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31. 发明授权

US07022884B2 Preparation of polyetherpolyols in the presence of a multimetal cyanide complex catalyst 失效
标题翻译：在多金属氰化物配合物催化剂存在下制备聚醚多元醇
公开(公告)号：US07022884B2
公开(公告)日：2006-04-04
申请号：US10203836
申请日：2001-02-16
申请人： Thomas Ostrowski , Kathrin Harre , Georg Heinrich Grosch , Jürgen Winkler
发明人： Thomas Ostrowski , Kathrin Harre , Georg Heinrich Grosch , Jürgen Winkler
IPC分类号： C07C41/03
CPC分类号： B01J27/26 , B01J19/18 , B01J2219/00085 , B01J2219/00092 , B01J2219/00094 , C08G65/2663 , C08G65/2696
摘要： Polyetherpolyols are prepared by reacting diols or polyols with ethylene oxide, propylene oxide, butylene oxide or a mixture thereof in the presence of a multimetal cyanide complex catalyst by a process which is carried out in a vertical, highly cylindrical reactor having a central stirrer and having heat exchanger plates through which a heat-exchange medium flows and which are arranged essentially in the longitudinal direction of the reactor, at an angle α of from 0 to 70° in the direction of rotation of the stirrer relative to the reactor radius.
摘要翻译：聚醚多元醇通过二醇或多元醇与环氧乙烷，环氧丁烷，环氧丁烷或其混合物在多金属氰化物配合物催化剂存在下反应来制备，所述方法是在具有中心搅拌器的垂直，高度圆柱形的反应器中进行，并且具有热交换介质流过热交换介质，其基本上沿反应器的纵向布置，在搅拌器相对于反应器半径的旋转方向上以0至70°的角度α。

32. 发明授权

US06906110B1 Method for the production of polyurethanes 有权
标题翻译：生产聚氨酯的方法
公开(公告)号：US06906110B1
公开(公告)日：2005-06-14
申请号：US10019998
申请日：2000-11-04
申请人： Reinhard Lorenz , Stephan Bauer , Dieter Junge , Eva Baum , Kathrin Harre , Jörg Erbes , Thomas Ostrowski , Georg Heinrich Grosch
发明人： Reinhard Lorenz , Stephan Bauer , Dieter Junge , Eva Baum , Kathrin Harre , Jörg Erbes , Thomas Ostrowski , Georg Heinrich Grosch
IPC分类号： C08G18/22 , C08G18/48 , C08G65/26 , C08K3/10 , C08K3/16 , C08K3/24 , C08K3/26 , C08K5/09
CPC分类号： C08G18/4866 , C08G18/225 , C08G65/2663 , C08G2101/0008 , C08G2101/0083
摘要： In a process for producing polyurethanes by reacting at least one polyisocyanate with at least one compound containing at least two hydrogen atoms which are reactive toward isocyanate groups, the compound having at least two active hydrogen atoms which is used is at least one polyether alcohol prepared by addition of alkylene oxides onto H-functional initiator substances by means of multimetal cyanide catalysis and the reaction is carried out in the presence of at least one metal salt.
摘要翻译：在通过使至少一种多异氰酸酯与至少一种含有至少两个对异氰酸酯基团具有反应性的氢原子的化合物反应来生产聚氨酯的方法中，使用至少两个活性氢原子的化合物是至少一种由通过多金属氰化物催化将氧化烯加成到H-官能引发剂物质上，并且反应在至少一种金属盐的存在下进行。

