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21. 发明授权

US5503819A Substituted fluoride smectite clays, process for preparing the clay and uses thereof 失效
标题翻译：取代氟化蒙脱石粘土，制备粘土的方法及其用途
公开(公告)号：US5503819A
公开(公告)日：1996-04-02
申请号：US214507
申请日：1994-03-18
申请人： Jennifer S. Holmgren
发明人： Jennifer S. Holmgren
IPC分类号： B01J21/16 , B01J23/00 , C01B33/40 , C07C2/08 , C07C2/10 , C07C2/54 , C10G47/12 , C10G50/00 , C01B33/26
CPC分类号： C01B33/40 , B01J21/16 , B01J23/007 , C01B33/405 , C07C2/08 , C07C2/10 , C07C2/54 , C10G47/12 , C10G50/00 , C07C2521/16
摘要： Novel fluoride containing substituted smectite clays are disclosed as well as their preparation and uses. The clay has the formulaA.sub.x (M.sub.y M'.sub.4--y)(Si.sub.8--x M.sub.t M'.sub.v)O.sub.20 (OH).sub.4--u F.sub.uwhere A is a cation, M and M' are metals having a +3 oxidation state, each selected from the group consisting of aluminum, gallium, iron and chromium, x is the moles of A, y is the moles of M, t and v are the moles of M and M' in the tetrahedral layer and t+v=x and u is the moles of F. The clay composition may be used as is or after pillaring to catalyze hydrocarbon conversion processes such as alkylation.
摘要翻译：公开了含氟取代绿土的新型粘土及其制备和用途。粘土具有式Ax（MyM'4-y）（Si8-xMtM'v）O20（OH）4-uFu，其中A是阳离子，M和M'是具有+3氧化态的金属，由铝，镓，铁和铬组成的组，x是A的摩尔数，y是M的摩尔数，t和v是四面体层中M和M'的摩尔数，t + v = x，u是粘土组合物可以原样使用或在柱后使用以催化烃转化过程如烷基化。

22. 发明授权

US5382705A Production of tertiary alkyl ethers and tertiary alkyl alcohols 失效
标题翻译：生产叔烷基醚和叔烷基醇
公开(公告)号：US5382705A
公开(公告)日：1995-01-17
申请号：US973888
申请日：1992-11-10
申请人： Harold S. Chung , Andrew Jackson , Margaret M. Wu
发明人： Harold S. Chung , Andrew Jackson , Margaret M. Wu
IPC分类号： C07C2/10 , C07C29/04 , C07C41/06
CPC分类号： C07C2/10 , C07C41/06 , C07C2521/08 , C07C2523/26
摘要： A process for upgrading a light olefin feed by converting the 1-olefins to higher molecular weight oligomers and the iso-oleins to fuel ethers or alcohols. The process provides substantial improvements in the production of lower alkyl tertiary alkyl ethers or tertiary alkyl alcohol, such as methyl tertiary butyl ether (MTBE), methyl tertiary amyl ether (TAME) or tertiary butyl alcohol. The 1-olefin component of the hydrocarbon feedstream is separated by selective oligomerization in contact with a reduced chromium oxide catalyst to form an olefin oligomer of higher molecular weight, such as gasoline, distillate and lube range hydrocarbons. The iso-olefins are separated by etherification with a lower alcohol such as methanol or by hydration to form an alcohol such as tertiary butanol. The oligomerization process can be integrated either upstream or downstream of the etherification step.
摘要翻译：通过将1-烯烃转化为较高分子量的低聚物和异油相到燃料醚或醇来提纯轻烯烃进料的方法。该方法提供了生产低级烷基叔烷基醚或叔烷基醇如甲基叔丁基醚（MTBE），甲基叔戊基醚（TAME）或叔丁醇的实质性改进。通过与还原的氧化铬催化剂接触的选择性低聚分离烃进料流的1-烯烃组分，以形成较高分子量的烯烃低聚物，例如汽油，馏出物和润滑油烃。通过用低级醇如甲醇醚化或通过水合将异烯烃分离以形成醇如叔丁醇。低聚过程可以在醚化步骤的上游或下游整合。

