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21. 发明申请

US20080009649A1 Process for Preparing Amino Acids Using the Amidocarbonylation Reaction 有权
标题翻译：使用酰胺基羰基化反应制备氨基酸的方法
公开(公告)号：US20080009649A1
公开(公告)日：2008-01-10
申请号：US11569319
申请日：2005-05-14
申请人： Martin Hateley , Thomas Haussner , Christoph Weckbecker , Klaus Huthmacher , Dieter Buss
发明人： Martin Hateley , Thomas Haussner , Christoph Weckbecker , Klaus Huthmacher , Dieter Buss
IPC分类号： C07C51/12 , C07C227/12 , C07C51/14 , C07C51/10
CPC分类号： B01J31/20 , B01J2531/845 , C07C227/20 , C07C319/20 , C07C323/58 , C07C323/59
摘要： The present invention relates to a sequence for the preparation of amino acids, for example alpha-amino acids, in particular methionine, by making use of an amidocarbonylation reaction in the presence of a cobalt carbonyl catalyst and separating the catalyst in the form of a Co(N-amino acid)2 compound.
摘要翻译：本发明涉及用于制备氨基酸的序列，例如α-氨基酸，特别是甲硫氨酸，通过在羰基钴催化剂存在下使用酰胺基羰基化反应，并以Co的形式分离催化剂（N-氨基酸）2 N 2化合物。

22. 发明申请

US20070299277A1 FLUIDIZABLE CARBON CATALYSTS 审中-公开
标题翻译：可流化碳催化剂
公开(公告)号：US20070299277A1
公开(公告)日：2007-12-27
申请号：US11853938
申请日：2007-09-12
申请人： Gerald Tustin , Joseph Zoeller , Richard Colberg
发明人： Gerald Tustin , Joseph Zoeller , Richard Colberg
IPC分类号： C07C67/36 , C07C29/00 , C07C51/10 , C07C51/14
CPC分类号： C07C67/04 , C07C51/12 , C07C67/36 , C07C53/08 , C07C69/01 , C07C69/14 , C07C69/15
摘要： Disclosed are fluidizable catalysts comprising carbonized, polysulfonated vinylaromatic polymer particles. These carbonized polymer particles can be active catalysts by themselves or can act as supports for active catalyst components. These novel catalysts show excellent fluidization behavior over a wide range of gas velocities. Also disclosed are processes for making fluidizable catalysts, for fluidizing these catalysts, and for the preparation of carbonylation products with these catalysts.
摘要翻译：公开了可流化的催化剂，其包含碳化，多磺化的乙烯基芳族聚合物颗粒。这些碳化聚合物颗粒本身可以是活性催化剂，或者可以作为活性催化剂组分的载体。这些新型催化剂在宽范围的气体速度下表现出优异的流化性能。还公开了制备可流化催化剂，用于使这些催化剂流化的工艺，以及用这些催化剂制备羰基化产物的方法。

