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21. 发明授权

US07745616B2 Bead for enantiomeric isomer resolution and process for producing the same 有权
标题翻译：用于对映异构体拆分的珠和其制备方法
公开(公告)号：US07745616B2
公开(公告)日：2010-06-29
申请号：US11918331
申请日：2006-04-28
申请人： Yoshio Okamoto , Chiyo Yamamoto , Tomoyuki Ikai , Masami Kamigaito
发明人： Yoshio Okamoto , Chiyo Yamamoto , Tomoyuki Ikai , Masami Kamigaito
IPC分类号： C08B3/12
CPC分类号： C08B33/00 , B01D15/3833 , B01J20/24 , B01J20/265 , B01J20/267 , B01J20/28004 , B01J20/28016 , B01J20/285 , B01J20/29 , B01J20/30 , B01J2220/4825 , C08B15/06 , C08B15/10 , G01N2030/525 , Y10T428/2982 , Y10T428/2998
摘要： There is provided a process for producing beads for enantiomeric isomer resolution with a satisfactory separation efficiency. The beads for enantiomeric isomer resolution include a polysaccharide derivative, in which the polysaccharide derivative has a structure crosslinked at the 6-position hydroxy group of constituent units of the polysaccharide with a crosslinking agent. The process for producing the beads for enantiomeric isomer resolution includes: the step of adding dropwise an organic solvent solution of the polysaccharide derivative to a coagulation bath being stirred to thereby produce beads; the step of taking out the beads and then optionally drying the same after washing; and the step of reacting the beads with a crosslinking agent in an organic solvent to react at least part of the 6-position hydroxy groups in the constituent units of the polysaccharide with the crosslinking agent, thereby obtaining a reaction mixture containing beads having a crosslinked structure.
摘要翻译：提供了一种以令人满意的分离效率制备对映异构体拆分的珠的方法。用于对映体异构体拆分的珠子包括多糖衍生物，其中多糖衍生物具有在多糖的构成单元的6-位羟基与交联剂交联的结构。用于制备对映体异构体拆分的珠粒的方法包括：将滴加有机溶剂的多糖衍生物的溶液搅拌至凝固浴的步骤，从而产生珠粒; 取出珠粒，然后洗涤后任选地干燥珠粒的步骤; 和将珠粒与交联剂在有机溶剂中反应的步骤，使多糖的构成单元中的6位羟基的至少一部分与交联剂反应，得到含有交联结构的珠粒的反应混合物。

22. 发明申请

US20090124798A1 Filler for Optical Isomer Separation 有权
标题翻译：光学异构体分离填料
公开(公告)号：US20090124798A1
公开(公告)日：2009-05-14
申请号：US12227151
申请日：2007-05-02
申请人： Yoshio Okamoto , Chiyo Yamamoto , Tomoyuki Ikai , Masami Kamigaito
发明人： Yoshio Okamoto , Chiyo Yamamoto , Tomoyuki Ikai , Masami Kamigaito
IPC分类号： C07H3/00
CPC分类号： B01J20/29 , B01J20/26 , B01J20/262 , B01J20/265 , B01J20/285 , C08B15/06
摘要： A polymer compound derivative, obtained by modifying part of the hydroxy or amino groups of a polymer compound having the hydroxy or amino groups with molecules of a compound represented by the following general formula (I): A-X—Si(Y)nR3-n (I), where A represents a reactive group which reacts with a hydroxy or amino group, X represents an alkylene group which has 1 to 18 carbon atoms and which may have a branch, or an arylene group which may have a substituent, Y represents a reactive group which reacts with a silanol group to form a siloxane bond, R represents an alkyl group which has 1 to 18 carbon atoms and which may have a branch, or an aryl group which may have a substituent, and n represents an integer of 1 to 3.
摘要翻译：通过用下列通式（I）表示的化合物的分子将具有羟基或氨基的高分子化合物的羟基或氨基的一部分羟基或氨基改性得到的高分子化合物衍生物：AX-Si（Y）nR3-n（ I），其中A表示与羟基或氨基反应的反应性基团，X表示具有1至18个碳原子且可具有支链的亚烷基，或可具有取代基的亚芳基，Y表示与硅烷醇基反应以形成硅氧烷键的反应性基团，R表示具有1至18个碳原子并且可以具有支链的烷基或可具有取代基的芳基，n表示1的整数到3。

