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31. 发明授权

US4356127A Preparation of 3-(2,2-dichloro-vinyl)-2,2-dimethyl-cyclopropane-1-carboxylic acid derivatives 失效
标题翻译： 3-（2,2-二氯 - 乙烯基）-2,2-二甲基 - 环丙烷-1-羧酸衍生物的制备
公开(公告)号：US4356127A
公开(公告)日：1982-10-26
申请号：US165928
申请日：1980-07-02
申请人： Hellmut Hoffmann
发明人： Hellmut Hoffmann
IPC分类号： C07C69/743 , C07C67/00 , C07C253/00 , C07C255/48 , C07F9/38 , C07F9/40 , C07F9/42 , C07C120/00 , C07C69/747 , C07C121/48
CPC分类号： C07F9/42 , C07F9/4006 , C07F9/4018 , C07F9/4065
摘要： A process for the preparation of a 3-(2,2-dichlorovinyl)-2,2-dimethyl-cyclopropane-1-carboxylic acid derivative of the formula ##STR1## in which Z is acetyl, cyano, carbamoyl, alkoxycarbonyl or --COOZ.sup.1, andZ.sup.1 is a radical customary in the alcohol part of pyrethroids,comprising reacting an .alpha.-hydroxy-phosphonic acid ester of the formula ##STR2## in which R each independently is alkyl or phenyl, or the two radicals R togehter are alkanediyl,with a dichloromethane derivative of the formula ##STR3## in which R.sup.1 and R.sup.2 each independently is alkyl, phenyl, alkoxy or phenoxy, or together are alkanedioxy,in the presence of a base and at a temperature between about -100.degree. and +100.degree. C.
摘要翻译：制备式“IMAGE”的3-（2,2-二氯乙烯基）-2,2-二甲基 - 环丙烷-1-羧酸衍生物的方法，其中Z是乙酰基，氰基，氨基甲酰基，烷氧基羰基或-COOZ1 并且Z1是拟除虫菊酯的醇部分中常规的基团，其包括使式（IMAGE）的α-羟基膦酸酯与其中R各自独立地为烷基或苯基，或两个基团R

32. 发明授权

US4296241A Preparation of 3-(2,2-dichlorovinyl)-2,2-dimethyl-cyclopropane-1-carboxylic acid derivatives 失效
标题翻译：制备3-（2,2-二氯乙烯基）-2,2-二甲基 - 环丙烷-1-羧酸衍生物
公开(公告)号：US4296241A
公开(公告)日：1981-10-20
申请号：US165871
申请日：1980-07-02
申请人： Hellmut Hoffmann , Fritz Maurer , Uwe Priesnitz , Hans-Jochem Riebel
发明人： Hellmut Hoffmann , Fritz Maurer , Uwe Priesnitz , Hans-Jochem Riebel
IPC分类号： C07C51/363 , C07F9/40 , C07C69/743
CPC分类号： C07F9/4006 , C07C51/363
摘要： A process for the preparation of a 3-(2,2-dichlorovinyl)-2,2-dimethyl-cyclopropane-1-carboxylic acid or derivative of the formula ##STR1## in which R is hydrogen, alkali metal, ammonium, an equivalent of an alkaline earth metal, alkyl, or a radical customary in the alcohol part of pyrethroids,comprising reacting a 3-formyl-2,2-dimethyl-cyclopropane-1-carboxylic acid derivative of the formula ##STR2## with a dichloromethane derivative of the formula ##STR3## in which R.sup.1 and R.sup.2 each independently is alkyl, phenyl, alkoxy or phenoxy, or together are alkanediyl or alkanedioxy,in the presence of a base at a temperature between about -50.degree. and +50.degree. C. The products are intermediates for the preparation of esters of pyrethroid-like insecticidal activity.
摘要翻译：制备3-（2,2-二氯乙烯基）-2,2-二甲基 - 环丙烷-1-羧酸或式“IMAGE”的衍生物的方法，其中R是氢，碱金属，铵，等同物的碱土金属，烷基或在拟除虫菊酯的醇部分中常用的基团，其包括使式（IMAGE）的3-甲酰基-2,2-二甲基 - 环丙烷-1-羧酸衍生物与在碱存在下，在约-50℃至+ 50℃之间的温度下，R1和R2各自独立地为烷基，苯基，烷氧基或苯氧基，或一起为烷二基或烷二氧基的式“IMAGE”。是制备拟除虫菊酯类杀虫活性酯的中间体。