23. 发明授权

US07161044B2 Catalytic gas phase oxidation reaction 有权
标题翻译：催化气相氧化反应
公开(公告)号：US07161044B2
公开(公告)日：2007-01-09
申请号：US10958015
申请日：2004-10-04
申请人： Daisuke Nakamura , Michio Tanimoto
发明人： Daisuke Nakamura , Michio Tanimoto
IPC分类号： C07C45/27 , C07C51/10 , C07C51/14 , C07C51/16
CPC分类号： C07C45/35 , C07C45/32 , C07C45/37 , C07C51/252 , C07C47/22 , C07C57/04
摘要： An object of the present invention is to provide a catalytic gas phase oxidation reaction in which: even under reaction conditions of a higher gas pressure, a higher concentration of the raw material gas and a larger space velocity of a reaction gas, the thermal accumulation at the hot spot portion can be sufficiently suppressed with ease and at low costs, so that the reaction can be continued for a long time while a high yield is maintained. As a means of achieving this object, a catalytic gas phase oxidation reaction according to the present invention is a catalytic gas phase oxidation reaction with molecular oxygen or a molecular-oxygen-containing gas by using a fixed-bed multitubular reactor packed with catalysts; with the catalytic gas phase oxidation reaction being characterized in that: a catalyst-packed layer of each reaction tube of the reactor is divided into at least two reaction zones in a tubular axial direction; and the packing of the catalysts is such that the occupation volumes of the catalysts differ between at least two of the reaction zones and that an inert substance molding is mixed in at least one of the reaction zones.
摘要翻译：本发明的目的是提供一种催化气相氧化反应，其中即使在较高气体压力，较高浓度的原料气体和较大的反应气体的空间速度的反应条件下，热累积在可以容易地且低成本地充分地抑制热点部分，使得反应可以长时间持续，同时保持高产率。作为实现该目的的手段，本发明的催化气相氧化反应是使用填充有催化剂的固定床多管反应器进行与分子氧或含分子氧气体的催化气相氧化反应，催化气相氧化反应的特征在于：将反应器的每个反应管的催化剂填充层分成至少两个沿管轴方向的反应区; 并且催化剂的填充使得催化剂的占有体积在至少两个反应区之间不同，并且惰性物质模制品在至少一个反应区中混合。

24. 发明申请

US20060247466A1 Process for the production of acetic acid 有权
公开(公告)号：US20060247466A1
公开(公告)日：2006-11-02
申请号：US11116771
申请日：2005-04-28
申请人： Raymond Zinobile , Mark Scates , Jonathan Makelki , Manuel Salado
发明人： Raymond Zinobile , Mark Scates , Jonathan Makelki , Manuel Salado
IPC分类号： C07C51/14 , C07C45/90
CPC分类号： C07C51/44 , C07C51/48 , C07C53/08
摘要： A process for the reduction and/or removal of permanganate reducing compounds formed by the carbonylation of methanol in the presence of a Group VIII metal carbonylation catalyst to produce acetic acid is disclosed. More specifically, a process for reducing and/or removing permanganate reducing compounds or their precursors from intermediate streams during the formation of acetic acid by said carbonylation processes is disclosed. In particular, a process in which a low boiling overhead vapor stream from a light ends column is subjected to a single distillation to obtain an overhead that is subjected to an extraction to selectively remove and/or reduce PRC's from the process is disclosed.

25. 发明申请

US20060155145A1 Vanadium catalysts and process for the direct conversion of methane into acetic acid 失效
标题翻译：钒催化剂和甲烷直接转化为乙酸的方法
公开(公告)号：US20060155145A1
公开(公告)日：2006-07-13
申请号：US10532387
申请日：2003-10-15
申请人： Armando Pombeiro , Joao Frausto Da Silva , Yuzo Fujiwara , Jose Silva , Patricia Reis , Antonio Palavra
发明人： Armando Pombeiro , Joao Frausto Da Silva , Yuzo Fujiwara , Jose Silva , Patricia Reis , Antonio Palavra
IPC分类号： C07C51/14
CPC分类号： B01J31/2243 , B01J31/04 , B01J31/223 , B01J31/26 , B01J31/36 , B01J2231/46 , B01J2531/56 , C07C51/285 , C07C53/08
摘要： The invention consists on the utilization of complexes of vanadium (in the +4 and +5 oxidation states) with bi- or poly-dentate ligands coordinated by nitrogen and oxygen (N,O) or by oxygen and oxygen (O,O) atoms, namely derivaties of aminoalcohols, (hydroxyimino)dicarboxylic acids, hydroxypyranones, trifluoroacetic acid, triflic acid or inorganic acid, as catalysts for the direct single-pot conversion, under mild conditions, of methane in acetic acid, either in the absence or in the presence of carbon monoxide, and in the presence of a peroxodisulfate salt (K2S2O8), in trifluoroacetic acid (CF3COOH), according to the general reaction (I).
摘要翻译：本发明包括使用钒（+4和+5氧化态）与氮和氧（N，O）或氧和氧（O，O）原子配位的双齿或多齿配体的配合物的利用，即氨基醇，（肟基）二羧酸，羟基吡喃酮，三氟乙酸，三氟甲酸或无机酸的衍生物，作为直接单锅转化的催化剂，在温和条件下，甲酸在乙酸中的存在或不存在根据一般反应（I），在三氟乙酸（CF 3 COOH）中存在一氧化碳，并存在过二硫酸盐（K2S2O8）存在下。

