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    • 31. 发明授权
    • Silsesquioxane photoinitiators
    • 倍半硅氧烷光引发剂
    • US08637585B2
    • 2014-01-28
    • US13130796
    • 2009-11-24
    • Markus FreyChristophe FrossardKatia StuderKarin PowellJean-Luc BirbaumMartin Müller
    • Markus FreyChristophe FrossardKatia StuderKarin PowellJean-Luc BirbaumMartin Müller
    • C08F2/50C08J3/28C08F283/12C08F283/00
    • C07F7/21B33Y70/00
    • Photoinitiator compounds comprising both a photoactive moiety and an amine functionality, bonded to a polyhedral oligomeric silsesquioxane, which photoinitiator is represented by formula (1) or (1′) wherein n is 2m; m is an integer of 2 to 30; the sum of n′+a is an integer 4-60; n′ is an even-numbered integer; a is an even- or uneven-numbered integer; and for example different A C1-C12alkyl, or a photoactive moiety Q1, or a group of formula (2); E for example is a direct bond, L is linear or branched C1-C3alkylene, preferably propylene; R1 and R2 for example are a photoactive moiety Q, or C2-20alkyl; Q is for example a group of formula (4); Z2 is for example C1-C6alkylene which is unsubstituted or substituted by one or more OR6; and R6, R12, R13 and R14 for example are hydrogen; are especially suitable as low-migrating photoinitiators.
    • 光引发剂化合物,其包含与多面体低聚倍半硅氧烷结合的光活性部分和胺官能团,该光引发剂由式(1)或(1')表示,其中n为2m; m为2〜30的整数, n'+ a的和为4-60的整数; n'是偶数整数; a是偶数或不均匀的整数; 例如不同的A C1-C12烷基或光活性部分Q1或式(2)的基团; E例如是直接键合,L是直链或支链C1-C3亚烷基,优选丙烯; R1和R2例如是光活性部分Q或C2-20烷基; Q例如是式(4)的一组; Z2为例如未被取代或被一个或多个OR 6取代的C 1 -C 6亚烷基; R 6,R 12,R 13和R 14例如为氢; 特别适用于低迁移性光引发剂。
    • 33. 发明授权
    • Apparatus and method for estimating stopped engine crank angle
    • 用于估计停止的发动机曲柄角的装置和方法
    • US08099998B2
    • 2012-01-24
    • US12783075
    • 2010-05-19
    • Martin Müller
    • Martin Müller
    • G01M15/06
    • F02D41/042F02D2041/0092F02D2041/0095
    • An engine control system, controller, and method for estimating a stopped engine crank angle of an internal combustion engine. Typical crank sensors do not output a reliable crank signal when the engine is about to stop, and do not indicate crank direction which is necessary to determine if engine bounce-back occurs. A crank sensor signal is analyzed as the engine coasts to a stop so that a coast-down model can be adjusted to accurately estimate the stopped engine crank angle. A bounce-back model is also used to estimate an engine bounce-back angle and to make further corrections to the estimated stopped engine crank angle.
    • 一种用于估计内燃机停止的发动机曲柄角的发动机控制系统,控制器和方法。 当发动机即将停止时,典型的曲柄传感器不会输出可靠的曲柄信号,并且不指示确定发动机反弹是否发生所必需的曲柄方向。 当发动机滑行停止时,分析曲柄传感器信号,以便可以调整滑行模型以精确地估计停止的发动机曲柄角。 反弹模型也用于估计发动机反弹角度,并进一步校正估计的停止的发动机曲轴角度。
    • 35. 发明授权
    • System and method for model based boost control of turbo-charged engines
    • 涡轮增压发动机的基于模型的增压控制系统和方法
    • US07788922B2
    • 2010-09-07
    • US11867376
    • 2007-10-04
    • Martin Müller
    • Martin Müller
    • F02D23/00
    • F02B37/18F02B37/12F02B37/24F02M26/05Y02T10/144
    • A system and method for controlling boost pressure in various turbo-charged engine configurations as well as variable geometry turbine (VGT) arrangements includes an electronic controller programmed to receive a predetermined desired boost pressure PBoostdes. A desired pressure delta ΔPWGdes across a waste-gate valve is determined using the desired boost pressure PBoostdes. A control signal is generated for controlling the waste-gate valve so as to achieve the desired pressure delta ΔPWGdes. In boost pressure and vacuum pneumatically-actuated waste-gate valve arrangements, the respective solenoid duty cycles are obtained through use of various data structures. Where a waste-gate valve position is controlled by an electrical motor, the valve position is determined using a data structure as a function of desired waste-gate valve flow at sonic standard conditions.
