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21. 发明授权

US4877907A Preparation process of 4,4'-biphenol, precursor of same and preparation process of precursor 失效
公开(公告)号：US4877907A
公开(公告)日：1989-10-31
申请号：US338206
申请日：1989-04-14
申请人： Tohru Miura , Teruyuki Nagata , Koju Okazaki , Masayuki Furuya , Emiko Nishida
发明人： Tohru Miura , Teruyuki Nagata , Koju Okazaki , Masayuki Furuya , Emiko Nishida
IPC分类号： C07C37/06 , C07C37/52 , C07C39/15 , C07C39/23
CPC分类号： C07C37/06 , C07C37/52 , C07C39/23 , C07C2101/14
摘要： A novel compound, 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol, and a novel preparation process of 4,4'-biphenol by using the novel compound as the raw material.4-(4-Hydroxyphenyl)-3-cyclohexene-1-ol can be obtained by conducting a thermal decomposition reaction of 4,4-bis(4-hydroxyphenyl)cyclohexanol. 4,4'-Biphenol can be industrially manufactured by conducting a dehydrogenation reaction of 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol.

22. 发明授权

US4873374A Preparation process of 4,4'-biphenol, precursor of same and preparation process of precursor 失效
标题翻译： 4,4'-联苯酚的制备方法，前体相同，前体的制备方法
公开(公告)号：US4873374A
公开(公告)日：1989-10-10
申请号：US178301
申请日：1988-04-06
申请人： Tohru Miura , Teruyuki Nagata , Koju Okazaki , Masayuki Furuya , Emiko Nishida
发明人： Tohru Miura , Teruyuki Nagata , Koju Okazaki , Masayuki Furuya , Emiko Nishida
IPC分类号： C07C37/06 , C07C37/52 , C07C39/15 , C07C39/23
CPC分类号： C07C37/06 , C07C37/52 , C07C39/23 , C07C2101/14
摘要： A novel compound, 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol, and a novel preparation process of 4,4'-biphenol by using the novel compound as the raw material.4-(4-Hydroxyphenyl)-3-cyclohexene-1-ol can be obtained by conducting a thermal decomposition reaction of 4,4-bis(4-hydroxyphenyl)cyclohexanol. 4,4'-Biphenol can be industrially manufactured by conducting a dehydrogenation reaction of 4-(4-hydroxyphenyl)-3-cyclohexene-1-ol.

23. 发明授权

US4798911A Catalyst composition and method for selective dehydrogenation 失效
标题翻译：催化剂组合物和选择性脱氢方法
公开(公告)号：US4798911A
公开(公告)日：1989-01-17
申请号：US75375
申请日：1987-07-20
申请人： Carl M. Lentz , Bruce L. Gustafson , Paul S. Wehner
发明人： Carl M. Lentz , Bruce L. Gustafson , Paul S. Wehner
IPC分类号： B01J23/89 , C07B35/04 , C07B61/00 , C07C5/00 , C07C5/32 , C07C5/333 , C07C11/02 , C07C37/06 , C07C39/15 , C07C41/18 , C07C43/215 , C07C45/65 , C07C47/548 , C07C49/794 , C07C51/347 , C07C63/64 , C07C69/76 , C07C69/94 , C07C317/14 , C07C5/367 , C07C39/12
CPC分类号： C07C41/18 , B01J23/8926 , C07C37/001 , C07C37/06 , C07C5/325 , C07C5/3337 , C07C67/297 , C07C67/317 , C07C2101/14 , C07C2521/18 , C07C2523/44 , C07C2523/72 , C07C2523/89
摘要： A method for selective dehydrogenation of a compound, comprising contacting a compound of the formula ##STR1## wherein each R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is independently selected from the group consisting of H, (C.sub.1 -C.sub.20) alkyl, (C.sub.3 -C.sub.20) cycloalkyl, (C.sub.6 -C.sub.20) aryl, (C.sub.7 -C.sub.20) alkylaryl, (C.sub.7 -C.sub.20) aralkyl groups, as well as substituted (C.sub.1 -C.sub.20) alkyl, (C.sub.3 -C.sub.20) cycloalkyl, (C.sub.6 -C.sub.20) aryl, (C.sub.7 -C.sub.20) aralkyl and (C.sub.7 -C.sub.20) arylalkyl moieties, optionally further substituted with --OR, wherein R is R.sup.1, R.sup.2, R.sup.3 or R.sup.4 ; and wherein R.sup.1 and R.sup.2 or R.sup.3 and R.sup.4 may be joined as part of a ring structure, at a dehydrogenation temperature in the presence of a catalyst comprising about 0.01 wt %-19.9 wt % Pd and about 0.01 wt %-19.9 wt % Cu on a carbon support, wherein the total amount of (Pd+Cu) on the support is about 0.02 wt % to 20 wt %, the weight ratio of Pd:Cu is about 1:1 to 10:1, and the carbon support has a surface area of at least about 100 m.sup.2 /g and is essentially free of reactive sulfur.A selective dehydrogenation catalyst having the composition described supra is disclosed as is a method of preparing the same. This catalyst is highly selective for dehydrogenating a variety of substrates while minimizing the formation of unwanted hydrogenolysis by-products.
摘要翻译：一种化合物的选择性脱氢的方法，包括使下式化合物与其中每个R 1，R 2，R 3和R 4独立地选自H，（C 1 -C 20）烷基，（C 3 -C 20）环烷基，（C 6 -C 20）芳基，（C 7 -C 20）烷基芳基，（C 7 -C 20）芳烷基以及取代的（C 1 -C 20）烷基，（C 3 -C 20）环烷基，（C 6 -C 20） C7-C20）芳烷基和（C7-C20）芳烷基部分，任选进一步被-OR取代，其中R是R 1，R 2，R 3或R 4; 并且其中R 1和R 2或R 3和R 4可以作为环结构的一部分在脱氢温度下在催化剂存在下接合，所述催化剂包含约0.01重量％-19.9重量％的Pd和约0.01重量％-19.9重量％的Cu 碳载体，其中载体上的（Pd + Cu）的总量为约0.02重量％至20重量％，Pd：Cu的重量比为约1:1至10:1，并且碳载体具有表面积至少约100m 2 / g，基本上不含活性硫。作为其制备方法，公开了具有上述组成的选择性脱氢催化剂。该催化剂对于使各种底物脱氢而具有高选择性，同时最小化不想要的氢解副产物的形成。