33. 发明授权

US06673972B2 Method for producing polyetherpolyols in the presence of a multi-metal cyanide complex catalyst 失效
标题翻译：在多金属氰化物配合物催化剂存在下制备聚醚多元醇的方法
公开(公告)号：US06673972B2
公开(公告)日：2004-01-06
申请号：US10169683
申请日：2002-07-05
申请人： Thomas Ostrowski , Kathrin Harre , Peter Zehner , Jörn Müller , Dieter Stützer , Georg Heinrich Grosch , Jürgen Winkler , Stephan Bauer
发明人： Thomas Ostrowski , Kathrin Harre , Peter Zehner , Jörn Müller , Dieter Stützer , Georg Heinrich Grosch , Jürgen Winkler , Stephan Bauer
IPC分类号： C07C4311
CPC分类号： C08G65/2696 , B01J27/26 , C08G65/2663
摘要： Polyetherpolyols are prepared by reacting diols or polyols with ethylene oxide, propylene oxide, butylene oxide or a mixture thereof in the presence of a multimetal cyanide complex catalyst by a process which is carried out in a vertical upright cylindrical reactor comprising a jet nozzle which is arranged in the upper reactor region and is directed downward and via which the starting materials and the reaction mixture are fed in, and comprising a take-off, preferably in the lower reactor region, via which the reaction mixture is fed back to the jet nozzle in an external circulation by means of a pump via an equilibration container, comprising a concentric guide tube which extends over the total length of the reactor, except for the reactor ends, and comprising a heat exchanger integrated in the annular space.
摘要翻译：聚醚多元醇通过二元醇或多元醇与环氧乙烷，环氧丙烷，环氧丁烷或其混合物在多金属氰化物配合物催化剂存在下反应来制备，该方法是在包括喷嘴的立式圆柱形反应器中进行的方法，在上反应器区域中并且向下引导起始材料和反应混合物，并且优选在较低的反应器区域中包含起飞物料，反应混合物经反应器区域被反馈到喷嘴中通过平衡容器通过泵的外部循环，包括在反应器的整个长度上延伸的同心引导管，除了反应器端部，并且包括集成在环形空间中的热交换器。

34. 发明授权

US06613714B2 Multimetal cyanide compounds, their preparation and their use 失效
标题翻译：多金属氰化合物，其制备及其用途
公开(公告)号：US06613714B2
公开(公告)日：2003-09-02
申请号：US09324145
申请日：1999-06-02
申请人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge
发明人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge
IPC分类号： B01J2726
CPC分类号： C08G65/2663 , B01J27/26 , B01J35/023
摘要： In multimetal cyanide complexes, more than 30% by weight of the primary particles have a platelet-like habit, i.e. the length and width of the primary particles is at least three times the thickness of the particles.
摘要翻译：在多金属氰化物络合物中，超过30重量％的初级颗粒具有血小板样习惯，即一次颗粒的长度和宽度至少为颗粒厚度的三倍。

35. 发明授权

US06551546B1 Method for producing a shaped body using a metal oxide sol 有权
标题翻译：使用金属氧化物溶胶制造成形体的方法
公开(公告)号：US06551546B1
公开(公告)日：2003-04-22
申请号：US09646902
申请日：2000-10-10
申请人： Georg Heinrich Grosch , Ulrich Müller , Michael Hesse , Christian Lockemann
发明人： Georg Heinrich Grosch , Ulrich Müller , Michael Hesse , Christian Lockemann
IPC分类号： B28B100
CPC分类号： C04B14/047 , B01J29/04 , B01J29/06 , B01J29/89 , B01J37/0009 , B01J37/0018 , B01J37/0045 , B01J37/033 , B01J2229/42 , C04B28/00 , C04B28/24 , C04B38/08 , C07D301/12 , C04B24/32 , C04B38/0051 , C04B40/0071 , C04B14/066
摘要： A process for producing a shaped body comprising at least one porous oxidic material and at least one metal oxide comprises the following step (i): (i) mixing the porous oxidic material or materials with at least one metal oxide sol which has a low content of alkali metal and alkaline earth metal ions and/or at least one metal oxide which has a low content of alkali metal and alkaline earth metal ions.
摘要翻译：一种生产包含至少一种多孔氧化物材料和至少一种金属氧化物的成形体的方法包括以下步骤（i）：（i）将多孔氧化物材料与至少一种具有低含量的金属氧化物溶胶混合的碱金属和碱土金属离子和/或至少一种具有低碱金属和碱土金属离子含量的金属氧化物。

