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    • 35. 发明授权
    • Sheet magnet having microcrystalline structure and method of manufacturing the same, and method of manufacturing isotropic permanent magnet powder
    • 具有微晶结构的片状磁体及其制造方法以及制造各向同性永磁体粉末的方法
    • US06168673A
    • 2001-01-02
    • US09284604
    • 1999-05-20
    • Hirokazu KanekiyoSatoshi Hirosawa
    • Hirokazu KanekiyoSatoshi Hirosawa
    • H01F1053
    • B82Y25/00H01F1/0571H01F1/0579
    • An object of this invention is to provide a thin-film magnet having a residual magnetic flux density Br of not less than 10 kG, a cost performance equal to that of a hard ferrite magnet, and a thickness of 70-300 &mgr;m contributing to the miniaturization and thinning of a magnetic circuit, and a method of manufacturing the same. When a molten alloy of a predetermined structure having a small content of a rare earth element is subjected to continuous casting using a cooling roll in an inert gas atmosphere with reduced pressures of not more than 30 kPa at a predetermined peripheral speed of the roll, it turns into a crystalline structure substantially not less than 90% of which comprises a Fe3B type compound and a compound phase having &agr; —Fe and Nd2Fe14B type crystalline structures compatible with the former. A continuous thin-film magnet of 70-300 &mgr;m in thickness comprising a microcrystalline structure of 10-50 nm in average crystal grain diameter having magnetic characteristics of iHc≧2 kOe, Br≧10 kG and practically usable as a permanent magnet can be obtained. A thin-film magnet which has heretofore been difficult to be industrially produced can be mass-produced at a low price by a simple method.
    • 本发明的目的是提供一种具有不小于10kG的剩余磁通密度Br,与硬质铁氧体磁体相同的成本性能和70-300μm的厚度的薄膜磁体, 磁路的小型化和薄化及其制造方法。 使用稀土元素含量少的预定结构的熔融合金,在辊的预定圆周速度下,在惰性气体气氛中以不超过30kPa的减压下,使用冷却辊进行连续铸造, 变成基本上不小于90%的晶体结构,其包含Fe 3 B型化合物和具有与前者相容的α-Fe和Nd 2 Fe 14 B型结晶结构的化合物相。 具有70-300μm厚度的连续薄膜磁体,其包含具有iHc> = 2kOe,Br> = 10kG的磁特性并且实际上可用作永磁体的平均晶粒直径为10-50nm的微晶结构 得到。 迄今为止难以在工业上生产的薄膜磁体可以通过简单的方法以低价格批量生产。
    • 37. 发明授权
    • R-Fe-B microcrystalline high-density magnet and process for production thereof
    • R-Fe-B微晶高密度磁铁及其制造方法
    • US08128758B2
    • 2012-03-06
    • US12254967
    • 2008-10-21
    • Noriyuki NozawaTakeshi NishiuchiSatoshi HirosawaTomohito Maki
    • Noriyuki NozawaTakeshi NishiuchiSatoshi HirosawaTomohito Maki
    • H01F1/057
    • H01F41/0273B22F3/11B22F2003/248B22F2998/10C22C38/005C22C2202/02H01F1/0573H01F1/0576H01F1/0577H01F1/0578H01F41/0293B22F3/02B22F3/24
    • An R—Fe—B based rare-earth alloy powder with a mean particle size of less than about 20 μm is provided and compacted to make a powder compact. Next, the powder compact is subjected to a heat treatment at a temperature of about 550° C. to less than about 1,000° C. within hydrogen gas, thereby producing hydrogenation and disproportionation reactions (HD processes). Then, the powder compact is subjected to another heat treatment at a temperature of about 550° C. to less than about 1,000° C. within either a vacuum or an inert atmosphere, thereby producing desorption and recombination reactions and obtaining a porous material including fine crystal grains, of which the density is about 60% to about 90% of their true density and which have an average crystal grain size of about 0.01 μm to about 2 μm (DR processes). Thereafter, the porous material is subjected to yet another heat treatment at a temperature of about 750° C. to less than about 1,000° C. within either the vacuum or the inert atmosphere, thereby further increasing its density to about 93% or more of their true density and making an R—Fe—B based microcrystalline high-density magnet.
    • 提供平均粒度小于约20μm的R-Fe-B基稀土合金粉末并压实成粉末压块。 接着,在氢气中,在约550℃至小于约1000℃的温度下对粉体进行热处理,由此进行氢化和歧化反应(HD工艺)。 然后,在真空或惰性气氛中,将粉末压块在约550℃至小于约1000℃的温度下进行另外的热处理,从而产生解吸和重组反应,并获得包括精细的多孔材料 晶粒,其密度为其真密度的约60%至约90%,并且其平均晶粒尺寸为约0.01μm至约2μm(DR工艺)。 此后,多孔材料在真空或惰性气氛中在约750℃至小于约1000℃的温度下进行另外的热处理,从而进一步将其密度提高到约93%以上 它们的真实密度并制成R-Fe-B基微晶高密度磁体。
    • 40. 发明申请
    • MAGNETIC ALLOY MATERIAL AND METHOD OF MAKING THE MAGNETIC ALLOY MATERIAL
    • 磁性合金材料及制备磁性合金材料的方法
    • US20070137732A1
    • 2007-06-21
    • US11673729
    • 2007-02-12
    • Ryosuke KOGUREHirokazu KANEKIYOTakeshi NISHIUCHISatoshi HIROSAWA
    • Ryosuke KOGUREHirokazu KANEKIYOTakeshi NISHIUCHISatoshi HIROSAWA
    • H01F1/055
    • H01F1/015H01F1/0571
    • A method of making a magnetic alloy material includes the steps of: preparing a melt of an alloy material having a predetermined composition; rapidly cooling and solidifying the melt to obtain a rapidly solidified alloy represented by: Fe100-a-b-cREaAbTMC where RE is at least one rare-earth element selected from La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er and Tm and including at least about 90 at % of La; A is at least one element selected from Al, Si, Ga, Ge and Sn; TM is at least one transition metal element selected from Sc, Ti, V, Cr, Mn, Co, Ni, Cu and Zn; and 5 at %≦a≦10 at 5%, 4.7 at% ≦b≦18 at % and 0 at %≦c≦9 at %; and producing a compound phase having an NaZn13-type crystal structure in at least about 70 vol % of the rapidly solidified alloy.
    • 制造磁性合金材料的方法包括以下步骤:制备具有预定组成的合金材料的熔体; 快速冷却和固化熔体以获得由以下组成的快速固化的合金:Fe 100 B a C B C / SUB>其中RE是选自La,Ce,Pr,Nd,Pm,Sm,Eu,Gd,Tb,Dy,Ho,Er和Tm中的至少一种稀土元素,并且包括至少约90at%的La ; A是选自Al,Si,Ga,Ge和Sn中的至少一种元素; TM是选自Sc,Ti,V,Cr,Mn,Co,Ni,Cu和Zn中的至少一种过渡金属元素; 和5 at%<= a <= 10在5%,4.7 at%<= b <= 18 at%和0 at%<= c <= 9 at%; 并在至少约70vol%的快速凝固合金中生产具有NaZn 13 N型晶体结构的化合物相。