24. 发明授权

US4319054A Process for producing pyrogallol 失效
标题翻译：连苯三酚生产工艺
公开(公告)号：US4319054A
公开(公告)日：1982-03-09
申请号：US213900
申请日：1980-12-08
申请人： Takao Maki , Kenji Murayama
发明人： Takao Maki , Kenji Murayama
IPC分类号： C07C37/06 , C07C37/72 , C07C39/10
CPC分类号： C07C37/72 , B01J21/18 , B01J23/44 , B01J23/50 , B01J23/52 , B01J23/58 , B01J23/6442 , B01J27/0573 , B01J27/0576 , B01J37/18 , B01J37/20 , B01J38/14 , C07C37/06 , Y02P20/584
摘要： There is disclosed a process for producing pyrogallol by dehydrogenation of cyclohexane-1,2,3-triol in the presence of a platinum group metal catalyst in an inert gas stream. The catalyst contains, as modifier, (a) at least one alkali metal salt and/or (b) at least one member selected from the group consisting of gold, tellurium, silver, arsenic, selenium, indium, antimony, bismuth, copper and zinc, with the Pd-Te catalyst being preferred. The catalyst ingredients are supported on a carrier. The process gives high selectivity of pyrogallol.
摘要翻译：公开了在惰性气体流中在铂族金属催化剂存在下，通过环己烷-1,2,3-三醇的脱氢生产连苯三酚的方法。催化剂含有（a）至少一种碱金属盐和/或（b）至少一种选自金，碲，银，砷，硒，铟，锑，铋，铜和锌，Pd-Te催化剂是优选的。催化剂成分负载在载体上。该方法提供了连苯三酚的高选择性。

25. 发明授权

US4080390A Process for the production of o-phenylphenol 失效
标题翻译：邻苯基苯酚生产工艺
公开(公告)号：US4080390A
公开(公告)日：1978-03-21
申请号：US695039
申请日：1976-06-11
申请人： Juichi Imamura
发明人： Juichi Imamura
IPC分类号： B01J23/00 , C07B61/00 , C07C27/00 , C07C37/06 , C07C37/07 , C07C39/15 , C07C67/00
CPC分类号： C07C37/06 , B01J21/04 , B01J21/08 , B01J21/12 , B01J23/745 , B01J23/8906 , B01J23/8946 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J37/0201 , B01J37/18
摘要： A process for the production of o-phenylphenol in the presence of a catal composed of a .gamma.-alumina or silica-alumina support having a BET surface area of 150 - 300 m.sup.2 /g, a pore capacity of 0.50 - 0.85 ml/g and an iron content of at most 0.1 % by weight in terms of Fe.sub.2 O.sub.3 and an alumina content of at least 90 %, the support carrying thereon platinum in an amount of 0.1 - 5.0 % by weight based on the support, iridium in an amount of 0.1 - 0.4 times that of the platinum and an alkali metal oxide in an amount of 0.5 - 8.0 % by weight of the support. o-Phenylphenol is prepared at a high selectivity over a long period of time by supplying onto the catalyst maintained at 300.degree. - 420.degree. C o-cyclohexylphenol or a dehydrodimerized condensate obtained by aldol condensation of cyclohexanone together with gaseous hydrogen in an amount per hour in terms of liquid volume of 0.1 - 1.5 times the volume of the catalyst, and elevating the reaction temperature stepwise or continuously with the lapse of the reaction time, while slowing down, if necessary, the rate of supplying the starting materials, to effect a dehydrogenation reaction.
摘要翻译：在由γ-氧化铝或二氧化硅 - 氧化铝载体组成的催化剂存在下制备邻苯基苯酚的方法，所述催化剂的BET表面积为150-300m2 / g，孔容为0.50〜0.85ml / g，铁含量以Fe 2 O 3为最多0.1重量％，氧化铝含量为至少90％，载体上载持量为0.1-5.0重量％的载体，铱的量为0.1 - 铂的量的0.4倍，碱金属氧化物的量为载体重量的0.5〜8.0％。通过向保持在300-420℃邻苯二酚的催化剂供应邻苯二酚，通过将环己酮与气态氢醇缩合得到的脱氢二聚缩合物以每小时的量在液体体积为催化剂体积的0.1〜1.5倍的范围内，随着反应时间的延长逐步或连续地升高反应温度，同时如果需要，可以减缓原料的供给速度，脱氢反应。