33. 发明授权

US4176181A Combating pests with N-(aminomethylene)-(monothio and dithio)-phosphoric acid diester-amides 失效
标题翻译：用N-（氨基亚甲基） - （单硫代和二硫代） - 磷酸二酯 - 酰胺
公开(公告)号：US4176181A
公开(公告)日：1979-11-27
申请号：US931046
申请日：1978-08-04
申请人： Hellmut Hoffmann , Ingeborg Hammann , Bernhard Homeyer
发明人： Hellmut Hoffmann , Ingeborg Hammann , Bernhard Homeyer
IPC分类号： A01N57/28 , C07F9/24 , A01N9/36
CPC分类号： A01N57/28 , C07F9/2458
摘要： N-(Aminomethylene)-(monothio and dithio)-phosphoric acid diester-amides of the formula ##STR1## wherein R and R.sup.1 each independently is alkoxy or alkylthio,R.sup.2 is alkyl, andX is oxygen or sulphur,which possess arthropodicidal and nematicidal properties.
摘要翻译：其中R和R 1各自独立地为烷氧基或烷硫基，R 2为烷基，X为氧或硫，具有杀虫和杀线虫剂的N-（氨基亚甲基） - （单硫代二硫代） - 磷酸二酯 - 酰胺属性。

34. 发明授权

US4139615A O-alkyl-S-alkyl-O-(4-trifluoromethylthio-phenyl)-(thiono)-thiol-phos phoric acid esters and pesticidal compositions and methods 失效
标题翻译： O-烷基-S-烷基-O-（4-三氟甲硫基 - 苯基） - （硫醇） - 硫醇 - 磷酸酯和杀虫组合物和方法
公开(公告)号：US4139615A
公开(公告)日：1979-02-13
申请号：US798746
申请日：1977-05-19
申请人： Hellmut Hoffmann , Erich Klauke , Ingeborg Hammann , Wilhelm Stendel
发明人： Hellmut Hoffmann , Erich Klauke , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： A01N57/14 , C07F9/18 , A01N9/36 , C07F9/165
CPC分类号： A01N57/14 , C07F9/18
摘要： O-Alkyl-S-alkyl-O-(4-trifluoromethylthiophenyl)-(thiono)-thiol-phosphoric acid esters of the formula ##STR1## in which R and R.sup.1 each independently is alkyl,R.sup.2 is hydrogen or alkyl, andX is oxygen or sulphur,Which possess insecticidal, acaricidal and nematicidal properties.
摘要翻译：式（I）的O-烷基-S-烷基-O-（4-三氟甲硫基苯基） - （硫醇） - 硫醇 - 磷酸酯，其中R和R 1各自独立地为烷基，R 2为氢或烷基， X是氧或硫，具有杀菌，杀虫和非特异性。

35. 发明授权

US4119715A Pesticidally active O-(1-fluoro-2-halogeno-ethyl)-thionophosphoric (phosphonic) acid esters 失效
标题翻译：杀虫活性O-（1-氟-2-卤代乙基） - 硫代磷酸（膦酸）酯
公开(公告)号：US4119715A
公开(公告)日：1978-10-10
申请号：US808227
申请日：1977-06-20
申请人： Hellmut Hoffmann , Dieter Arlt , Bernhard Homeyer , Ingeborg Hammann
发明人： Hellmut Hoffmann , Dieter Arlt , Bernhard Homeyer , Ingeborg Hammann
IPC分类号： A01N57/12 , A01N57/06 , A01N57/14 , A01N57/20 , C07F9/165 , C07F9/20 , C07F9/40 , C07F9/42 , A01N9/36
CPC分类号： C07F9/425 , A01N57/06 , C07F9/1651 , C07F9/20 , C07F9/4075
摘要： O-(1-Fluoro-2-halogeno-ethyl)-thionophosphoric (phosphonic) acid esters of the formula ##STR1## in which R is alkyl, phenyl or phenyl carrying at least one substituent selected from the group consisting of halogen, alkyl, alkylthio and nitro,R.sup.1 is alkyl or alkoxy, andHal is halogen,Which possess arthropodicidal and nematicidal properties.
摘要翻译：式（I）的O-（1-氟-2-卤代乙基） - 硫代磷酸（膦酸）酯，其中R是烷基，苯基或苯基，其携带至少一个选自卤素，烷基，烷硫基和硝基，R1是烷基或烷氧基，Hal是卤素，具有极性的抗坏血酸和碱性。