23. 发明授权

US5342814A Extruded catalyst based on silica/alumina gel, and process for preparing it 失效
标题翻译：基于二氧化硅/氧化铝凝胶的挤出催化剂及其制备方法
公开(公告)号：US5342814A
公开(公告)日：1994-08-30
申请号：US985552
申请日：1992-12-03
申请人： Stefano Peratello , Carlo Perego , Giuseppe Bellussi
发明人： Stefano Peratello , Carlo Perego , Giuseppe Bellussi
IPC分类号： B01J21/12 , B01J35/02 , B01J35/10 , B01J37/00 , C07C2/10
CPC分类号： B01J37/0009 , B01J21/12 , B01J35/023 , C07C2/10 , B01J35/1038 , B01J35/1042 , C07C2521/02 , C07C2521/12
摘要： The preparation is disclosed of an extruded catalyst based on a silica/alumina gel, which catalyst is particularly active in acid-catalyzed reactions, such as the oligomerization of light olefins, e.g., propylene.
摘要翻译：公开了基于二氧化硅/氧化铝凝胶的挤出催化剂的制备，该催化剂在酸催化的反应中是特别有活性的，例如轻质烯烃如丙烯的低聚。

24. 发明授权

US4996384A Regeneration of reduced metal oxide oligomerization catalyst 失效
标题翻译：还原金属氧化物低聚催化剂的再生
公开(公告)号：US4996384A
公开(公告)日：1991-02-26
申请号：US481279
申请日：1990-02-20
申请人： Bruce P. Pelrine , Margaret M. Wu
发明人： Bruce P. Pelrine , Margaret M. Wu
IPC分类号： B01J23/92 , B01J38/12 , C07C2/10
CPC分类号： B01J23/92 , B01J38/12 , C07C2/10 , C07C2521/08 , C07C2523/26 , Y02P20/584
摘要： A process for producing oligomers from alpha-olefins, such as 1-decene, in which the olefins are oligomerized over a supported, reduced metal oxide catalyst from Group VIB of the Periodic Table to give oligomers with a branch ratio of less than 0.19. The catalyst, preferably a chromium/silica catalyst the catalyst can be regenerated to allow repeated recycling of the catalyst without a loss in yield of the oligomer product. The regeneration process comprises: (i) purging or stripping the deactivated catalyst with inert gas at elevated temperature to strip unreacted olefin and oligomer product from the catalyst; (ii) contacting the deactivated and purged catalyst with a stream of oxidizing gas while heating to elevated temperature to oxidize the metal component of the catalyst and remove carbonaceous deposits from the catalyst; (iii) cooling the oxidized catalyst and contacting it with a stream of reducing gas to reduce the metal component of the oxidized catalyst to a lower valence state. The oligomerization may be carried out at relatively high temperatures of about 90.degree. to 250.degree. C. to produce liquid lubricant products of high viscosity index, typically above 130, or at lower temperatures from about -20.degree. to about +90.degree. C. to product products of higher molecular weight which may be used as lubricant additives, e.g. VI improvers. The high molecular weight products are generally characterized by a branch ratio less than 0.19, a weight average molecular weight from about 15,000 to 200,000, a number average molecular weight from about 5,000 to about 50,000 and a molecular weight distribution from about 1 to about 5. They are also shear stable under high temperature, high shear rate conditions of 150.degree. C. and a shear rate of 10.sup.6 second.sup.-1.
摘要翻译：从α-烯烃如1-癸烯制备低聚物的方法，其中烯烃在负载型还原的金属氧化物催化剂上从元素周期表VIB中低聚，得到分支比小于0.19的低聚物。催化剂，优选铬/二氧化硅催化剂，催化剂可以被再生以允许催化剂的反复循环而不会使低聚物产物的产率降低。再生方法包括：（i）在升高的温度下用惰性气体吹扫或汽提失活的催化剂，以从催化剂中除去未反应的烯烃和低聚物产物; （ii）在加热至高温以使氧化催化剂的金属组分并从催化剂中除去含碳沉积物的同时使失活和净化的催化剂与氧化气体流接触; （iii）冷却氧化的催化剂并将其与还原气体流接触，以将氧化催化剂的金属组分降至更低的化合价态。低聚反应可以在约90℃至250℃的相对高的温度下进行，以产生高粘度指数（通常在130以上）或在约-20℃至约+90℃的较低温度至可用作润滑剂添加剂的较高分子量的产品，例如 VI改进剂高分子量产物通常的特征在于分支比小于0.19，重均分子量为约15,000至200,000，数均分子量为约5,000至约50,000，分子量分布为约1至约5。它们在150℃的高温，高剪切速率条件和106秒-1的剪切速率下也剪切稳定。