23. 再颁专利

USRE39557E1 Laundry detergent compositions with cellulosic based polymers to provide appearance and integrity benefits to fabrics laundered therewith 失效
标题翻译：具有纤维素基聚合物的洗衣洗涤剂组合物，以为洗涤的织物提供外观和完整性
公开(公告)号：USRE39557E1
公开(公告)日：2007-04-10
申请号：US10835583
申请日：1998-09-15
申请人： Jennifer Leupin Moe (formerly, Jennifer Ann Leupin , Eugene Paul Gosselink
发明人： Jennifer Leupin Moe (formerly, Jennifer Ann Leupin , Eugene Paul Gosselink
IPC分类号： C11D3/22 , C11D3/37 , B08B3/04
CPC分类号： C11D3/225 , C08B11/12 , C08B11/193 , C08B11/20 , C08B15/00 , C08B15/06 , C08G73/02 , C08G73/022 , C08G73/0273 , C08G73/0616 , C11D3/0015 , C11D3/227 , C11D3/3723 , C11D3/3776
摘要： Compositions and methods which utilize certain cellulosic based polymer or oligomeric materials as fabric treatment agents that can impart fabric appearance and integrity benefits to fabrics and textiles laundered in washing solutions which contain such materials. Specifically, the cellulosic based polymers or oligomers are of the general formula: Wherein each R is selected from the group consisting of R2, RC, and each R2 is independently selected from the group consisting of H and C1-C4 alkyl; each RC is each Z is independently selected from the group consisting of M, R2, RC, and RH; and each RH is independently selected from the group consisting of C5-C20 alkyl, C5-C7 cycloalkyl, C7-C20 alkylaryl, C7-C20 arylalkyl, substituted alkyl, hydroxyalkyl, C1-C20 alkoxy-2-hydroxyalkyl, C7-C20 alkylaryloxy-2-hydroxyalkyl, (R4)2N-alkyl, (R4)2N-2-hydroxyalkyl, (R4)3N-alkyl, (R4)3N-2-hydroxyalkyl, C6-C12 aryloxy-2-hydroxyalkyl, The Degree of Substitution for group RH in these cellulosic based polymers or oligomers is between about 0.001 and 0.1, and the Degree of Substitution for group RC wherein Z is H or M in these cellulosic based polymers or oligomers is between about 0.2 and 2.0.
摘要翻译：使用某些基于纤维素的聚合物或低聚材料作为织物处理剂的组合物和方法，其可以赋予织物外观和完整性优点，洗涤在含有这种材料的洗涤溶液中的织物和织物。具体来说，纤维素类聚合物或低聚物是一般形式

24. 发明申请

US20060081522A1 Separating agent for optical isomers 审中-公开
标题翻译：光学异构体分离剂
公开(公告)号：US20060081522A1
公开(公告)日：2006-04-20
申请号：US11254689
申请日：2005-10-21
申请人： Atsushi Onishi , Keiko Kudo
发明人： Atsushi Onishi , Keiko Kudo
IPC分类号： B01D15/08
CPC分类号： B01J20/262 , B01J20/265 , B01J20/285 , B01J20/29 , C08B15/06
摘要： A separating agent for optical isomers which contains a polysaccharide derivative as an active ingredient, wherein the polysaccharide derivative serving as an active ingredient is one formed by replacing at least part of the hydrogen atoms of the hydroxyl groups and amino groups of a polysaccharide with at least one member selected out of a benzoyl group having a specific alkyl group and a carbamoyl group in which one hydrogen atom has been replaced with an aromatic group having a specific alkyl group. It is a novel separating agent for optical isomers which has the high ability to asymmetrically identify the target compound to be analyzed and isolated.
摘要翻译：含有多糖衍生物作为有效成分的光学异构体用分离剂，其中，作为活性成分的多糖衍生物是通过至少将至少一部分羟基的氢原子和多糖的氨基取代而形成的选自具有特定烷基的苯甲酰基和其中一个氢原子被具有特定烷基的芳族基团取代的氨基甲酰基的一个成员。它是用于光学异构体的新型分离剂，其具有对不对称鉴定待分析和分离的目标化合物的高能力。

25. 发明申请

US20050234229A1 Method for the production of cellulose carbamate moulded bodies 审中-公开
标题翻译：生产纤维素氨基甲酸酯成型体的方法
公开(公告)号：US20050234229A1
公开(公告)日：2005-10-20
申请号：US10515787
申请日：2003-05-09
申请人： Fritz Loth , Eckehart Schaaf , Peter Weigel , Hans-Peter Fink
发明人： Fritz Loth , Eckehart Schaaf , Peter Weigel , Hans-Peter Fink
IPC分类号： C08B15/06 , C08L1/08 , D01F2/00 , D01F2/24 , C08B5/00 , B27N3/00
CPC分类号： D01F2/00 , C08B15/06 , C08L1/08 , D01F2/24
摘要： The invention relates to a method for the direct production of fibres, films, beads, sponges and other moulded articles made of cellulose carbamate which was obtained by conversion of cellulose with urea at increased temperature and direct dissolution of the reaction product in sodium hydroxide solution without an additional washing and cleaning operation.
摘要翻译：本发明涉及一种直接生产由纤维素氨基甲酸酯制成的纤维，薄膜，珠粒，海绵和其它模塑制品的方法，该方法是通过在温度升高下将脲纤维素与尿素转化而获得的，并且将反应产物直接溶解在氢氧化钠溶液中而没有额外的洗涤和清洁操作。

