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1. 发明授权

US06872865B1 Selective disproportionation catalyst and process 失效
标题翻译：选择性歧化催化剂和工艺
公开(公告)号：US06872865B1
公开(公告)日：2005-03-29
申请号：US09479302
申请日：2000-01-06
申请人： Susan C. Koster , Jennifer S. Holmgren
发明人： Susan C. Koster , Jennifer S. Holmgren
IPC分类号： B01J29/06 , B01J29/40 , B01J29/80 , B01J29/86 , B01J35/00 , C07C5/52 , C07C6/12
CPC分类号： B01J35/0006 , B01J29/40 , B01J29/80 , B01J29/86 , B01J2229/12 , B01J2229/34 , B01J2229/42 , B01J2229/62 , C07C6/123 , C07C2529/70 , C07C2529/86 , Y02P20/52 , C07C15/08
摘要： An improved catalytic composite and process are disclosed for the selective disproportionation of toluene. The process uses a layered composite comprising a catalytically active core which comprises a zeolitic aluminosilicate having a SiO2:Al2O3 ratio of 8 to 50 and a relatively inactive protective mantle which preferably comprises boralite. Optionally, the composite is selectively precoked prior to toluene disproportionation. The composite and process provide improved selectivity for the production of paraxylene.
摘要翻译：公开了改进的催化复合物和方法用于甲苯的选择性歧化。该方法使用包含催化活性核心的层状复合物，其包含SiO 2 :Al 2 O 3比率为8至50的沸石硅铝酸盐和相对无活性的保护性外壳，其优选包含硼石。任选地，在甲苯歧化之前选择性地先除去复合物。复合材料和工艺为对二甲苯的生产提供了更好的选择性。

2. 发明授权

US6063977A Selective aromatics disproportionation process 有权
标题翻译：选择性芳烃歧化过程
公开(公告)号：US6063977A
公开(公告)日：2000-05-16
申请号：US213959
申请日：1998-12-17
申请人： Gregory J. Gajda , Edwin P. Boldingh , Jennifer S. Holmgren
发明人： Gregory J. Gajda , Edwin P. Boldingh , Jennifer S. Holmgren
IPC分类号： B01J27/16 , B01J29/40 , B01J29/70 , B01J37/00 , C07C6/12 , C07C5/22
CPC分类号： B01J37/0009 , B01J27/16 , B01J29/40 , B01J29/70 , B01J37/0072 , C07C6/123 , B01J2229/26 , B01J2229/42 , C07C2529/06 , Y02P20/52
摘要： An improved catalyst and process are disclosed for the selective disproportionation of toluene. The process uses a zeolitic catalyst which is oil-dropped in an aluminum phosphate binder and has an X-ray diffraction pattern showing characteristic intensities at specified Bragg angles. Optionally, the catalyst is selectively precoked prior to toluene disproportionation. The catalyst and process provide improved selectivity for the production of paraxylene.
摘要翻译：公开了改进的催化剂和方法用于甲苯的选择性歧化。该方法使用在磷酸铝粘合剂中油滴的沸石催化剂，并且具有在特定布拉格角下显示特征强度的X射线衍射图。任选地，在甲苯歧化之前选择性地预先催化剂。催化剂和方法为对二甲苯的生产提供了改进的选择性。

3. 发明授权

US5807475A Process for removing sulfur compounds from hydrocarbon streams 失效
标题翻译：从烃流中除去硫化合物的方法
公开(公告)号：US5807475A
公开(公告)日：1998-09-15
申请号：US751829
申请日：1996-11-18
申请人： Santi Kulprathipanja , Laszlo T. Nemeth , Jennifer S. Holmgren
发明人： Santi Kulprathipanja , Laszlo T. Nemeth , Jennifer S. Holmgren
IPC分类号： C10G25/00 , C10G25/05 , C10G17/00
CPC分类号： C10G25/05 , C10G25/003
摘要： A process for removing sulfur containing compounds from various hydrocarbon streams is disclosed and claimed. The process involves contacting the feedstream with an adsorbent such as nickel exchanged zeolite X or Y, or a smectite layered clay having a surface area of at least 150 m.sup.2 /g, thereby adsorbing the sulfur compounds onto the adsorbent.
摘要翻译：公开并要求保护从各种烃流中除去含硫化合物的方法。该方法包括使进料流与诸如镍交换的沸石X或Y的吸附剂或表面积至少为150m 2 / g的蒙皂石层状粘土接触，从而将硫化合物吸附到吸附剂上。