25. 发明授权

US4831006A Method for intercalating organic-swelled layered metal chalcogenide with polymer chalcogenide by treatment with organic, hydrolyzable, polymeric chalcogenide precursor wherein organic hydrolysis by-products are removed 失效
标题翻译：通过用有机，可水解，聚合硫族化物前体处理有机溶胀的层状金属硫族化物与聚合物硫族化物的方法，其中除去有机水解副产物
公开(公告)号：US4831006A
公开(公告)日：1989-05-16
申请号：US140528
申请日：1988-01-04
申请人： Brent A. Aufdembrink
发明人： Brent A. Aufdembrink
IPC分类号： B01J21/06 , B01J29/04 , C01B13/14 , C01B17/20 , C01B17/42 , C01B19/00 , C01G23/00 , C07C2/08 , C07C2/10 , C10G45/04 , C10G47/02 , C10G49/04 , C10G49/08
CPC分类号： B01J29/049 , C01B13/145 , C01B17/20 , C01B17/42 , C01B19/007 , C01G23/003 , C07C2/08 , C07C2/10 , C10G45/04 , C01P2002/02 , C01P2002/22 , C01P2002/70 , C01P2002/72 , C01P2002/74 , C01P2002/78 , C01P2006/12 , C01P2006/42 , C01P2006/80 , C07C2521/06 , C07C2521/08 , C07C2521/12 , Y10S502/525
摘要： Organic-swelled layered metal chalcogenides, e.g., titanometallates or silicotitanates, are intercalated with polymeric chalcogenide, e.g., polymeric silica by treatment with organic hydrolyzable polymeric chalcogenide precursor wherein hydrolysis to polymeric chalcogenide is enhanced by removal of organic hydrolysis by-products, during hydrolysis, e.g., by exposure of the reaction mixture to elevated temperatures.
摘要翻译：有机溶胀的层状金属硫族化物，例如钛金属酸盐或硅钛酸盐，通过用有机可水解聚合物硫属化物前体进行处理，插入聚合硫属化物，例如聚合二氧化硅，其中通过在水解期间除去有机水解副产物来增强水解成聚合硫族化物，例如，通过将反应混合物暴露于升高的温度。