26. 发明申请

US20050215828A1 Oxo process 失效
标题翻译：氧化过程
公开(公告)号：US20050215828A1
公开(公告)日：2005-09-29
申请号：US10509191
申请日：2003-03-28
申请人： Ronald Garton , James Ritchie , Raphael Caers
发明人： Ronald Garton , James Ritchie , Raphael Caers
IPC分类号： C07C45/49 , C07C45/50 , C07C51/14
CPC分类号： C07C45/50 , C07C47/02
摘要： The Oxo Process that recycles its cobalt primarily as cobalt salt is improved by concentration of the cobalt salt solution from the demetalling section and the addition of a separation step for organic acid and water. This allows for a higher reuse of acid in the process and thus a lower amount of acid in the waste water. Injecting a higher concentration of cobalt salt solution to the reaction section also reduces the requirement for cobalt source.
摘要翻译：通过从脱金属部分浓缩钴盐溶液和加入有机酸和水的分离步骤，主要以钴盐回收其钴的Oxo方法得到改善。这允许在该方法中更高程度地使用酸，从而在废水中更少量的酸。向反应段注入较高浓度的钴盐溶液也降低了钴源的需求。

27. 发明申请

US20050090694A1 Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore 有权
标题翻译：因此烯属不饱和化合物和催化剂的羰基化方法
公开(公告)号：US20050090694A1
公开(公告)日：2005-04-28
申请号：US10505019
申请日：2003-02-18
申请人： Eit Drent , Renata Van Der Made , Robert Pugh , Paul Pringle
发明人： Eit Drent , Renata Van Der Made , Robert Pugh , Paul Pringle
IPC分类号： B01J31/24 , B01J31/28 , C07B61/00 , C07C45/49 , C07C51/14 , C07C51/54 , C07C53/122 , C07C67/36 , C07C67/38 , C07C69/738 , C07F9/6564 , C07F9/6568
CPC分类号： B01J31/2485 , B01J31/28 , B01J2231/321 , B01J2531/80 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/847 , C07C51/14 , C07F9/65683 , C07C53/122
摘要： A process for the carbonylation of an ethylenically unsaturated compound with carbon monoxide and a co-reactant. The carbonylation reaction is carried out in the presence of a novel catalyst involving: a) a source of a group VIII metal; b) a bidentate diphosphine of formula I, wherein R1 represents a bivalent radical that together with the phosphorus atom to which it is attached is an optionally substituted 2-phospha-tricyclo[3.3.1.1{3,7}]-decyl group or a derivative thereof in which one or more of the carbon atoms are replaced by heteroatoms (“2-PA” group); wherein R2 and R3 independently represent univalent radicals of up to 20 atoms or jointly form a bivalent radical of up to 20 atoms; and wherein A1 and A2 independently represent optionally substituted alkylene groups and R represents an optionally substituted aromatic group; and, c) a source of anions.
摘要翻译：用一氧化碳和共反应物羰基化烯属不饱和化合物的方法。羰基化反应在新型催化剂存在下进行，包括：a）VIII族金属源; b）式I的二齿二膦，其中R 1表示与连接的磷原子一起为任选取代的2-磷杂三环[3.3.1.1 {3， 7}] - 癸基或其衍生物，其中一个或多个碳原子被杂原子（“2-PA”基团）代替）; 其中R 2和R 3独立地表示至多20个原子的一价基团或共同形成至多20个原子的二价基团; 并且其中A 1和A 2独立地表示任选取代的亚烷基，R表示任选取代的芳族基团; 和c）阴离子的来源。

