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21. 发明授权

US07988944B2 Peroxide decomposition catalyst 有权
标题翻译：过氧化物分解催化剂
公开(公告)号：US07988944B2
公开(公告)日：2011-08-02
申请号：US11993892
申请日：2006-06-20
申请人： Takeshi Ishiyama , Hideyuki Higashimura , Hiroshi Takigawa
发明人： Takeshi Ishiyama , Hideyuki Higashimura , Hiroshi Takigawa
IPC分类号： C01B13/00 , G01N33/44 , C07F3/12
CPC分类号： B01J31/2243 , B01J23/30 , B01J23/34 , B01J31/1815 , B01J31/183 , B01J31/2239 , B01J2531/0216 , B01J2531/025 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845
摘要： An object of the present invention is to provide a catalyst which decomposes a peroxide effectively and economically under a high temperature while suppressing generation of free radicals, and the present invention provides a peroxide decomposition catalyst containing a base metal atom, wherein a value A indicating a free radical generation amount represented by the (equation 1) is not more than 0.20, and a value B indicating a reaction rate represented by the (equation 2), which can be easily applied to utility such as an agent for preventing deterioration of a polymer electrolyte-type fuel cell and a water electrolysis apparatus, and an antioxidant for medicaments, agrochemicals and foods. A=(Mw(S)/Mw)−1 (equation 1) (wherein Mw is a weight average molecular weight of poly(sodium 4-styrenesulfonate) after a hydrogen peroxide decomposition test in the test at 80° C. in the presence of poly(sodium 4-styrenesulfonate), and Mw(S) is a weight average molecular weight of poly(sodium 4-styrenesulfonate) before the test) B=N(PO)/N(cat) (equation 2) (wherein N(po) is a mole number of hydrogen peroxide decomposed per 20 minutes in a hydrogen peroxide decomposition test in the (equation 1), and N(cat) is a mole number per metal atom of a catalyst used).
摘要翻译：本发明的目的在于提供一种在高温下有效且经济地分解过氧化物同时抑制自由基产生的催化剂，本发明提供了含有贱金属原子的过氧化物分解催化剂，其中A表示由（式1）表示的自由基产生量不大于0.20，表示由（式2）表示的反应速度的值B，其可以容易地应用于防止聚合物劣化的试剂电解质型燃料电池和水电解装置，以及用于药物，农药和食品的抗氧化剂。 A =（Mw（S）/ Mw）-1（式1）（式中，Mw是在80℃下在过氧化氢分解试验中聚（4-苯乙烯磺酸钠）的重均分子量，的聚（4-苯乙烯磺酸钠），Mw（S）是试验前的聚（4-苯乙烯磺酸钠）的重均分子量）B = N（PO）/ N（cat）（式2）（式中，N （po）是在（式1）的过氧化氢分解试验中每20分钟分解的过氧化氢的摩尔数，N（cat）是使用的催化剂的每个金属原子的摩尔数）。

22. 发明申请

US20110172454A1 METHOD FOR PRODUCING DIPHENYLCARBONATE HAVING CATALYST COMPRISING IONIC FLUIDS 失效
标题翻译：生产含有包含离子液体的催化剂的二苯基碳酸酯的方法
公开(公告)号：US20110172454A1
公开(公告)日：2011-07-14
申请号：US13120086
申请日：2009-09-17
申请人： Alexandra Große Böwing , Aurel Wolf , Kilian Tellmann , Leslaw Mleczko
发明人： Alexandra Große Böwing , Aurel Wolf , Kilian Tellmann , Leslaw Mleczko
IPC分类号： C07C68/00 , B01J31/02 , B01J31/04 , B01J31/30 , B01J31/32
CPC分类号： C07D207/06 , B01J31/0212 , B01J31/0278 , B01J31/30 , B01J2531/72 , B01J2531/824 , C07C68/005 , C07D233/58 , C07C69/96
摘要： The invention relates to a method for producing diphenylcarbonate while using a catalyst composition comprising ionic fluids.
摘要翻译：本发明涉及一种使用包含离子流体的催化剂组合物生产碳酸二苯酯的方法。

