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31. 发明申请

US20100076231A1 PROCESSES FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE, A PROCESS FOR PRODUCING 1-CHLORO-2,3,3,3-PENTAFLUOROPROPANE AND AZEOTROPIC COMPOSITIONS OF 1-CHLORO-2,3,3,3-TETRAFLUOROPROPENE WITH HF 有权
公开(公告)号：US20100076231A1
公开(公告)日：2010-03-25
申请号：US12442955
申请日：2007-10-31
申请人： Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
发明人： Mario Joseph Nappa , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： C07C17/25 , C07C17/278
CPC分类号： C07C17/25 , C07C17/23 , C07C17/278 , C07C21/18 , C07C19/08 , C07C19/10
摘要： A process is disclosed for making CH2═CFCF3. The process involves contacting CH2ClCF2CF3 with H2 in a reaction zone in the presence of a catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina, to produce CH2═CFCF3. The mole ratio of H2 to the CH2ClCF2CF3 fed to the reaction zone is between about 1:1 and about 4:1. Also disclosed is another process for making CH2═CFCF3 that involves (a) reacting CH2ClCF2CF3 with H2 in the presence of a catalytically effective amount of hydrogenation catalyst to form CH3CF2CF3; and (b) dehydrofluorinating CH3CF2CF3 from (a) to form CH2═CFCF3; and another process for making CH2═CFCF3 that involves (1) dehydrofluorinating CH2ClCF2CF3 in the presence of a catalytically effective amount of dehydrofluorination catalyst to form CHCl═CFCF3; and (2) hydrogenating CHCl═CFCF3 from (1) in the presence of a hydrogenation catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina to form CH2═CFCF3. Also disclosed is a process for making CH2ClCF2CF5. This process involves reacting CH2ClF with CF2═CF2 in a reaction zone in the presence of a catalytically effective amount of an aluminum halide composition having a bulk formula of AlClxBryF3-x-y wherein the average value of x is 0 to 3, the average value of y is 0 to 3-x, provided that the average values of x and y are not both 0. Also disclosed is an azeotropic composition including CF3CF═CHCl and HF.

32. 发明授权

US07659436B2 Process for the preparation of 1,1,1,3,3-penta-fluoropropane and/or 1,1,1,3,3,3-hexafluoropropane 失效
标题翻译：制备1,1,1,3,3-五氟丙烷和/或1,1,1,3,3,3-六氟丙烷的方法
公开(公告)号：US07659436B2
公开(公告)日：2010-02-09
申请号：US11988436
申请日：2006-08-04
申请人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
发明人： Velliyur Nott Mallikarjuna Rao , H. David Rosenfeld , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： C07C17/00 , C07C17/10
CPC分类号： B01J23/868 , B01J37/0009 , B01J37/03 , C07C17/206 , C07C17/21 , C07C17/23 , C07C17/25 , C07C19/08 , C07C21/18 , C07C19/10
摘要： A process for the manufacture of CF3CH2CHF2 and/or CF3CH2CF3 is disclosed. The process involves (a) reacting HF and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or Cl) to produce a product including both CF3CCI═CF2 and CF3CHCICF3; (b) reacting CF3CCI═CF2 and/or CF3CHCICF3 produced in (a) with hydrogen to produce a product including CF3CH2CHF2 and/or CF3CH2CF3; and (c) recovering CF3CH2CHF2 and/or CF3CH2CF3 from the product produced in (b). In (a), the CF3CCI═CF2 and CF3CHCICF3 are produced in the presence of a fluorination catalyst comprising at least one chromium-containing component selected from (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.
摘要翻译：公开了制备CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3的方法。该方法包括（a）使HF和式CX3CCI-CCIX（其中每个X独立地为F或Cl）至少一种卤代丙烯反应以产生包含CF 3 CCl-CF 2和CF 3 CHCICF 3的产物; （b）使（a）中制备的CF 3 CCl-CF 2和/或CF 3 CHCICF 3与氢反应以产生包含CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3的产物; 和（c）从（b）中制备的产物中回收CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3。在（a）中，CF 3 CCl-CF 2和CF 3 CHCICF 3在含有至少一种含铬组分的氟化催化剂的存在下制备，所述含铬组分选自（i）结晶α-氧化铬，其中至少0.05原子％所述α-氧化铬晶格被二价铜取代，和（ii）已经用氟化剂处理的（i）的含铬组合物。

