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    • 26. 发明授权
    • Detergent
    • 洗涤剂
    • US06486116B1
    • 2002-11-26
    • US09743461
    • 2001-04-06
    • Gerald Thomas Hinton
    • Gerald Thomas Hinton
    • C11D3395
    • C11D17/0039C11D1/66C11D1/72C11D3/225C11D3/3942C11D17/0091
    • A detergent composition comprising a granulated percarbonate and a blend which encapsulates the percarbonate is describe. The blend comprises a sulphate, carboxymethyl cellulose and a nonionic surfactant. The detergent composition comprises sodium metasilicate and does not include a zeolite, a perborate or a phosphate. The composition is capable of being stored in a water-soluble PVA film packaging for at least nine months and wherein the composition comprises between 1% and 15% percarbonate. The composition can include a phosphate substitute such as a polyacrylate. The composition can be compressed into a tablet format and used as a laundering product.
    • 描述包含粒状过碳酸盐和包封过碳酸盐的共混物的洗涤剂组合物。 共混物包含硫酸盐,羧甲基纤维素和非离子表面活性剂。 洗涤剂组合物包含偏硅酸钠,不包括沸石,过硼酸盐或磷酸盐。 该组合物能够储存在水溶性PVA薄膜包装中至少9个月,其中组合物含有1%-15%过碳酸盐。 组合物可以包括磷酸盐替代物,例如聚丙烯酸酯。 组合物可以压缩成片剂形式并用作洗涤产品。
    • 30. 发明授权
    • Sequesterants as hypochlorite bleach enhancers
    • 螯合剂作为次氯酸盐漂白剂增强剂
    • US06297209B1
    • 2001-10-02
    • US08642981
    • 1996-05-10
    • Thomas W. KaaretWilliam L. Smith
    • Thomas W. KaaretWilliam L. Smith
    • C11D3395
    • C11D3/3956C11D3/3765
    • Sequestering agents for use as a whitening and fabric strength enhancer for aqueous hypochlorite bleach compositions are provided. It was found that the sequesterants when used with hypochlorite in the presence of soluble heavy metal ions, particularly iron and manganese ions, provide significantly improved whitening and fabric protection. Most preferably, the sequesterants are selected from polyacrylic acid, a polyacrylic acid derivative, a copolymer of acrylic acid or methacrylic acid and a comonomer which is maleic acid or maleic anhydride and mixtures thereof. In one aspect, the sequesterants are employed in a method for laundering fabrics comprising: a) providing, in a wash liquor containing (i) at least about 40 ppb of iron cations or (ii) at least about 10 ppb of manganese cations, or (iii) the cations of both (i) and (ii), and a fabric piece; and b) adding either prior to, contemporaneously with, or after, the step of providing of said fabric piece to said wash liquor a hypochlorite composition which comprises one or more of said sequesterants. Preferably the sequesterant comprises at least 0.1 ppm by weight of said wash liquor and the hypochlorite composition is an alkali metal hypochlorite and said sequesterant has a molecular weight of between about 500 and 500,000 daltons.
    • 提供了用作次氯酸盐漂白剂组合物的增白剂和织物强度增强剂的螯合剂。 已发现,在可溶性重金属离子,特别是铁和锰离子存在下,与次氯酸盐一起使用时,螯合剂可显着改善美白和织物保护。 最优选地,螯合剂选自聚丙烯酸,聚丙烯酸衍生物,丙烯酸或甲基丙烯酸的共聚物和作为马来酸或马来酸酐的共聚单体及其混合物。 一方面,螯合剂用于洗涤织物的方法中,包括:a)在含有(i)至少约40ppb的铁阳离子或(ii)至少约10ppb的锰阳离子的洗涤液中,或 (iii)(i)和(ii)两者的阳离子和织物片; 和b)在向所述洗涤液提供包含一种或多种所述螯合剂的次氯酸盐组合物的步骤之前,同时或之后加入所述织物片的步骤。 优选地,螯合剂包含至少0.1ppm重量的所述洗涤液,次氯酸盐组合物是碱金属次氯酸盐,所述螯合剂的分子量为约500至500,000道尔顿。