26. 发明申请

US20050100518A1 Use of modified cellulose derivatives as thickening agent for the organic phase of a nail varnish composition 审中-公开
标题翻译：改性纤维素衍生物作为增粘剂用于指甲油组合物的有机相的使用
公开(公告)号：US20050100518A1
公开(公告)日：2005-05-12
申请号：US10883819
申请日：2004-07-06
申请人： Philippe Ilekti , Jean Mondet , Florence Tournilhac
发明人： Philippe Ilekti , Jean Mondet , Florence Tournilhac
IPC分类号： A61K8/00 , A61K8/72 , A61K8/73 , A61Q1/06 , A61Q1/10 , A61Q3/02 , C08B3/00 , C08B11/00 , C08B15/06 , C08L83/08 , A61K7/04
CPC分类号： C08B11/00 , A61K8/731 , A61Q1/06 , A61Q1/10 , A61Q3/02 , C08B3/00 , C08B15/06
摘要： The invention relates to the use of certain specific cellulose derivatives chosen from cellulose esters and nitrocelluloses as thickening agents for the organic phase of a nail varnish composition, in particular when the said organic phase comprises at least one ester solvent.
摘要翻译：本发明涉及使用选自纤维素酯和硝基纤维素的某些特定纤维素衍生物作为指甲油组合物的有机相的增稠剂，特别是当所述有机相包含至少一种酯溶剂时。

27. 发明授权

US06342592B1 Chiral compounds, their synthesis and use as a support 失效
标题翻译：手性化合物，其合成和用作支持
公开(公告)号：US06342592B1
公开(公告)日：2002-01-29
申请号：US09039266
申请日：1998-03-16
申请人： Raphaël Duval , Hubert Leveque
发明人： Raphaël Duval , Hubert Leveque
IPC分类号： C07H1500
CPC分类号： C07B57/00 , B01J20/3204 , B01J20/3208 , B01J20/3219 , B01J20/3274 , B01J20/3282 , C08B15/06 , Y02P20/544
摘要： The invention relates to a method which comprises synthesising bifunctional compounds then chiral compounds from the bifunctional compounds, also to synthesising supports comprising these chiral compounds, and the use of these supports for preparing or separating enantiomers, or for asymmetric synthesis. The invention also relates to bifunctional compounds, their use as a source of functionalised polymers, and to the chiral compounds, also to the use of these chiral compounds in a chiral support in the form of a three-dimensional network or for separating or preparing enantiomers, principally for analytical or preparative chromatography, and in a support for the production of chiral molecules by asymmetric synthesis.
摘要翻译：本发明涉及一种方法，其包括双官能化合物，然后合成来自双功能化合物的手性化合物，以及合成包含这些手性化合物的载体，以及这些载体用于制备或分离对映异构体或用于不对称合成的方法。本发明还涉及双功能化合物，它们作为官能化聚合物的来源的用途以及手性化合物，也涉及这些手性化合物在三维网络形式的手性载体中的用途或用于分离或制备对映异构体，主要用于分析或制备色谱，以及支持通过不对称合成生产手性分子。

28. 发明授权

US6071505A Cationic cellulose derivatives of controlled charge density useful in cosmetic preparations 失效
标题翻译：具有控制电荷密度的阳离子纤维素衍生物可用于化妆品制剂
公开(公告)号：US6071505A
公开(公告)日：2000-06-06
申请号：US286814
申请日：1999-04-06
申请人： Melissa A. Manuszak-Guerrini , Doris A. Culberson , William H. Daly
发明人： Melissa A. Manuszak-Guerrini , Doris A. Culberson , William H. Daly
IPC分类号： A01N43/16 , A61K8/73 , A61Q5/02 , A61Q5/06 , A61Q5/12 , C08B11/193 , C08B11/20 , C08B15/06 , A61K7/06 , C07H5/04 , C07H11/02 , C08B15/04
CPC分类号： A61Q5/02 , A01N43/16 , A61K8/731 , A61Q5/06 , A61Q5/12 , C08B11/193 , C08B11/20 , C08B15/06 , A61K2800/5426
摘要： Water-soluble quaternary ammonium cellulosic derivatives of controlled charge density are disclosed. These derivatives are useful in cosmetic preparations, such as hair and skin formulations, for example hair conditioners. These quaternized cellulosic derivatives are useful as thickeners, conditioners, film formers, fixatives, emulsifiers, or additives in hair or skin formulations to improve combing, manageability, body, curl retention, moisture resistance, and binding of ingredients to keratin. Compared to existing agents, these compounds have improved temperature stability, improved interactions with surfactants (such as in shampoos), improved binding to keratin, improved mechanical properties, and can mend split ends on hair. A major advantage of these compounds is that they may be applied to hair directly from an aqueous solution, and do not require a volatile organic compound solvent as carrier. Alternatively, smaller amounts of VOC's may be used than is the case in current products, to improve drying times for the formulations. The compounds are also useful as antistatic agents, bactericides, flocculating agents, and as drug binding or drug delivery agents.
摘要翻译：公开了具有受控电荷密度的水溶性季铵纤维素衍生物。这些衍生物可用于化妆品制剂，例如头发和皮肤制剂，例如头发调理剂。这些季铵化的纤维素衍生物可用作毛发或皮肤制剂中的增稠剂，调理剂，成膜剂，固定剂，乳化剂或添加剂，以改善组合，可管理性，身体，卷曲保留性，耐湿性和成分与角蛋白的结合。与现有的试剂相比，这些化合物具有改善的温度稳定性，改善与表面活性剂的相互作用（如洗发剂），改善的与角蛋白的结合，改进的机械性能，以及修补头发上的分叉端。这些化合物的主要优点是它们可以直接从水溶液中施用于毛发，并且不需要挥发性有机化合物溶剂作为载体。或者，可以使用比当前产品更小量的VOC，以改善制剂的干燥时间。这些化合物也可用作抗静电剂，杀菌剂，絮凝剂，以及药物结合或药物递送剂。