23. 发明授权

US07928049B2 Use of metal complex compounds as oxidation catalysts 有权
标题翻译：使用金属络合物作为氧化催化剂
公开(公告)号：US07928049B2
公开(公告)日：2011-04-19
申请号：US12669797
申请日：2008-07-14
申请人： Barbara Wagner , Hauke Rohwer , Marie-Josée Dubs , Nicole End , Menno Hazenkamp , Sophie Marquais-Bienewald
发明人： Barbara Wagner , Hauke Rohwer , Marie-Josée Dubs , Nicole End , Menno Hazenkamp , Sophie Marquais-Bienewald
IPC分类号： C11D1/02 , C11D1/66 , C11D3/28 , C11D3/39 , C11D3/395
CPC分类号： B01J31/1815 , B01J31/1825 , B01J31/2217 , B01J2231/70 , B01J2531/0238 , B01J2531/0258 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/81 , C07D213/88 , C07D215/38 , C07D401/12 , C11D3/0021 , C11D3/168 , C11D3/3932 , C11D3/3935 , C11D3/48
摘要： The present invention relates to the use of metal complex compounds having hydrazide ligands as oxidation catalysts. Further aspects of the invention are formulations comprising such metal complex compounds, novel metal complex compounds and novel ligands. The metal complex compounds are used especially for enhancing the action of peroxides, for example in the treatment of textile material, without at the same time causing any appreciable damage to fibers and dyeings. There is also no appreciable damage to fibers and dyeings if these metal complexes are used in combination with an enzyme or a mixture of enzymes.
摘要翻译：本发明涉及具有酰肼配位体的金属络合物作为氧化催化剂的用途。本发明的其它方面是包含这种金属络合物，新型金属络合物和新型配体的制剂。金属络合物特别用于增强过氧化物的作用，例如在纺织材料的处理中，而不会同时对纤维和染色造成明显的损害。如果这些金属配合物与酶或酶的混合物组合使用，纤维和染色也不会有明显的损害。

24. 发明申请

US20100300929A1 COMPOSITIONS AND METHODS FOR IMPROVING A CATALYTIC REFORMER 审中-公开
标题翻译：用于改进催化改性剂的组合物和方法
公开(公告)号：US20100300929A1
公开(公告)日：2010-12-02
申请号：US12472736
申请日：2009-05-27
申请人： Allen A. ARADI , Joseph W. ROOS , Michael W. MEFFERT
发明人： Allen A. ARADI , Joseph W. ROOS , Michael W. MEFFERT
IPC分类号： C10L1/04 , B01J23/34 , C10G35/06 , B01J8/00
CPC分类号： B01J31/2295 , B01J2231/70 , B01J2531/72 , C10G35/04 , C10G35/085 , C10G2300/1044 , C10G2300/202 , C10G2300/305 , C10G2300/708
摘要： The present disclosure relates to a catalytic reformer system, including a feed stream to a catalytic reformer comprising naphtha and at least one manganese-containing compound. There is also disclosed a reformer catalyst. Methods of improving the reformer catalyst durability are also disclosed.
摘要翻译：本公开涉及一种催化重整器系统，其包括向包含石脑油和至少一种含锰化合物的催化重整器的进料流。还公开了一种改性剂催化剂。还公开了提高重整器催化剂耐久性的方法。

25. 发明申请

US20100105909A1 MODIFIED METAL COMPLEX AND USE THEREOF 有权
标题翻译：改性金属复合物及其用途
公开(公告)号：US20100105909A1
公开(公告)日：2010-04-29
申请号：US12530174
申请日：2008-03-10
申请人： Tadafumi Matsunaga , Nobuyoshi Koshino , Hideyuki Higashimura , Hiroshi Hamamatsu
发明人： Tadafumi Matsunaga , Nobuyoshi Koshino , Hideyuki Higashimura , Hiroshi Hamamatsu
IPC分类号： C07F15/06 , C07F13/00 , C07F15/02
CPC分类号： C07D213/30 , B01J31/1805 , B01J31/1815 , B01J31/183 , B01J31/223 , B01J2531/0252 , B01J2531/16 , B01J2531/56 , B01J2531/72 , B01J2531/842 , B01J2531/845 , C07D471/04
摘要： A modified metal complex obtained by subjecting a metal complex containing an organic compound having one nitrogen-containing aromatic heterocycle and four or more structures of a phenol, thiophenol, aniline or nitrogen-containing aromatic heterocyclic ring or an organic compound having two or more phenol rings and three or more nitrogen-containing aromatic heterocycles, in its molecule as a ligand, to a heating, radiation irradiation or discharge treatment until a mass reduction rate after the treatment becomes from 1 to 90 mass %, thereby the complex shows a carbon content after the treatment of 5 mass % or more.
摘要翻译：一种改性金属络合物，其通过使含有一个含氮芳族杂环的有机化合物和四种或更多种酚，苯硫酚，苯胺或含氮芳族杂环的结构的金属络合物或具有两个或多个酚环的有机化合物在其分子中含有3个以上的含氮芳香族杂环作为配体，进行加热，放射线照射或放电处理，直到处理后的质量降低率为1〜90质量％，由此，复合物显示出碳后的碳含量治疗5％以上。