28. 发明申请

US20050038289A1 Chemical reactions in compressed carbon dioxide 审中-公开
标题翻译：压缩二氧化碳中的化学反应
公开(公告)号：US20050038289A1
公开(公告)日：2005-02-17
申请号：US10484457
申请日：2002-07-23
申请人： Richard Gordon , Tessa Early , Andrew Holmes
发明人： Richard Gordon , Tessa Early , Andrew Holmes
IPC分类号： B01J3/00 , B01J23/44 , B01J31/04 , B01J31/06 , B01J31/16 , B01J31/18 , B01J31/24 , C07B37/04 , C07C1/32 , C07C41/30 , C07C51/09 , C07C67/343 , C07C205/06 , C07C205/56 , C07C51/10 , C07C51/14
CPC分类号： C07C41/30 , B01J3/008 , B01J23/44 , B01J31/06 , B01J31/1658 , B01J31/1805 , B01J31/2404 , B01J2219/00094 , B01J2231/4205 , B01J2231/4255 , B01J2231/4261 , B01J2231/4266 , B01J2531/824 , B01J2531/922 , C07B37/04 , C07B2200/11 , C07C1/321 , C07C51/09 , C07C67/343 , C07C201/12 , C07C2521/18 , C07C2523/44 , C07C15/00 , C07C59/84 , C07C63/331 , C07C57/44 , C07C69/732 , C07C69/65 , C07C69/734 , C07C69/738 , C07C69/618 , C07C205/06 , C07C205/56 , C07C43/205
摘要： A palladium-catalysed carbon-carbon bond forming reaction in compressed carbon dioxide is provided wherein at least one of the reagents used in said reaction is bounded to a solid polymer support. In a second aspect, a palladium-catalysed carbon-carbon bond forming reaction in compressed carbon dioxide is provided wherein said reaction is performed in the presence of a tetra-alkylammonium acetate. In a third aspect, a palladium-catalysed carbon-carbon bond forming reaction in compressed carbon dioxide is provided wherein said palladium catalyst does not have any fluorinated phosphine ligands but does have at least one phosphine ligand that has at least one substituent that is selected from tert-alkyl groups, cycloalkyl groups and optionally substituted phenyl groups or 1′-diphenylphosphino-biphenyl. In a fourth aspect, there is provided a palladium-catalysed Suzuki or Heck reaction in compressed carbon dioxide wherein both of the substrates being combined in said reactions are boronic acids.
摘要翻译：提供了在压缩二氧化碳中形成钯催化的碳 - 碳键反应，其中所述反应中使用的至少一种试剂与固体聚合物载体结合。在第二方面，提供了在压缩二氧化碳中形成钯催化的碳 - 碳键反应，其中所述反应在四烷基乙酸铵存在下进行。在第三方面，提供了在压缩二氧化碳中形成钯催化的碳 - 碳键反应，其中所述钯催化剂不具有任何氟化膦配体，但是具有至少一个具有至少一个选自以下的取代基的膦配体：叔烷基，环烷基和任选取代的苯基或1'-二苯基膦基 - 联苯。在第四方面，提供了在压缩二氧化碳中的钯催化的Suzuki或Heck反应，其中在所述反应中组合的两种底物都是硼酸。

