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31. 发明授权

US6083898A Water-soluble or water-dispersible cross-linked nitrogenated compounds in washing and cleaning agents 失效
标题翻译：水溶性或水分散性交联氮化合物在洗涤和清洗剂中
公开(公告)号：US6083898A
公开(公告)日：2000-07-04
申请号：US284456
申请日：1999-05-12
申请人： Hubert Meixner , Ulrich Steuerle , Jurgen Decker , Wolfgang Paulus , Dieter Boeckh , Jurgen Alfred Lux , Beate Ehle
发明人： Hubert Meixner , Ulrich Steuerle , Jurgen Decker , Wolfgang Paulus , Dieter Boeckh , Jurgen Alfred Lux , Beate Ehle
IPC分类号： C08G73/02 , C11D3/00 , C11D3/37 , C11D3/386 , C11D3/30
CPC分类号： C11D3/3719 , C08G73/02 , C08G73/0206 , C08G73/028 , C11D3/0036 , C11D3/3723 , C11D3/3769 , C11D3/3788 , C11D3/38663
摘要： The invention relates to the use of crosslinked nitrogenous compounds which are soluble or dispersible in water and are obtainable by crosslinking of(a) compounds containing at least three NH groups with(b) at least bifunctional crosslinkers which react with NH groups,in detergents and cleaners, especially soil release agents.Compounds (a) are preferably selected from the group consisting of oligo- and polyamines, polyalkylenepolyamines, polyamidoamines, polyamidoamines grafted with (poly)ethyleneimnine, and mixtures thereof
摘要翻译： PCT No.PCT / EP97 / 05744 Sec。 371日期1999年5月12日 102（e）日期1999年5月12日PCT 1997年10月17日PCT公布。第WO98 / 17764号公报日期：1998年04月30日本发明涉及可溶于水或可分散于水中的交联含氮化合物的用途，其可通过交联（a）含有至少三个NH基团的化合物与（b）至少双官能交联剂与NH 组，洗涤剂和清洁剂，特别是去污剂。化合物（a）优选选自由寡聚和多胺，聚亚烷基多胺，聚酰胺胺，接枝（聚）乙烯亚胺的聚酰氨基胺及其混合物

32. 发明授权

US5952438A Polymeric polyamines from alternating polyketones 失效
标题翻译：交替聚酮的聚合多胺
公开(公告)号：US5952438A
公开(公告)日：1999-09-14
申请号：US992530
申请日：1997-12-17
申请人： Detlef Kratz , Ferdinand Lippert , Peter Schwab , Dieter Boeckh , Johannes Perner
发明人： Detlef Kratz , Ferdinand Lippert , Peter Schwab , Dieter Boeckh , Johannes Perner
IPC分类号： A61K8/84 , A61Q5/00 , A61Q19/00 , B01F17/00 , B01F17/52 , C08G59/50 , C08G67/02 , C08G73/02 , C08G73/06 , C08L63/00 , C09J179/02 , C09K3/00 , C09K15/30 , C10L1/22 , C10L1/238 , C10L1/2383 , C10L1/28 , C10L10/18 , C10M149/02 , C10M149/14 , C11D3/37 , D06P1/52 , D06P5/08
CPC分类号： D06P5/08 , A61K8/84 , A61Q19/00 , A61Q5/00 , B01F17/005 , C08G67/02 , C08G73/0611 , C08G73/0672 , C08L63/00 , C09K15/30 , C10L1/238 , C10L1/285 , C10M149/14 , C11D3/0021 , C11D3/3723 , D06P1/5278
摘要： Polymeric polyamines obtainable by reacting linear, alternating carbon monoxide/1-alkene copolymers with ammonia or amines of the formula (I)R--NH.sub.2 (I)where R is --NH.sub.2, --OH, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.20 -aryl, C.sub.7 -C.sub.20 -arylalkyl, C.sub.7 -C.sub.20 -alkylaryl or an organosilicon radical having 3 to 30 carbon atoms,or with a reagent which releases ammonia or the amine (I), and subsequent hydrogenation.
摘要翻译：通过使线性交替一氧化碳/ 1-烯烃共聚物与式（I）R-NH 2（I）的胺反应获得的聚合多胺，其中R是-NH 2，-OH，C 1 -C 10 - 烷基，C 6 -C 20 - 芳基，C7-C20芳基烷基，C7-C20烷基芳基或具有3-30个碳原子的有机硅基团，或与释放氨或胺（I）的试剂反应，然后进行氢化。

