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    • 32. 发明授权
    • Silver halide photographic materials and method for manufacture thereof
    • 卤化银照相材料及其制造方法
    • US5153115A
    • 1992-10-06
    • US742497
    • 1991-08-05
    • Shoichiro YasunamiYasuo Mukunoki
    • Shoichiro YasunamiYasuo Mukunoki
    • C08F16/36C08F16/38C08F18/00C08F18/24C08F20/10C08F20/26C08F20/34C08F20/38C08F20/52C08F20/54G03C1/85G03C1/89
    • G03C1/89G03C1/853G03C1/895
    • Silver halide photographic materials are disclosed, comprising a support having thereon at least one photosensitive silver halide emulsion layer, wherein at least one layer of said photographic material is formed by polymerizing a film which contains a compound represented by formula (I): ##STR1## wherein X represents --CO--, --COO--, --OCO-- or an arylene group; L represents an alkylene group, an aralkylene group or an arylene group, any of which can optionally have substituents; Y represents --CO--, --SO.sub.2 -- or --NHCO--; m and p each independently represents 0 to 1, provided that when X is ##STR2## m is 1; Z represents --O--, --S-- or ##STR3## R.sub.1 represents a hydrogen atom, an alkyl group, a halogen atom or a cyano group; R.sub.2, R.sub.3 and R.sub.4 represent lower alkylene groups; R.sub.5 represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an aralkyl group, --CO--R.sub.9 or --SO.sub.2 R.sub.9, any of which, other than a hydrogen atom, can optionally have substituents; R.sub.6, R.sub.7 and R.sub.8 represent hydrogen atoms, alkyl groups or alkenyl groups, any of which, other than hydrogen atoms, can optionally have substituents; R.sub.9 represents an alkyl group, an alkenyl group, an aryl group or an aralkyl group, any of which can optionally have substituents; and a, b and c each independently represents an integer of value from 0 to 30, and a, b and c are not all equal to 0.
    • 公开了卤化银照相材料,其包括其上具有至少一个光敏卤化银乳剂层的载体,其中至少一层所述照相材料是通过聚合含有由式(I)表示的化合物的膜形成的: (I)其中X表示-CO - , - COO - , - OCO-或亚芳基; L表示亚烷基,亚芳烷基或亚芳基,其中任何一个可任选具有取代基; Y表示-CO-,-SO 2 - 或-NHCO-; m和p各自独立地表示0至1,条件是当X是m时,m是1; Z表示-O - , - S-或R1表示氢原子,烷基,卤素原子或氰基。 R2,R3和R4表示低级亚烷基; R5表示氢原子,烷基,烯基,芳基,芳烷基,-CO-R9或-SO2R9,氢原子以外的任何一个都可以具有取代基; R 6,R 7和R 8表示氢原子,烷基或链烯基,除氢原子之外,任选具有取代基; R9表示烷基,烯基,芳基或芳烷基,其中任何一个可任选地具有取代基; a,b和c各自独立地表示0〜30的整数,a,b,c不全部为0。
    • 37. 发明授权
    • Negative resist composition
    • 负阻抗组成
    • US06773862B2
    • 2004-08-10
    • US10274386
    • 2002-10-21
    • Koji ShirakawaYutaka AdegawaShoichiro Yasunami
    • Koji ShirakawaYutaka AdegawaShoichiro Yasunami
    • G03C173
    • G03F7/0045G03F7/0382Y10S430/106Y10S430/107Y10S430/108Y10S430/115Y10S430/143Y10S430/167Y10S430/168
    • A negative resist composition comprising: (A) a compound being capable of generating an acid upon irradiation with an actinic ray or a radiation; (B) an alkali-soluble polymer; and (C) at least two crosslinking agents being capable of generating crosslinking with the polymer (B) by an action of an acid, wherein the crosslinking agent (C) comprises at least two compounds having a different skeleton from each other, which are selected from phenol derivatives having at least one of a hydroxymethyl group and an alkoxymethyl group on a benzene ring thereof, in which a sum of the hydroxymethyl group and the alkoxymethyl group is two or more, one of the at least two crosslinking agents comprises one or two benzene rings in the molecule thereof, and other one of the at least two crosslinking agents comprises from 3 to 5 benzene rings in the molecule thereof.
    • 一种负性抗蚀剂组合物,其包含:(A)能够在用光化射线或辐射照射时能够产生酸的化合物; (B)碱溶性聚合物; 和(C)至少两种能够通过酸的作用与聚合物(B)发生交联的交联剂,其中所述交联剂(C)包含至少两种具有彼此不同骨架的化合物,其被选择 在苯环上具有羟甲基和烷氧基甲基中的至少一个的苯酚衍生物,其中羟甲基和烷氧基甲基的和为两个或多个,所述至少两种交联剂中的一种包含一个或两个 其分子中的苯环,并且所述至少两种交联剂中的另一种在其分子中包含3至5个苯环。
    • 40. 发明授权
    • Silver halide photographic material
    • 卤化银照相材料
    • US5250409A
    • 1993-10-05
    • US935336
    • 1992-08-27
    • Shoichiro YasunamiYasuo Mukunoki
    • Shoichiro YasunamiYasuo Mukunoki
    • G03C1/89G03C1/35
    • G03C1/89
    • A silver halide photographic material which comprises a support having thereon one or more constituent layers including at least one silver halide emulsion layer, wherein at least one of said constituent layers is a layer formed by (a) coating a composition which contains a high molecular weight compound having at least one repeating unit represented by the following formula (I), and then (b) making the composition undergo a crosslinking reaction: ##STR1## wherein R.sub.1 represents a hydrogen atom, an alkyl group, a chlorine atom, or a cyano group; R.sub.2 and R.sub.3, which may be the same or different, each represents an alkyl group; L.sub.1 and L.sub.2 each represents a divalent linking group; Y represents --O--, or ##STR2## wherein R.sub.4 represents a hydrogen atom, or an alkyl group; X represents a crosslinking group containing an activated vinyl component; and Z represents a counter ion for balancing the electric charge.
    • 一种卤化银照相材料,其包含其上具有一个或多个包含至少一个卤化银乳剂层的构成层的载体,其中所述构成层中的至少一个是通过(a)涂覆含有高分子量的组合物形成的层 具有至少一个由下式(I)表示的重复单元的化合物,然后(b)使组合物进行交联反应:其中R 1表示氢原子,烷基,氯原子, 或氰基; R 2和R 3可以相同或不同,各自表示烷基; L1和L2各自表示二价连接基团; Y表示-O-或其中R 4表示氢原子或烷基; X表示含有活性乙烯基成分的交联基团; Z表示用于平衡电荷的抗衡离子。