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    • 37. 发明授权
    • Uretdione diisocyanates and a process for their production
    • 脲二异氰酸酯及其制备方法
    • US5750629A
    • 1998-05-12
    • US788726
    • 1997-01-23
    • Hans-Josef LaasReinhard HalpaapJosef PedainKlaus Konig
    • Hans-Josef LaasReinhard HalpaapJosef PedainKlaus Konig
    • B01D3/28B01J31/24C07B61/00C07D229/00C08G18/79C08G18/80C09D175/00C09D175/04
    • C08G18/8016C07D229/00C08G18/798
    • The present invention relates to a process for preparing pure bis(isocyanatoalkyl)monouretdiones corresponding to formula (I) ##STR1## wherein R represents identical or different, linear or branched alkyl groups having 4 to 9 carbon atoms, by oligomerizing at least a portion of the isocyanate groups of aliphatic diisocyanates in the presence of catalysts which accelerate the dimerization of isocyanate groups, terminating the reaction at the desired degree of oligomerization, removing unreacted excess diisocyanate by extraction or thin film distillation to obtain a distillation residue, subjecting the distillation residue to thin film distillation at a temperature of 160.degree. to 220.degree. C. and a pressure of 0.01 to 1.0 mbar and obtaining bis(isocyanato-alkyl)monouretdiones corresponding to formula (I) as the distillate. The present invention also relates to the resulting bis(isocyanato-alkyl)monouretdiones corresponding to formula I and to their use for the production of polyisocyanate addition products, in particular as the isocyanate components in polyurethane coatings compositions, in which the isocyanate groups may optionally be present in blocked form.
    • 本发明涉及一种制备对应于式(I)的纯双(异氰酸根合烷基)单脲基的方法,其中R表示相同或不同的具有4至9个碳原子的直链或支链烷基,至少通过低聚 一部分脂族二异氰酸酯的异氰酸酯基团在催化剂存在下加速异氰酸酯基团的二聚反应,以期望的低聚程度终止反应,通过萃取或薄膜蒸馏除去未反应的过量二异氰酸酯,得到蒸馏残渣, 蒸馏残渣,在160〜220℃的温度和0.01〜1.0mbar的压力下进行薄膜蒸馏,得到与式(I)相应的作为馏出物的双(异氰酸基 - 烷基)单脲。 本发明还涉及所得到的对应于式I的双(异氰酸根合 - 烷基)单脲基团,以及其用于制备多异氰酸酯加成产物的用途,特别是作为聚氨酯涂料组合物中的异氰酸酯组分,其中异氰酸酯基团可任选地为 以阻塞形式存在。