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31. 发明授权

US07351859B2 Heat activated tertiary amine urethane catalysts 有权
标题翻译：热活化叔胺氨基甲酸酯催化剂
公开(公告)号：US07351859B2
公开(公告)日：2008-04-01
申请号：US10838136
申请日：2004-05-03
申请人： Robert A. Grigsby, Jr. , Robert L. Zimmerman
发明人： Robert A. Grigsby, Jr. , Robert L. Zimmerman
IPC分类号： C07C55/06
CPC分类号： C08G18/1875 , C07C217/08
摘要： This invention concerns a compound formed from a tertiary amine-carboxylic acid salt, where the carboxylic acid and tertiary amine are selected such that the catalyst salt is blocked at room temperature and becomes unblocked at an elevated temperature. The compound is useful as a heat activated urethane catalyst.
摘要翻译：本发明涉及由叔胺 - 羧酸盐形成的化合物，其中选择羧酸和叔胺，使得催化剂盐在室温下被阻断并在升高的温度下被阻断。该化合物可用作热活化聚氨酯催化剂。

32. 发明授权

US06495722B1 Mannich polyols for rigid spray foams 失效
标题翻译：曼尼希多元醇用于刚性喷雾泡沫
公开(公告)号：US06495722B1
公开(公告)日：2002-12-17
申请号：US09953776
申请日：2001-09-17
申请人： Robert L. Zimmerman , Marshall P. Devine , Patrick L. Weaver
发明人： Robert L. Zimmerman , Marshall P. Devine , Patrick L. Weaver
IPC分类号： C07C21700
CPC分类号： C08G18/6674 , C08G18/5033 , C08G2101/0083 , C08G2150/50
摘要： Provided herein are polyurethane foams which may be prepared by spray techniques. The foams of the invention are prepared using conventional isocyanates and a novel Mannich condensate polyol having a hydroxy number in the range of 250-340 and a viscosity of 3500 cps or less, and wherein the Mannich condensate polyol is derived from nonylphenol, formaldehyde, an alkanolamine, and propylene oxide as the sole alkoxylating agent. Polyurethane foams prepared according to the invention possess superior physical properties over sprayed polyurethane foams prepared using Mannich condensate polyols which are made using mixtures of propylene oxide and ethylene oxide.
摘要翻译：本文提供的是可以通过喷雾技术制备的聚氨酯泡沫。本发明的泡沫体使用常规异氰酸酯和羟基数在250-340范围内且粘度为3500cps以下的新型曼尼希缩合多元醇制备，其中曼尼希缩合多元醇衍生自壬基酚，甲醛，链烷醇胺和环氧丙烷作为唯一的烷氧基化剂。根据本发明制备的聚氨酯泡沫与使用使用环氧丙烷和环氧乙烷的混合物制备的曼尼希缩合多元醇制备的喷涂聚氨酯泡沫具有优异的物理性能。