26. 发明授权

US3340311A Stabilized catalyst for the dehydrogenation of 1-tetralone and/or 1-tetralol 失效
标题翻译：用于1-四氢萘酮和/或1-四氢化萘脱氢的稳定催化剂
公开(公告)号：US3340311A
公开(公告)日：1967-09-05
申请号：US51517065
申请日：1965-12-20
申请人： UNION CARBIDE CORP
发明人： CHITWOOD HENRY C , FREURE BENJAMIN T , CUNNINGHAM ROBERT W
IPC分类号： B01J23/86 , C07C37/06 , C07C37/07
CPC分类号： C07C37/06 , B01J23/868 , C07C37/07 , C07C39/14

27. 发明授权

US09061270B2 Cyclohexanone dehydrogenation catalyst and process 有权
标题翻译：环己酮脱氢催化剂及工艺
公开(公告)号：US09061270B2
公开(公告)日：2015-06-23
申请号：US13520467
申请日：2010-12-17
申请人： Teng Xu , Terry E. Helton , Jihad M. Dakka , Tan-Jen Chen , Sabato Miseo , Lorenzo C. Decaul , Edward A. Lemon, Jr.
发明人： Teng Xu , Terry E. Helton , Jihad M. Dakka , Tan-Jen Chen , Sabato Miseo , Lorenzo C. Decaul , Edward A. Lemon, Jr.
IPC分类号： C07C37/08 , C07C37/00 , B01J29/04 , B01J21/00 , B01J23/58 , B01J21/08 , B01J37/02 , B01J37/12 , C07C2/74 , C07C37/06 , C07C45/53 , C07C407/00 , C07C37/07
CPC分类号： B01J23/58 , B01J21/08 , B01J37/0205 , B01J37/12 , C07C2/74 , C07C37/06 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2529/70 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403 , C07C409/14
摘要： A catalyst composition comprising: (i) a support; (ii) a first component comprising at least one metal component selected from Group 1 and Group 2 of the Periodic Table of Elements; and (iii) a second component comprising at least one metal component selected from Groups 6 to 10 of the Periodic Table of Elements, wherein the catalyst composition exhibits an oxygen chemisorption of greater than 50%.
摘要翻译：一种催化剂组合物，其包含：（i）载体; （ii）包含选自元素周期表第1族和第2族的至少一种金属成分的第一成分; 和（iii）包含选自元素周期表第6至10族的至少一种金属组分的第二组分，其中催化剂组合物显示出大于50％的氧化学吸附。