33. 发明申请

US20090264689A1 Tetrafluoropropene Production Processes 有权
标题翻译：四氟丙烯生产工艺
公开(公告)号：US20090264689A1
公开(公告)日：2009-10-22
申请号：US12301077
申请日：2007-06-22
申请人： Velliyur Nott Mallikarjuna Rao , Mario Joseph Nappa , Allen Capron Sievert
发明人： Velliyur Nott Mallikarjuna Rao , Mario Joseph Nappa , Allen Capron Sievert
IPC分类号： C07C17/23
CPC分类号： C07C21/18 , C07C17/25
摘要： A process is disclosed for producing 2,3,3,3-tetrafluoropropene and 1,3,3,3-tetrafluoropropene. The process involves pyrolyzing 1,1,1,2,3-pentafluoropropane.
摘要翻译：公开了一种制备2,3,3,3-四氟丙烯和1,3,3,3-四氟丙烯的方法。该方法包括热解1,1,1,2,3-五氟丙烷。

34. 发明申请

US20090127496A1 Tetrafluoropropene Production Processes 有权
标题翻译：四氟丙烯生产工艺
公开(公告)号：US20090127496A1
公开(公告)日：2009-05-21
申请号：US12301070
申请日：2007-06-22
申请人： Velliyur Nott Mallikarjuna Rao , Mario Joseph Nappa , Allen Capron Sievert
发明人： Velliyur Nott Mallikarjuna Rao , Mario Joseph Nappa , Allen Capron Sievert
IPC分类号： C09K5/00 , C07C17/25
CPC分类号： B01J37/26 , B01J21/04 , B01J27/125 , C07C17/25 , C07C17/386 , C07C21/18 , C07C19/08
摘要： A process is disclosed for the manufacture of CF3CF═CH2 and CF3CH═CHF. The process involves dehydrofluorinating CF3CHFCH2F in the presence of a dehydrofluorination catalyst to produce a product mixture comprising CF3CF═CH2 and CF3CH═CHF, and recovering said CF3CF═CH2 and CF3CH═CHF from the product mixture.The present invention also provides a composition comprising (a) the Z-isomer of CF3CH═CHF and (b) HF; wherein the HF is present in an effective amount to form an azeotropic combination with the Z—CF3CH═CHF.
摘要翻译：公开了用于制造CF 3 CF-CH 2和CF 3 CH-CHF的方法。该方法包括在脱氟化氢催化剂的存在下对CF 3 CHFCH 2 F进行脱氟化氢，以产生包含CF 3 CF-CH 2和CF 3 CH-CHF的产物混合物，并从产物混合物回收所述CF 3 CF-CH 2和CF 3 CH-CHF。本发明还提供一种组合物，其包含（a）CF 3 CH-CHF的Z-异构体和（b）HF; 其中HF以有效量存在以与Z-CF 3 CH-CHF形成共沸组合。

