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31. 发明授权

US4534838A Siloxane polyphotoinitiators of the substituted acetophenone type 失效
标题翻译：取代苯乙酮型硅氧烷聚光引发剂
公开(公告)号：US4534838A
公开(公告)日：1985-08-13
申请号：US655398
申请日：1984-09-27
申请人： Samuel Q. S. Lin , Anthony F. Jacobine
发明人： Samuel Q. S. Lin , Anthony F. Jacobine
IPC分类号： C08F2/46 , C08F2/50 , C08G77/38 , C08K5/5419 , G03F7/075
CPC分类号： G03F7/0757 , C08F2/50 , C08G77/38 , C08K5/5419 , Y10S522/904
摘要： An organopolysiloxane photoinitiator having an average of at least two siloxane units, of which at least an average of one siloxane unit per organopolysiloxane molecule has the formula:X.sub.a R.sub.b SiO(.sub.4-a-b)/2 (I)wherein a is an integer of 1-3, b is an integer of 0-2 and a plus b equals 1-3; R is C.sub.1 -C.sub.10 hydrocarbyl or halogen substituted C.sub.1 -C.sub.10 hydrocarbyl; and X is a substituted acetophenone photomoiety selected from: ##STR1## where R.sup.1 is any substituent which will not interfere with hydrosilation, n is an integer between 0 and 5 in formulas (II), (IIa), (III), (IIIa), (IV) and (IVa) and between 0 and 4 in formula (III) and (IIIa); m is 0 or 1; R.sup.2 is alkyl or substituted alkyl; R.sup.3 is H, alkyl or aryl; R.sup.4 is a divalent hydrocarbon group having between 2 and 10 carbon atoms or an alkylene oxy alkylene group; R.sup.5 is a group selected from H, alkyl, aryl, organosilyl, or the reaction product of an isocyanate esterification reagent or an etherification reagent with the hydroxyl product formed when R.sup.5 is H and R.sup.6 is a trivalent hydrocarbon or hydrocarbon oxyhydrocarbon group.The silicones are prepared by hydrosilation of the corresponding olefinically or acetylenically unsaturated acetophenones.
摘要翻译：平均具有至少两个硅氧烷单元的有机聚硅氧烷光引发剂，其中至少一个每个有机聚硅氧烷分子的一个硅氧烷单元的平均值具有下式：XaRbSiO（4-ab）/ 2（I）其中a是1-3的整数 b是0-2的整数，加上b等于1-3; R是C1-C10烃基或卤素取代的C1-C10烃基; （IIIa）（IIIa）（IVa）（IVa）（IVa）其中R1是任何一个，其中R 1是任何式（II），（IIa），（III），（IIIa），（IV）和（IVa）中的0和5之间的整数，式（III）中0和4之间的整数为0〜）和（IIIa）; m为0或1; R2是烷基或取代的烷基; R3是H，烷基或芳基; R4是具有2-10个碳原子的二价烃基或亚烷基氧基亚烷基; R5为选自H，烷基，芳基，有机甲硅烷基或异氰酸酯酯化试剂或醚化试剂与R5为H形成羟基的反应产物，R6为三价烃基或烃氧基烃基时的反应产物。硅氧烷通过相应的烯属或非炔属不饱和苯乙酮的硅氢化来制备。

32. 发明申请

US20090025874A1 Novel Adducts Useful As Cure Components For Anaerobic Curable Compositions 有权
标题翻译：新型加合物作为无氧可固化组合物的固化组分有用
公开(公告)号：US20090025874A1
公开(公告)日：2009-01-29
申请号：US11781306
申请日：2007-07-23
申请人： Andrew D. Messana , Anthony F. Jacobine
发明人： Andrew D. Messana , Anthony F. Jacobine
IPC分类号： C09J167/00 , C09J5/00
CPC分类号： C09J4/06 , C08F8/30 , C08F20/00 , C08F22/06
摘要： The present invention relates to novel polymer-bound adducts useful as cure components for anaerobic curable compositions. The compositions are particularly useful as adhesives and sealants.
摘要翻译：本发明涉及可用作厌氧可固化组合物的固化组分的新型聚合物结合的加合物。组合物特别可用作粘合剂和密封剂。

