N. Nickias , David D. Devore , Francis J. Timmers , Robert K. Rosen , Robert D. Mussell
发明人： Peter N. Nickias , David D. Devore , Francis J. Timmers , Robert K. Rosen , Robert D. Mussell
IPC分类号： C08F4/64 , C07F5/02 , C07F7/10 , C07F9/50 , C07F17/00 , C08F4/60 , C08F4/659 , C08F4/6592 , C08F4/74 , C08F10/00 , C07C7/00
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/6592
摘要： Addition polymerization catalysts comprising a derivative of a titanium or zirconium in the +4 oxidation state prepared by metal center oxidation and cation complex formation of a reduced metal precursor complex via electron transfer in a single step by use of a neutral organic oxidant, optionally in the presence of a Lewis acid mitigator.
摘要翻译：包含通过金属中心氧化制备的+4氧化态的钛或锆的衍生物的加成聚合催化剂，并且通过使用中性有机氧化剂在一个步骤中通过电子转移阳离子络合物形成还原金属前体复合物，任选地在存在路易斯酸缓释剂。

35. 发明申请

US20130133515A1 Separation of Acidic Constituents by Self Assembling Polymer Membranes 审中-公开
标题翻译：通过自组装聚合物膜分离酸性成分
公开(公告)号：US20130133515A1
公开(公告)日：2013-05-30
申请号：US13577582
申请日：2011-02-11
申请人： Scott T. Matteucci , Leonardo C. Lopez , Shawn D. Feist , Peter N. Nickias , William J. Harris
发明人： Scott T. Matteucci , Leonardo C. Lopez , Shawn D. Feist , Peter N. Nickias , William J. Harris
IPC分类号： B01D71/48 , B01D71/56 , B01D71/54 , B01D53/22 , B01D71/52
CPC分类号： B01D71/48 , B01D53/228 , B01D71/52 , B01D71/54 , B01D71/56 , B01D71/80
摘要： A method of removing an acidic gas from a gas stream by contacting said gas stream with a polymer, wherein the polymer is a macromolecularly self assembling polymeric material, the method including the steps of contacting the gas mixture with the membrane; and extracting the acidic gas from the gas stream.
摘要翻译：一种通过使所述气流与聚合物接触而从气流中除去酸性气体的方法，其中所述聚合物是大分子自组装聚合物材料，所述方法包括使气体混合物与膜接触的步骤; 并从气流中提取酸性气体。

36. 发明授权

US6087293A Supported catalyst containing tethered cation forming activator 失效
标题翻译：负载催化剂含有束缚阳离子形成活化剂
公开(公告)号：US6087293A
公开(公告)日：2000-07-11
申请号：US117470
申请日：1998-03-02
申请人： Edmund M. Carnahan , Michael J. Carney , David R. Neithamer , Peter N. Nickias , Keng-Yu Shih , Lee Spencer
发明人： Edmund M. Carnahan , Michael J. Carney , David R. Neithamer , Peter N. Nickias , Keng-Yu Shih , Lee Spencer
IPC分类号： C08F4/02 , C08F4/603 , C08F4/619 , C08F4/6192 , C08F4/643 , C08F4/645 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , B01J31/00 , C08F4/06 , C08F4/44
CPC分类号： C08F10/00 , C08F10/02 , C08F4/025 , C08F110/02 , C08F210/16 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/65912 , C08F4/6592 , C08F4/65925 , Y10S526/943
摘要： A support for use in preparing supported catalysts for addition polymerizations comprising the reaction product of: (A) an inorganic oxide material comprising reactive surface hydroxyl groups, at least some of said hydroxyl groups optionally having been functionalized an converted to a reactive silano moiety corresponding to the formula: --OSiR.sub.2 H, wherein R, independently each occurrence, is hydrogen C.sub.1-20 hydrocarbyl, or C.sub.1-20 hydrocarbyloxy, said inorganic oxide or functionalized derivative thereof comprising less than 1.0 mmol of reactive surface hydroxyl functionality per gram, and (B) an activator compound comprising: b.sub.1) a cation which is capable of reacting with a transition metal compound to form a catalytically active transition metal complex, and b.sub.2) a compatible anion containing at least one substituent able to react with the inorgnaic oxide, with residual hydroxyl functionality of the inorganic oxide, or with the reactive silane moiety, hereby covalently bonding the compatible anion to the support, catalysts formed therefrom, process of manufacture and the method to use.
摘要翻译： PCT No.PCT / US96 / 17140 Sec。 371日期1998年3月2日 102（e）1998年3月2日PCT PCT 1996年10月25日PCT公布。公开号WO97 / 19959 日期1997年6月5日，用于制备用于加成聚合的载体催化剂的载体，其包括以下反应产物：（A）包含反应性表面羟基的无机氧化物材料，至少一些所述羟基任选已被官能化转化为对应于式-OSiR 2 H的反应性硅烷基部分，其中R各自独立地为氢C 1-20烃基或C 1-20烃氧基，所述无机氧化物或其官能化衍生物包含小于1.0mmol反应性表面羟基官能度/克和（B）活化剂化合物，其包含：b1）能够与过渡金属化合物反应形成催化活性过渡金属络合物的阳离子，和b2）含有至少一个能够与无规性反应的取代基的相容阴离子氧化物，具有无机氧化物的残余羟基官能团，或与反应性硅烷部分共价共轭将相容的阴离子与载体，由其形成的催化剂，制备方法和使用方法相结合。

