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1. 发明授权

US4555263A Herbicidal cyclohexane-1,3-dione derivatives 失效
标题翻译：除草环己烷-1,3-二酮衍生物
公开(公告)号：US4555263A
公开(公告)日：1985-11-26
申请号：US447137
申请日：1982-12-06
申请人： Alexander Serban , Keith G. Watson , Graham J. Bird , Graeme J. Farquharson , Timothy L. Houston
发明人： Alexander Serban , Keith G. Watson , Graham J. Bird , Graeme J. Farquharson , Timothy L. Houston
IPC分类号： A01N39/00 , A01N35/10 , A01N37/38 , A01N41/04 , A01N41/06 , C07C67/00 , C07C313/00 , C07C319/20 , C07C323/47 , A01N33/24 , C07C131/00
CPC分类号： C07C323/00 , A01N35/10 , A01N41/06
摘要： The invention concerns novel compounds of the formula I ##STR1## wherein: R.sup.1 is selected from alkyl, alkenyl, alkynyl, cycloalkyl benzyl and substituted benzyl;A is selected from hydrogen, halogen, nitro, alkyl, alkoxy, alkylthio, alkenylthio, alkynylthio, cycloalkoxy, cycloalkylthio, sulfamoyl, N-(C.sub.1 to C.sub.6 alkyl)sulfamoyl, N,N-di(C.sub.1 to C.sub.6 alkyl)sulfamoyl, benzylthio and substituted benzylthio;R.sup.2 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, acyl, alkylsulfonyl, benzenesulfonyl, substituted benzenesulfonyl, and an inorganic or organic cation;R.sup.3 is selected from alkyl, alkenyl, alkynyl, substituted alkyl, haloalkenyl and haloalkynyl; andR.sup.4 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl and phenyl.The compounds are herbicides and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of compounds of formula I, herbicidal compositions containing as active ingredient a compound of formula I, and processes for severely damaging or killing unwanted plants by applying to the plants or to the growth medium of the plants an effective amount of a compound of formula I.
摘要翻译：本发明涉及式I的新型化合物其中：R1选自烷基，烯基，炔基，环烷基苄基和取代的苄基; A选自氢，卤素，硝基，烷基，烷氧基，烷硫基，烯硫基，炔硫基，环烷氧基，环烷硫基，氨磺酰基，N-（C1至C6烷基）氨磺酰基，N，N-二（C1至C6烷基）氨磺酰基，和取代的苄硫基; R 2选自氢，烷基，烯基，炔基，取代的烷基，酰基，烷基磺酰基，苯磺酰基，取代的苯磺酰基和无机或有机阳离子; R 3选自烷基，烯基，炔基，取代的烷基，卤代烯基和卤代炔基; 并且R 4选自烷基，氟烷基，烯基，炔基和苯基。化合物是除草剂，并且在进一步的实施方案中，本发明提供了制备式I化合物的方法，可用于制备式I化合物的中间体，含有作为活性成分的式I化合物的除草组合物，以及用于严重破坏或通过向植物或植物的生长培养基施用有效量的式I化合物来杀死不想要的植物。