33. 发明授权

US06399736B1 Method of preparing spray elastomer systems 失效
标题翻译：制备喷雾弹性体体系的方法
公开(公告)号：US06399736B1
公开(公告)日：2002-06-04
申请号：US09481245
申请日：2000-01-11
申请人： Dudley J. Primeaux, II , Robert L. Zimmerman , Kenneth M. Hillman
发明人： Dudley J. Primeaux, II , Robert L. Zimmerman , Kenneth M. Hillman
IPC分类号： C08G1832
CPC分类号： C08G18/5024 , C08G18/10 , C08G18/3821 , C08G18/4804 , C08G2150/50 , C08G18/6685
摘要： This invention concerns a method for the preparation of polyurea elastomers, comprising: (a) reacting an amine chain extender with dialkyl maleate to form an aspartic ester, wherein the chain extender has a molar amount of amine groups that is greater than the moles of dialkyl maleate; (b) blending the aspartic ester with one or more polyoxyalkyleneamines to prepare a resin blend; (c) contacting the resin blend with an isocyanate under conditions effective to form a polyurea elastomer. This invention concerns a method for the preparation of polyurethane elastomers, comprising: (a) reacting an diamine chain extender with dialkyl maleate or fumarate, wherein the mole ratio of primary amine functionality in the diamine chain extender to dialkyl maleate or fumarate is more than 1:1; (b) coating a substrate with effective film forming amounts of the product of step (a), an isocyanate, and a polyhydroxyl compound under conditions effective to form a the polyurethane elastomer.
摘要翻译：本发明涉及一种制备聚脲弹性体的方法，包括：（a）使胺扩链剂与马来酸二烷基酯反应形成天冬氨酸酯，其中扩链剂的胺基摩尔量大于二烷基马来酸盐（b）将天冬氨酸酯与一种或多种聚氧化烯胺混合以制备树脂共混物; （c）在有效形成聚脲弹性体的条件下使树脂共混物与异氰酸酯接触。本发明涉及一种制备聚氨酯弹性体的方法，包括：（a）使二胺扩链剂与马来酸二烷基酯或富马酸盐反应，其中二胺扩链剂中伯胺官能度与马来酸二烷基酯或富马酸盐的摩尔比大于1 ：1; （b）在有效形成聚氨酯弹性体的条件下，用有效成膜量的步骤（a）的产物，异氰酸酯和多羟基化合物涂覆基材。

34. 发明授权

US5189221A Amine separation process 失效
标题翻译：胺分离过程
公开(公告)号：US5189221A
公开(公告)日：1993-02-23
申请号：US617339
申请日：1990-11-19
申请人： Roger G. Duranleau , Robert L. Zimmerman
发明人： Roger G. Duranleau , Robert L. Zimmerman
IPC分类号： C07C209/86 , C07C211/04
CPC分类号： C07C209/86 , Y02P20/582
摘要： A mixture of C.sub.1 -C.sub.4 mono-, di- and trialkylamines is separated by adding at least about an equimolar amount, based on the amine mixture, of a formyldialkanolamine selected from the group consisting of formyldiethanolamine, formyl aminoethylethanolamine and formyl 2-(2-aminoethylamino)-ethanol to the alkyl amine mixture, at a temperature of about 120.degree. to about 160.degree. C. and a pressure of about 500 to about 3,000 psig to provide a reaction mixture comprising the trialkylamine, the formyl dialkylamine and the formyl monoalkylamine, together with unreacted formyldialkanolamine and the corresponding alkanolamine, by separately recovering the trialkyl amine, the formyl dialkylamine and the formyl monoalkylamine from the reaction mixture, by reacting the dialkyl amine with said alkanolamine at atmospheric pressure at temperature of about 120.degree. to about 140.degree. C. to provide a reaction mixture comprising the dialkyl amine and formyldialkanolamine, by recovering the dialkyl amine from the formyl reaction mixture, by separately reacting the monoalkyl amine with said alkanolamine at atmospheric pressure at a temperature of about 120.degree. to about 140.degree. C. to provide a reaction mixture comprising the monoalkyl amine and formyl dialkanolamine and recovering the monoalkyl amine from the reaction mixture.
摘要翻译：通过加入基于胺混合物的至少约等摩尔量的选自甲酰基二乙醇胺，甲酰基氨基乙基乙醇胺和甲酰基2-（2-甲氧基苯基）甲酰基二烷醇胺来分离C1-C4单 - ，二 - 和三烷基胺的混合物，氨基乙基氨基） - 乙醇加入到烷基胺混合物中，在约120℃至约160℃的温度和约500至约3,000psig的压力下提供包含三烷基胺，甲酰基二烷基胺和甲酰基单烷基胺的反应混合物，通过在大约120℃至大约140℃的温度下，在大气压下使二烷基胺与所述链烷醇胺反应，通过从反应混合物中分别回收三烷基胺，二烷基二烷基胺和甲酰基单烷基胺，与未反应的甲酰基二烷醇胺和相应的链烷醇胺一起以提供包含二烷基胺和甲酰基二烷醇胺的反应混合物，通过从中回收二烷基胺甲酰基反应混合物，通过在约120℃至约140℃的温度下，在大气压下分别使单烷基胺与所述链烷醇胺反应，得到包含单烷基胺和甲酰基二链烷醇胺的反应混合物，并从反应混合物中回收单烷基胺。