33. 发明授权

US5773541A Preparation of copolymers of vinyl esters and monoethylenically unsaturated carboxylic acids and their use 失效
标题翻译：乙烯基酯和单烯属不饱和羧酸的共聚物的制备及其用途
公开(公告)号：US5773541A
公开(公告)日：1998-06-30
申请号：US693220
申请日：1996-08-21
申请人： Dieter Boeckh , Axel Kistenmacher , Walter Denzinger , Iris Rau , Angelika Funhoff , Richard Baur , Alexander Kud , Volker Schwendemann
发明人： Dieter Boeckh , Axel Kistenmacher , Walter Denzinger , Iris Rau , Angelika Funhoff , Richard Baur , Alexander Kud , Volker Schwendemann
IPC分类号： C08F2/00 , C08F2/16 , C08F2/38 , C08F2/44 , C08F4/40 , C08F8/12 , C08F218/04 , C08F218/08 , C08F218/10 , C08F220/04 , C08F220/06 , C08F222/02 , C11D3/37
CPC分类号： C11D3/3784 , C08F218/08 , C08F218/10 , C08F220/04 , C08F220/06 , C08F222/02 , C08F8/12 , C11D3/3757 , C11D3/3769
摘要： A process for preparing copolymers of vinyl esters and monoethylenically unsaturated carboxylic acids by free-radical copolymerization of (a) 20 to 80 mol % of vinyl esters of aliphatic monocarboxylic acids having at least 2 carbon atoms and (b) 80-20 mol % of monoethylenically unsaturated carboxylic acids, with or without (c) 0-30 mol % of other copolymerizable monoethylenically unsaturated monomers and/or (d) 0-10 mol % of monomers which contain at least two non-conjugated ethylenic double bonds in the molecule, in the presence of at least one sulfur, phosphorus and/or nitrogen compound with a reducing action and of 0.05-30% by weight, based on the monomers, of at least one surface-active agent in aqueous medium in the presence of initiators and in the presence or absence of regulators, and the use of the copolymers or of the copolymers which are obtainable therefrom by hydrolysis and/or oxidation and have vinyl alcohol units as additive to detergents and cleaners.
摘要翻译： PCT No.PCT / EP95 / 00575 Sec。 371日期1996年8月21日 102（e）日期1996年8月21日PCT提交1995年2月17日PCT公布。公开号WO95 / 22569 日期1995年8月24日一种通过自由基共聚合（a）20至80mol％具有至少2个碳原子的脂肪族单羧酸的乙烯基酯和（b）80（a）的自由基共聚合制备乙烯基酯和单烯属不饱和羧酸的共聚物的方法 -20摩尔％的单烯属不饱和羧酸，具有或不具有（c）0-30摩尔％的其它可共聚单烯属不饱和单体和/或（d）0-10摩尔％的含有至少两个非共轭烯属双键的单体在具有还原作用的至少一种硫，磷和/或氮化合物和基于单体的0.05-30重量％的存在下，分子中的至少一种表面活性剂在水介质中的键引发剂的存在和存在或不存在调节剂，以及通过水解和/或氧化可获得的共聚物或共聚物的用途，并且具有乙烯醇单元作为洗涤剂和清洁剂的添加剂。