    • 用于控制各种涡轮增压发动机配置以及可变几何涡轮机(VGT)装置中的增压压力的系统和方法包括被编程为接收预定的所需增压压力PBoostdes的电子控制器。 使用期望的增压压力PBoostdes确定跨废气阀门的期望压力δ&Dgr; PWGdes。 产生控制信号以控制废门阀,以达到所需的压力差ΔDgr; PWGdes。 在增压压力和真空气动致动的废闸阀装置中,通过使用各种数据结构获得各自的螺线管占空比。 在废电闸阀位置由电动机控制的情况下,阀位置是使用在声波标准条件下作为所需废门阀流量的函数的数据结构确定的。
    • 38. 发明授权
    • Cathode for a direct methanol fuel cell and method for operating the same
    • 直接甲醇燃料电池的阴极及其操作方法
    • US07638225B2
    • 2009-12-29
    • US10553574
    • 2004-04-08
    • Hendrik DohleMartin MüllerJan BringmannJürgen MergelDetlef Stolten
    • Hendrik DohleMartin MüllerJan BringmannJürgen MergelDetlef Stolten
    • H01M4/00H01M8/00
    • H01M4/8605H01M8/04156H01M8/1004H01M8/1009H01M2004/8689Y02E60/523
    • In low-temperature fuel cells according to prior art, the problem often arises that the diffusion layer of the cathode is filled by water which is permeated or produced on the cathode, such that oxygen can no longer be transported to the catalyst layer of the cathode in a frictionless manner. As a result, said fuel cells are regularly used with a high excess of oxygen in order to reduce the cited transport problems for the oxygen. The inventive fuel cell enables said problem to be solved in that the arrangement of the diffusion layer and the catalyst layer of the cathode is inverted. The diffusion layer, which is embodied in such a way as to also conduct ions, is directly adjacent to the electrolyte membrane. The catalyst layer oriented towards the free cathode space can advantageously directly react with the supplied oxygen without further transport problems. A further advantage lies in the fact that the water produced on the catalyst layer of the cathode and/or permeated by the electrolyte membrane and the diffusion layer can be easily withdrawn via the free cathode space.
    • 在根据现有技术的低温燃料电池中,经常出现的问题是阴极的扩散层被在阴极上渗透或产生的水填充,使得氧不再能够传输到阴极的催化剂层 以无摩擦的方式。 结果,所述燃料电池常规地使用大量的氧气,以便减少所引用的氧气运输问题。 本发明的燃料电池能够解决这个问题,即扩散层和阴极的催化剂层的布置被反转。 以能够进行离子的方式实施的扩散层与电解质膜直接相邻。 朝向自由阴极空间取向的催化剂层可以有利地直接与供应的氧气反应,而不会有进一步的运输问题。 另一个优点在于,可以通过自由阴极空间容易地排出在阴极的催化剂层上产生的和/或被电解质膜和扩散层渗透的水。
    • 39. 发明申请
    • Semiconductor Laser Device
    • 半导体激光器件
    • US20090304038A1
    • 2009-12-10
    • US12224572
    • 2007-02-08
    • Wolfgang SchmidMartin Müller
    • Wolfgang SchmidMartin Müller
    • H01S5/183
    • H01S5/183H01S5/026H01S5/041H01S5/22H01S5/4031
    • A semiconductor laser device comprising an optically pumped surface emitting vertical emitter (1), which emits in a vertical main radiation direction, and at least one monolithically integrated pump radiation source (2) for optically pumping the vertical emitter (1), wherein the pump radiation source (2) emits pump radiation in a pump main radiation direction running transversely with respect to the vertical main radiation direction. In a first embodiment, the semiconductor laser device includes at least one vertical section of the pump radiation source (2) that is embodied in index-guiding fashion for the pump radiation in a lateral direction transversely with respect to the pump main radiation direction and transversely with respect to the vertical main radiation direction. In a second embodiment, the semiconductor laser device includes a pump radiation source (2) that has a smaller width in a lateral direction transversely with respect to the pump main radiation direction in at least one vertical section than in a further vertical section. What is achieved in this way given suitable dimensioning is that modes of the pump radiation are forced completely or at least partly in a vertical direction from this section, whereby it is possible to reduce absorption losses of the pump radiation at conductive layers.
    • 一种半导体激光器件,包括发射在垂直主辐射方向上的垂直发射器(1)的光学泵浦表面和至少一个用于光学泵浦垂直发射器(1)的整体式泵浦辐射源(2),其中泵 辐射源(2)沿相对于垂直主辐射方向横向运行的泵主辐射方向发射泵浦辐射。 在第一实施例中,半导体激光装置包括泵浦辐射源(2)的至少一个垂直部分,其以相对于泵主辐射方向横向的横向方向上的泵辐射的折射率引导方式体现,并且横向地 相对于垂直主辐射方向。 在第二实施例中,半导体激光装置包括在至少一个垂直部分中相对于泵主辐射方向横向相比在另一垂直部分中具有较小宽度的泵浦辐射源(2)。 以这种方式实现的给定适当的尺寸是,泵浦辐射的模式被完全地或者至少部分地沿着该部分的垂直方向强制,由此可以减少导电层处的泵浦辐射的吸收损失。