35. 发明授权

US5130491A Continuous preparation of secondary amines from nitriles using a nickel catalyst 失效
标题翻译：使用镍催化剂从腈中连续制备仲胺
公开(公告)号：US5130491A
公开(公告)日：1992-07-14
申请号：US583110
申请日：1990-09-17
申请人： Robert L. Zimmerman
发明人： Robert L. Zimmerman
IPC分类号： C07C209/48
CPC分类号： C07C209/48
摘要： A method for producing secondary amines, particularly fatty secondary amines such as ditallowamine from fatty nitriles, such as tallow nitrile over a nickel catalyst promoted with copper, chromium and molybdenum has been discovered. The reaction gives high selectivity of secondary amine over the coproduced primary and tertiary amines. The reaction may be conducted continuously in the presence of ammonia and hydrogen. The secondary amine proportion may be increased by a second stage using the same catalyst as the first stage, but in the absence of ammonia. The same catalyst may be used in both steps if a two stage process is used.
摘要翻译：已经发现了用铜，铬和钼促进的镍催化剂上生产仲胺，特别是脂肪仲胺如来自脂肪腈的二牛油如牛脂腈。该反应使得仲胺比共制的伯胺和叔胺具有高的选择性。反应可以在氨和氢的存在下连续进行。仲胺比例可以使用与第一阶段相同的催化剂，但不存在氨可以增加第二阶段。如果使用两级方法，则可以在两个步骤中使用相同的催化剂。

36. 发明授权

US5013813A Polyurea elastomer with rapid dry time 失效
标题翻译：聚脲弹性体具有快速干燥时间
公开(公告)号：US5013813A
公开(公告)日：1991-05-07
申请号：US452158
申请日：1989-12-18
申请人： Robert L. Zimmerman , Dudley J. Primeaux, II
发明人： Robert L. Zimmerman , Dudley J. Primeaux, II
IPC分类号： C08G18/10 , C08G18/50
CPC分类号： C08G18/5024 , C08G18/10 , C08G2120/00 , C08G2150/50
摘要： A polyurea elastomer which exhibits a rapid dry time is disclosed. The elastomer includes an isocyanate, an amine terminated polytetrahydrofuran and a chain extender. The isocyanate is preferably a quasi-prepolymer of an isocyanate and a material selected from at least one polyol, a high molecular weight polyoxyalkyleneamine or a combination thereof.

37. 发明授权

US4698428A Catalytic method for the manufacture of N,N'-dimethylpiperazine 失效
标题翻译：用于制造N，N'-二甲基哌嗪的催化方法
公开(公告)号：US4698428A
公开(公告)日：1987-10-06
申请号：US871954
申请日：1986-06-09
申请人： Robert L. Zimmerman , Steven H. Vanderpool
发明人： Robert L. Zimmerman , Steven H. Vanderpool
IPC分类号： C07D295/023 , C07D241/04 , C07C85/06
CPC分类号： C07D295/023
摘要： It has been surprisingly discovered in accordance with the present invention that N-methylethanolamine may be converted to N,N'-dimethylpiperazine when using a catalyst composed of titania to which from about 0.5 to about 7 wt. % of phosphorus has been thermally chemically bonded in the form of phosphate linkages.
摘要翻译：根据本发明令人惊奇地发现，当使用由二氧化钛组成的催化剂时，N-甲基乙醇胺可以转化成N，N'-二甲基哌嗪，其中约0.5至约7wt。磷的百分比已经以磷酸盐键的形式热化学键合。