33. 发明授权

US5028661A Adhesion promoters for thiolene adhesive formulations 失效
标题翻译：硫醇粘合剂配方的粘合促进剂
公开(公告)号：US5028661A
公开(公告)日：1991-07-02
申请号：US443046
申请日：1989-11-27
申请人： Paul J. Clark , Anthony F. Jacobine , David M. Glaser
发明人： Paul J. Clark , Anthony F. Jacobine , David M. Glaser
IPC分类号： C08G75/04
CPC分类号： C08G75/045
摘要： Compounds useful as adhesion promoters for thermally cured thiolene adhesives include a) acrylic or norbornene acid phosphate esters such as ##STR1## b) maleic, acrylic, methacrylic, norbornene dicarboxylic, and fumaric acids and half acid esters and peresters of maleic fumaric and norbornene dicarboxylic acids; and c) norbornene, acrylic or methacrylic silanes having two or three hydrolyzable groups bound to the silicon atom thereof, such as 5-(triacetoxysilyl) norbornene.The adhesion promoters may be employed as surface primers for conventional thiolene compositions. Alternatively the thiolene compositions themselves may be modified by addition of 0.1 to 10% by weight of the adhesion promoter. Preferred thiolene compositions employ norbornene functional ene ingredients.
摘要翻译：可用作热固化硫醇粘合剂的粘合促进剂的化合物包括：a）丙烯酸或降冰片烯酸性磷酸酯，例如马来酸，丙烯酸，甲基丙烯酸，降冰片烯二羧酸和富马酸，马来酸的半酸酯和过酸酯富马酸和降冰片烯二羧酸; 和c）具有两个或三个与其硅原子结合的可水解基团的降冰片烯，丙烯酸或甲基丙烯酸硅烷如5-（三乙酰氧基甲硅烷基）降冰片烯。粘合促进剂可用作常规硫羟组合物的表面引物。或者，硫醇组合物本身可以通过加入0.1至10重量％的粘合促进剂来改性。优选的硫醇组合物使用降冰片烯功能烯成分。

34. 发明授权

US4425208A Compositions and process 失效
公开(公告)号：US4425208A
公开(公告)日：1984-01-10
申请号：US290689
申请日：1981-08-06
申请人： Anthony F. Jacobine
发明人： Anthony F. Jacobine
IPC分类号： C08F2/48 , C08F2/50 , G03F7/031
CPC分类号： C08F2/50 , G03F7/031
摘要： The photopolymerization of ethylenically unsaturated compounds is effected using a combination of an aromatic ketone photosensitizer and a tetrasubstituted urea (e.g. N,N,N',N'-tetramethylurea) or N,N-disubstituted acid amide. Storage stable liquid photoinitiator compositions comprising an aromatic ketone sensitizer (e.g. benzophenone) and a tetrasubstituted urea (e.g. N,N,N',N'-tetramethylurea) are also disclosed. The use of the tetrasubstituted urea or N,N-disubstituted amide possesses advantages (storage stability, lack of discoloration on curing) over photosensitizers such as Michler's ketone which have been used previously in combination with aromatic ketone photosensitizers.

35. 发明授权

US08609881B2 Cure accelerators for anaerobic curable compositions 有权
标题翻译：用于厌氧可固化组合物的固化促进剂
公开(公告)号：US08609881B2
公开(公告)日：2013-12-17
申请号：US12116500
申请日：2008-05-07
申请人： Andrew Messana , Anthony F. Jacobine , Steven Thomas Nakos , David M. Glaser
发明人： Andrew Messana , Anthony F. Jacobine , Steven Thomas Nakos , David M. Glaser
IPC分类号： C07C69/76 , C07C303/00 , C07C307/00 , C07C309/00 , C07C311/00 , C07C315/00 , C07C317/00 , C07C321/00 , C07C323/00 , C07C381/00 , C07C261/00 , C07C269/00 , C07C271/00 , C07C69/74 , C07C273/00 , C07C275/00
CPC分类号： C07C281/02 , C07C243/28
摘要： The present invention provides compound(s) selected from the group of compounds represented by structural Formula (I): wherein X, Y and R1 are as described herein, use of such compounds as anaerobic cure accelerators, and compostions including such compounds.
摘要翻译：本发明提供选自由结构式（I）表示的化合物组的化合物：其中X，Y和R 1如本文所述，使用这些化合物作为厌氧固化促进剂和包括这些化合物的组合物。

