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    • 32. 发明授权
    • Herbicidal cyclohexane-1,3-dione derivatives
    • 除草环己烷-1,3-二酮衍生物
    • US4639267A
    • 1987-01-27
    • US774526
    • 1985-09-10
    • Graeme J. FarquharsonKeith G. WatsonGraham J. Bird
    • Graeme J. FarquharsonKeith G. WatsonGraham J. Bird
    • A01N35/10A01N37/34A01N37/42C07C45/45C07C45/46C07C49/755C07C67/00C07C239/00C07C251/44C07C313/00C07C323/12C07C323/47C07C323/63C07C131/00
    • C07C49/755A01N35/10C07C45/45C07C45/455C07C45/46
    • The invention concerns novel compounds of the formula I and isomers thereof ##STR1## wherein: n is an integer selected from 2 to 4;m is zero or an integer selected from 1 to 3;X, which may be the same or different, are independently selected from halogen, alkyl, alkoxy and alkylthio;R.sup.1 is selected from hydrogen, acyl and an inorganic or organic cation;R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl; andR.sup.4 is selected from hydrogen, halogen, alkyl, cyano and alkoxycarbonyl.The compounds of the invention show herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of the compounds of the formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.
    • 本发明涉及式I的新化合物及其异构体,其中:n是选自2至4的整数; m为0或选自1至3的整数; X可以相同或不同,独立地选自卤素,烷基,烷氧基和烷硫基; R1选自氢,酰基和无机或有机阳离子; R2选自烷基,取代的烷基,烯基,卤代烯基,炔基和卤代炔基; R3选自烷基,氟烷基,烯基,炔基和苯基; 并且R 4选自氢,卤素,烷基,氰基和烷氧基羰基。 本发明的化合物显示除草性质和植物生长调节性质,并且在进一步的实施方案中,本发明提供了制备式I化合物的方法,可用于制备式I化合物的中间体,作为活性成分的化合物 的式I化合物,以及利用式I化合物的除草和植物生长调节方法。
    • 33. 发明授权
    • Herbicidal cyclohexane-1,3-dione derivatives
    • 除草环己烷-1,3-二酮衍生物
    • US4555263A
    • 1985-11-26
    • US447137
    • 1982-12-06
    • Alexander SerbanKeith G. WatsonGraham J. BirdGraeme J. FarquharsonTimothy L. Houston
    • Alexander SerbanKeith G. WatsonGraham J. BirdGraeme J. FarquharsonTimothy L. Houston
    • A01N39/00A01N35/10A01N37/38A01N41/04A01N41/06C07C67/00C07C313/00C07C319/20C07C323/47A01N33/24C07C131/00
    • C07C323/00A01N35/10A01N41/06
    • The invention concerns novel compounds of the formula I ##STR1## wherein: R.sup.1 is selected from alkyl, alkenyl, alkynyl, cycloalkyl benzyl and substituted benzyl;A is selected from hydrogen, halogen, nitro, alkyl, alkoxy, alkylthio, alkenylthio, alkynylthio, cycloalkoxy, cycloalkylthio, sulfamoyl, N-(C.sub.1 to C.sub.6 alkyl)sulfamoyl, N,N-di(C.sub.1 to C.sub.6 alkyl)sulfamoyl, benzylthio and substituted benzylthio;R.sup.2 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, acyl, alkylsulfonyl, benzenesulfonyl, substituted benzenesulfonyl, and an inorganic or organic cation;R.sup.3 is selected from alkyl, alkenyl, alkynyl, substituted alkyl, haloalkenyl and haloalkynyl; andR.sup.4 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl and phenyl.The compounds are herbicides and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of compounds of formula I, herbicidal compositions containing as active ingredient a compound of formula I, and processes for severely damaging or killing unwanted plants by applying to the plants or to the growth medium of the plants an effective amount of a compound of formula I.
