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    • 31. 发明授权
    • Process for preparing an ortho-substituted 5-halophenol and a synthesis intermediate thereof
    • 制备邻位取代的5-卤代苯酚的方法及其合成中间体
    • US08975431B2
    • 2015-03-10
    • US13698985
    • 2010-05-19
    • Claude MercierFloryan De CampoSébastien Righini
    • Claude MercierFloryan De CampoSébastien Righini
    • C07C309/75C07C41/01C07C303/28C07C41/26C07C303/30
    • C07C303/28C07C41/26C07C303/30C07C309/66C07C43/23
    • A process for preparing a 5-halophenol, ortho-substituted by an electron-donating group, is described. Also described, is a process for preparing a sulphonic ester of an ortho-substituted phenol, which is the synthesis intermediate for the ortho-substituted 5-halophenol. The process for preparing a phenol ortho-substituted by an electron-donating group and protected in the form of a sulphonic ester can include reacting a phenol ortho-substituted by an electron-donating group with a sulphonylating agent in the presence of a Lewis acid. The process for preparing a 5-halophenol ortho-substituted by an electron-donating group can include a first step of preparing a phenol ortho-substituted by an electron-donating group and protected in the form of a sulphonic ester, as described above; a second step of halogenating the protected phenol intermediate obtained in the preceding step, in the position para to the electron-donating group; and a third step of deprotecting the sulphonic ester function to hydroxyl.
    • 描述了由给电子基团取代的5-卤代苯酚的制备方法。 还描述的是制备邻位取代的苯酚的磺酸酯的方法,其为邻位取代的5-卤代苯酚的合成中间体。 制备由供电子基团取代并以磺酸酯形式保护的苯酚的方法可以包括在路易斯酸存在下将由供电子基团邻位取代的苯酚与磺酰化剂反应。 制备由给电子基团取代的5-卤代苯酚的方法可以包括如上所述制备被供电子基团邻位取代并以磺酸酯形式保护的苯酚的第一步骤; 将前述步骤中获得的被保护的苯酚中间体卤化到给电子基团的对位的第二步骤; 以及将磺酸酯功能脱保护成羟基的第三步骤。
    • 37. 发明授权
    • Process for the preparation of terpene peroxides and peroxides thus
obtained
    • 制备由此获得的萜烯过氧化物和过氧化物的方法
    • US4933501A
    • 1990-06-12
    • US311047
    • 1989-02-16
    • Claude Mercier
    • Claude Mercier
    • C07C67/00C07C407/00C07C409/16C07C409/18C07F7/08
    • C07F7/0894C07C407/00C07C409/16C07C409/18C07C2101/14
    • Terpene peroxides of formula: ##STR1## in which R denotes a tertiary alkyl radical substituted, if desired, by one or more phenyl radicals, a cycloalkyl radical or a trialkylsilyl radical, R.sub.1, R.sub.2 and R.sub.3, which are identical or different, each denote hydrogen or an aliphatic radical optionally containing one or more double or triple bonds and optionally substituted, and R.sub.4 denotes an aliphatic radical optionally containing one or more double or triple bonds and optionally substituted or R.sub.3 denotes hydrogen and R.sub.2 and R.sub.4 together form an alkylene radical which may be substituted by one or more methyl radicals, are obtained by reaction of a hydroperoxide of formula R--OOH with a compound of formula: ##STR2## the operation being carried out in a basic aprotic solvent.
    • 式中:IMA GE denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote denote 氢或任选地含有一个或多个双键或三键并任选取代的脂族基团,并且R 4表示任选含有一个或多个双键或三键并且任选取代的脂族基团或R 3表示氢,且R 2和R 4一起形成亚烷基, 可通过一种或多种甲基自由基代替,其通过式R-OOH的氢过氧化物与式(IIIa)或(IIIb)化合物(IIIb)的反应获得:该操作是在碱性非质子 溶剂。
    • 38. 发明授权
    • Method and device for manufacturing charcoal
    • 生产木炭的方法和装置
    • US4926763A
    • 1990-05-22
    • US297409
    • 1989-01-17
    • Andre-Jean LerouxClaude Mercier
    • Andre-Jean LerouxClaude Mercier
    • C10B53/02
    • C10L9/083C10B53/02Y02E50/14Y02E50/15Y02P20/145Y10T428/31989
    • A charcoal manufacturing device includes at least two bottomless furnaces of which, in operation, at least one is in a carbonization phase and at least one other is charged with wet wood to be dried. An incinerator is provided for burning the gas produced during the carbonization phase, connected to the at least one furnace. A first hot gas diluter is connected to this incinerator and an extractor is connected to the first diluter. An optional washing device is connected to the extractor. Hot gas produced by the at least one furnace during the carbonization phase is drawn off upstream of the extractor and conveyed to the at least one other furnace by a system that includes a second hot gas diluter. This second diluter renders the temperature of the hot gas compatible with the wet wood to be dried.
    • 木炭制造装置包括至少两个无底炉,在操作中,至少一个处于碳化阶段,并且至少另一个装有待干燥的湿木材。 提供了一种焚化炉,用于燃烧在碳化阶段产生的气体,连接至至少一个炉。 第一热气稀释器连接到该焚烧炉,并且提取器连接到第一稀释器。 可选的洗涤装置连接到提取器。 在碳化阶段期间由至少一个炉产生的热气体从萃取器的上游排出,并通过包括第二热气稀释器的系统输送到至少另一个炉。 该第二稀释器使热气体的温度与待干燥的湿木材相容。
    • 40. 发明授权
    • Calibrating distributor of cylindrical members
    • 圆柱形零件校准分配器
    • US4651880A
    • 1987-03-24
    • US829522
    • 1986-02-14
    • Marcel MabbouxClaude Mercier
    • Marcel MabbouxClaude Mercier
    • B65G47/84B07C5/06B65G47/90G21C17/06G21C21/02
    • B07C5/06G21C17/06
    • A calibrating distributor of cylindrical members incorporating a cylindrical member supply station, a drum for transferring the members between the supply and a distribution station, the drum having equidistant cavities, each of which receive one of the members, a calibrating plate to transfer the cylindrical members having a diameter exceeding a maximum permitted diameter between the distribution station and an ejection station, the plate having equidistant calibrated holes, which are at least partly frustum-shaped, whose smallest diameter is equal to the maximum permitted diameter, a drive for the stepwise rotation of the transfer drum and the calibrating plate, and a pusher for forcing the cylindrical members contained in the cavities into and through calibrated holes whereby the members having a diameter exceeding the maximum permitted diameter remain jammed in the holes and are ejected at the ejection station.
    • 包括圆柱形构件供应站的圆柱形构件的校准分配器,用于在构件和分配站之间传送构件的滚筒,具有等距空腔的滚筒,每个凹槽容纳其中一个构件;校准板,用于将圆柱形构件 具有超过分配站和排出站之间的最大允许直径的直径,该板具有等距的校准孔,其至少部分截头圆锥形,其最小直径等于最大允许直径;逐步旋转的驱动 的转印鼓和校准板,以及推动器,用于将容纳在空腔中的圆柱形构件插入并通过校准孔,由此具有超过最大允许直径的直径的构件保持卡在孔中并在排出台处弹出。