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31. 发明授权

US4461863A Process for concentrating aqueous dispersions of polymers of conjugated dienes 失效
标题翻译：浓缩共轭二烯聚合物的水分散体的方法
公开(公告)号：US4461863A
公开(公告)日：1984-07-24
申请号：US444068
申请日：1982-11-24
申请人： Adolf Schmidt
发明人： Adolf Schmidt
IPC分类号： C08F6/00 , C08C1/075 , C08F6/06 , C08F6/20 , C08F36/00 , C08F36/04 , C08K5/42
CPC分类号： C08C1/075 , C08K5/42
摘要： The invention relates to a process for the production of an aqueous dispersion, fluid under normal conditions, based on homo- and co-polymers of conjugated dienes and having solids contents of from 35 to 55%, by weight, and average particle diameters of from 20 to 150 nm from an aqueous dispersion based on homo- and co-polymers of conjugated dienes which has been obtained by conventional methods, is fluid under normal conditions and does not contain alkane polysulphonates, having a solids content of from 25 to 35%, by weight, and average particle diameters of from 20 to 150 nm by concentration in the presence of a water-soluble salt of at least one alkane polysulphonate.
摘要翻译：本发明涉及一种基于共轭二烯的均聚物和共聚物在正常条件下制备水性分散体的方法，其固体含量为35至55重量％，平均粒径为基于通过常规方法获得的共轭二烯的均聚物和共聚物的水性分散体为20至150nm，在正常条件下为流体，不含有固体含量为25至35％的烷烃聚合物，，在至少一种烷烃聚磺酸盐的水溶性盐的存在下，通过浓度浓缩平均粒径为20-150nm。

32. 发明授权

US4452737A Surface-active azo compounds 失效
标题翻译：表面活性偶氮化合物
公开(公告)号：US4452737A
公开(公告)日：1984-06-05
申请号：US373962
申请日：1982-05-03
申请人： Adolf Schmidt , Ernst Roos
发明人： Adolf Schmidt , Ernst Roos
IPC分类号： C08F2/00 , B01F17/26 , C07C67/00 , C07C257/14 , C07C301/00 , C07C303/38 , C07C311/01 , C07C311/51 , C08F2/22 , C08F2/24 , C08F4/00 , C08F4/04 , B01F17/00 , C07C107/02
CPC分类号： C07C257/14 , C08F4/04 , Y10S516/01 , Y10S516/07 , Y10S534/02
摘要： The invention relates to surface-active azo compounds obtainable by reacting azo compounds corresponding to the following general formula (I): ##STR1## in which X and Y are the same or different and represent ##STR2## and R represents C.sub.1 -C.sub.4 -alkyl, with at least one C.sub.10 -C.sub.18 -paraffin disulphonic acid dihalide in aqueous medium or a solvent or solvent mixture which is inert to the reactants under the process conditions and in which the reactants are at least partly soluble, at temperatures in the range of from 0.degree. to +.degree. C. and in the presence of a base in a quantity substantially equivalent to the hydrolysable halogen, the reaction being accompanied by the elimination of hydrogen halide. The new azo compounds give low electrolyte, low-foam dispersions in emulsion and dispersion polymersation.
摘要翻译：本发明涉及通过使对应于下列通式（I）的偶氮化合物反应获得的表面活性偶氮化合物：其中X和Y相同或不同并且表示 + TR 并且R表示C1-C4-烷基，与至少一种C10-C18-链烷烃二磺酸二卤化物在水性介质中或在反应物在反应物处于至少部分溶解，在0℃至+℃的温度范围内，并且在基本上等于可水解卤素的碱存在下，反应伴随着卤化氢的消除。新的偶氮化合物在乳液和分散体聚合反应中产生低电解质，低泡沫分散体。

33. 外观设计

USD271047S Lens for a combined vehicle headlight and signal light 失效
公开(公告)号：USD271047S
公开(公告)日：1983-10-18
申请号：US177712
申请日：1980-08-13
申请人： Werner Heinz , Arno Jambor , Adolf Schmidt
设计人： Werner Heinz , Arno Jambor , Adolf Schmidt