4. 发明授权

US5733439A Hydrocarbon conversion processes using substituted fluoride smectite clays 失效
标题翻译：使用取代氟化物蒙脱石粘土的烃转化方法
公开(公告)号：US5733439A
公开(公告)日：1998-03-31
申请号：US571665
申请日：1995-12-13
申请人： Jennifer S. Holmgren
发明人： Jennifer S. Holmgren
IPC分类号： B01J21/16 , B01J23/00 , C01B33/40 , C07C2/08 , C07C2/10 , C07C2/54 , C10G47/12 , C10G50/00 , C10G47/02 , C07C2/02 , C07C2/58
CPC分类号： B01J21/16 , B01J23/007 , C01B33/40 , C01B33/405 , C07C2/08 , C07C2/10 , C07C2/54 , C10G47/12 , C10G50/00 , C07C2521/16
摘要： Hydrocarbon conversion processes, e.g., alkylation, are disclosed and claimed which use as the catalyst novel fluoride containing substituted smectite clays. The clay has the formula A.sub.x (M.sub.y M'.sub.4-y)(Si.sub.8-x M.sub.t M'.sub.v)O.sub.20 (OH).sub.4-u F.sub.u where A is a cation, M and M' are metals having a +3 oxidation state, each selected from the group consisting of aluminum, gallium, iron and chromium, x is the moles of A, y is the moles of M, t and v are the moles of M and M' in the tetrahedral layer and t+v=x and u is the moles of F. The clay composition may be used as is or after pillaring to catalyze hydrocarbon conversion processes such as alkylation.
摘要翻译：烃转化方法，例如烷基化，被公开和要求保护，其用作催化剂新型含氟取代的绿土粘土。粘土具有式Ax（MyM'4-y）（Si8-xMtM'v）O20（OH）4-uFu，其中A是阳离子，M和M'是具有+3氧化态的金属，由铝，镓，铁和铬组成的组，x是A的摩尔数，y是M的摩尔数，t和v是四面体层中M和M'的摩尔数，t + v = x，u是粘土组合物可以原样使用或在柱后使用以催化烃转化过程如烷基化。

5. 发明授权

US5413701A Process for sweetening a sour hydrocarbon fraction using a supported metal chelate and a solid base 失效
$Process for sweetening a sour hydrocarbon fraction using a supported metal chelate and a solid base$
标题翻译：使用负载的金属螯合物和固体碱使酸性烃馏分变甜的方法
公开(公告)号：US5413701A
公开(公告)日：1995-05-09
申请号：US151632
申请日：1993-11-15
申请人： Ralph D. Gillespie , Jeffery C. Bricker , Blaise J. Arena , Jennifer S. Holmgren
发明人： Ralph D. Gillespie , Jeffery C. Bricker , Blaise J. Arena , Jennifer S. Holmgren
IPC分类号： C10G27/10
CPC分类号： C10G27/10
摘要： A catalytic system of physically separate and discrete solid materials and a mercaptan oxidation process for using the catalytic system have been developed. The catalytic system comprises a supported metal chelate dispersed on a non-basic solid support and a solid base. The process involves contacting a sour middle distillate hydrocarbon fraction which contains mercaptans first with the solid base and then, in the presence of an oxidizing agent and a polar compound, with the supported metal chelate. The process is unique in that both the catalyst and the base are solid materials and that the solid base is in a separate fixed bed from the supported metal chelate.
摘要翻译：已经开发了物理上分离和离散的固体材料的催化体系和用于使用催化体系的硫醇氧化方法。催化体系包含分散在非碱性固体载体和固体碱上的负载金属螯合物。该方法包括使含有硫醇的酸性中间馏分烃馏分首先与固体碱接触，然后在氧化剂和极性化合物的存在下与负载的金属螯合物接触。该方法是独特的，因为催化剂和碱都是固体材料，固体碱与负载的金属螯合物在单独的固定床中。