2. 发明授权

US5110989A Herbicidal compounds and compositions 失效
标题翻译：除草剂及组合物
公开(公告)号：US5110989A
公开(公告)日：1992-05-05
申请号：US553413
申请日：1990-07-17
申请人： Alexander Serban , Keith G. Watson , Graham J. Bird , Graeme J. Farquharson , Linsay E. Cross
发明人： Alexander Serban , Keith G. Watson , Graham J. Bird , Graeme J. Farquharson , Linsay E. Cross
IPC分类号： C07C1/22 , C07C17/00 , C07C45/45 , C07C45/46 , C07C45/65 , C07C45/67 , C07C45/74 , C07C47/546 , C07C47/55 , C07C47/575 , C07C49/657 , C07C49/697 , C07C49/747 , C07C49/753 , C07C49/835
CPC分类号： C07C1/22 , C07C17/35 , C07C45/455 , C07C45/46 , C07C45/65 , C07C45/673 , C07C45/74 , C07C47/546 , C07C47/55 , C07C47/575 , C07C49/657 , C07C49/697 , C07C49/747 , C07C49/753 , C07C49/835 , C07C2102/08
摘要： The invention concerns novel compounds of the formula I ##STR1## wherein: W are selected from alkyl, alkenyl and alkynyl;X are selected from halogen, nitro, cyano, alkyl, substituted alkyl, hydroxy, alkoxy, substituted alkoxy, alkenyl, alkynyl, alkenyloxy, alkynyloxy, acyloxy, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, sulfamoyl, substituted sulfamoyl, amino, substituted amino, and the groups formyl and alkanoyl and the oxime, imine and Schiff base derivatives thereof, and an alkylene group which bridges two adjacent carbon atoms of the benzene ring;R.sup.1 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, alkylsulfonyl, arylsulfonyl, acyl and an inorganic or organic cation;R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl;p is zero or an integer selected from 1 to 4;n is zero or an integer selected from 1 to 3; andm is zero or an integer selected from 1 to 3.The compounds of the invention show cereal selective herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of the compounds of formula I, intermediates useful in the preparation of the compounds of formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.
摘要翻译：本发明涉及式I的新型化合物其中：W选自烷基，烯基和炔基; X选自卤素，硝基，氰基，烷基，取代的烷基，羟基，烷氧基，取代的烷氧基，烯基，炔基，烯氧基，炔氧基，酰氧基，烷氧基羰基，烷硫基，烷基亚磺酰基，烷基磺酰基，氨磺酰基，取代氨磺酰基，氨基，取代的氨基，和甲酰基和烷酰基以及其肟，亚胺和席夫碱衍生物和桥接苯环的两个相邻碳原子的亚烷基; R 1选自氢，烷基，烯基，炔基，取代的烷基，烷基磺酰基，芳基磺酰基，酰基和无机或有机阳离子; R2选自烷基，取代的烷基，烯基，卤代烯基，炔基和卤代炔基; R3选自烷基，氟烷基，烯基，炔基和苯基; p为零或选自1至4的整数; n为0或选自1至3的整数; 本发明的化合物显示谷物选择性除草性质和植物生长调节性质，并且在进一步的实施方案中，本发明提供了制备式I化合物的方法，可用于式I化合物的制备，含有式I化合物作为活性成分的组合物，以及利用式I化合物的除草和植物生长调节方法。

3. 发明授权

US4952722A Compounds and compositions 失效
标题翻译：化合物和组合物
公开(公告)号：US4952722A
公开(公告)日：1990-08-28
申请号：US461003
申请日：1983-01-26
申请人： Alexander Serban , Keith G. Watson , Graham J. Bird , Graeme J. Farquharson , Lindsay E. Cross
发明人： Alexander Serban , Keith G. Watson , Graham J. Bird , Graeme J. Farquharson , Lindsay E. Cross
IPC分类号： A01N35/06 , A01N35/10 , A01N37/10 , A01N37/48 , A01N37/50 , A01N41/04 , A01N41/06 , C07C1/22 , C07C17/00 , C07C45/00 , C07C45/45 , C07C45/46 , C07C45/65 , C07C45/67 , C07C45/74 , C07C47/546 , C07C47/55 , C07C47/575 , C07C49/657 , C07C49/697 , C07C49/747 , C07C49/753 , C07C49/835 , C07C67/00 , C07C205/46 , C07C239/00 , C07C251/42 , C07C251/44 , C07C251/48 , C07C251/52 , C07C255/56 , C07C301/00 , C07C303/28 , C07C303/40 , C07C309/63 , C07C309/73 , C07C311/16 , C07C311/37 , C07C313/00 , C07C315/04 , C07C317/32 , C07C317/36 , C07C317/46 , C07C323/12 , C07C323/47
CPC分类号： C07C1/22 , C07C17/35 , C07C45/455 , C07C45/46 , C07C45/65 , C07C45/673 , C07C45/74 , C07C47/546 , C07C47/55 , C07C47/575 , C07C49/657 , C07C49/697 , C07C49/747 , C07C49/753 , C07C49/835 , C07C2102/08
摘要： The invention concerns novel compounds of the formula I ##STR1## wherein: W are selected from alkyl, alkenyl and alkynyl;X are selected from halogen, nitro, cyano, alkyl, substituted alkyl, hydroxy, alkoxy, substituted alkoxy, alkenyl, alkynyl, alkenyloxy, alkynyloxy, acyloxy, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, sulfamoyl, substituted sulfamoyl, amino, substituted amino, and the groups formyl and alkanoyl and the oxime and imine derivatives thereof, and an alkylene group which bridges two adjacent carbon atoms of the benzene ring;R.sup.1 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, alkylsulfonyl, arylsulfonyl, acyl and an inorganic or organic cation;R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl;p is zero or an integer selected form 1 to 4;n is zero or an integer selected from 1 to 3; andm is zero or an integer selected from 1 to 3.The compounds of the invention show cereal selective herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of the compounds of formula I, intermediates useful in the preparation of the compounds of formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.
摘要翻译：本发明涉及式I的新型化合物其中：W选自烷基，烯基和炔基; X选自卤素，硝基，氰基，烷基，取代的烷基，羟基，烷氧基，取代的烷氧基，烯基，炔基，烯氧基，炔氧基，酰氧基，烷氧基羰基，烷硫基，烷基亚磺酰基，烷基磺酰基，氨磺酰基，取代氨磺酰基，氨基，取代的氨基，并且甲酰基和烷酰基及其肟和亚胺衍生物和桥接苯环的两个相邻碳原子的亚烷基; R 1选自氢，烷基，烯基，炔基，取代的烷基，烷基磺酰基，芳基磺酰基，酰基和无机或有机阳离子; R2选自烷基，取代的烷基，烯基，卤代烯基，炔基和卤代炔基; R3选自烷基，氟烷基，烯基，炔基和苯基; p为零或选自1至4的整数; n为0或选自1至3的整数; 本发明的化合物显示谷物选择性除草性质和植物生长调节性质，并且在进一步的实施方案中，本发明提供了制备式I化合物的方法，可用于式I化合物的制备，含有式I化合物作为活性成分的组合物，以及利用式I化合物的除草和植物生长调节方法。