34. 发明授权

US5739241A Vinyl formate copolymers, preparation thereof, and use thereof in detergents and cleaners 失效
标题翻译：甲酸乙烯酯共聚物，其制备方法及其在洗涤剂和清洁剂中的应用
公开(公告)号：US5739241A
公开(公告)日：1998-04-14
申请号：US750472
申请日：1996-12-16
申请人： Dieter Boeckh , Axel Kistenmacher , Walter Denzinger , Thomas Ruhl , Angelika Funhoff , Richard Baur , Alexander Kud , Volker Schwendemann
发明人： Dieter Boeckh , Axel Kistenmacher , Walter Denzinger , Thomas Ruhl , Angelika Funhoff , Richard Baur , Alexander Kud , Volker Schwendemann
IPC分类号： C08F218/06 , C08F220/04 , C08F222/02 , C11D3/37 , C08F22/02 , C08F20/10
CPC分类号： C11D3/3757 , C08F218/06 , C08F220/04
摘要： Copolymers containing (a) from 5 to 90 mol % of vinyl formate units, (b) from 10 to 95 mol % of units of monoethylenically unsaturated carboxylic acids, (c) from 0 to 70 mol % of units of monoethylenically unsaturated dicarboxylic acids, and (d) from 0 to 30 mol % of units of other monoethylenically unsaturated monomers in copolymerized form and having K values of at least 8 (determined by the method of H. Fikentscher in 1% strength by weight aqueous solution on the sodium salt of the copolymers at pH 7 and 25.degree. C.), processes for their preparation by copolymerizing monomer mixtures of (a) from 5 to 90 mol % of vinyl formate, (b) from 10 to 95 mol % of monoethylenically unsaturated carboxylic acids, (c) from 0 to 70 mol % of monoethylenically unsaturated dicarboxylic acids, and (d) from 0 to 30 mol % of other monoethylenically unsaturated monomers in an aqueous medium or in an organic solvent in the presence of free-radical polymerization initiators and use of the vinyl formate copolymers and of the vinyl alcohol copolymers obtainable therefrom by hydrolysis and/or oxidation as detergent and cleaner additives.
摘要翻译： PCT No.PCT / EP95 / 02053 Sec。 371日期1996年12月16日第 102（e）日期1996年12月16日PCT提交1995年5月31日PCT公布。公开号WO95 / 34587 日期：1995年12月21日含有（a）5〜90摩尔％甲酸乙烯酯单元的聚合物，（b）10〜95摩尔％的单烯属不饱和羧酸单元，（c）0〜70摩尔％单烯属不饱和二羧酸，和（d）0至30摩尔％的共聚形式的其它单烯属不饱和单体的单元，并且K值至少为8（通过H.Fikentscher在1％重量比浓度的水溶液中测定）在共聚物的钠盐上，在pH7和25℃下），其制备方法是通过使（a）5-90mol％的甲酸乙烯酯，（b）10至95mol％的单烯属的单体混合物不饱和羧酸，（c）0-70摩尔％的单烯属不饱和二羧酸，和（d）0-30摩尔％的其它单烯属不饱和单体在水性介质或有机溶剂中，在自由基存在下聚合引发剂和使用v 甲酸丁酯共聚物和通过水解和/或氧化作为洗涤剂和清洁剂添加剂得到的乙烯醇共聚物。