29. 发明授权

US06844463B2 Method for the carbonylation of pentenoic acid and its derivatives thereof 失效
标题翻译：戊烯酸及其衍生物的羰基化方法
公开(公告)号：US06844463B2
公开(公告)日：2005-01-18
申请号：US10433034
申请日：2001-12-03
申请人： Michael Slany , Martin Schäfer , Michael Röper
发明人： Michael Slany , Martin Schäfer , Michael Röper
IPC分类号： C07B61/00 , C07C51/14 , C07C67/38 , C07C69/44 , C07C253/30 , C07C255/19 , C07C255/00 , C07C57/02 , C07C69/34
CPC分类号： C07C253/30 , C07C51/14 , C07C67/38 , C07C55/02 , C07C69/44
摘要： Process for the carbonylation of n-pentenoic acid or its derivatives of the formula (I) C4H7—R1 (I) where R1 is —CN or COOR2 where R2 is hydrogen, alkyl or aryl by reaction of a compound of the formula (I) with carbon monoxide and a compound (II) containing a hydroxyl group in the presence of a catalyst system, wherein the catalyst system is obtainable by reaction of a) a source for a metal ion of a metal (III) of the 8th subgroup of the Periodic Table of the Elements with b) a bidentate phosphine ligand of the formula (IV) (R3R4R5C)(R6R7R8C)P-L1-X-L2-P(CR9R10R11) (CR12R13R14) (IV) where R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14 independently of one another is an organic radical which in each case contains a carbon atom, via which the respective radical is linked to the relevant tertiary carbon atom mentioned in formula (IV); L1, L2 independently of one another are a lower alkylene group; X is an arylene group.
摘要翻译：羰基化式（I）的正戊烯酸或其衍生物的方法，其中R 1是-CN或COOR 2，其中R 2是氢，烷基或芳基，通过式（I）与一氧化碳和含有羟基的化合物（II）在催化剂体系的存在下反应，其中催化剂体系可通过以下方法获得：a）第8族金属（III）的金属离子源的元素周期表b）一种式（Ⅳ）的二齿膦配体，其中R 3，R 4，R 5，R 6，R 7，R 8，R 8， R 9，R 10，R 11，R 12，R 13，R 14彼此独立地是有机基团，其在每种情况下均含有碳原子，通过该有机基团，各自的基团与式（IV）中所述的相关叔碳原子连接; L 1，L 2彼此独立地为低级亚烷基; X为亚芳基。

30. 发明授权

US6011171A Process for synthesis of tertiary carboxylic acids and the esters thereof 失效
标题翻译：合成叔羧酸的方法及其酯
公开(公告)号：US6011171A
公开(公告)日：2000-01-04
申请号：US964319
申请日：1997-11-04
申请人： Qiang Xu , Yoshie Souma
发明人： Qiang Xu , Yoshie Souma
IPC分类号： C07C51/12 , C07C51/14 , C07C51/145 , C07C67/38
CPC分类号： C07C51/12 , C07C51/14 , C07C51/145
摘要： The present invention provides a process for synthesizing tertiary carboxylic acids or the esters thereof having one or two more carbon atoms than the raw material has, comprising reacting in a strong acid (e.g., sulfuric acid, sulfuric acid-phosphoric acid, hydrogen fluoride, fluorosulfuric acid, boron trifluoride.water complex and trifluoromethanesulfonic acid) a raw material compound (i.e., olefin, alcohol, diene, diol or saturated hydrocarbon) with carbon monoxide in the presence of a specific metal carbonyl catalyst (i.e., platinum carbonyl catalyst, palladium carbonyl catalyst and gold dicarbonyl catalyst).The metal carbonyl catalyst is formed by reacting in a strong acid at least one specific metal compounds (e.g., platinum compound such as platinum (II, IV) oxide, platinum (II, IV) hydroxide, a platinum powder, etc.; palladium compound such as palladium (II, III, IV) oxide, palladium (II) hydroxide, palladium (II) sulfate, palladium (II) carboxylate, a palladium powder, etc.; and gold compound such as gold (I, III) oxide, gold (I, III) hydroxide, a gold powder, etc.) with carbon monoxide.
摘要翻译：本发明提供了一种合成叔羧酸或其具有比原料具有一个或两个以上碳原子的酯的方法，包括在强酸（例如硫酸，硫酸 - 磷酸，氟化氢，氟硫酸）酸，三氟化硼，水络合物和三氟甲磺酸）在特定的羰基羰基催化剂（即铂羰基催化剂，羰基钯催化剂）存在下，将一种原料化合物（即烯烃，醇，二烯，二醇或饱和烃）与一氧化碳催化剂和二羰基催化剂）。金属羰基催化剂通过在强酸中至少一种特定的金属化合物（例如，铂化合物如氧化铂（II），氢氧化铂（II），IV），铂粉等），钯化合物例如氧化钯（II，III，IV），氢氧化钯（II），硫酸钯（II），羧酸钯（II），钯粉等）和金化合物如氧化金（I，III）金（I，III）氢氧化物，金粉等）与一氧化碳。

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