34. 发明授权

US4384056A Aqueous dispersions based on (meth)acrylic acid alkyl ester polymers with two pronounced, substantially non-overlapping peaks in the particle size distribution within specific particle size ranges, and a process for the preparation and use thereof 失效
标题翻译：基于（甲基）丙烯酸烷基酯聚合物的水性分散体，其具有在特定粒度范围内的粒度分布中具有两个显着的，基本上不重叠的峰，以及其制备和使用的方法
公开(公告)号：US4384056A
公开(公告)日：1983-05-17
申请号：US258285
申请日：1981-04-28
申请人： Adolf Schmidt , Gunter Kolb , Werner Clarenz
发明人： Adolf Schmidt , Gunter Kolb , Werner Clarenz
IPC分类号： C08L33/00 , C08J3/02 , C08J3/03 , C08L33/02 , C08L33/04 , C08L33/06 , C09D133/04 , C09D133/06 , C08L35/02
CPC分类号： C08J3/03 , C09D133/06 , C08J2333/06 , C08L2205/02 , C08L33/06
摘要： Aqueous dispersions of polymers containing (meth)acrylic acid alkyl ester units which contain the polymer in the form of relatively large, non-agglomerated, spherical particles (=main spheres) and relatively small, non-agglomerated, spherical particles (=filler spheres), wherein the smaller filler spheres have an average particle diameter d.sub.F measured using an electron microscope of from 50 to 150 nanometers (nm) and the average diameter of the large main spheres d.sub.H is from 1.35 to 3.5 times larger than the average particle diameter d.sub.F, provided that d.sub.H is at least 140 nm, and wherein the ratio of the total mass of the polymer composed of main spheres M.sub.H to the total mass of the polymer composed of filler spheres M.sub.F isM.sub.H :M.sub.F =20:1 to M.sub.H :M.sub.F =1:20and wherein at least 70% of the number of main spheres and at least 70% of the number of filler spheres lie in the range of .+-.25% of the respective average value of d.sub.H or d.sub.F.Dispersions of this type dry to form clear, lustrous and waterproof films, even with a solids content of from 37 to 45% by weight, and even if that solids content has been obtained from more highly concentrated dispersions by dilution with water. The dispersions are used as binders in or as aqueous paint and coating agents for plastics, metals, wood, glass, paper, and cardboard articles, as binders in print dyes, road marking paints and in impregnation or reinforcing agents for paper, leather, woven and non-woven textiles.
摘要翻译：含有（甲基）丙烯酸烷基酯单元的聚合物的水分散体，其含有相对大的非团聚的球形颗粒（=主球体）和相对小的非团聚的球形颗粒（=填料球体）形式的聚合物，其中较小的填料球具有使用50至150纳米（nm）的电子显微镜测量的平均粒径dF，并且主要主球体dH的平均直径比平均粒径dF大1.35至3.5倍，条件是dH为至少140nm，并且其中由主球体MH组成的聚合物的总质量与由填料球MF组成的聚合物的总质量的比率为MH：MF = 20:1至MH：MF = 1:20，并且其中主球数和至少70％的填充球数的至少70％在相应的dH或dF的平均值的+/- 25％的范围内。该类型的分散体干燥以形成透明，有光泽和防水的膜，即使固体含量为37至45重量％，并且即使通过用水稀释从更高浓度的分散体中获得固体含量。分散体用作塑料，金属，木材，玻璃，纸和纸板制品的水性涂料和涂料中的粘合剂，作为印刷染料中的粘合剂，道路标线漆以及用于纸，皮革，编织物的浸渍或增强剂和无纺布。