6. 发明授权

US5340465A Use of a metal oxide solid solution for sweetening a sour hydrocarbon fraction 失效
$Use of a metal oxide solid solution for sweetening a sour hydrocarbon fraction$
标题翻译：使用金属氧化物固溶体来减轻酸性烃馏分
公开(公告)号：US5340465A
公开(公告)日：1994-08-23
申请号：US136056
申请日：1993-10-14
申请人： Ralph D. Gillespie , Jennifer S. Holmgren
发明人： Ralph D. Gillespie , Jennifer S. Holmgren
IPC分类号： C10G27/04 , C10G19/073 , C10G29/16
CPC分类号： C10G27/04
摘要： An improved process for treating a sour hydrocarbon stream has been developed. This process involves contacting the sour hydrocarbon fraction with a metal oxide solid solution in the presence of an oxidizing agent such as air or oxygen. One example of a solid solution which can be used is a nickel oxide/magnesium oxide/aluminum oxide solid solution.
摘要翻译：已经开发了用于处理酸性烃流的改进方法。该方法包括在氧化剂如空气或氧气存在下使酸性烃馏分与金属氧化物固溶体接触。可以使用的固溶体的一个实例是氧化镍/氧化镁/氧化铝固溶体。

7. 发明授权

US5286368A Hydrocarbon conversion process using a novel beidellite clay 失效
标题翻译：碳氢转化过程中使用新型贝得石粘土
公开(公告)号：US5286368A
公开(公告)日：1994-02-15
申请号：US981728
申请日：1992-11-25
申请人： Jennifer S. Holmgren
发明人： Jennifer S. Holmgren
IPC分类号： B01J20/12 , B01J21/16 , C10G11/04 , C07C2/66 , C10G47/04
CPC分类号： B01J20/12 , B01J21/16 , B01J2229/32
摘要： This invention relates to a hydrocarbon conversion process using a novel beidellite layered clay as the catalyst. The clay is characterized in that it is substantially free of sodium cations, is composed of crystals whose average crystallites size is about 50-150 Angstroms, has a surface area of at least 80 m.sup.2 /g and has its 060 X-ray diffraction peak at a d-spacing of 1.50 Angstroms. The clay is prepared from a reaction mixture containing reactive sources of aluminum and silicon, a templating agent and water. The mixture is reacted at a pH of about 8.5 to about 14, a temperature of about 150.degree. to about 210.degree. C. for a time of about 1 to about 20 days. The clay may be used as is or after pillaring the layers with pillars such as alumina, ZrO.sub.2, TiO.sub.2, etc. The hydrocarbon processes which can be catalyzed by this clay are cracking, hydrocracking and alkylation of both aromatic and paraffinic hydrocarbons.
摘要翻译：本发明涉及一种使用新颖的贝得石层状粘土作为催化剂的烃转化方法。该粘土的特征在于其基本上不含钠阳离子，由平均微晶尺寸约为50-150埃的晶体组成，其表面积至少为80m 2 / g，其060 X射线衍射峰位于 d-spacing为1.50埃。粘土由含有铝和硅的反应性源，模板剂和水的反应混合物制备。混合物在约8.5至约14的pH，约150至约210℃的温度下反应约1至约20天的时间。粘土可以按原样使用，也可以在用诸如氧化铝，ZrO 2，TiO 2等的柱子支撑层之后使用。可以由该粘土催化的烃工艺是芳烃和链烷烃的裂化，加氢裂化和烷基化。

8. 发明授权

US5214211A Alkylation of diarylamines with olefins using rare earth modified pillared clays 失效
标题翻译：使用稀土改性柱状粘土使烯烃与二芳基胺烷基化
公开(公告)号：US5214211A
公开(公告)日：1993-05-25
申请号：US805747
申请日：1991-12-12
申请人： Paul R. Kurek , Jennifer S. Holmgren
发明人： Paul R. Kurek , Jennifer S. Holmgren
IPC分类号： C07C209/68
CPC分类号： C07C209/68
摘要： Rare earth pillared clays, and especially cerium and lanthanum aluminum chlorohydrite pillared clays, are quite effective catalysts in the alkylation of diaryl amines at temperatures in the range of 100.degree.-225.degree. C. The catalysts effect alkylation using olefins as the alkylating agent with high conversion and with minimal cracking of either the olefin or the alkylated product. Catalysts may be regenerated by heating in air at temperatures of at least about 550.degree.-600.degree. C. Water in small amounts also modifies the reaction to further reduce cracking although it also reduces the activity of the catalyst.
摘要翻译：稀土柱状粘土，特别是铈和镧铝氯铝石柱状粘土，在二氧化碳烷基化的温度范围为100-225℃时是非常有效的催化剂。催化剂使用烯烃作为烷基化剂，具有高的烷基化作用转化和烯烃或烷基化产物的最小裂化。催化剂可以通过在空气中在至少约550-600℃的温度下加热而再生。少量的水也改变了反应以进一步减少裂化，尽管它也降低了催化剂的活性。