4. 发明授权

US4511391A Cyclohexane-1,3-dione derivatives and their herbicidal compositions and methods 失效
标题翻译：环己烷-1,3-二酮衍生物及其除草组合物和方法
公开(公告)号：US4511391A
公开(公告)日：1985-04-16
申请号：US497683
申请日：1983-05-24
申请人： Alexander Serban , Keith G. Watson , Graham J. Bird , Graeme J. Farquharson
发明人： Alexander Serban , Keith G. Watson , Graham J. Bird , Graeme J. Farquharson
IPC分类号： A01N43/12 , A01N43/30 , A01N43/32 , C07D307/79 , C07D317/54 , C07D317/58 , C07D317/62 , C07D319/18 , C07D307/78
CPC分类号： C07D307/79 , A01N43/12 , A01N43/30 , A01N43/32 , C07D317/54 , C07D317/58 , C07D317/62 , C07D319/18
摘要： The invention concerns novel compounds of the formula I ##STR1## wherein: X is selected from halogen, nitro, cyano, alkyl, substituted alkyl, alkenyl, alkynyl, hydroxy, alkoxy, substituted alkoxy, alkenyloxy, alkynyloxy, alkanoyloxy, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, sulfamoyl, substituted sulfamoyl, benzyloxy, substituted benzyloxy, amino, substituted amino, and the groups formyl and alkanoyl and the oxime, imine and Schiff base derivatives thereof;Y and Z are independently selected from methylene, oxygen and sulfur provided that at least one of Y and Z is selected from oxygen and sulfur;R.sup.1 is selected from hydrogen, alkyl, alkenyl alkynyl, substituted alkyl, acyl, alkylsulfonyl, benzenesulfonyl, substituted benzenesulfonyl, and an inorganic or organic cation;R.sup.2 is selected from alkyl, alkenyl, alkynyl, substituted alkyl, haloalkenyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl and phenyl;R.sup.4 is selected from hydrogen, halogen, cyano, C.sub.1 to C.sub.6 alkyl and (C.sub.1 to C.sub.6 alkoxy)carbonyl;n is an integer selected from 1 to 3; andm is zero or an integer selected from 1 to 3.The compounds are cereal selective herbicides and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of compounds of formula I, intermediates useful in the preparation of compounds of formula I, herbicidal compositions containing as active ingredient a compound of formula I, and processes for severely damaging or killing unwanted plants by applying to the plants or to the growth medium of the plants an effective amount of a compound of formula I.
摘要翻译：本发明涉及式I的新化合物其中：X选自卤素，硝基，氰基，烷基，取代的烷基，烯基，炔基，羟基，烷氧基，取代的烷氧基，烯氧基，炔氧基，烷酰氧基，烷氧基羰基，烷硫基烷基亚磺酰基，烷基磺酰基，氨磺酰基，取代的氨磺酰基，苄氧基，取代的苄氧基，氨基，取代的氨基，以及甲酰基和烷酰基及其肟，亚胺和席夫碱衍生物; Y和Z独立地选自亚甲基，氧和硫，条件是Y和Z中的至少一个选自氧和硫; R 1选自氢，烷基，烯基炔基，取代的烷基，酰基，烷基磺酰基，苯磺酰基，取代的苯磺酰基和无机或有机阳离子; R2选自烷基，烯基，炔基，取代的烷基，卤代烯基和卤代炔基; R3选自烷基，氟烷基，烯基，炔基和苯基; R 4选自氢，卤素，氰基，C 1至C 6烷基和（C 1至C 6烷氧基）羰基; n是选自1至3的整数; 并且m为0或选自1至3的整数。化合物是谷物选择性除草剂，并且在进一步的实施方案中，本发明提供了制备式I化合物的方法，可用于制备式I化合物的中间体，式I化合物的制备，含有作为活性成分的式I化合物的除草组合物，以及通过向植物或植物的生长培养基施用有效量的式（I）化合物而严重损害或杀死有害植物的方法，一世。