35. 发明授权

US5508394A Citric esters of polyhydroxy compounds and use thereof in detergents 失效
标题翻译：多羟基化合物的柠檬酸酯及其在洗涤剂中的用途
公开(公告)号：US5508394A
公开(公告)日：1996-04-16
申请号：US117134
申请日：1993-09-16
申请人： Elisabeth Kappes , Alfred Oftring , Richard Baur , Alexander Kud , Dieter Boeckh , Heinrich Hartmann , Volker Schwendemann
发明人： Elisabeth Kappes , Alfred Oftring , Richard Baur , Alexander Kud , Dieter Boeckh , Heinrich Hartmann , Volker Schwendemann
IPC分类号： C07C67/08 , C07C69/704 , C07C219/06 , C07H13/04 , C07H15/04 , C11D3/20 , C11D3/22 , C11D3/30 , C07H5/04 , A01N43/04 , C07H5/06 , C07H13/02
CPC分类号： C07H13/04 , C07C69/704 , C07H15/04 , C11D3/2093 , C11D3/221 , C11D3/30
摘要： Esters of citric acid or acetylcitric anhydride with compounds of at least 3 OH groups selected from the group consisting of polyglycerol, sugarcarboxylic acids, alkyl glucosides, derivatives of oligosaccharides, aminosorbitol, aminodisorbitol, glucosamine, triethanolamine and trishydroxyethylmelamine, each OH group of the alcohol component of the esters being esterified on average with from 0.15 to 1 molecule of citric acid or acetylcitric anhydride, are useful as additives in low-phosphate or phosphate-free detergents.
摘要翻译： PCT No.PCT / EP92 / 00512 Sec。 371日期：1993年9月16日 102（e）1993年9月16日PCT PCT 1991年3月7日PCT公布。 WO92 / 16493 PCT出版物日期：1992年10月1日。具有至少3个OH基团的化合物的柠檬酸或乙酰柠檬酸酯选自聚甘油，糖羧酸，烷基葡糖苷，寡糖衍生物，氨基异山梨醇，氨基二异山梨醇，葡糖胺，三乙醇胺和三羟乙基三聚氰胺，酯的醇组分的每个OH基团平均被0.15至1分子的柠檬酸或乙酰柠檬酸酐酯化，可用作低磷酸盐或无磷酸盐洗涤剂中的添加剂。

36. 发明授权

US4914172A Water-soluble copolymers and their preparation 失效
标题翻译：水溶性共聚物及其制备方法
公开(公告)号：US4914172A
公开(公告)日：1990-04-03
申请号：US179477
申请日：1988-04-08
申请人： Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann , Wolfgang Trieselt
发明人： Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann , Wolfgang Trieselt
IPC分类号： A01N25/26 , C08F20/02 , C08F220/04 , C08F220/26 , C08F220/28 , C08F222/02 , C08L101/16
CPC分类号： A01N25/26 , C08F220/04
摘要： Water-soluble copolymers having a K value of from 8 to 100 (determined according to H. Fikentscher on sodium salt in aqueous solution at 25.degree. C., a pH of 7 and a polymer concentration of the Na salt of 1% by weight) contain, in polymerized form,(a) not less than 15 mol % of one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids,(b) from 0.5 to 84.5 mol % of one or more ethylenically unsaturated C.sub.4 -C.sub.6 -dicarboxylic acids,(c) from 0 to 20 mol % of one or more hydroxyalkyl esters, where hydroxyalkyl is of 2 to 6 carbon atoms, of monoethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids,(d) from 0 to 30 mol % of other water-soluble, monoethylenically unsaturated monomers copolymerizable with (a), (b) and (c),(e) from 0.5 to 15 mol % of a comonomer which possesses two or more ethylenically unsaturated, nonconjugated double bonds and one or more --CO--OH groups and/or their salt with an alkali metal, ammonium or alkaline earth metal base and, if required,(f) up to 10 mol % of one or more comonomers which differ from (e) and possess two or more ethylenically unsaturated, nonconjugated double bonds,are prepared by copolymerization of the monomers (a) to (f) and are used for coating seed.
摘要翻译： K值为8〜100（根据H.Fikentscher在25℃的水溶液中的钠盐，pH为7，Na盐的聚合物浓度为1重量％）测定的水溶性共聚物，含有（a）不小于15摩尔％的一种或多种单烯属不饱和C3-C6-一元羧酸，（b）0.5-84.5摩尔％的一种或多种烯属不饱和C4-C6-二羧酸，（c）0至20摩尔％的一种或多种羟烷基酯（其中羟基烷基为2至6个碳原子）为单烯属不饱和C 3 -C 6羧酸，（d）0至30摩尔％的其它水溶性可与（a），（b）和（c）共聚的单烯属不饱和单体，（e）0.5〜15摩尔％的共聚单体，其具有两个或多个烯属不饱和的非共轭双键和一个或多个-CO-OH基团和/或其与碱金属，铵或碱土金属碱的盐，如果需要，（f）至多10mol％的o 通过单体（a）至（f）的共聚制备不同于（e）并具有两个或更多个烯属不饱和非共轭双键的共聚单体，并用于涂覆种子。

