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1. 发明申请

US20120142793A1 SILSESQUIOXANE PHOTOINITIATORS 有权
标题翻译： SILSESQUIOXANE照相机
公开(公告)号：US20120142793A1
公开(公告)日：2012-06-07
申请号：US13130796
申请日：2009-11-24
申请人： Markus Frey , Christophe Frossard , Katia Studer , Karin Powell , Jean-Luc Birbaum , Martin Müller
发明人： Markus Frey , Christophe Frossard , Katia Studer , Karin Powell , Jean-Luc Birbaum , Martin Müller
IPC分类号： C08F2/46 , C08G77/38 , C08J9/00 , C09D137/00 , C09D11/10 , C09J137/00 , C08G77/388 , C08F224/00
CPC分类号： C07F7/21 , B33Y70/00
摘要： Photoinitiator compounds comprising both a photoactive moiety and an amine functionality, bonded to a polyhedral oligomeric silsesquioxane, which photoinitiator is represented by formula (1) or (1′) wherein n is 2m; m is an integer of 2 to 30; the sum of n′+a is an integer 4-60; n′ is an even-numbered integer; a is an even- or uneven-numbered integer; and for example different A C1-C12alkyl, or a photoactive moiety Q1, or a group of formula (2); E for example is a direct bond, L is linear or branched C1-C3alkylene, preferably propylene; R1 and R2 for example are a photoactive moiety Q, or C2-20alkyl; Q is for example a group of formula (4); Z2 is for example C1-C6alkylene which is unsubstituted or substituted by one or more OR6; and R6, R12, R13 and R14 for example are hydrogen; are especially suitable as low-migrating photoinitiators.
摘要翻译：光引发剂化合物，其包含与多面体低聚倍半硅氧烷结合的光活性部分和胺官能团，该光引发剂由式（1）或（1'）表示，其中n为2m; m为2〜30的整数， n'+ a的和为4-60的整数; n'是偶数整数; a是偶数或不均匀的整数; 例如不同的A C1-C12烷基或光活性部分Q1或式（2）的基团; E例如是直接键合，L是直链或支链C1-C3亚烷基，优选丙烯; R1和R2例如是光活性部分Q或C2-20烷基; Q例如是式（4）的一组; Z2为例如未被取代或被一个或多个OR 6取代的C 1 -C 6亚烷基; R 6，R 12，R 13和R 14例如为氢; 特别适用于低迁移性光引发剂。

2. 发明授权

US08637585B2 Silsesquioxane photoinitiators 有权
标题翻译：倍半硅氧烷光引发剂
公开(公告)号：US08637585B2
公开(公告)日：2014-01-28
申请号：US13130796
申请日：2009-11-24
申请人： Markus Frey , Christophe Frossard , Katia Studer , Karin Powell , Jean-Luc Birbaum , Martin Müller
发明人： Markus Frey , Christophe Frossard , Katia Studer , Karin Powell , Jean-Luc Birbaum , Martin Müller
IPC分类号： C08F2/50 , C08J3/28 , C08F283/12 , C08F283/00
CPC分类号： C07F7/21 , B33Y70/00
摘要： Photoinitiator compounds comprising both a photoactive moiety and an amine functionality, bonded to a polyhedral oligomeric silsesquioxane, which photoinitiator is represented by formula (1) or (1′) wherein n is 2m; m is an integer of 2 to 30; the sum of n′+a is an integer 4-60; n′ is an even-numbered integer; a is an even- or uneven-numbered integer; and for example different A C1-C12alkyl, or a photoactive moiety Q1, or a group of formula (2); E for example is a direct bond, L is linear or branched C1-C3alkylene, preferably propylene; R1 and R2 for example are a photoactive moiety Q, or C2-20alkyl; Q is for example a group of formula (4); Z2 is for example C1-C6alkylene which is unsubstituted or substituted by one or more OR6; and R6, R12, R13 and R14 for example are hydrogen; are especially suitable as low-migrating photoinitiators.
摘要翻译：光引发剂化合物，其包含与多面体低聚倍半硅氧烷结合的光活性部分和胺官能团，该光引发剂由式（1）或（1'）表示，其中n为2m; m为2〜30的整数， n'+ a的和为4-60的整数; n'是偶数整数; a是偶数或不均匀的整数; 例如不同的A C1-C12烷基或光活性部分Q1或式（2）的基团; E例如是直接键合，L是直链或支链C1-C3亚烷基，优选丙烯; R1和R2例如是光活性部分Q或C2-20烷基; Q例如是式（4）的一组; Z2为例如未被取代或被一个或多个OR 6取代的C 1 -C 6亚烷基; R 6，R 12，R 13和R 14例如为氢; 特别适用于低迁移性光引发剂。

3. 发明申请

US20120178844A1 MACROPHOTOINITIATORS 有权
标题翻译：大理石师
公开(公告)号：US20120178844A1
公开(公告)日：2012-07-12
申请号：US13386954
申请日：2010-07-26
申请人： Markus Frey , Christophe Frossard , Katia Studer , Bruno Spony , Patrizia Sgambati
发明人： Markus Frey , Christophe Frossard , Katia Studer , Bruno Spony , Patrizia Sgambati
IPC分类号： C08F2/46 , C07C67/00 , C09K3/00 , C07C221/00 , C07C225/10 , C07C69/00
CPC分类号： C07C217/36 , C07C219/06 , C08F2/50 , G03F7/031
摘要： The invention pertains to high-molecular photoinitiator compounds comprising a photoactive moiety Q and an amine functionality, preferably a tertiary amino group, where the photoactive moiety Q is a benzoyl photoactive moiety.
摘要翻译：本发明涉及包含光活性部分Q和胺官能团，优选叔氨基的高分子光引发剂化合物，其中光活性部分Q是苯甲酰基光活性部分。

4. 发明授权

US08906979B2 Macrophotoinitiators 有权
标题翻译：大分子引发剂
公开(公告)号：US08906979B2
公开(公告)日：2014-12-09
申请号：US13386954
申请日：2010-07-26
申请人： Markus Frey , Christophe Frossard , Katia Studer , Bruno Spony , Patrizia Sgambati
发明人： Markus Frey , Christophe Frossard , Katia Studer , Bruno Spony , Patrizia Sgambati
IPC分类号： G03F7/031 , C08F2/46 , C07C221/00 , C07C67/00 , C07C225/10 , C07C69/00 , C07C217/36 , C07C219/06 , C08F2/50
CPC分类号： C07C217/36 , C07C219/06 , C08F2/50 , G03F7/031
摘要： The invention pertains to high-molecular photoinitiator compounds comprising a photoactive moiety Q and an amine functionality, preferably a tertiary amino group, where the photoactive moiety Q is a benzoyl photoactive moiety.
摘要翻译：本发明涉及包含光活性部分Q和胺官能团，优选叔氨基的高分子光引发剂化合物，其中光活性部分Q是苯甲酰基光活性部分。

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