36. 发明授权

US3996367A N,N-dimethyl-O-[1-methyl-3-N-methylcarbaminyl-methyl-pyrazo l(5)yl]-carbamic acid ester 失效
标题翻译： N，N-二甲基-O- {8 1-甲基-3-N-甲基氨基甲酰基 - 甲基 - 吡唑（5）基{9-氨基甲酸酯
公开(公告)号：US3996367A
公开(公告)日：1976-12-07
申请号：US566464
申请日：1975-04-09
申请人： Hellmut Hoffmann , Ingeborg Hammann
发明人： Hellmut Hoffmann , Ingeborg Hammann
IPC分类号： A01N47/18 , C07D231/20 , A01N9/22
CPC分类号： C07D231/20
摘要： N,N-dimethyl-O-[1-methyl-3-N-methylcarbaminyl-methyl-pyrazol(5)yl]-carbamic acid ester of the formula ##SPC1##Which possesses insecticidal properties.
摘要翻译： N，N-二甲基-O- [1-甲基-3-N-甲基氨基甲酰基 - 甲基 - 吡唑（5）基] - 卡马明酸酯，其具有杀虫剂性质。

37. 发明授权

US3949022A N-[N',N'-disubstituted-aminomethylidene]-(thiono)thiol-phosphoric acid ester imides 失效
标题翻译： N- {8 N {40，N {40-二取代 - 氨基亚甲基{9-（硫醇）硫醇 - 磷酸酯酰亚胺
公开(公告)号：US3949022A
公开(公告)日：1976-04-06
申请号：US435055
申请日：1974-01-21
申请人： Hellmut Hoffmann , Ingeborg Hammann , Gunter Unterstenhofer
发明人： Hellmut Hoffmann , Ingeborg Hammann , Gunter Unterstenhofer
IPC分类号： C07F9/24 , A01N9/36
CPC分类号： C07F9/2458
摘要： N-[N',N'-disubstituted-aminomethylidene]-(thiono)thiolphosphoric acid ester imides of the formula ##EQU1## in which R is alkyl with 1 to 6 carbon atoms,R' is alkyl, alkenyl or alkynyl with up to 6 carbon atoms, lower alkylmercapto-lower alkyl or N-alkyl-carbamoylmethyl,R" and R'" each independently is alkyl or alkenyl with up to 6 carbon atoms, or conjointly with the nitrogen atom form a heterocyclic ring, and X is oxygen or sulfur,Which possess insecticidal, acaricidal and nematocidal properties.
摘要翻译：式R'SXR“PARALLEL ANGLE PN = CH-N ANGLE（I）ROR”的N- [N'，N'-二取代 - 氨基亚甲基] - （硫杂）硫醇磷酸酯酰亚胺其中R是烷基与 1至6个碳原子，R'是具有至多6个碳原子的烷基，烯基或炔基，低级烷基巯基 - 低级烷基或N-烷基 - 氨基甲酰基甲基，R“和R”'各自独立地为烷基或烯基，直至 6个碳原子，或与氮原子一起形成杂环，X是氧或硫，具有无毒的杀虫剂，杀虫剂和杀虫剂的性质。