26. 发明授权

US4827073A Process for manufacturing olefinic oligomers having lubricating properties 失效
标题翻译：制备具有润滑性能的烯烃低聚物的方法
公开(公告)号：US4827073A
公开(公告)日：1989-05-02
申请号：US210434
申请日：1988-06-23
申请人： Margaret M. Wu
发明人： Margaret M. Wu
IPC分类号： C10G50/02 , C10M143/08 , C07C2/10
CPC分类号： C10G50/02 , C10M143/08 , C10M2205/00 , C10M2205/028 , C10N2220/02
摘要： A process for oligomerizing alpha olefin to produce lubricant range hydrocarbon stock including the step of contacting said alpha olefin with a supported solid reduced Group VIB (e.g., chromium) catalyst under oligomerization conditions at a temperature of about 90.degree. to 250.degree. C. to produce liquid lubricant hydrocarbon. The product comprises the polymeric residue of linear C.sub.6 -C.sub.20 1-alkenes, said composition having a branch ratio of less than 0.19. The weight average molecular weight is between 420 and 45,000, number average molecular weight between 420 and 18,000, molecular weight distribution between 1 and 5 and pour point below -15.degree. C. The hydrogenated lubricant range hydrocarbon product has viscosity index of about 130 to 280 and viscosity up to about 750 cS. The process is particularly useful where the starting alpha olefin consists essentially of olefinic hydrocarbon having 8 to 14 carbon atoms or mixtures thereof; wherein the process conditions include reaction temperature of about 100.degree. to 180.degree.; and wherein the support catalyst includes porous inert silica.
摘要翻译：一种使α-烯烃低聚以产生润滑剂范围的烃原料的方法，包括在低温条件下在约90℃至250℃的温度下使所述α-烯烃与负载的固体还原的VIB族（例如铬）催化剂接触的步骤，以产生液体润滑剂烃。产物包含线性C 6 -C 20 1-烯烃的聚合残基，所述组合物具有小于0.19的分支比例。重均分子量为420至45,000，数均分子量为420至18,000，分子量分布为1至5，倾点低于-15℃。氢化润滑剂范围烃产物的粘度指数为约130至280 粘度高达约750cS。当起始α-烯烃基本上由具有8-14个碳原子的烯烃或其混合物组成时，该方法特别有用; 其中所述工艺条件包括约100°至180°的反应温度; 并且其中所述载体催化剂包括多孔惰性二氧化硅。

27. 发明授权

US4392002A Process for upgrading olefinic C.sub.4 cuts 失效
标题翻译：烯烃C4馏分升级方法
公开(公告)号：US4392002A
公开(公告)日：1983-07-05
申请号：US311828
申请日：1981-10-16
申请人： Jean Cosyns , Bernard Juguin , Jean-Francois Le Page , Jean Miquel
发明人： Jean Cosyns , Bernard Juguin , Jean-Francois Le Page , Jean Miquel
IPC分类号： C10G69/12 , C07C2/10 , C07C5/25 , C07C9/16 , C10G50/00 , C10L1/06 , C07C2/08 , C07C2/58
CPC分类号： C10L1/06 , C07C2/10 , C07C5/2556 , C07C9/16 , C07C2521/02 , C07C2521/04 , C07C2521/12 , C07C2523/44 , C07C2523/75 , C07C2523/755
摘要： A C.sub.4 cut is upgraded according to the following steps:(a) the dried C.sub.4 cut is polymerized in the presence of fluorinated alumina, boron-alumina or silica-alumina, to convert at least 95% of isobutene to dimers and trimers, the conversion of the normal butenes being at most 3%,(b) the whole polymerization effluent is hydro-isomerized in the presence of a group VIII metal catalyst, to isomerize at least 90% of the 1-butene of said effluent,(c) the hydro-isomerization effluent is fractionated and a resultant fraction is alkylated.Resultant alkylate and mixture of dimers and trimers can be mixed and used as gasoline.
摘要翻译： C4馏分根据以下步骤升级：（a）干燥的C4馏分在氟化氧化铝，硼 - 氧化铝或二氧化硅 - 氧化铝的存在下聚合，以将至少95％的异丁烯转化为二聚体和三聚体，转化率（b）在第VIII族金属催化剂存在下将整个聚合流出物加氢异构化，使至少90％的所述流出物的1-丁烯异构化，（c）分批加氢异构化流出物，并将所得馏分烷基化。得到的烷基化物和二聚体和三聚体的混合物可以混合并用作汽油。

