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    • 34. 发明授权
    • Mixtures with special softening agents suited as a solid electrolyte or separator for electrochemical cells
    • 具有适合作为电解质电池的固体电解质或隔膜的特殊软化剂的混合物
    • US06642294B1
    • 2003-11-04
    • US09509690
    • 2000-07-17
    • Stephan BauerBernd BronstertHelmut MöhwaldHans-Josef SterzelWerner Hesse
    • Stephan BauerBernd BronstertHelmut MöhwaldHans-Josef SterzelWerner Hesse
    • C08K318
    • H01G9/025A01N59/16C08J5/2256C08J2381/06C08J2385/02C08K3/01C08K5/0016H01G9/02H01M2/1653H01M10/052H01M10/0525H01M10/0565A01N2300/00
    • A mixture Ia comprises a mix IIa composed of a) from 1 to 95% by weight of a solid III, preferably a basic solid III, with a primary particle size of from 5 nm to 20 &mgr;m and b) from 5 to 99% by weight of a polymeric composition IV, obtainable by polymerizing b1) from 5 to 100% by weight, based on the composition IV, of a condensation product V of &agr;) at least one compound VI which is capable of reacting with a carboxylic acid or with a sulfonic acid or with a derivative or a iixture of two or more of these, and &bgr;) at least 1 mol per mole of the compound VI of a carboxylic acid or sulfonic acid VII which has at least one functional group capable of free-radical polymerization, or of a derivative thereof or of a mixture of two or more thereof and b2) from 0 to 95% by weight, based on the composition IV, of another compound VIII with an average molecular weight (number average) of at least 5000 having polyether segments in its main or side chain and at least one ester of the formula (E1) to (E5) where each of R1, R2, R3 and R4 is identical with or different from the others and, independently of the others, is linear or branched-chain C1-C4-alkyl (—CH2—CH2—O)n—CH3, where n is from 1 to 3, C3-C6-cycloalkyl or an aromatic hydrocarbon group which may in turn be substituted, with the proviso that at least one of the groups R1, R2, R3 or R4 is (—CH2—CH2—O)n—CH3, where n is from 1 to 3.
    • 混合物Ia包含由以下组成的混合物IIa:a)1至95重量%的固体III,优选碱性固体III,一次粒径为5nm至20μm,和b)5至99重量%的 聚合物组合物IV,其可通过以下方式获得:b)基于组合物IV的5至100重量%的α的缩合产物V至少一种能够与羧酸或与磺酸反应的化合物VI,或 或其中两种或更多种的衍生物或混合物,和β)至少1摩尔每摩尔具有至少一个能够自由基聚合的官能团的羧酸或磺酸VII的化合物VI,或 衍生物或其两种或多种的混合物和b2)0至95重量%,基于组合物IV,另一种平均分子量(数均)至少为5000的化合物VIII在其主体中具有聚醚链段 或侧链和至少一个式(E1)的酯, 至(E5)其中R 1,R 2,R 3和R 4各自与其它基团相同或不同,并且独立地为直链或支链C1-C4 - 烷基(-CH 2 -CH 2 -O)n -CH 3,其中n为1至3,可以被取代的C 3 -C 6环烷基或芳族烃基,条件是基团R R 1,R 3,R 3或R 4为(-CH 2 -CH 2 -O)n -CH 3,其中n为1至3。
    • 36. 发明授权
    • Polymers suitable as dispersing resins
    • US6008303A
    • 1999-12-28
    • US101687
    • 1998-07-15
    • Franz WeingartWolfgang PaulusStephan Bauer
    • Franz WeingartWolfgang PaulusStephan Bauer
    • C08F291/00B01F17/52C08F257/00C08F259/04C08F263/02C08F265/04C09B67/46C09D17/00C08F14/00
    • C09D17/002C08F257/00C08F259/04C08F263/02C08F265/04C09B67/0085
    • Polymers I suitable as dispersing resins are obtained by reactingA. a polymer II obtained by reacting at least one compound III selected from the group consisting ofa) an ester IV ofa1) an .alpha.,.beta.-unsaturated carboxylic acid V anda2) an alkyl alcohol VI of 1 to 25 carbon atoms,b) an ester VII ofb1) vinyl alcohol andb2) a saturated carboxylic acid VIII of 1 to 4 carbon atoms,c) vinyl chlorided) styrene or vinyl benzenes which carry an alkyl group of 1 to 4 carbon atoms on the benzene ring, in the presence of a compound IX which contains an N-oxyl radical function, withB. at least one compound X comprisinga) 50 to 100% by weight, based on X, of at least one compound XI selected from the group consisting ofa1) an ester XII ofa) an .alpha.,.beta.-unsaturated carboxylic acid XIII andb) an alkyl alcohol XIV of 2 to 10 carbon atoms which carries at least one polar or acidic group,a2) an amide XV ofa) an .alpha.,.beta.-unsaturated carboxylic acid XVI andb) ammonia or an amine XVII of 2 to 10 carbon atoms which carries at least one polar or acidic group,a3) N-vinyl compounds XVIII,a4) styrene sulfonic acid or vinylbenzenesulfonic acid which carries an alkyl group of 1 to 4 carbon atoms on the ring, andb) from 0 to 50% by weight based on X, of at least one compound XIX selected from the group consisting ofb1) an ester XX ofa) an .alpha.,.beta.-unsaturated carboxylic acid XXI andb) an alkyl alcohol XXII of 1 to 25 carbon atoms,b2) an ester XXIII ofa) vinyl alcohol andb) a saturated carboxylic acid XXIV of 1 to 4 carbon atoms,b3) vinyl chloride,b4) styrene or vinylbenzenes, which carry an alkyl group of 1 to 4 carbon atoms on the benzene ring, in the presence of a compound XXV which contains an N-oxyl radical function,polymer I containing from 10 to 90% by weight of II and in total from 10 to 90% by weight of X.The polymer may be used as dispersing resins for pigment-containing coatings.