9. 发明授权

US5192726A Beidellite clay and process for preparing the clay 失效
标题翻译：贝多像粘土和制备粘土的方法
公开(公告)号：US5192726A
公开(公告)日：1993-03-09
申请号：US753514
申请日：1991-09-03
申请人： Jennifer S. Holmgren
发明人： Jennifer S. Holmgren
IPC分类号： B01J20/12 , B01J21/16
CPC分类号： B01J20/12 , B01J21/16 , B01J2229/32
摘要： This invention relates to a novel beidellite layered clay, a process for preparing the clay and a process using the clay. The clay is characterized in that it is substantially free of sodium cations, is composed of crystals whose average crystallites size is about 50-150 Angstroms, has a surface area of at least 80 m.sup.2 /g and has its 060 X-ray diffraction peak at a d-spacing of 1.50 Angstroms. The clay is prepared from a reaction mixture containing reactive sources of aluminum and silicon, a templating agent and water. Examples of templating agents are quaternary ammonium compounds such as tetramethylammonium hydroxide. Reactive source of aluminum and silicon include boehmite alumina and colloidal silica. The mixture is reacted at a pH of about 8.5 to about 14, a temperature of about 150.degree. to about 210.degree. C. for a time of about 1 to about 20 days. The clay composition may be used as is or after pillaring to catalyze hydrocarbon conversion processes such as alkylation.
摘要翻译：本发明涉及一种新颖的贝得石层状粘土，一种制备粘土的方法和一种使用该粘土的方法。该粘土的特征在于其基本上不含钠阳离子，由平均微晶尺寸约为50-150埃的晶体组成，其表面积至少为80m 2 / g，其060 X射线衍射峰位于 d-spacing为1.50埃。粘土由含有铝和硅的反应性源，模板剂和水的反应混合物制备。模板剂的实例是季铵化合物，例如四甲基氢氧化铵。铝和硅的反应源包括勃姆石氧化铝和胶体二氧化硅。混合物在约8.5至约14的pH，约150至约210℃的温度下反应约1至约20天的时间。粘土组合物可以原样使用或在柱后使用以催化烃转化过程如烷基化。

10. 发明授权

US5160032A Hydrocarbon conversion process using alumina clay compositions 失效
标题翻译：使用氧化铝粘土组合物的烃转化方法
公开(公告)号：US5160032A
公开(公告)日：1992-11-03
申请号：US808136
申请日：1991-12-16
申请人： Jennifer S. Holmgren , Stanley A. Gembicki , Michael W. Schoonover , Joseph A. Kocal
发明人： Jennifer S. Holmgren , Stanley A. Gembicki , Michael W. Schoonover , Joseph A. Kocal
IPC分类号： B01J21/16 , B01J29/04 , C07C4/06 , C10G47/12
CPC分类号： C10G47/12 , B01J21/16 , B01J29/049 , C07C4/06 , B01J2229/42 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/16 , C07C2527/16
摘要： This invention relates to hydrocarbon conversion process using a catalyst consisting essentially of a layered clay homogeneously dispersed in an inorganic oxide matrix. The clay is dispersed in such a way that the clay layers are completely surrounded by the inorganic oxide matrix. The inorganic oxide is selected from the group consisting of alumina, titania, silica, zirconia, P.sub.2 O.sub.5 and mixtures thereof. The clay can be a natural clay such as montmorillonite, a metal exchanged clay (Fe.sup.+3 exchanged) or a pillared clay such as aluminum chlorohydrate (ACH) pillared clay. The hydrocarbon conversion process is carried out by contacting a hydrocarbon feed with the catalyst at hydrocarbon conversion conditions to give a hydroconverted product. Examples of the hydrocarbon conversion processes are alkylation and hydrocracking.
摘要翻译：本发明涉及使用基本上由均匀分散在无机氧化物基质中的层状粘土组成的催化剂的烃转化方法。粘土以这样的方式分散，即粘土层被无机氧化物基体完全包围。无机氧化物选自氧化铝，二氧化钛，二氧化硅，氧化锆，P 2 O 5及其混合物。粘土可以是天然粘土，例如蒙脱石，金属交换的粘土（Fe + 3交换的）或柱状粘土如水合氯化铝（ACH）柱状粘土。烃转化过程是通过在烃转化条件下使烃进料与催化剂接触以得到加氢转化产物来进行的。烃转化方法的实例是烷基化和加氢裂化。

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