35. 发明授权

US07435700B2 Chromium oxide compositions containing zinc, their preparation and their use as catalysts and catalyst precursors 有权
标题翻译：含有锌的氧化铬组合物，它们的制备及其作为催化剂和催化剂前体的用途
公开(公告)号：US07435700B2
公开(公告)日：2008-10-14
申请号：US10572628
申请日：2004-10-13
申请人： Tammy Georgette Amos , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert , Shekhar Subramoney
发明人： Tammy Georgette Amos , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： B01J21/00 , C07C17/00
CPC分类号： B01J23/86 , B01J23/002 , B01J23/26 , B01J35/0006 , B01J35/002 , B01J37/03 , B01J2523/00 , C07C17/25 , C07C17/37 , C07C21/18 , B01J2523/27 , B01J2523/67
摘要： A chromium-containing catalyst is disclosed which includes both ZnCr2O4 and crystalline α-chromium oxide. The ZnCr2O4 contains between about 10 atom percent and 67 atom percent of the chromium in the composition and at least about 70 atom percent of the zinc in the composition, and at least about 90 atom percent of the chromium present as chromium oxide in the composition is present as ZnCr2O4 or crystalline α-chromium oxide. Also disclosed are a method for preparing this composition comprising ZnCr2O4 and crystalline α-chromium oxide; and a chromium-containing catalyst composition prepared by treatment of the composition comprising ZnCr2O4 and crystalline α-chromium oxide with a fluorinating agent. Also disclosed is a process for changing the fluorine distribution in a halogenated hydrocarbon, or incorporating fluorine in a saturated or unsaturated hydrocarbon, in the presence of at least one composition selected from the group consisting of (i) the ZnCr2O4 and crystalline α-chromium oxide compositions and (ii) the ZnCr2O4 and crystalline α-chromium oxide compositions which have been treated with a fluorinating agent.
摘要翻译：公开了一种含铬催化剂，其包括ZnCr 2 O 4 O 4和结晶α-氧化铬。 ZnCr 2 O 4 4含有组合物中铬的约10原子％至67原子％，组合物中的锌的至少约70原子％，以及作为组合物中作为氧化铬存在的至少约90原子％的铬以ZnCr 2 O 4 O 4或结晶α-氧化铬存在。还公开了一种制备该组合物的方法，该组合物包含ZnCr 2 O 4 O 4和结晶α-氧化铬; 以及通过用氟化剂处理包含ZnCr 2 O 4 O 4和结晶α-氧化铬的组合物制备的含铬催化剂组合物。还公开了一种改变卤代烃中的氟分布或在饱和或不饱和烃中引入氟的方法，所述方法是在至少一种选自（i）ZnCr 2 SO 2 O 3和结晶α-氧化铬组合物和（ii）ZnCr 2 O 4 O 4和结晶α-氧化铬组合物，它们具有用氟化剂处理。

36. 发明授权

US07384572B2 Azeotrope-like compositions containing fluoroethane 失效
标题翻译：含有氟乙烷的类共沸组合物
公开(公告)号：US07384572B2
公开(公告)日：2008-06-10
申请号：US11585536
申请日：2006-10-24
申请人： Barbara Haviland Minor , Vinci Martinez Felix , Allen Capron Sievert
发明人： Barbara Haviland Minor , Vinci Martinez Felix , Allen Capron Sievert
IPC分类号： C09K5/04
CPC分类号： C07C19/08 , C08J9/146 , C08J9/149 , C08J2203/14 , C08J2203/142 , C08J2207/04 , C09K3/30 , C09K5/045 , C09K2205/11 , C09K2205/12 , C09K2205/22 , C09K2205/32
摘要： The present invention relates to the discovery of compositions which include fluoroethane, 2-fluoropropane or tert-butylfluoride. These compositions are useful as pure components or with at least one of tetrafluoroethane, difluoroethane, hexafluoropropane, a hydrocarbon or dimethylether.These compositions are useful as aerosol propellants, refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.
摘要翻译：本发明涉及发现包括氟乙烷，2-氟丙烷或叔丁基氟化物的组合物。这些组合物可用作纯组分或与四氟乙烷，二氟乙烷，六氟丙烷，烃或二甲醚中的至少一种有用。这些组合物可用作气溶胶推进剂，制冷剂，清洁剂，聚烯烃和聚氨酯的膨胀剂，制冷剂，传热介质，气体电介质，灭火剂，动力循环工作流体，聚合介质，颗粒去除流体，载体流体，抛光磨料代理和置换干燥剂。