37. 发明授权

US4897458A Water-soluble copolymers and their preparation 失效
标题翻译：水溶性共聚物及其制备方法
公开(公告)号：US4897458A
公开(公告)日：1990-01-30
申请号：US179049
申请日：1988-04-08
申请人： Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann , Wolfgang Trieselt
发明人： Hans-Peter Seelmann-Eggebert , Dieter Boeckh , Heinrich Hartmann , Wolfgang Trieselt
IPC分类号： C07C69/533 , A01N25/26 , C08F2/10 , C08F220/04 , C08F290/00 , C08F299/00 , C08L101/16
CPC分类号： C08F220/04 , A01N25/26
摘要： Water-soluble copolymers having a K value of from 15 to 120 (determined according to H. Fikentscher in an aqueous solution of their sodium salt at 25.degree. C., a pH of 7 and a polymer concentration of the Na salt of 1% by weight) contain, in polymerized form,(a) not less than 80 mol % of one or more monoethylenically unsaturated C.sub.3 -C.sub.6 -monocarboxylic acids,(b) from 0.5 to 20 mol % of a comonomer which possesses two or more ethylenically unsaturated, non-conjugated double bonds and one or more --CO--OX groups and/or their salt with an alkali metal, ammonium or alkaline earth metal base, and, if required,(c) not more than 10 mol % of one or more comonomers which differ from (b) and possess two or more ethylenically unsaturated, non-conjugated double bonds, and the said copolymers are prepared by copolymerization of the monomers (a), (b) and, if required (c) in aqueous solution and are used for coating seed.
摘要翻译： K值为15〜120的水溶性共聚物（根据H.Fikentscher在25℃的钠盐水溶液中测定，pH为7，Na盐的聚合物浓度为1％的聚合物浓度由重量）含有（a）不小于80摩尔％的一种或多种单烯属不饱和C3-C6-一元羧酸，（b）0.5-20摩尔％的具有两个或更多个烯属不饱和的共聚单体，非共轭双键和一个或多个-CO-OX基团和/或其与碱金属，铵或碱土金属的碱的盐，如果需要，（c）不大于10摩尔％的一种或多种共聚单体其不同于（b）并且具有两个或更多个烯键式不饱和的非共轭双键，并且所述共聚物通过单体（a），（b）和（如果需要（c））在水溶液中共聚而制备，并且用于涂覆种子。

38. 发明授权

US08475538B2 Method for gently aftertreating dyed textiles 有权
标题翻译：轻装染色纺织品的方法
公开(公告)号：US08475538B2
公开(公告)日：2013-07-02
申请号：US13058112
申请日：2009-07-30
申请人： Pia Baum , Klaus Scheuermann , Dieter Boeckh
发明人： Pia Baum , Klaus Scheuermann , Dieter Boeckh
IPC分类号： C11D3/00
CPC分类号： D06P5/02 , D06P1/52 , D06P1/60 , D06P3/54 , D06P3/79 , D06P3/794 , D06P5/08
摘要： A process for aftertreating dyed and/or printed textiles to remove excess portions of colorants comprises utilizing an aqueous formulation comprising at least one graft copolymer having a hydrophilic main chain and also surfactants.
摘要翻译：用于后处理染色和/或印刷纺织品以除去多余部分着色剂的方法包括使用包含至少一种具有亲水主链的接枝共聚物和表面活性剂的水性制剂。