38. 发明授权

US4342704A Process for the preparation of 1,1-dichloroalkenes 失效
标题翻译：制备1,1-二氯烯烃的方法
公开(公告)号：US4342704A
公开(公告)日：1982-08-03
申请号：US165872
申请日：1980-07-02
申请人： Hellmut Hoffmann , Fritz Maurer , Uwe Priesnitz , Hans-Jochem Riebel
发明人： Hellmut Hoffmann , Fritz Maurer , Uwe Priesnitz , Hans-Jochem Riebel
IPC分类号： C07C17/263 , C07B31/00 , C07B37/04 , C07C17/00 , C07C17/26 , C07C21/19 , C07C22/00 , C07C22/04 , C07C25/28 , C07C45/00 , C07C45/41 , C07C45/54 , C07C45/68 , C07C49/355 , C07C49/557 , C07C62/18 , C07C67/00 , C07C253/00 , C07C255/48 , C07F9/40 , C07F9/42 , C07C120/00 , C07C45/61 , C07C102/00 , C07C121/48
CPC分类号： C07C17/2635 , C07C21/19 , C07C22/00 , C07C22/04 , C07C25/28 , C07C45/41 , C07C45/54 , C07C45/68 , C07C49/355 , C07C62/18 , C07F9/4006 , C07F9/4018 , C07F9/4065 , C07F9/42
摘要： A process for the preparation of a 1,1-dichloroalkene of the formula ##STR1## in which R.sup.1 is hydrogen or an optionally substituted alkyl, alkenyl, alkynyl, aralkyl or aryl radical, andR.sup.2 is an optionally substituted alkyl, alkenyl, alkynyl, aralkyl, aralkenyl or aryl radical, or cycloalkyl which is optionally substituted by halogen, alkyl, alkanoyl, carbamoyl, cyano or phenyl, orR.sup.1 and R.sup.2 together form a hydrocarbon chain which is optionally branched and/or optionally contains a fused benzene ring,comprising reacting an aldehyde or ketone of the formula ##STR2## with a dichloromethane-phosphonic acid ester of the formula ##STR3## in which R.sup.3 each independently is alkyl or phenyl or the two radicals R.sup.3 together are alkanediyl,in the presence of a base at a temperature between about -50.degree. and +50.degree. C. Preferably either the base is metered into a mixture of the aldehyde or ketone and phosphonic acid ester or the ester is added to a mixture of the base and aldehyde or ketone.
摘要翻译：制备式“IMAGE”的1,1-二氯烯烃的方法，其中R 1为氢或任选取代的烷基，烯基，炔基，芳烷基或芳基，R 2为任选取代的烷基，烯基，炔基，芳烷基，芳烯基或芳基，或任选被卤素，烷基，烷酰基，氨基甲酰基，氰基或苯基取代的环烷基，或R 1和R 2一起形成任选支链和/或任选地含有稠合苯环的烃链，包括使式“IMAGE”的醛或酮与式“IMAGE”的二氯甲烷 - 膦酸酯反应，其中R 3各自独立地为烷基或苯基，或两个基团R 3一起为烷二基，在碱的存在下，温度在约-50℃和+ 50℃之间。优选地将碱定量为醛或酮和膦酸酯的混合物，或将酯加入到碱和醛或酮的混合物中。