36. 发明授权

US08362112B2 Cure accelerators for anaerobic curable compositions 有权
标题翻译：用于厌氧可固化组合物的固化促进剂
公开(公告)号：US08362112B2
公开(公告)日：2013-01-29
申请号：US13284176
申请日：2011-10-28
申请人： David P. Birkett , Martin Wyer , Andrew Messana , David P. Dworak , Anthony F. Jacobine
发明人： David P. Birkett , Martin Wyer , Andrew Messana , David P. Dworak , Anthony F. Jacobine
IPC分类号： C07D215/06 , C08F120/34 , C09J4/00
CPC分类号： C08G18/765 , C08F290/067 , C08G18/10 , C08G18/3293 , C08G18/3844 , C08G18/4854 , C08G18/672 , C08L33/14 , C09J133/14 , C09J175/16 , C08G18/48
摘要： The present invention relates to cure accelerators useful for anaerobic curable compositions, such as adhesives and sealants. The cure accelerators are constructed as urethane/urea/thiourethane (meth)acrylate resins from diols and include a unit embraced within structure A where X is C1-20 alkyl, C2-20 alkenyl, or C7-20 alkaryl, any of which may be interrupted by one or more hereto atoms, and which are functionalized by at least one and preferably at least two groups selected from —OH, —NH2 or —SH and z is 1-3.
摘要翻译：本发明涉及可用于厌氧可固化组合物如粘合剂和密封剂的固化促进剂。固化促进剂由二醇构成为氨基甲酸酯/脲/硫代氨基甲酸酯（甲基）丙烯酸酯树脂，并且包括包含在结构A中的单元，其中X是C 1-20烃基，C 2-20烯基或C 7-20烷芳基，其中任何一种可以是由一个或多个原子间隔，并且由至少一个选自-OH，-NH2或-SH的至少一个并优选至少两个基团官能化，z为1-3。

37. 发明授权

US5399624A High purity resins for thiol-ene polymerizations and method for producing same 失效
标题翻译：用于硫醇烯聚合的高纯度树脂及其制备方法
公开(公告)号：US5399624A
公开(公告)日：1995-03-21
申请号：US56128
申请日：1993-04-30
申请人： David M. Glaser , Anthony F. Jacobine , Paul J. Grabek
发明人： David M. Glaser , Anthony F. Jacobine , Paul J. Grabek
IPC分类号： B29C67/00 , C08F6/02 , C08F8/34 , C08F8/42 , C08G75/02 , C08G75/04 , G03F7/00 , G03F7/027 , C08F279/00
CPC分类号： B29C67/0066 , C08F6/02 , C08G75/045 , G03F7/0037 , G03F7/0275
摘要： A treatment method for polyene resins used in thiol-ene formulations, especially norbornene resins, significantly stabilizes thiol-ene compositions made from batches of polyene resin which otherwise give compositions with poor dark stability. The treatment comprises contacting the polyene with an amphoteric treating agent selected from the group consisting of silicated magnesium oxide, basic aluminum oxide, silica gel, magnesium oxide, magnesium hydroxide, calcium oxide, calcium hydroxide, barium oxide, and barium hydroxide, and then separating the resin from the treating agent prior to mixture with a polythiol to form a thiol-ene composition. The treatment method significantly reduces ionic content in polyene resins, particularly chloride ion but also sodium and potassium ions. Consequently, treatment is also beneficial with polyene resins which do not produce substantial dark stability problems. Reduction of the ionic content of the resin is desirable to produce cured thiolene polymers with low electrical conductivity and low corrosiveness.
摘要翻译：用于硫醇烯制剂，特别是降冰片烯树脂中的多烯树脂的处理方法显着地稳定了一批由多烯树脂制成的硫醇烯组合物，否则会产生具有差的黑色稳定性的组合物。处理包括使多烯与选自硅酸镁，碱性氧化铝，硅胶，氧化镁，氢氧化镁，氧化钙，氢氧化钙，氧化钡和氢氧化钡的两性处理剂接触，然后分离在与多硫醇混合之前来自处理剂的树脂形成硫醇 - 烯组合物。处理方法显着降低了多烯树脂中的离子含量，特别是氯离子，而且钠离子和钾离子。因此，对于不产生实质的黑暗稳定性问题的多烯树脂，处理也是有益的。需要降低树脂的离子含量以生产具有低导电性和低腐蚀性的固化硫醇聚合物。