28. 发明申请

US20150158800A1 METHOD OF MANUFACTURING 4,4"-DIHYDROXY-M-TERPHENYL 有权
公开(公告)号：US20150158800A1
公开(公告)日：2015-06-11
申请号：US14401098
申请日：2013-05-14
申请人： Honshu Chemical Industry Co., Ltd.
发明人： Kazuhito Ashida , Yuki Hashimoto , Tomoya Yamamoto , Xuwang Lu
IPC分类号： C07C37/06 , C07C37/52 , C07C37/20
CPC分类号： C07C37/06 , C07C37/20 , C07C37/52 , C07C39/15 , C07C39/23 , C07C39/17
摘要： To achieve the object of providing a new method of manufacturing 4,4″-dihydroxy-m-terphenyl, the present invention provides a method of manufacturing 4,4″-dihydroxy-m-terphenyl expressed by General Formula (4) below, characterized in that such method uses a 2-cyclohexene-1-one expressed by General Formula (1) below or 3-hydroxycyclohexane-1-one expressed by General Formula (2) below, and phenol expressed by General Formula (3) below as materials and implements Step (A), Step (B), and Step (C) below, in this order, or Step (D) and Step (C) below, in this order: (In the formulas, each R2 independently represents an alkyl group, alkoxy group, aromatic hydrocarbon group, or halogen atom, while m independently indicates 0 or an integer of 1 to 4, where R2 substitution does not occur in the third position when m is 1 or greater, and when m is 2 or greater, R2's may be identical or different, and R2 substitution does not occur in two positions of the same carbon atom. In addition, R2 and m in General Formula (1) may be identical to or different from R2 and m in General Formula (2), respectively.) (In the formula, each R1 independently represents an alkyl group, alkoxy group, aromatic hydrocarbon group, halogen atom, or hydroxyl group, while n indicates 0 or an integer of 1 to 4, where R1's may be identical or different when n is 2 or greater.) Step (A): Step to obtain a 1,1,3-trisphenol by causing the 2-cyclohexene-1-one or 3-hydroxycyclohexane-1-one and phenol to react with each other in the presence of a catalyst. Step (B): Step to obtain a bis(4-hydroxyphenyl)cyclohexene by causing the 1,1,3-trisphenol to undergo breakdown reaction. Step (C): Step to obtain a 4,4″-dihydroxy-m-terphenyl by dehydrogenating the bis(4-hydroxyphenyl)cyclohexene. Step (D): Step to obtain a bis(4-hydroxyphenyl)cyclohexene by causing the 2-cyclohexene-1-one or 3-hydroxycyclohexane-1-one and phenol to react with each other in the presence of a catalyst. (In the formula, each R1 and n is independently the same as the corresponding items in General Formula (3), respectively, while R2 and m are the same as the corresponding items in General Formula (1) or General Formula (2), respectively.)

29. 发明申请

US20140135470A1 LIGNIN CONVERSION PROCESS 审中-公开
标题翻译： LIGNIN转换过程
公开(公告)号：US20140135470A1
公开(公告)日：2014-05-15
申请号：US14124028
申请日：2012-06-15
申请人： CHEMTEX ITALIA, S.p.A.
发明人： Aaron Murray , Steven Ryba
IPC分类号： C07C29/156 , C08G63/78 , C07C1/22
CPC分类号： C07C29/156 , C07C1/22 , C07C37/06 , C08G63/183 , C08G63/78 , C08H6/00 , C10G1/065 , C10G1/083 , C10G1/086 , C10G3/45 , C10G3/50 , C10G2300/1014 , C10G2300/805 , D21C3/003 , Y02E50/32 , Y02P30/20
摘要： This specification discloses a complete method to manufacture polyester articles from freshly harvested ligno-cellulosic biomass. The process steps include pretreating the biomass and the converting the lignin to one of several possible organic steams by deoxygenating and dehydrogenating the lignin in the presence of a Raney Nickel catalyst, separating the organics, and then processing the organics into polyester feedstocks and converting those feedstocks to polyester.
摘要翻译：本说明书公开了一种从新鲜收获的木质纤维素生物质制造聚酯制品的完整方法。方法步骤包括通过在阮内镍催化剂存在下脱木素和脱木质素分离生物质并将木质素转化为几种可能的有机蒸汽之一，分离有机物，然后将有机物加工成聚酯原料并转化成这些原料到聚酯。

30. 发明申请

US20040049086A1 Diphenol and process for producing the same 有权
标题翻译：二苯酚及其制备方法
公开(公告)号：US20040049086A1
公开(公告)日：2004-03-11
申请号：US10467187
申请日：2003-08-05
发明人： Kouji Muragaki , Tadashi Hiramine , Hiroyasu Ohno
IPC分类号： C07C039/12 , C07C039/16
CPC分类号： C07C39/23 , C07C37/003 , C07C37/06 , C07C37/20 , C07C37/52 , C07C39/15 , C07C39/17 , C07C2601/14 , C07C2601/16
摘要： The invention provides a diphenol represented by the general formula (I) 1 wherein X is a divalent cyclic hydrocarbon group selected from 1-cyclohexene-1,4-ylene group, 1,4-cyclohexylene group and p-phenylene group, R is an alkyl group of 1-4 carbon atoms, n is 0 or an integer of 1-3 when X is 1-cyclohexene-1,4-ylene group and an integer of 1-3 when X is 1,4-cyclohexylene group or p-phenylene group. The invention further provides a process for the production of the same.
摘要翻译：本发明提供由通式（I）表示的二酚，其中X为选自1-环己烯-1,4-亚基，1,4-亚环己基和对亚苯基的二价环状烃基，R为烷基 1-4个碳原子的基团，当X是1-环己烯-1,4-亚基时，n是0或1-3的整数，当X是1,4-亚环己基或对 - 亚苯基。本发明还提供了一种制备该方法的方法。

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