28. 发明授权

US4197185A Process for the conversion of olefinic C.sub.4 cuts from steam cracking to high octane gasoline and butane 失效
标题翻译：烯烃C4馏分从蒸汽裂解转化为高辛烷值汽油和丁烷的方法
公开(公告)号：US4197185A
公开(公告)日：1980-04-08
申请号：US936965
申请日：1978-08-25
申请人： Jean-Francois Le Page , Jean Cosyns , Jean Miquel , Bernard Juguin
发明人： Jean-Francois Le Page , Jean Cosyns , Jean Miquel , Bernard Juguin
IPC分类号： B01J21/00 , B01J27/00 , C07B61/00 , C07C1/00 , C07C2/06 , C07C2/10 , C07C2/74 , C07C5/03 , C07C9/10 , C07C9/21 , C07C67/00 , C10G50/00 , C10G69/12 , C10L1/06 , C07C9/20
CPC分类号： C10L1/06 , C07C2/10 , C07C5/03 , C10G69/126 , C07C2521/02 , C07C2521/04 , C07C2521/12 , C07C2523/75 , C07C2523/755 , C10G2400/02
摘要： Process for producing butane and gasoline of high isooctane content, from a C.sub.4 olefin cut issued from a steam cracking unit, comprising the steps of:polymerizing at least 90% of the isobutene of the cut mainly to dimers and trimers thereof,hydrogenating the resulting polymerization mixture to normal butane, isooctane and isododecane,supplying the effluent from the hydrogenation unit to a separation zone to recover a gaseous fraction and a liquid mixture, andfractionating the liquid mixture to separate gasoline of high isooctane content, a C.sub.3.sup.- fraction and a butane fraction which is recycled to the steam cracking unit.
摘要翻译：从蒸汽裂解装置发出的C4烯烃切割制备高异辛烷含量的丁烷和汽油的方法，包括以下步骤：将切割的至少90％的异丁烯聚合成二聚体和三聚体，将所得聚合物氢化与正丁烷，异辛烷和异十二烷的混合物，将来自氢化单元的流出物供应到分离区以回收气态馏分和液体混合物，并将液体混合物分馏分离出高异辛烷含量的汽油，C3馏分和丁烷再循环到蒸汽裂解装置的馏分。

29. 发明授权

US4112011A Oligomerization process 失效
标题翻译：低聚过程
公开(公告)号：US4112011A
公开(公告)日：1978-09-05
申请号：US804628
申请日：1977-06-08
申请人： Alexander John Kolombos
发明人： Alexander John Kolombos
IPC分类号： B01J23/00 , B01J23/08 , C07C1/00 , C07C2/10 , C07C11/02 , C07C67/00 , C07C3/20
CPC分类号： C07C2/10 , B01J23/08 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2523/08
摘要： A process for producing unsaturated hydrocarbons by oligomerizing a C.sub.3 -C.sub.8 monoolefin in the presence of a gallium catalyst deposited on a support.
摘要翻译：在沉积在载体上的镓催化剂存在下使C3-C8单烯烃低聚制备不饱和烃的方法。

30. 发明授权

US3558737A Olefin polymerization 失效
标题翻译： OLEFIN聚合
公开(公告)号：US3558737A
公开(公告)日：1971-01-26
申请号：US3558737D
申请日：1968-07-26
申请人： TEXAS DEV CORP
发明人： SAINES GEORGE S
IPC分类号： C07C2/10 , C10L1/16 , C07C3/20
CPC分类号： C07C2/10 , C07C2521/04 , C07C2527/06 , C10L1/1641
摘要： A PROCESS FOR THE POLYMERIZATION AND CO-POLYMERIZATION OF PROPYLENE AND BUTENES BY CONTAC TING THE OLEFIN WITH A CATALYST COMPOSED OF GAMMA-ALUMINA AND CHLORINE OR BROMINE HAVING A SURFACE AREA OF 75 TO 150 SQUARE METERS PER GRAM AND ABOUT 3.0 TO 15.0 WEIGHT PERCENT CHLORINE AND BROMINE. POLYMERIZATION IS CONDUCTED AT TEMPERATURES RANGING FROM ABOUT -20*C. TO ABOUT 50*C. SUCH THAT LIQUID POLYMERS AND CO-POLYMERS HAVING AN AVERAGE MOLECULAR WEIGHT OF AT LEAST 800 ARE PROVIDED WHICH ARE USEFUL AS ADDITIVES FOR LUBE OILS, CAULKING COMPOUNDS AND GASOLINE ADDITIVES.

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