39. 发明申请

US20100261634A1 AMPHIPHILIC WATER-SOLUBLE ALKOXYLATED POLYALKYLENEIMINES HAVING AN INNER POLYETHYLENE OXIDE BLOCK AND AN OUTER POLYPROPYLENE OXIDE BLOCK 有权
标题翻译：具有内部聚乙烯氧化物块和外部聚丙烯氧化物块的水溶性可溶性烷氧基聚亚烷基
公开(公告)号：US20100261634A1
公开(公告)日：2010-10-14
申请号：US12739747
申请日：2008-11-07
申请人： Andrea Misske , Sophia Ebert , Stefan Frenzel , Dieter Boeckh , Frank Huelskoetter , James Danziger
发明人： Andrea Misske , Sophia Ebert , Stefan Frenzel , Dieter Boeckh , Frank Huelskoetter , James Danziger
IPC分类号： C11D3/26 , C07C249/02 , C08G73/00
CPC分类号： C08L79/02 , C08G73/0206 , C08G73/024
摘要： The present invention relates to amphiphilic water-soluble alkoxylated polyalkyleneimines having an inner polyethylene oxide block comprising 20 to 50 polyethylene oxide units and an outer polypropylene oxide block comprising 10 to 50 polyethylene oxide units and especially to such alkoxylated polyalkyleneimines wherein the ratio of polyethylene oxide units and polypropylene oxide units is proportionally related to the square root of the number of polyalkyleneimine units present in the backbone. The present invention further relates to the use of these alkoxylated polyalkyleneimines as a soil detachment promoting additive to laundry detergents and cleaning compositions and to laundry detergents and cleaning compositions which comprise these alkoxylated mono- or polyalkyleneimines.
摘要翻译：本发明涉及具有包含20-50个聚环氧乙烷单元的内部聚环氧乙烷嵌段的两亲性水溶性烷氧基化聚亚烷基亚胺和包含10-50个聚环氧乙烷单元的外部聚环氧丙烷嵌段，特别涉及这样的烷氧基化聚亚烷基亚胺，其中聚环氧乙烷单元和聚丙烯氧化物单元与存在于主链中的聚亚烷基亚胺单元的数量的平方根成比例地相关。本发明还涉及这些烷氧基化聚亚烷基亚胺作为洗涤剂和清洁组合物的促进添加剂的土壤剥离剂以及包含这些烷氧基化单 - 或聚亚烷基亚胺的衣物洗涤剂和清洁组合物的用途。

40. 发明申请

US20100234631A1 ALKOXYLATED POLYALKANOLAMINES 有权
标题翻译：烷氧基聚烷醇胺
公开(公告)号：US20100234631A1
公开(公告)日：2010-09-16
申请号：US12740050
申请日：2008-11-07
申请人： Andrea Misske , Sophia Ebert , Stefan Frenzel , Dieter Boeckh , Frank Huelskoetter , James Danziger
发明人： Andrea Misske , Sophia Ebert , Stefan Frenzel , Dieter Boeckh , Frank Huelskoetter , James Danziger
IPC分类号： C07C305/10 , C07C217/50
CPC分类号： C08G73/024
摘要： The present invention relates to polymers obtainable by condensation of N-(hydroxy-alkyl)amines and reacting the remaining hydroxy and/or secondary amino groups of the condensation product with alkylene oxides and to derivatives obtainable by quaternization, protonation, sulphation and/or phosphation of said polymers, as well as to a process for preparing said polymers and a process for preparing said derivatives.
摘要翻译：本发明涉及通过N-（羟基 - 烷基）胺的缩合和使缩合产物的剩余羟基和/或仲氨基与环氧烷反应得到的聚合物和通过季铵化，质子化，硫酸化和/或磷酸化得到的衍生物的所述聚合物，以及制备所述聚合物的方法和制备所述衍生物的方法。

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