37. 发明授权

US06242658B1 Process for the manufacture of fluorine-substituted hydrocarbons 失效
标题翻译：氟取代烃的制造方法
公开(公告)号：US06242658B1
公开(公告)日：2001-06-05
申请号：US09155262
申请日：1999-08-06
申请人： Ralph Thomas Baker , Richard Paul Beatty , Allen Capron Sievert , Robert Lewis Wallace, Jr.
发明人： Ralph Thomas Baker , Richard Paul Beatty , Allen Capron Sievert , Robert Lewis Wallace, Jr.
IPC分类号： C07C1908
CPC分类号： C07F15/04 , C07B31/00 , C07B37/02 , C07C17/00 , C07C19/08
摘要： Processes involving certain nickel metallacycles with phosphite ligands are disclosed as useful for the manufacture of selected substituted hydrocarbons. Also disclosed are selected compounds including both nickel and phosphite ligands.
摘要翻译：涉及涉及某些具有亚磷酸酯配体的镍金属螯合物的方法被公开用于制备所选取代的烃。还公开了选择的化合物，包括镍和亚磷酸酯配体。

38. 发明授权

US06207869B1 Process for perhalofluorinated butanes and hexanes 失效
标题翻译：全氟化丁烷和己烷的方法
公开(公告)号：US06207869B1
公开(公告)日：2001-03-27
申请号：US09519791
申请日：2000-03-07
申请人： Mario Joseph Nappa , Allen Capron Sievert
发明人： Mario Joseph Nappa , Allen Capron Sievert
IPC分类号： C07C1908
CPC分类号： C07C19/14 , B01J27/125 , C07C17/23 , C07C17/278 , C07C19/08 , C07C19/10
摘要： The instant invention relates to producing perhalofluorobutanes and perhalofluorohexanes, more particularly it relates to their production by utilizing tetrafluoroethylene (hereinafter referred to as “TFE”) and chlorotrifluoro-ethylene (hereinafter referred to as “CTFE”) with selected perhalofluoroethanes containing 2 to 4 nonfluorine halogen and 2 to 4 fluorine substituents in the presence of a polyvalent metal halide such as an aluminum chloride or chlorofluoride as catalyst.
摘要翻译：本发明涉及生产全氟全氟代丁烷和全卤代己烷，更具体地说，涉及其使用四氟乙烯（以下称为“TFE”）和氯三氟乙烯（以下称为“CTFE”）的制备方法，该选择性全卤代乙烷含有2-4个非氟卤素和2至4个氟取代基在多价金属卤化物如氯化铝或氯氟化物作为催化剂存在下进行。