39. 发明授权

US4330482A Process for the preparation of halogenoalkenes 失效
标题翻译：卤代烯烃的制备方法
公开(公告)号：US4330482A
公开(公告)日：1982-05-18
申请号：US218394
申请日：1980-12-18
申请人： Hellmut Hoffmann
发明人： Hellmut Hoffmann
IPC分类号： C07C69/743 , C07B31/00 , C07B37/04 , C07C17/00 , C07C17/263 , C07C45/00 , C07C45/68 , C07C49/567 , C07C67/00 , C07C253/00 , C07C255/06 , C07C255/48 , C07F9/38 , C07F9/40 , C07C21/19 , C07C121/48
CPC分类号： C07F9/4065 , C07C45/68 , C07C49/567 , C07F9/4018 , C07F9/4056
摘要： In the process for the production of a halogenoalkene of the formula ##STR1## in which R.sup.1 is an optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, aralkyl, aralkenyl or aryl radical or an optionally substituted heterocyclic radical,R.sup.2 represents a halogen atom, a cyano group, an optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, aralkenyl, aryl, alkylcarbonyl, arylcarbonyl, alkoxycarbonyl or aminocarbonyl radical or an optionally substituted heterocyclic radical, andX is a halogen atom,in which an .alpha.-hydroxy-phosphonic acid ester of the formula ##STR2## in which R.sup.3 each independently is an alkyl or phenyl radical, or the two radicals R.sup.3 together are an alkanediyl (alkylene) radical,is reacted with a phosphorus-containing olefinating agent of the formula ##STR3## in which Z.sup.1 is the phosphorus-containing radical ##STR4## R.sup.4 and R.sup.5 each independently is an alkyl, phenyl, alkoxy or phenoxy radical or together are an alkanedioxy radical, andR.sup.6 is an alkyl or phenyl radical,in the presence of a base at a temperature between about -70.degree. and +150.degree. C., the improvement which comprises effecting the reaction in the presence of a halogen carrier. The end products are useful as intermediates such as in synthesizing pyrethroid-like insecticides.
摘要翻译：在制备其中R 1为任选取代的烷基，烯基，炔基，环烷基，环烯基，芳烷基，芳烯基或芳基或任选取代的杂环基团的式IMAMA的卤代烯烃的方法中，R 2表示卤素原子，氰基，任选取代的烷基，烯基，炔基，环烷基，芳烯基，芳基，烷基羰基，芳基羰基，烷氧基羰基或氨基羰基或任选取代的杂环基，X是卤素原子，其中α-羟基膦酸其中R 3各自独立地是烷基或苯基，或者两个基团R 3一起是烷二基（亚烷基）基团的式“IMAGE”的酸酯与式“IMAGE”的含磷烯烃化合物在其中Z 1是含磷基团R 4和R 5各自独立地是烷基，苯基，烷氧基或苯氧基，或者一起是烷二氧基，R 6是烷基 1或苯基，在碱存在下，温度在约-70℃至+ 150℃之间，其改进包括在卤素载体存在下进行反应。最终产物可用作合成拟除虫菊酯类杀虫剂的中间体。

40. 发明授权

US4317783A 1-Oxo-3-methyl-2-butene phosphonic acid esters 失效
标题翻译： 1-氧代-3-甲基-2-丁烯膦酸酯
公开(公告)号：US4317783A
公开(公告)日：1982-03-02
申请号：US170377
申请日：1980-07-21
申请人： Hellmut Hoffmann
发明人： Hellmut Hoffmann
IPC分类号： C07F9/38 , C07D333/46 , C07F9/40 , C07F9/6574 , C07C57/66
CPC分类号： C07F9/4065 , C07D333/46
摘要： A process for the preparation of an .alpha.-oxo-.alpha.-(3-alkoxycarbonyl-2,2-dimethyl-cycloprop-1-yl)-methane-phosphonic acid ester of the formula ##STR1## in which R is alkyl or a radical customary in the alcohol component of pyrethroids, andR.sup.1 is alkyl or phenyl, or the two radicals R.sup.1 together are alkanediyl,comprising reacting .DELTA., .DELTA.-dimethyl-acrylic acid chloride of the formula ##STR2## with a phosphorous acid ester of the formulaR.sup.4 O-P(OR.sup.1).sub.2in whichR.sup.4 is alkyl,at a temperature between about 0.degree. and 100.degree. C., to produce the novel compound 1-oxo-3-methyl-2-butene-phosphonic acid of the formula ##STR3## which is then reacted with a sulphuranylidene-acetic acid ester of the formula ##STR4## in which R.sup.2 and R.sup.3 each independently is alkyl or together are alkanediyl, at a temperature between about 0.degree. and 100.degree. C.
摘要翻译：制备式“IMAGE”的α-氧代-α-（3-烷氧基羰基-2,2-二甲基 - 环丙-1-基） - 甲烷 - 膦酸酯的方法，其中R是烷基或基团通常在拟除虫菊酯的醇组分中，R 1是烷基或苯基，或者两个基团R 1一起是烷二基，包括使式（IMAGE）的DELTA，DELTA-二甲基 - 丙烯酰氯与式R4O的亚磷酸酯反应 -P（OR 1）2，其中R 4是烷基，在约0℃至100℃的温度下反应，得到新的化合物1-氧代-3-甲基-2-丁烯 - 膦酸，其具有下式然后将其与式“IMAGE”的亚硫酰亚基 - 乙酸酯反应，其中R 2和R 3各自独立地为烷基或一起为烷二基，温度为约0℃至100℃。

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