5. 发明授权

US4717418A Herbicidal cyclohexane-1,3-dione derivatives 失效
标题翻译：除草环己烷-1,3-二酮衍生物
公开(公告)号：US4717418A
公开(公告)日：1988-01-05
申请号：US440592
申请日：1982-11-10
申请人： Richard B. Warner , Alexander Serban , Keith G. Watson , Graham J. Bird , Lindsay E. Cross , Graeme J. Farquharson
发明人： Richard B. Warner , Alexander Serban , Keith G. Watson , Graham J. Bird , Lindsay E. Cross , Graeme J. Farquharson
IPC分类号： A01N35/10 , A01N37/02 , A01N37/10 , C07C45/00 , C07C45/45 , C07C45/64 , C07C45/67 , C07C49/217 , C07C49/657 , C07C49/747 , C07C49/835 , C07C67/00 , C07C239/00 , C07C249/08 , C07C251/42 , C07C251/44 , C07C251/48 , C07C251/50 , C07C251/52 , C07C261/02 , C07C309/73 , C07C313/00 , C07C323/12 , C07C323/19 , C07C323/20 , C07C323/66 , A01N31/04 , A01N33/08 , C07C83/00 , C07C131/00
CPC分类号： C07C49/835 , A01N35/10 , A01N37/02 , A01N37/10 , C07C45/455 , C07C45/64 , C07C45/673 , C07C49/217 , C07C49/657 , C07C49/747
摘要： The invention concerns novel compounds of the formula I ##STR1## wherein R.sup.1 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, acyl, alkylsulfonyl, benzenesulfonyl, substituted benzenesulfonyl, and an inorganic or organic cation;R.sup.2 is selected from alkyl, alkenyl, alkynyl, substituted alkyl, haloalkenyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl and phenyl; andn is an integer chosen from 2 to 5.The compounds are cereal selective herbicides and in further embodiments of the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of compounds of formula I, herbicidal compositions containing as active ingredient a compound of formula I, and processes for severely damaging or killing unwanted plants by applying to the plants or to the growth medium of the plants an effective amount of a compound of formula I.
摘要翻译：本发明涉及式I的新化合物，其中R 1选自氢，烷基，烯基，炔基，取代的烷基，酰基，烷基磺酰基，苯磺酰基，取代的苯磺酰基和无机或有机阳离子; R2选自烷基，烯基，炔基，取代的烷基，卤代烯基和卤代炔基; R3选自烷基，氟烷基，烯基，炔基和苯基; 并且n是选自2至5的整数。化合物是谷类选择性除草剂，并且在本发明的其它实施方案中提供了制备式I化合物的方法，可用于制备式I化合物的中间体，含有活性成分是式I化合物，以及通过向植物或植物的生长培养基施加有效量的式I化合物来严重损害或杀死有害植物的方法。