    • 本发明涉及式I的新型化合物其中:R1选自烷基,烯基,炔基,环烷基苄基和取代的苄基; A选自氢,卤素,硝基,烷基,烷氧基,烷硫基,烯硫基,炔硫基,环烷氧基,环烷硫基,氨磺酰基,N-(C1至C6烷基)氨磺酰基,N,N-二(C1至C6烷基)氨磺酰基, 和取代的苄硫基; R 2选自氢,烷基,烯基,炔基,取代的烷基,酰基,烷基磺酰基,苯磺酰基,取代的苯磺酰基和无机或有机阳离子; R 3选自烷基,烯基,炔基,取代的烷基,卤代烯基和卤代炔基; 并且R 4选自烷基,氟烷基,烯基,炔基和苯基。 化合物是除草剂,并且在进一步的实施方案中,本发明提供了制备式I化合物的方法,可用于制备式I化合物的中间体,含有作为活性成分的式I化合物的除草组合物,以及用于严重破坏或 通过向植物或植物的生长培养基施用有效量的式I化合物来杀死不想要的植物。
    • 35. 发明授权
    • Herbicidal compounds and compositions
    • 除草剂及组合物
    • US5110989A
    • 1992-05-05
    • US553413
    • 1990-07-17
    • Alexander SerbanKeith G. WatsonGraham J. BirdGraeme J. FarquharsonLinsay E. Cross
    • Alexander SerbanKeith G. WatsonGraham J. BirdGraeme J. FarquharsonLinsay E. Cross
    • C07C1/22C07C17/00C07C45/45C07C45/46C07C45/65C07C45/67C07C45/74C07C47/546C07C47/55C07C47/575C07C49/657C07C49/697C07C49/747C07C49/753C07C49/835
    • C07C1/22C07C17/35C07C45/455C07C45/46C07C45/65C07C45/673C07C45/74C07C47/546C07C47/55C07C47/575C07C49/657C07C49/697C07C49/747C07C49/753C07C49/835C07C2102/08
    • The invention concerns novel compounds of the formula I ##STR1## wherein: W are selected from alkyl, alkenyl and alkynyl;X are selected from halogen, nitro, cyano, alkyl, substituted alkyl, hydroxy, alkoxy, substituted alkoxy, alkenyl, alkynyl, alkenyloxy, alkynyloxy, acyloxy, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, sulfamoyl, substituted sulfamoyl, amino, substituted amino, and the groups formyl and alkanoyl and the oxime, imine and Schiff base derivatives thereof, and an alkylene group which bridges two adjacent carbon atoms of the benzene ring;R.sup.1 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, alkylsulfonyl, arylsulfonyl, acyl and an inorganic or organic cation;R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl;p is zero or an integer selected from 1 to 4;n is zero or an integer selected from 1 to 3; andm is zero or an integer selected from 1 to 3.The compounds of the invention show cereal selective herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of the compounds of formula I, intermediates useful in the preparation of the compounds of formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.
    • 本发明涉及式I的新型化合物其中:W选自烷基,烯基和炔基; X选自卤素,硝基,氰基,烷基,取代的烷基,羟基,烷氧基,取代的烷氧基,烯基,炔基,烯氧基,炔氧基,酰氧基,烷氧基羰基,烷硫基,烷基亚磺酰基,烷基磺酰基,氨磺酰基,取代氨磺酰基,氨基,取代的氨基, 和甲酰基和烷酰基以及其肟,亚胺和席夫碱衍生物和桥接苯环的两个相邻碳原子的亚烷基; R 1选自氢,烷基,烯基,炔基,取代的烷基,烷基磺酰基,芳基磺酰基,酰基和无机或有机阳离子; R2选自烷基,取代的烷基,烯基,卤代烯基,炔基和卤代炔基; R3选自烷基,氟烷基,烯基,炔基和苯基; p为零或选自1至4的整数; n为0或选自1至3的整数; 本发明的化合物显示谷物选择性除草性质和植物生长调节性质,并且在进一步的实施方案中,本发明提供了制备式I化合物的方法,可用于 式I化合物的制备,含有式I化合物作为活性成分的组合物,以及利用式I化合物的除草和植物生长调节方法。
    • 37. 发明授权
    • Process for the synthesis of phenoxyalkane derivatives
    • 合成苯氧基烷烃衍生物的方法
    • US4837355A
    • 1989-06-06
    • US367229
    • 1982-03-31
    • Keith G. Watson
    • Keith G. Watson
    • C07C59/68C07C69/734C07C69/736C07C255/53
    • C07C59/68C07C303/24
    • The invention concerns a process for the synthesis of a compound of formula I ##STR1## wherein: U and V may be chosen from a range of substituents including hydrogen, halogen, alkyl and alkoxy; R.sup.1 and R.sup.2 may be chosen from a range of substituents including hydrogen and alkyl; n is 0, 1 or 2; and W may be chosen from a range of substitutents including the group ##STR2## which may be a free carboxylic acid or derivative thereof; the process comprising reacting a sulfate ester of formula II, wherein Q is a cation, with a compound of formula III, wherein L is a leaving group ##STR3## and hydrolyzing the sulfate ester formed. Preferably the sulfate ester of formula II is prepared by the oxidation of a phenol of formula IV with a persulfate. ##STR4##