38. 发明授权

US4487912A Reaction injection molded elastomers containing acid amides 失效
标题翻译：含酰胺的反应注射成型弹性体
公开(公告)号：US4487912A
公开(公告)日：1984-12-11
申请号：US579236
申请日：1984-02-13
申请人： Robert L. Zimmerman , Richard J. G. Dominguez
发明人： Robert L. Zimmerman , Richard J. G. Dominguez
IPC分类号： C08G18/38 , C08G18/66 , C08K5/20 , C08G18/32 , C08G18/34 , C08G18/50
CPC分类号： C08G18/6685 , C08G18/3825 , C08K5/20 , C08G2120/00 , C08G2125/00
摘要： The invention relates to reaction injection molded elastomers derived from high molecular weight active hydrogen containing materials, a chain extender, a polyisocyanate and an acid amide as an internal mold release agent imparting superior hot tear strength. The reaction injection molded (RIM) elastomers of this invention are useful, for example, as automobile body parts.
摘要翻译：本发明涉及衍生自高分子量含活性氢的材料的反应注射成型的弹性体，扩链剂，多异氰酸酯和酰胺作为赋予优异热撕裂强度的内部脱模剂。本发明的反应注射成型（RIM）弹性体可用作例如汽车车身部件。

39. 发明授权

US4442237A Novel aromatic amide polyols from the reaction of phthalic acid residues, alkylene glycols and amino alcohols 失效
标题翻译：来自邻苯二甲酸残基，亚烷基二醇和氨基醇反应的新型芳香族酰胺多元醇
公开(公告)号：US4442237A
公开(公告)日：1984-04-10
申请号：US443726
申请日：1982-11-22
申请人： Robert L. Zimmerman , Kenneth G. McDaniel
发明人： Robert L. Zimmerman , Kenneth G. McDaniel
IPC分类号： C08G69/00 , C08G18/00 , C08G18/02 , C08G18/42 , C08G18/46 , C08G18/60 , C08G69/44 , C08G18/14
CPC分类号： C08G18/4615 , C08G18/4213 , C08G18/4225 , C08G2105/02
摘要： Mixtures of aromatic polyols containing tertiary amine and ester functionalities suitable for use in rigid foams prepared by reacting a phthalic acid residue with an alkylene glycol and an amino alcohol are described. These novel polyols may be blended with conventional polyols to yield rigid polyurethane foams with better flammability resistance as compared with foams made from conventional polyols alone.
摘要翻译：描述了含有叔胺和适用于通过邻苯二甲酸残基与亚烷基二醇和氨基醇反应制备的硬质泡沫中的酯官能团的芳族多元醇的混合物。与常规多元醇单独制成的泡沫相比，这些新型多元醇可与常规多元醇共混以产生具有更好的耐燃性的硬质聚氨酯泡沫。

40. 发明授权

US4376832A Catalyst-solvent system for polyester-based polyurethane foams comprising N-butylmorpholine and N,N'-dimethylpiperazine and the solvent 失效
标题翻译：用于包含N-丁基吗啉和N，N'-二甲基哌嗪和溶剂的聚酯基聚氨酯泡沫的催化剂 - 溶剂体系
公开(公告)号：US4376832A
公开(公告)日：1983-03-15
申请号：US328291
申请日：1981-12-07
申请人： George P. Speranza , Robert L. Zimmerman
发明人： George P. Speranza , Robert L. Zimmerman
IPC分类号： C08G18/00 , C08G18/18 , C08G18/20 , C08G18/14
CPC分类号： C08G18/2009
摘要： N-butylmorpholine and N,N'-dimethylpiperazine may be used together as a catalyst system in an activator solution to give finer, more uniform cells to polyester-based polyurethane foams if a solvent is employed. It was surprisingly discovered that the components must be used together as a catalyst-solvent system to avoid the disadvantages observed when one of the components is changed or left out. For example, if the solvent were not present in the activator solution in proportions of at least 1 wt. %, the activator solution would not be homogeneous.
摘要翻译：如果使用溶剂，可以将N-丁基吗啉和N，N'-二甲基哌嗪作为催化剂体系一起用于活化剂溶液中，以使聚酯基聚氨酯泡沫更细，更均匀的细胞。令人惊奇地发现，组分必须一起用作催化剂 - 溶剂体系，以避免当其中一种组分改变或排除时观察到的缺点。例如，如果溶剂在活化剂溶液中不以至少1重量％的比例存在，％，活化剂溶液将不均匀。

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