6. 发明授权

US4643763A Herbicidal cyclohexane-1,3-dione derivatives 失效
标题翻译：除草环己烷-1,3-二酮衍生物
公开(公告)号：US4643763A
公开(公告)日：1987-02-17
申请号：US774527
申请日：1985-09-10
申请人： Graeme J. Farquharson , Keith G. Watson , Graham J. Bird
发明人： Graeme J. Farquharson , Keith G. Watson , Graham J. Bird
IPC分类号： A01N47/34 , A01N35/10 , A01N37/08 , A01N37/10 , A01N37/34 , A01N37/50 , A01N41/06 , A01N45/02 , A01N47/30 , C07C45/31 , C07C67/00 , C07C239/00 , C07C251/42 , C07C251/44 , C07C251/52 , C07C291/12 , C07C301/00 , C07C303/40 , C07C311/29 , C07C313/00 , C07C319/20 , C07C323/47 , C07C325/00 , C07C327/12 , C07C327/16 , C07C335/18 , C07C381/00 , A01N31/08 , A01N33/04 , C07C131/00
CPC分类号： C07C251/52 , A01N35/10 , A01N37/08 , A01N37/10 , A01N41/06 , A01N45/02 , A01N47/30 , C07C251/42 , C07C45/31 , C07C2103/94
摘要： The invention concerns novel compounds of the formula I ##STR1## wherein: m is an integer selected from 1 to 4;n is zero or an integer selected from 1 to 4;x are selected from halogen, nitro, cyano, alkyl, substituted alkyl, hydroxy, alkoxy, alkylthio, sulfamoyl, substituted sulfamoyl, amino, substituted amino, the group --(CH.sub.2).sub.p C(.dbd.A)Z in which p is zero or one A is oxygen or sulfur, and Z is hydrogen, hydroxy, alkoxy, alkylthio, alkyl, substituted alkyl, amino or substituted amino; the group --NHC(.dbd.B(NR.sup.7 R.sup.8 in which B is oxygen or sulfur and R.sup.7 and R.sup.8 are hydrogen or alkyl;R.sup.1 is selected from hydrogen, acyl and an inorganic or organic cation;R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl; andR.sup.4 is selected from hydrogen, halogen, alkyl, cyano and alkoxycarbonyl.The compounds of the invention show herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of the compounds of formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.
摘要翻译：本发明涉及式I的新型化合物其中：m是选自1至4的整数; n为0或选自1至4的整数; x选自卤素，硝基，氰基，烷基，取代的烷基，羟基，烷氧基，烷硫基，氨磺酰基，取代的氨磺酰基，氨基，取代的氨基，其中p为0或1的 - （CH 2）pC（= A） A是氧或硫，Z是氢，羟基，烷氧基，烷硫基，烷基，取代的烷基，氨基或取代的氨基; 基团-NHC（= B（NR7R8，其中B是氧或硫，R7和R8是氢或烷基; R1选自氢，酰基和无机或有机阳离子; R2选自烷基，取代的烷基，烯基，卤代烯基，炔基和卤代炔基; R3选自烷基，氟烷基，烯基，炔基和苯基; R4选自氢，卤素，烷基，氰基和烷氧基羰基，本发明化合物显示出除草性质和植物生长调节性质，在进一步的实施方案中，本发明提供了制备式I化合物的方法，可用于制备式I化合物的中间体，含有式I化合物作为活性成分的组合物，以及利用式I化合物的除草和植物生长调节方法一世。