35. 发明授权

US4329738A Cover for motor vehicle lights 失效
标题翻译：汽车灯盖
公开(公告)号：US4329738A
公开(公告)日：1982-05-11
申请号：US124262
申请日：1980-02-25
申请人： Werner Heinz , Adolf Schmidt , Arno Jambor
发明人： Werner Heinz , Adolf Schmidt , Arno Jambor
IPC分类号： B60Q1/04 , F21V5/00 , F21V15/00 , F21V17/00 , F21V5/04 , F21V13/00
CPC分类号： F21S48/1208 , F21S48/1233
摘要： A cover for lights, especially automobile lights, wherein at least a part of the cover which is located within a flat area of a reflector opening of the light when the cover is installed is provided with a number of individual sections. The sections are staggered in a stepwise fashion within a plane which is horizontal in the installed position and/or in a vertical plane with the sections extending in a direction opposite to an intended direction of travel of the atuomobile.
摘要翻译：一种用于灯，特别是汽车灯的罩，其中当安装盖时位于光的反射器开口的平坦区域内的盖的至少一部分设置有多个单独的部分。这些部分在平面内以逐步的方式交错，该平面在安装位置处是水平的，和/或在垂直平面中，其中部分沿着与运动的预期行进方向相反的方向延伸。

36. 发明授权

US4327004A Aqueous dispersions of plastics in which the average diameter of the dispersion particles is in the range from about 50 to 500 nm, and a process for their preparation 失效
标题翻译：其中分散体颗粒的平均直径在约50至500nm范围内的塑料的水分散体及其制备方法
公开(公告)号：US4327004A
公开(公告)日：1982-04-27
申请号：US173568
申请日：1980-07-30
申请人： Adolf Schmidt , August Bockmann
发明人： Adolf Schmidt , August Bockmann
IPC分类号： C08F2/00 , C08F2/26 , C08L27/06
CPC分类号： C08F2/26
摘要： An aqueous dispersion of a synthetic polymer of average diameter in the range of 50 to 500 nm and especially above 75 nm is disclosed, the aqueous dispersion having a solids content of 5 to 50 parts by weight per 100 parts per weight of total dispersion. The aqueous dispersion is provided by effecting polymerization in the presence of an emulsifier which comprises an alkali metal salt of a polysulfonic acid of an alkane of medium chain length e.g. 8 to 22 carbon atoms.
摘要翻译：公开了平均直径在50至500nm，特别是高于75nm范围内的合成聚合物的水性分散体，该水性分散体的固含量为每100重量份总分散体5至50重量份。通过在乳化剂的存在下进行聚合来提供水分散体，所述乳化剂包含中链链烷烃的多磺酸的碱金属盐，例如， 8至22个碳原子。

37. 发明授权

US06767964B2 Polymer compositions with an improved constancy of characteristics 有权
标题翻译：具有改善的特性恒定性的聚合物组合物
公开(公告)号：US06767964B2
公开(公告)日：2004-07-27
申请号：US10204147
申请日：2002-08-16
申请人： Herbert Eichenauer , Adolf Schmidt , Ulrich Jansen
发明人： Herbert Eichenauer , Adolf Schmidt , Ulrich Jansen
IPC分类号： C08G6348
CPC分类号： C08L51/04 , C08F279/04 , C08L25/12 , C08L55/02 , C08L2205/02 , C08L2666/24 , C08L2666/02
摘要： A thermoplastic molding composition that features constancy of properties, especially toughness and processability is disclosed. The composition contains a first graft rubber polymer that is a product of emulsion polymerisation of styrene and acrylonitrile in the presence of a butadiene polymer latex (A) with a mean particle diameter d50 of 80 to 220 nm, a second graft rubber polymer obtained by emulsion polymerisation of styrene and acrylonitrile in the presence of a butadiene polymer latex (B) with a mean particle diameter d50 of 340 to 480 nm, and a rubber-free copolymer of styrene and acrylonitrile. Importantly, the butadiene polymer latex (A) is the product of seed polymerization using a seed latex with a mean particle diameter of 10 to 100 nm, and the butadiene polymer latex (B) is the product of seed polymerisation using the butadiene polymer latex (A) as seed latex.

