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    • 3. 发明授权
    • Negative resist composition
    • 负阻抗组成
    • US06773862B2
    • 2004-08-10
    • US10274386
    • 2002-10-21
    • Koji ShirakawaYutaka AdegawaShoichiro Yasunami
    • Koji ShirakawaYutaka AdegawaShoichiro Yasunami
    • G03C173
    • G03F7/0045G03F7/0382Y10S430/106Y10S430/107Y10S430/108Y10S430/115Y10S430/143Y10S430/167Y10S430/168
    • A negative resist composition comprising: (A) a compound being capable of generating an acid upon irradiation with an actinic ray or a radiation; (B) an alkali-soluble polymer; and (C) at least two crosslinking agents being capable of generating crosslinking with the polymer (B) by an action of an acid, wherein the crosslinking agent (C) comprises at least two compounds having a different skeleton from each other, which are selected from phenol derivatives having at least one of a hydroxymethyl group and an alkoxymethyl group on a benzene ring thereof, in which a sum of the hydroxymethyl group and the alkoxymethyl group is two or more, one of the at least two crosslinking agents comprises one or two benzene rings in the molecule thereof, and other one of the at least two crosslinking agents comprises from 3 to 5 benzene rings in the molecule thereof.
    • 一种负性抗蚀剂组合物,其包含:(A)能够在用光化射线或辐射照射时能够产生酸的化合物; (B)碱溶性聚合物; 和(C)至少两种能够通过酸的作用与聚合物(B)发生交联的交联剂,其中所述交联剂(C)包含至少两种具有彼此不同骨架的化合物,其被选择 在苯环上具有羟甲基和烷氧基甲基中的至少一个的苯酚衍生物,其中羟甲基和烷氧基甲基的和为两个或多个,所述至少两种交联剂中的一种包含一个或两个 其分子中的苯环,并且所述至少两种交联剂中的另一种在其分子中包含3至5个苯环。
    • 7. 发明授权
    • Negative resist composition
    • 负阻抗组成
    • US07432034B2
    • 2008-10-07
    • US10642291
    • 2003-08-18
    • Shoichiro YasunamiKoji Shirakawa
    • Shoichiro YasunamiKoji Shirakawa
    • G03F7/004G03F7/30
    • G03F7/0382Y10S430/106Y10S430/111
    • A negative resist composition of the present invention comprises: (A) an alkali-soluble resin; (B-1) a cross-linking agent capable of cross-linking with the alkali-soluble resin (A) by the action of an acid, in which the cross-linking agent is a phenol compound containing: in the molecule one or more benzene rings; and at least two cross-linking groups bonded to any of the benzene rings, the cross-linking group being a group selected from the group consisting of a hydroxymethyl group, an alkoxymethyl group and an acyloxymethyl group; (B-2) a cross-linking agent capable of cross-linking with the alkali-soluble resin (A) by the action of an acid, in which the cross-linking agent contains at least two specific groups; and (C) a compound capable of generating an acid upon irradiation with an actinic ray or radiation.
    • 本发明的负光刻胶组合物包含:(A)碱溶性树脂; (B-1)能够通过酸的作用与碱溶性树脂(A)交联的交联剂,其中交联剂是酚化合物,其在分子中含有一个或多个 苯环; 和至少两个与任何苯环结合的交联基团,所述交联基团是选自羟甲基,烷氧基甲基和酰氧基甲基的基团; (B-2)能够通过酸的作用与碱溶性树脂(A)交联的交联剂,其中交联剂含有至少两个特定基团; 和(C)能够在用光化射线或辐射照射时能产生酸的化合物。