7. 发明授权

US4640708A Herbicidal cyclohexane-1,3-dione derivatives 失效
标题翻译：除草环己烷-1,3-二酮衍生物
公开(公告)号：US4640708A
公开(公告)日：1987-02-03
申请号：US591372
申请日：1984-03-20
申请人： Graham J. Bird , Graeme J. Farquharson , Keith G. Watson
发明人： Graham J. Bird , Graeme J. Farquharson , Keith G. Watson
IPC分类号： A01N31/08 , A01N35/10 , A01N37/00 , A01N37/02 , A01N37/10 , A01N37/18 , A01N37/22 , A01N37/34 , A01N37/44 , A01N37/50 , A01N37/52 , A01N41/02 , A01N43/40 , A01N43/42 , A01N43/48 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/64 , A01N43/707 , A01N43/713 , A01N47/44 , C07C43/188 , C07C43/20 , C07C45/00 , C07C45/45 , C07C45/46 , C07C45/56 , C07C45/63 , C07C45/67 , C07C47/55 , C07C49/657 , C07C49/697 , C07C49/747 , C07C49/753 , C07C49/755 , C07C49/835 , C07C49/84 , C07C67/00 , C07C239/00 , C07C251/42 , C07C251/44 , C07C251/48 , C07C251/52 , C07C251/54 , C07C251/58 , C07C301/00 , C07C303/30 , C07C309/63 , C07C311/16 , C07C313/00 , C07C317/30 , C07C317/32 , C07C317/36 , C07C317/46 , C07C323/12 , C07C323/19 , C07C323/47 , C07C323/60 , C07C323/63 , C07D215/12 , C07D215/14 , C07D215/18 , C07D217/10 , C07D217/12 , C07D217/16 , C07D217/22 , C07D217/24 , C07D217/26 , A01N33/04 , C07C131/00
CPC分类号： C07D217/26 , A01N35/10 , A01N37/50 , A01N43/42 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/707 , C07C205/45 , C07C309/00 , C07C43/188 , C07C43/202 , C07C45/455 , C07C45/46 , C07C45/565 , C07C45/63 , C07C45/673 , C07C47/55 , C07C49/657 , C07C49/697 , C07C49/747 , C07C49/753 , C07C49/755 , C07C49/835 , C07D215/14 , C07D215/18 , C07D217/22 , C07D217/24
摘要： Compounds of the formula ##STR1## wherein: R.sup.5 is a bicyclic aryl or nitrogen-containing heteroaryl ring system such as naphthyl, quinolyl, isoquinolyl or tetrahydroisoquinolyl, optionally substituted by a wide variety of groups;R.sup.4 and R.sup.1 are preferably hydrogen but may be other groups andR.sup.2 and R.sup.3 are selected from alkyl, haloalkyl, alkenyl, haloalkenyl and alkynyl, show high general grass-killing activity with good selectivity to many broad-leaf crops and in some instances selectivity to small-grain cereals. Processes for the preparation of compounds of formula I, intermediates in the preparation of compounds I and the herbicidal properties of compounds I are described.
摘要翻译：式I的化合物其中：R 5是任选被多种基团取代的双环芳基或含氮杂芳环系统，例如萘基，喹啉基，异喹啉基或四氢异喹啉基; R4和R1优选为氢，但可以是其它基团，R2和R3选自烷基，卤代烷基，烯基，卤代烯基和炔基，显示出高的一般杀草活性，对许多阔叶作物具有良好的选择性，在某些情况下选择性小粒谷物。描述了制备式I化合物的方法，化合物I的制备中的中间体和化合物I的除草性质。

8. 发明授权

US4631081A Herbicidal cyclohexane-1,3-dione derivatives 失效
标题翻译：除草环己烷-1,3-二酮衍生物
公开(公告)号：US4631081A
公开(公告)日：1986-12-23
申请号：US536392
申请日：1983-09-27
申请人： Keith G. Watson , Graham J. Bird , Graeme J. Farquharson , Richard J. Conway , Peter G. Tucker
发明人： Keith G. Watson , Graham J. Bird , Graeme J. Farquharson , Richard J. Conway , Peter G. Tucker
IPC分类号： A01N43/40 , C07D213/48 , C07D213/50 , C07D213/53 , C07D213/55 , C07D213/61 , C07D213/64 , C07D213/69 , C07D213/70 , C07D213/80 , C07D213/82 , C07D213/85 , C07D213/89
CPC分类号： C07D213/53 , A01N43/40 , C07D213/48 , C07D213/50 , C07D213/55 , C07D213/61 , C07D213/64 , C07D213/69 , C07D213/70 , C07D213/80 , C07D213/82 , C07D213/85 , C07D213/89
摘要： The invention concerns novel compounds of the formula I ##STR1## wherein: Z is selected from oxygen and the group --YAn wherein Y is selected from C.sub.1 to C.sub.6 alkyl and benzyl and An is an anion;k is zero or the integer 1;n is an integer selected from 3 and 4;X is selected from halogen, nitro, cyano, alkyl, substituted alkyl, hydroxy, alkoxy, substituted alkoxy, alkenyl, alkenyloxy, alkynyl, alkynyloxy, acyloxy, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, sulfamoyl, substituted sulfamoyl, alkanoyloxy, benzyloxy, substituted benzyloxy, amino, substituted amino and the groups formyl and alkanoyl and the oxime, imine and Schiff base derivatives thereof;R.sup.1 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, alkylsulfonyl, arylsulfonyl, acyl and an inorganic or organic cation;R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl; andR.sup.4 is selected from hydrogen, halogen, alkyl, cyano and alkoxycarbonyl.The compounds of the invention show herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of the compounds of formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.
摘要翻译：本发明涉及式I的新型化合物其中：Z选自氧和基团-YAn，其中Y选自C1至C6烷基和苄基，An为阴离子; k为零或整数1; n是选自3和4的整数; 卤素，硝基，氰基，烷基，取代的烷基，羟基，烷氧基，取代的烷氧基，烯基，烯氧基，炔基，炔氧基，酰氧基，烷氧基羰基，苄氧基，氨基，取代氨基和甲酰基和烷酰基及其肟，亚胺和席夫碱衍生物; R 1选自氢，烷基，烯基，炔基，取代的烷基，烷基磺酰基，芳基磺酰基，酰基和无机或有机阳离子; R2选自烷基，取代的烷基，烯基，卤代烯基，炔基和卤代炔基; R3选自烷基，氟烷基，烯基，炔基和苯基; 并且R 4选自氢，卤素，烷基，氰基和烷氧基羰基。本发明的化合物显示除草性质和植物生长调节性质，并且在进一步的实施方案中，本发明提供了制备式I化合物的方法，可用于制备式I化合物的中间体，作为活性成分的化合物式I，以及利用式I化合物的除草和植物生长调节方法。