    • PCT No.PCT / AU81 / 00101 Sec。 371日期1982年3月31日 102(e)1982年3月31日PCT PCT 1991年7月31日PCT公布。 公开号WO82 / 00639 日本公报1982年3月4日。本发明涉及一种合成式I化合物的方法,其中:U和V可以选自包括氢,卤素,烷基和烷氧基的一系列取代基; R 1和R 2可以选自包括氢和烷基在内的一系列取代基; n为0,1或2; 并且W可以从包括可以是游离羧酸或其衍生物的组的一系列取代基中选择; 该方法包括使式II的硫酸酯(其中Q是阳离子)与式III化合物反应,其中L是离去基团II,并水解形成的硫酸酯。 优选地,式II的硫酸酯通过用过硫酸盐氧化式IV的酚来制备。 IV
    • 38. 发明授权
    • 2-quinoxalinyloxy phenoxy compounds
    • 2-喹喔啉氧基苯氧基化合物
    • US4803273A
    • 1989-02-07
    • US939694
    • 1986-12-09
    • Alexander SerbanKeith G. WatsonGrame J. Farquharson
    • Alexander SerbanKeith G. WatsonGrame J. Farquharson
    • A01N43/60C07C59/68C07D241/44C07D241/52A01N43/06
    • C07D241/52A01N43/60C07C59/68C07D241/44
    • The invention concerns novel compounds of the formula I ##STR1## wherein: D and U are independently chosen from halogen, methyl and halomethyl;G is chosen from hydroxy, alkoxy, alkenyloxy, alkynyloxy, alkylthio, alkenylthio, alkynylthio, cycloalkoxy and the group OM wherein M is an alkali metal or alkaline earth metal ion; andk and l are independently chosen from 0 and 1.The compounds are herbicides and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of compounds of formula I, herbicidal compositions containing as active ingredient a compound of formula I, and processes for severely damaging or killing unwanted plants by applying to the plants or to the growth medium of the plants and effective amount of a compound of formula I. Intermediates for making the compounds I wherein the group ##STR2## is replaced by hydroxy or C.sub.1 to C.sub.6 alkoxy are included.
    • 本发明涉及式I的新型化合物其中:D和U独立地选自卤素,甲基和卤代甲基; G选自羟基,烷氧基,烯氧基,炔氧基,烷硫基,烯硫基,炔硫基,环烷氧基和基团OM,其中M是碱金属或碱土金属离子; 并且k和l独立地选自0和1.化合物是除草剂,并且在进一步的实施方案中,本发明提供了制备式I化合物的方法,可用于制备式I化合物的中间体,含有作为活性成分的除草组合物 式I的化合物,以及通过施用于植物或植物的生长培养基而严重损害或杀死有害植物的方法和有效量的式I化合物。用于制备化合物I的中间体,其中基团 被羟基取代或包括C1-C6烷氧基。
    • 39. 发明授权
    • Herbicidal bis(cyclohexane-1,3-dione)derivatives
    • 除草双(环己烷-1,3-二酮)衍生物
    • US4746350A
    • 1988-05-24
    • US851150
    • 1986-04-14
    • Keith G. Watson
    • Keith G. Watson
    • C07D333/28A01N35/10A01N37/22A01N37/24A01N37/36A01N37/50A01N41/06A01N43/10C07C67/00C07C239/00C07C251/44C07C301/00C07C303/40C07C311/29C07C313/00C07C323/47C07C325/00C07C327/26C07D207/32C07D207/335C07D207/337C07D207/34C07D307/52C07D333/22A01N43/00
    • C07D207/335A01N35/10A01N37/50A01N41/06A01N43/10C07D307/52C07D333/22
    • The invention concerns novel compounds of the formula I ##STR1## wherein: Y is selected from phenyl, furyl, thienyl and pyrrolyl rings (each optionally substituted by group X), optionally branched alkylene or alkylenethio(oxy)alkylene;X which may be the same or different are independently selected from halogen, nitro, alkyl, substituted alkyl, hydroxy, alkoxy, carboxy, alkoxycarbonyl, alkylthio, sulfamoyl, substituted sulfamoyl, amino, substituted amino and alkanoyl;R.sup.1 is selected from hydrogen, acyl and an inorganic or organic cation;R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl and alkynyl;R.sup.3 is selected from alkyl; andR.sup.4 is selected from hydrogen, alkyl, and alkoxycarbonyl.The compounds of the invention show herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of the compounds of formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.
    • 本发明涉及式I的新型化合物其中:Y选自苯基,呋喃基,噻吩基和吡咯基环(各自任选被X基团取代),任选支链亚烷基或亚烷基硫代(氧基)亚烷基; 可以相同或不同的X独立地选自卤素,硝基,烷基,取代的烷基,羟基,烷氧基,羧基,烷氧基羰基,烷硫基,氨磺酰基,取代的氨磺酰基,氨基,取代的氨基和烷酰基。 R1选自氢,酰基和无机或有机阳离子; R 2选自烷基,取代的烷基,烯基,卤代烯基和炔基; R3选自烷基; 并且R 4选自氢,烷基和烷氧基羰基。 本发明的化合物显示除草性质和植物生长调节性质,并且在进一步的实施方案中,本发明提供了制备式I化合物的方法,可用于制备式I化合物的中间体,作为活性成分的化合物 式I,以及利用式I化合物的除草和植物生长调节方法。