29. 发明授权

US5981737A Cationic cellulose derivatives of controlled charge density useful in cosmetic preparations 失效
公开(公告)号：US5981737A
公开(公告)日：1999-11-09
申请号：US822987
申请日：1997-03-21
申请人： Melissa A. Manuszak-Guerrini , Doris A. Culberson , William H. Daly
发明人： Melissa A. Manuszak-Guerrini , Doris A. Culberson , William H. Daly
IPC分类号： A01N43/16 , A61K8/73 , A61Q5/02 , A61Q5/06 , A61Q5/12 , C08B11/193 , C08B11/20 , C08B15/06
CPC分类号： A61Q5/02 , A01N43/16 , A61K8/731 , A61Q5/06 , A61Q5/12 , C08B11/193 , C08B11/20 , C08B15/06 , A61K2800/5426
摘要： Water-soluble quaternary ammonium cellulosic derivatives of controlled charge density are disclosed. These derivatives are useful in cosmetic preparations, such as hair and skin formulations, for example hair conditioners. These quaternized cellulosic derivatives are useful as thickeners, conditioners, film formers, fixatives, emulsifiers, or additives in hair or skin formulations to improve combing, manageability, body, curl retention, moisture resistance, and binding of ingredients to keratin. Compared to existing agents, these compounds have improved temperature stability, improved interactions with surfactants (such as in shampoos), improved binding to keratin, improved mechanical properties, and can mend split ends on hair. A major advantage of these compounds is that they may be applied to hair directly from an aqueous solution, and do not require a volatile organic compound solvent as carrier. Alternatively, smaller amounts of VOC's may be used than is the case in current products, to improve drying times for the formulations. The compounds are also useful as antistatic agents, bactericides, flocculating agents, and as drug binding or drug delivery agents.

30. 发明授权

US5691423A Polysaccharide-bound nitric oxide-nucleophile adducts 失效
标题翻译：多糖结合的一氧化氮 - 亲核试剂加合物
公开(公告)号：US5691423A
公开(公告)日：1997-11-25
申请号：US419424
申请日：1995-04-10
申请人： Daniel J. Smith , Debashish Chakravarthy , Larry K. Keefer
发明人： Daniel J. Smith , Debashish Chakravarthy , Larry K. Keefer
IPC分类号： A61K31/655 , A61K31/785 , A61K47/48 , C08F8/30 , C08B15/06 , C08B37/00
CPC分类号： A61K31/655 , A61K31/785 , A61K47/4823 , C08B15/06 , C08B37/0006 , C08F8/30
摘要： A polymeric composition capable of releasing nitric oxide comprises a polysaccharide including a nitric oxide-releasing N.sub.2 O.sub.2.sup.- functional group bound to the polymer; pharmaceutical compositions including the polymeric composition; and methods for treating biological disorders in which dosage with nitric oxide is beneficial. The compositions can be used as and/or incorporated into implants, injectables, condoms, prosthesis coatings, patches, and the like for use in a wide variety of medical applications.
摘要翻译：能够释放一氧化氮的聚合物组合物包括与聚合物结合的包含一氧化氮释放的N2O2-官能团的多糖; 包括聚合物组合物的药物组合物; 以及用于治疗一氧化氮剂量有益的生物学障碍的方法。组合物可以用作和/或并入植入物，注射剂，避孕套，假体涂层，贴剂等中，以用于各种各样的医疗应用。

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