9. 发明授权

US4806141A Herbicidal compounds and compositions 失效
标题翻译：除草剂及组合物
公开(公告)号：US4806141A
公开(公告)日：1989-02-21
申请号：US937467
申请日：1986-12-02
申请人： Keith G. Watson , Lynette A. Garson , Graham J. Bird , Graeme J. Farquharson
发明人： Keith G. Watson , Lynette A. Garson , Graham J. Bird , Graeme J. Farquharson
IPC分类号： A01N47/04 , A01N33/24 , A01N35/06 , A01N35/10 , A01N37/00 , A01N37/02 , A01N37/10 , A01N37/22 , A01N37/34 , A01N37/48 , A01N41/04 , A01N41/06 , A01N41/10 , C07C45/00 , C07C45/45 , C07C45/51 , C07C45/67 , C07C45/71 , C07C45/74 , C07C47/542 , C07C47/55 , C07C47/565 , C07C47/575 , C07C49/255 , C07C49/657 , C07C49/697 , C07C49/747 , C07C49/753 , C07C49/86 , C07C67/00 , C07C239/00 , C07C251/42 , C07C251/44 , C07C251/50 , C07C301/00 , C07C303/28 , C07C309/63 , C07C309/73 , C07C313/00 , C07C323/21 , A01N33/00
CPC分类号： C07C255/00 , A01N35/10 , A01N37/00 , A01N37/02 , A01N37/10 , A01N37/22 , A01N37/48 , A01N41/04 , A01N41/06 , A01N41/10 , C07C323/00 , C07C45/455 , C07C45/513 , C07C45/673 , C07C45/71 , C07C45/74 , C07C47/542 , C07C47/55 , C07C47/565 , C07C47/575 , C07C49/255 , C07C49/657 , C07C49/697 , C07C49/747 , C07C49/753 , C07C49/86
摘要： The invention concerns novel compounds of the formula I ##STR1## wherein Z is selected from hydrogen, halogen, C.sub.1 to C.sub.6 alkyl, and C.sub.1 to C.sub.6 alkoxy;Y is selected from halogen, C.sub.1 to C.sub.6 alkyl and C.sub.1 to C.sub.6 alkoxy;X is selected from halogen, C.sub.1 to C.sub.6 alkyl and C.sub.1 to C.sub.6 alkoxy and if Y is methyl and Z is hydrogen or methyl then at least one of X is not methyl;R.sup.1 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, alkylsulfonyl, arylsulfonyl, acyl and an inorganic or organic cation;R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl and phenyl; andm is an integer chosen from 1 to 3.The compounds are cereal selective herbicides and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of compounds of formula I, herbicidal compositions containing as active ingredient a compound of formula I, and processes for severely damaging or killing unwanted plants by applying to the plants or to the growth medium of the plants an effective amount of a compound of formula I.
摘要翻译：本发明涉及式I的新型化合物其中Z选自氢，卤素，C 1至C 6烷基和C 1至C 6烷氧基; Y选自卤素，C 1至C 6烷基和C 1至C 6烷氧基; X选自卤素，C 1至C 6烷基和C 1至C 6烷氧基，如果Y是甲基，Z是氢或甲基，那么X中的至少一个不是甲基; R 1选自氢，烷基，烯基，炔基，取代的烷基，烷基磺酰基，芳基磺酰基，酰基和无机或有机阳离子; R2选自烷基，取代的烷基，烯基，卤代烯基，炔基和卤代炔基; R3选自烷基，氟烷基，烯基，炔基和苯基; 并且m是选自1至3的整数。化合物是谷物选择性除草剂，并且在进一步的实施方案中，本发明提供了制备式I化合物的方法，可用于制备式I化合物的中间体，含有活性的除草组合物成分为式I化合物，以及通过向植物或植物的生长培养基施用有效量的式I化合物来严重损害或杀死有害植物的方法。