38. 发明授权

US4640940A Polyol terminated silicones and derivatives thereof 失效
标题翻译：多元醇封端的硅氧烷及其衍生物
公开(公告)号：US4640940A
公开(公告)日：1987-02-03
申请号：US765292
申请日：1985-08-13
申请人： Anthony F. Jacobine , David M. Glaser
发明人： Anthony F. Jacobine , David M. Glaser
IPC分类号： C08F2/46 , C08F30/08 , C08G77/38 , C08G77/382
CPC分类号： C08G77/382 , C08F30/08 , C08G77/38
摘要： Polyorganosiloxane polymers which include at least one group of the formula: ##STR1## where R.sup.1 is an organo group; R.sup.2 is alkylene or alkenylene; G is a n+1 valent hydrocarbon, oxyhydrocarbon or poly(oxyhydrocarbon) radical in which some or all of the hydrogen atoms may optionally be substituted by halogen atoms; R.sup.3 is H or an organic functional group, particularly polymerizable groups, polymerization accelerating groups or polymerization initiating groups; n is an integer of 2 or more provided that when n is 2 and one of R.sup.3 is H, the other R.sup.3 group is also H; and a is 0, 1 or 2.Additional polyorganosiloxane polymers include at least one group of the formula: ##STR2## where R.sup.4 R.sup.5 are H or a mono valent hydrocarbon group.
摘要翻译：包含至少一个下式的基团的聚有机硅氧烷聚合物：其中R 1是有机基团; R2是亚烷基或亚烯基; G是n + 1价烃，羟基烃或聚（氧代烃）基团，其中一些或全部氢原子可以任选被卤素原子取代; R3是H或有机官能团，特别是可聚合基团，聚合促进基团或聚合引发基团; n是2或更大的整数，条件是当n是2且R3中的一个是H时，另一个R3基也是H; 和a为0,1或2.另外的聚有机硅氧烷聚合物包括至少一个下式的基团：其中R 4 R 5是H或一价烃基。

39. 发明授权

US4518473A Compositions and process 失效
标题翻译：组成和过程
公开(公告)号：US4518473A
公开(公告)日：1985-05-21
申请号：US540225
申请日：1983-10-11
申请人： Anthony F. Jacobine
发明人： Anthony F. Jacobine
IPC分类号： C08F2/50 , G03F7/031 , C08F2/48
CPC分类号： G03F7/031 , C08F2/50 , Y10S430/12 , Y10S430/121
摘要： The photopolymerization of ethylenically unsaturated compounds is effected using a combination of an aromatic ketone photosensitizer and a tetrasubstituted urea (e.g. N,N,N',N'-tetramethylurea) or N,N-disubstituted acid amide. Storage stable liquid photoinitiator compositions comprising an aromatic ketone sensitizer (e.g. benzophenone) and a tetrasubstituted urea (e.g. N,N,N',N'-tetramethylurea) are also disclosed. The use of the tetrasubstituted urea or N,N-disubstituted amide possesses advantages (storage stability, lack of discoloration on curing) over photosensitizers such as Michler's ketone which have been used previously in combination with aromatic ketone photosensitizers.
摘要翻译：烯属不饱和化合物的光聚合使用芳族酮光敏剂和四取代脲（例如N，N，N'，N'-四甲基脲）或N，N-二取代的酰胺的组合进行。还公开了包含芳族酮敏化剂（例如二苯甲酮）和四取代脲（例如N，N，N'，N'-四甲基脲）的储存稳定的液体光引发剂组合物。使用四取代的脲或N，N-二取代的酰胺具有优于光敏剂如存在于以前与芳族酮光敏剂组合使用的米ler酮的优点（固化时缺乏变色）。

40. 发明授权

US08598279B2 Adducts useful as cure components for anaerobic curable compositions 有权
标题翻译：可用作厌氧可固化组合物的固化组分的加合物
公开(公告)号：US08598279B2
公开(公告)日：2013-12-03
申请号：US11781306
申请日：2007-07-23
申请人： Andrew D. Messana , Anthony F. Jacobine
发明人： Andrew D. Messana , Anthony F. Jacobine
IPC分类号： C08F8/30 , C08F8/06 , C08L23/26
CPC分类号： C09J4/06 , C08F8/30 , C08F20/00 , C08F22/06
摘要： The present invention relates to novel polymer-bound adducts useful as cure components for anaerobic curable compositions. The compositions are particularly useful as adhesives and sealants.
摘要翻译：本发明涉及可用作厌氧可固化组合物的固化组分的新型聚合物结合的加合物。组合物特别可用作粘合剂和密封剂。

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