38. 发明授权

US5674939A ABS moulding compounds with novel morphology 失效
标题翻译： ABS模塑料具有新颖的形态
公开(公告)号：US5674939A
公开(公告)日：1997-10-07
申请号：US557359
申请日：1995-11-13
申请人： Herbert Eichenauer , Adolf Schmidt , Edgar Leitz , Karl-Erwin Piejko
发明人： Herbert Eichenauer , Adolf Schmidt , Edgar Leitz , Karl-Erwin Piejko
IPC分类号： C08L51/04 , C08F279/00 , C08F279/04 , C08L55/00 , C08L55/02
CPC分类号： C08L55/02 , C08F279/04
摘要： Moulding compounds the ABS type consisting of at least one resin matrix and a particulate graft-rubber polymer distributed therein and produced by emulsion polymerisation, wherein at least 70% of the graft-rubber particles (number) exhibit a structure of the rubber phase which can be detected by photographs taken with the aid of a transmission electron microscope and in which the individual particles contain irregular cellular inclusions of resin-forming polymer and the surface of the particles exhibits an irregularly jagged structure such that, for each particle illustrated, 5 to 30 of such jagged projections are present which differ from an idealised round particle (with a diameter d) by virtue of a diameter d+d/x with x=3 to 15, as well as a process for the manufacture of said moulding compounds.
摘要翻译：成型化合物由至少一种树脂基质和分散在其中的颗粒状接枝橡胶聚合物组成的ABS类型，通过乳液聚合制备，其中至少70％的接枝橡胶颗粒（数量）表现出橡胶相的结构，其可以通过借助透射电子显微镜拍摄的照片进行检测，其中各个颗粒含有不规则的树脂形成性聚合物的细胞夹杂物，并且颗粒的表面呈现不规则的锯齿状结构，使得对于所示的每个颗粒为5〜30 存在这样的锯齿形突起，其与理想化的圆形颗粒（直径d）不同，其直径d = + d / x，x = 3〜15，以及制造所述模塑料的方法。

39. 发明授权

US5312997A Surface-active pereoxides and their use 失效
标题翻译：表面活性抗氧化剂及其用途
公开(公告)号：US5312997A
公开(公告)日：1994-05-17
申请号：US57230
申请日：1993-05-04
申请人： Martin Bohnenpoll , Adolf Schmidt , Heinrich Alberts
发明人： Martin Bohnenpoll , Adolf Schmidt , Heinrich Alberts
IPC分类号： C07C409/38 , C07C409/42 , C08F2/26 , C08F4/34 , C07C409/00
CPC分类号： C07C409/42 , C07C409/38 , C08F4/34 , Y10S516/01 , Y10S516/02 , Y10S516/05
摘要： The present invention relates to surface-active peroxides which can be employed as emulsifying initiators for the preparation of low-electrolyte polymer dispersions having a low tendency to foam.
摘要翻译：本发明涉及可用作乳化引发剂的表面活性过氧化物，用于制备低泡沫倾向的低电解质聚合物分散体。

40. 发明授权

US5248727A Vinyl chloride polymer based moulding compositions with reduced fogging 失效
标题翻译：基于氯乙烯聚合物的模塑组合物具有减少的雾化
公开(公告)号：US5248727A
公开(公告)日：1993-09-28
申请号：US892397
申请日：1992-05-18
申请人： Christian Lindner , Adolf Schmidt , Herbert Eichenauer , Karl-Erwin Piejko , Karl-Heinz Ott
发明人： Christian Lindner , Adolf Schmidt , Herbert Eichenauer , Karl-Erwin Piejko , Karl-Heinz Ott
IPC分类号： C08F2/26 , C08F291/02 , C08L27/06
CPC分类号： C08F291/02 , C08F2/26 , C08L27/06
摘要： Thermoplastic molding compositions of a vinyl chloride polymer and one or more emulsion polymers made with special emulsifiers have improved properties for technical application, such as reduced fogging. They are used for the production of molded articles, sheet products and films.
摘要翻译：氯乙烯聚合物和由特殊乳化剂制成的一种或多种乳液聚合物的热塑性模塑组合物具有改进的技术应用性能，例如减少雾化。它们用于生产模制品，片材和薄膜。

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