39. 发明授权

US6066769A Process for the manufacture of halogenated propanes containing end-carbon fluorine 有权
标题翻译：制造含有末端碳氟的卤代丙烷的方法
公开(公告)号：US6066769A
公开(公告)日：2000-05-23
申请号：US155841
申请日：1998-10-06
申请人： Mario Joseph Nappa , Allen Capron Sievert , Edwin J. Warwas
发明人： Mario Joseph Nappa , Allen Capron Sievert , Edwin J. Warwas
IPC分类号： B01J23/26 , B01J27/132 , B01J37/08 , C07C17/20 , C07C17/21 , C07C19/08 , C07C19/10 , C07C17/08
CPC分类号： B01J23/26 , B01J27/132 , B01J37/088 , C07C17/206 , C07C17/21 , C07C19/08 , C07C19/10
摘要： A process is disclosed for producing a compound of the formula: CF.sub.3 CHXCF.sub.3-z Y.sub.2 where X and Y are independently selected from the group consisting of H and Cl, and z is 0 or 1. The process involves (1) contacting CCl.sub.3 CHXCC.sub.3-z Y.sub.z,CCl.sub.2-z .dbd.CXCC.sub.3, and/or CCl.sub.2 CX.dbd.CC.sub.3-z Y.sub.z starting material, with hydrogen fluoride at a temperature of less than 200.degree. C. to produce a fluorination product of said starting material which includes at least 90 mole percent total of C.sub.3 HXY.sub.z Cl.sub.6-z-x F.sub.x saturated compounds and C.sub.3 XY.sub.z Cl.sub.5-z-y F.sub.y olefinic compounds, wherein x is an integer from 1 to 6-z and y is an integer from 1 to 5-z, (the fluorination product including no more than about 40 mole percent of the desired product, CF.sub.3 CHXCF.sub.3-z Y.sub.z); (2) contacting saturated compounds and olefinic compounds produced in (1) with hydrogen fluoride in the vapor phase at a temperature of from 200.degree. C. to about 400.degree. C. in the presence of a fluorination catalyst; and (3) reacting a sufficient amount of said compounds, wherein x is an integer from 1 to 5-z and olefinic compounds produced in (1) with hydrogen fluoride in the vapor phase at a temperature of from 200.degree. C. to about 400.degree. C. in the presence of a vapor phase fluorination catalyst to provide an overall selectivity to CF.sub.3 CHXCF.sub.3-z Y.sub.z of at least about 90 percent based upon the amount of starting material reacted with HF in (1) and (2).
摘要翻译： PCT No.PCT / US97 / 06013 371 1998年10月6日第 102（e）日期1998年10月6日PCT 1997年4月4日PCT PCT。 WO97 / 37956 PCT公开号日期1997年10月16日公开了制备下式化合物的方法：CF 3 CHXCF 3 -ZY 2其中X和Y独立地选自H和Cl，z是0或1.该方法包括（1） CCl 3 CHXCC 3 -ZYz，CCl 2 -Z = CXCC 3和/或CCl 2 C X = CCl 3 -ZYz起始原料，在低于200℃的温度下加入氟化氢，以产生所述原料的氟化产物，其包含至少90摩尔％总共C3HXYzCl6-z-xFx饱和化合物和C3XYzCl5-z-yFy烯属化合物，其中x是1至6-z的整数，y是1至5-z的整数（氟化产物不超过约 40摩尔％的所需产物，CF 3 CHXCF 3 -ZYz）; （2）在氟化催化剂存在下，将温度为200℃至约400℃的气相中的（1）中产生的饱和化合物和烯烃化合物与氟化氢接触; 和（3）将足量的所述化合物（其中x是1至5-z的整数）和（1）中制备的烯烃化合物与气相中的氟化氢在200℃至约400℃的温度下反应在气相氟化催化剂的存在下，基于在（1）和（2）中与HF反应的原料的量，提供至少约90％的CF 3 CHXCF 3 -ZYz的总体选择性。

40. 发明授权

US6066768A Perhalofluorinated butanes and hexanes 失效
标题翻译：全氟化丁烷和己烷
公开(公告)号：US6066768A
公开(公告)日：2000-05-23
申请号：US738117
申请日：1996-10-25
申请人： Mario Joseph Nappa , Allen Capron Sievert
发明人： Mario Joseph Nappa , Allen Capron Sievert
IPC分类号： B01J27/125 , C07C17/23 , C07C17/278 , C07C19/08 , C07C19/10 , C07C19/14
CPC分类号： C07C19/14 , B01J27/125 , C07C17/23 , C07C17/278 , C07C19/08 , C07C19/10
摘要： The instant invention relates to producing perhalofluorobutanes and perhalofluorohexanes, more particularly it relates to their production by utilizing tetrafluoroethylene (hereinafter referred to as "TFE") and chlorotrifluoro-ethylene (hereinafter referred to as "CTFE") with selected perhalofluoroethanes containing 2 to 4 nonfluorine halogen and 2 to 4 fluorine substituents in the presence of a polyvalent metal halide such as an aluminum chloride or chlorofluoride as catalyst.
摘要翻译：本发明涉及生产全氟全氟代丁烷和全卤代己烷，更具体地说，涉及其使用四氟乙烯（以下称为“TFE”）和氯三氟乙烯（以下称为“CTFE”）的制备方法，该选择性全卤代乙烷含有2-4个非氟卤素和2至4个氟取代基在多价金属卤化物如氯化铝或氯氟化物作为催化剂存在下进行。

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