37. 发明授权

US5541349A Metal complexes containing partially delocalized II-bound groups and addition polymerization catalysts therefrom 失效
标题翻译：含有部分离域II结合基团的金属络合物及其加成聚合催化剂
公开(公告)号：US5541349A
公开(公告)日：1996-07-30
申请号：US304301
申请日：1994-09-12
申请人： David R. Wilson , David R. Neithamer , Peter N. Nickias , W. Jack Kruper, Jr.
发明人： David R. Wilson , David R. Neithamer , Peter N. Nickias , W. Jack Kruper, Jr.
IPC分类号： C07F7/00 , C07F7/28 , C07F17/00 , C08F4/642 , C08F4/659 , C08F10/00 , C07F5/02 , C07F7/10
CPC分类号： C07F17/00 , C07F7/00 , C07F7/28 , C08F10/00 , C08F4/659 , C08F4/65908 , C08F4/65912
摘要： Novel Group 4 metal complexes wherein the metal is in the +2 or +4 formal oxidation state containing a cyclic or noncyclic, non-aromatic, anionic, dienyl ligand group bound to M and having a bridged ligand structure, catalytic derivatives of such complexes including novel zwitterionic complexes; and the use thereof as catalysts for polymerizing addition polymerizable monomers are disclosed.
摘要翻译：新型4族金属络合物，其中金属为+2或+4形式氧化态，其含有与M结合并具有桥连配体结构的环状或非环状，非芳族，阴离子，二烯基配体基团，所述络合物的催化衍生物包括新型两性离子复合物; 并且公开了其作为用于聚合加成聚合单体的催化剂的用途。

38. 发明授权

US5536797A Syndiotactic prochiral olefin polymerization process 失效
标题翻译：间规前置手性烯烃聚合方法
公开(公告)号：US5536797A
公开(公告)日：1996-07-16
申请号：US316748
申请日：1994-10-03
申请人： Peter N. Nickias , Karen K. Borodychuk , Thomas H. Newman
发明人： Peter N. Nickias , Karen K. Borodychuk , Thomas H. Newman
IPC分类号： C08F4/642 , C07F17/00 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/14 , C08F12/00 , C08F12/04 , C08F36/00 , C08F36/20
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6592
摘要： Octahydrofluorenyltitanium metal complexes or ring substituted octahydrofluorenyltitanium metal complexes wherein the metal is in the +2, +3 or +4 formal oxidation state and activating cocatalysts or activating techniques are used to produce catalysts useful for polymerizing prochiral olefins to form highly syndiotactic polymers.
摘要翻译：八氢芴基钛金属络合物或环取代的八氢芴基钛金属络合物，其中金属为+2，+3或+4形式氧化态，活化助催化剂或活化技术用于制备可用于聚合前手性烯烃形成高度间同立构聚合物的催化剂。

39. 发明授权

US5495036A Metal (III) complexes containing conjugated, non-aromatic anionic II-bound groups and addition polymerization catalysts therefrom 失效
标题翻译：含有共轭非芳族阴离子II键合基团的金属（III）配合物及其加成聚合催化剂
公开(公告)号：US5495036A
公开(公告)日：1996-02-27
申请号：US304315
申请日：1994-09-12
申请人： David R. Wilson , David R. Neithamer , Peter N. Nickias , W. Jack Kruper, Jr.
发明人： David R. Wilson , David R. Neithamer , Peter N. Nickias , W. Jack Kruper, Jr.
IPC分类号： C07F5/00 , C07F7/00 , C07F13/00 , C07F17/00 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C07F7/28
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/6592
摘要： Novel Group 4, Group 3 or Lanthanide metal complexes wherein the metal is in the +3 formal oxidation state containing a cyclic or non-cyclic, nonaromatic, anionic, dienyl ligand group bound to M and having a bridged ligand structure, catalytic derivatives of such complexes; and the use thereof as catalysts for polymerizing addition polymerizable monomers are disclosed.
摘要翻译：新型第4族，第3族或镧系元素金属络合物，其中金属为+3形式氧化态，其含有与M结合并具有桥连配体结构的环状或非环状，非芳族，阴离子，二烯基配体基团，复合物并且公开了其作为用于聚合加成聚合单体的催化剂的用途。

40. 发明申请

US20120116121A1 PROCESS FOR THE SULFOCHLORINATION OF HYDROCARBONS 审中-公开
标题翻译：烃类化合物的过程
公开(公告)号：US20120116121A1
公开(公告)日：2012-05-10
申请号：US13320773
申请日：2010-07-28
申请人： Kurt F. Hirsekorn , William Tenn , Peter N. Nickias
发明人： Kurt F. Hirsekorn , William Tenn , Peter N. Nickias
IPC分类号： C07C303/10
CPC分类号： C07C303/10 , C07C309/80
摘要： Produce a sulfo-chlorinated hydrocarbon using liquid sulfur dioxide, a chlorinating agent such as chlorine or sulfuryl chloride, and a metal complex catalyst, the catalyst being represented as LnM where L is at least one of an amine, phosphine, chloride or oxide, n is an integer within a range of from 1 to 6, and M is a metal selected from a group consisting of copper (Cu), ruthenium (Ru), iron (Fe), chromium (Cr), lanthanum (La), nickel (Ni), palladium (Pd), rhodium (Rh), rhenium (Re), molybdenum (Mo) and manganese (Mn).
摘要翻译：使用液体二氧化硫，氯化剂或磺酰氯等氯化剂和金属络合物催化剂生产磺基氯化烃，催化剂表示为LnM，其中L是胺，膦，氯化物或氧化物中的至少一种，n 为1〜6的整数，M为选自铜（Cu），钌（Ru），铁（Fe），铬（Cr），镧（La），镍（ Ni），钯（Pd），铑（Rh），铼（Re），钼（Mo）和锰（Mn）。

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