36. 发明授权

US06548714B1 Method for producing polyetherols by ring-opening polymerisation of alkylene oxides 失效
标题翻译：通过环氧烷开环聚合生产聚醚的方法
公开(公告)号：US06548714B1
公开(公告)日：2003-04-15
申请号：US09744512
申请日：2001-01-24
申请人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Kathrin Harre
发明人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Kathrin Harre
IPC分类号： C07C4100
CPC分类号： B01J23/007 , B01J27/232 , B01J27/236 , B01J27/26 , C08G65/2642 , C08G65/2657 , C08G65/2663 , C08G65/269
摘要： A process for preparing polyetherols by ring-opening polymerization of alkylene oxides onto H-functional initiator molecules comprises at least one process step a) in which a compound of the formula (I) M′aM″b(OH)cOd* Ae*Lf (I), is applied to a solid inert support or incorporated in the latter or molded to form a shaped body is used as catalyst, and at least one process step b) in which a multimetal cyanide compound of the formula (II) M1a[M2(CN)b(A)c]d·fM1gXn·h(H20) eL (II) is applied to a solid, inert support or incorporated in the latter or molded to form a shaped body or in powder or paste form is used as catalyst.
摘要翻译：通过环氧烷烃在H-官能引发剂分子上的开环聚合制备聚醚的方法包括至少一种方法步骤a），其中将式（I）化合物施用于固体惰性载体或并入其中用于形成成形体的成型体用作催化剂，以及至少一种方法步骤b），其中将式（II）的多金属氰化物化合物施加到固体惰性载体上或并入其中，或者模制成形成身体或以粉末或糊状形式用作催化剂。

37. 发明授权

US06491861B1 Process for production of a zeolite-containing molding 有权
标题翻译：含沸石成型体的制造方法
公开(公告)号：US06491861B1
公开(公告)日：2002-12-10
申请号：US09424857
申请日：1999-12-06
申请人： Georg Heinrich Grosch , Ulrich Müller , Andreas Walch , Norbert Rieber , Wolfgang Harder
发明人： Georg Heinrich Grosch , Ulrich Müller , Andreas Walch , Norbert Rieber , Wolfgang Harder
IPC分类号： B28B320
CPC分类号： B01J37/0018 , B01J29/04 , B01J29/89 , C04B38/08 , C04B2111/00129 , C07D301/12 , C04B35/01 , C04B38/0051 , C04B35/16 , C04B35/6325 , C04B2103/0093
摘要： A process for the production of a molding containing at least one zeolite, wherein the at least one zeolite contains a titanium-, zirconium-, chromium-, niobium-, iron- or vanadium-containing zeolite: (I) adding a mixture consisting of at least one alcohol selected from the group consisting of methanol, ethanol, propanol or butanol, and water to a mixture containing said zeolite or a mixture of two or more thereof, and (II) kneading, molding, drying and calcining the mixture from (I); wherein the molding is useful as a catalyst, particularly in epoxidation reactions.
摘要翻译：一种制备含有至少一种沸石的模塑方法，其中所述至少一种沸石含有含钛，锆，铬，铌，铁或钒的沸石：（I）加入由将选自甲醇，乙醇，丙醇或丁醇的至少一种醇和水混合到含有所述沸石或其两种或更多种的混合物的混合物中，和（II）将混合物从（ I）;其中模制物可用作催化剂，特别是在环氧化反应中。

38. 发明授权

US06436867B1 One-step synthesis of double metal cyanides 失效
标题翻译：双金属氰化物的一步合成
公开(公告)号：US06436867B1
公开(公告)日：2002-08-20
申请号：US09629692
申请日：2000-08-01
申请人： Edward Michael Dexheimer , Georg Heinrich Grosch
发明人： Edward Michael Dexheimer , Georg Heinrich Grosch
IPC分类号： B01J2726
CPC分类号： B01J27/26 , C08G65/2663
摘要： An improved method for synthesizing a double metal cyanide (DMC) catalyst is disclosed. The method combines an aqueous solution of a first metal salt, such as ZnCl2, with an aqueous solution of a second metal salt, such as CoCl2, and with an aqueous solution of an alkali metal cyanide, such as KCN, in a single step to synthesize the DMC catalyst, Zn3[Co(CN)6]2.
摘要翻译：公开了一种合成双金属氰化物（DMC）催化剂的改进方法。该方法将第一金属盐如ZnCl 2的水溶液与第二金属盐如CoCl 2的水溶液和碱金属氰化物如KCN的水溶液在一个步骤中结合，合成DMC催化剂，Zn3 [Co（CN）6] 2。