10. 发明授权

US4680400A Herbicidal cyclohexane-1,3-dione-5-isoquinoline derivatives 失效
标题翻译：除草环己烷-1,3-二酮-5-异喹啉衍生物
公开(公告)号：US4680400A
公开(公告)日：1987-07-14
申请号：US929473
申请日：1986-11-12
申请人： Graham J. Bird , Graeme J. Farquharson , Keith G. Watson
发明人： Graham J. Bird , Graeme J. Farquharson , Keith G. Watson
IPC分类号： A01N31/08 , A01N35/10 , A01N37/00 , A01N37/02 , A01N37/10 , A01N37/18 , A01N37/22 , A01N37/34 , A01N37/44 , A01N37/50 , A01N37/52 , A01N41/02 , A01N43/40 , A01N43/42 , A01N43/48 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/64 , A01N43/707 , A01N43/713 , A01N47/44 , C07C43/188 , C07C43/20 , C07C45/00 , C07C45/45 , C07C45/46 , C07C45/56 , C07C45/63 , C07C45/67 , C07C47/55 , C07C49/657 , C07C49/697 , C07C49/747 , C07C49/753 , C07C49/755 , C07C49/835 , C07C49/84 , C07C67/00 , C07C239/00 , C07C251/42 , C07C251/44 , C07C251/48 , C07C251/52 , C07C251/54 , C07C251/58 , C07C301/00 , C07C303/30 , C07C309/63 , C07C311/16 , C07C313/00 , C07C317/30 , C07C317/32 , C07C317/36 , C07C317/46 , C07C323/12 , C07C323/19 , C07C323/47 , C07C323/60 , C07C323/63 , C07D215/12 , C07D215/14 , C07D215/18 , C07D217/10 , C07D217/12 , C07D217/16 , C07D217/22 , C07D217/24 , C07D217/26 , C07D471/04
CPC分类号： C07D217/26 , A01N35/10 , A01N37/50 , A01N43/42 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/707 , C07C205/45 , C07C309/00 , C07C43/188 , C07C43/202 , C07C45/455 , C07C45/46 , C07C45/565 , C07C45/63 , C07C45/673 , C07C47/55 , C07C49/657 , C07C49/697 , C07C49/747 , C07C49/753 , C07C49/755 , C07C49/835 , C07D215/14 , C07D215/18 , C07D217/22 , C07D217/24
摘要： The invention concerns novel compounds of the formula I ##STR1## wherein: A, B, D and E are selected from CH, N and N-Z wherein Z is selected from oxygen and the group YAn wherein Y is selected from alkyl and benzyl and An is an anion, and provided that no more than three of A, B, D and E are selected from N and N-Z and no more than one of A, B, D and E is selected from N-Z;W is a saturated or unsaturated C.sub.2 to C.sub.5 hydrocarbon chain;X and X.sup.1 are independently selected from halogen, nitro, cyano, alkyl, substituted alkyl, hydroxy, alkoxy, substituted alkoxy, alkenyl, alkenyloxy, alkynyl, alkynyloxy, acyloxy, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, sulfamoyl, substituted sulfamoyl, alkanoyloxy, benzyloxy, substituted benzyloxy, amino, substituted amino and the groups formyl and alkanoyl and the oxime, imine and Schiff base derivatives thereof, or two of X.sup.1 on the same carbon atom may form an oxo group;R.sup.1 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, alkylsulfonyl, arylsulfonyl, acyl and an inorganic or organic cation;R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl;R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl;R.sup.4 is selected from hydrogen, halogen, alkyl, cyano and alkoxycarbonyl;n is 0 or an integer chosen from 1 to 3; andn.sup.1 is 0 or an integer chosen from 1 to 5.The compounds of the invention show herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of the compounds of formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.

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