39. 发明授权

US06303833B1 Multi-metal cyanide complexes as catalysts and their use in preparing polyetherpolyols 有权
标题翻译：多金属氰化物络合物作为催化剂及其在制备聚醚多元醇中的应用
公开(公告)号：US06303833B1
公开(公告)日：2001-10-16
申请号：US09509515
申请日：2000-03-29
申请人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Eugen Gehrer , Ulrich Treuling
发明人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Eugen Gehrer , Ulrich Treuling
IPC分类号： C07C4311
CPC分类号： B01J27/26 , C08G65/2663
摘要： A crystalline multimetal cyanide complex of the formula (I) M1a[M2(CN)bL1c]d*e(M1fXg)*hL2′iH2O (I) where M1 is at least one element from the group consisting of Zn(II), Fe(II), Co(III), Ni(II), Mn(II), Co(II), Sn(II). Pb(II), Fe(III), Mo(IV), Mo(VI), Al(III), V(IV), V(V), Sr(II, W(IV), W(VI), Cu(II), and Cr(III), M2 is at least one element from the group consisting of Fe(II), Fe(III), Co(III), Cr(III), Mn(II), Mn(III), Ir(III), Rh(III), Ru(II), V(IV), V(V), Co(II) and Cr(II), L1 is at least one ligand from the group consisting of cyanide, carbonyl, cyanate, isocyanate, nitrile, thiocyanate and nitrosyl, X is a formate anion, an acetate anion or propionate anion, L2 is at least one water-miscible ligand from the group consisting of alcohols, aldehydes, ketones, ethers, polyethers, esters, urea derivatives, amides, nitriles and sulfides, a, b, c, d, e, f, g, h, i are integers, with a, b, c and d being chosen so that the electrical neutrality condition is satisfied, and f and g being chosen so that the electrical neutrality condition is satisfied, the X-ray diffiactogram of which shows reflections at particular d values, can be employed as catalyst.
摘要翻译：式（I）的结晶多金属氰化物络合物，其中M 1是由Zn（II），Fe（II），Co（III），Ni（II），Mn（II），Co（II）组成的组中的至少一种元素），Sn（II）。 Pb（II），Fe（III），Mo（IV），Mo（VI），Al（III），V（IV），V（V）（II），Fe（Ⅲ），Co（Ⅲ），Cr（Ⅲ），Mn（Ⅱ），Mn（Ⅲ）等元素中的至少一种元素，，Ir（III），Rh（III），Ru（II），V（IV），V（V），Co（II）和Cr（II），L1是至少一种由氰化物，羰基，氰酸酯，异氰酸酯，腈，硫氰酸酯和亚硝酰基，X是甲酸根阴离子，乙酸根阴离子或丙酸根阴离子，L2是至少一种与醇，醛，酮，醚，聚醚，酯，尿素衍生物，酰胺，腈和硫化物，a，b，c，d，e，f，g，h，i是整数，其中选择a，b，c和d，使得满足电中性条件，被选择为使得电中性条件满足，其X射线衍射图示出特定d值的反射可用作催化剂。

40. 发明授权

US06239315B1 Single-step method for producing glycol monoethers from olefins 失效
标题翻译：从烯烃生产乙二醇单醚的单步法
公开(公告)号：US06239315B1
公开(公告)日：2001-05-29
申请号：US09403590
申请日：1999-10-25
申请人： Ulrich Müller , Georg Heinrich Grosch , Andreas Walch , Norbert Rieber
发明人： Ulrich Müller , Georg Heinrich Grosch , Andreas Walch , Norbert Rieber
IPC分类号： C07C4311
CPC分类号： B01J37/04 , B01J29/005 , B01J29/06 , B01J29/40 , B01J29/42 , B01J29/7007 , B01J29/86 , B01J29/89 , C07C41/06 , C07C43/13
摘要： A process for preparing glycol monoethers from olefins comprises reacting the olefins with an epoxidizing reagent in the simultaneous presence of hydroxyl-containing organic compounds over a mixture of epoxidation catalysts and alkoxylation catalysts.
摘要翻译：从烯烃制备乙二醇单醚的方法包括在环氧化催化剂和烷氧基化催化剂的混合物中同时存在含羟基的有机化合物的同时使烯烃与环氧化试剂反应。

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