26. 发明申请

US20100041545A1 CATALYSTS AND METHODS FOR CATALYTIC OXIDATION 审中-公开
标题翻译：催化氧化催化剂和方法
公开(公告)号：US20100041545A1
公开(公告)日：2010-02-18
申请号：US12603772
申请日：2009-10-22
申请人： Daryle Hadley Busch , Simon Robert Collinson , Timothy Jay Hubin
发明人： Daryle Hadley Busch , Simon Robert Collinson , Timothy Jay Hubin
IPC分类号： B01J31/22 , B01J31/18
CPC分类号： C11D3/3932 , B01J31/182 , B01J2231/70 , B01J2231/72 , B01J2531/0238 , B01J2531/0258 , B01J2531/16 , B01J2531/56 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2531/72 , B01J2531/821 , B01J2531/824 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07F13/005
摘要： Catalytic systems and methods for oxidizing materials in the presence of metal catalysts (preferably manganese-containing catalysts) complexed with selected macropolycyclic rigid ligands, preferably cross-bridged macropolycyclic ligands. Included are using these metal catalysts in such processes as: synthetic organic oxidation reactions such as oxidation of organic functional groups, hydrocarbons, and heteroatoms, including enantiomeric epoxidation of alkenes, enynes, sulfides to sulfones and the like; oxidation of oxidizable compounds (e.g., stains) on surfaces such as fabrics, dishes, countertops, dentures and the like; oxidation of oxidizable compounds in solution, dye transfer inhibition in the laundering of fabrics; and further in the bleaching of pulp and paper products.
摘要翻译：在选择的大多环刚性配体，优选跨桥联的大多环配体络合的金属催化剂（优选含锰催化剂）存在下氧化材料的催化体系和方法。包括在这些方法中使用这些金属催化剂：合成有机氧化反应，例如有机官能团，烃和杂原子的氧化，包括烯烃的对映体环氧化，烯烃，硫化物到砜等; 在诸如织物，餐具，台面，假牙等的表面上氧化可氧化化合物（例如污点）; 溶液中可氧化化合物的氧化，织物洗涤中的染料转移抑制; 并进一步在纸浆和纸制品的漂白。

27. 发明申请

US20100020088A1 GRAPHICS RENDERING DEVICE AND GRAPHICS RENDERING METHOD 审中-公开
标题翻译：图形渲染设备和图形渲染方法
公开(公告)号：US20100020088A1
公开(公告)日：2010-01-28
申请号：US12526496
申请日：2007-02-28
申请人： Hideaki Harumoto
发明人： Hideaki Harumoto
IPC分类号： G09G5/36 , G06T1/60
CPC分类号： G09G5/395 , B01J31/04 , B01J31/26 , B01J2231/70 , B01J2531/72 , B01J2531/845 , G06T15/005 , G09G5/001 , G09G2350/00
摘要： When moving images such as three-dimensional graphics, or the like are displayed, high-quality images can be displayed by keeping a display frame rate, suppressing a breakdown of display contents, and making a drawing engine exhibit processing abilities to maximum. A graphics rendering device includes a frame buffer 40 in which a plurality of areas are provided, a rendering frame counter 15 for counting a number of frames in which the rendering is ended, a display frame counter 17 for counting a number of frames in which a display on a screen is completed within respective frames whose rendering is ended, a rendering controlling portion 11 for determining whether or not an empty area is present on the frame buffer based on the value of the rendering frame counter and the value of the display frame counter and permitting the rendering of the display element in the next frame when the empty area is present, a rendering necessary-time predicting portion 13 for predicting a rendering required time, and a rendering omission controlling portion 12 for determining whether or not the rendering is completed before display based on the value of the display frame counter, a display period of the frame, and a predicted rendering required time and going to a process in the next frame by omitting an execution of a succeeding rendering command when the rendering is not completed.
摘要翻译：当显示诸如三维图形等的图像时，可以通过保持显示帧率，抑制显示内容的故障，使绘图引擎的处理能力最大化来显示高质量的图像。图形绘制装置包括其中提供多个区域的帧缓冲器40，用于对渲染结束的帧数进行计数的渲染帧计数器15，用于对其中的屏幕上的显示在其渲染结束的各个帧内完成，渲染控制部分11用于基于渲染帧计数器的值和显示帧计数器的值来确定帧缓冲器上是否存在空区域并且当空白区域存在时允许显示元素在下一帧中的渲染，用于预测渲染所需时间的渲染必要时间预测部分13以及用于确定渲染是否完成的渲染省略控制部分12 在显示基于显示帧计数器的值，帧的显示周期和预测渲染所需时间之前进行显示当渲染未完成时，通过省略执行后续渲染命令来在下一帧中处理。

28. 发明申请

US20100010285A1 DECONTAMINATION SYSTEM 审中-公开
标题翻译：去污系统
公开(公告)号：US20100010285A1
公开(公告)日：2010-01-14
申请号：US12491736
申请日：2009-06-25
申请人： Von Howard M. Ebron , Yevgenia V. Ulyanova , Patrick J. Kinlen
发明人： Von Howard M. Ebron , Yevgenia V. Ulyanova , Patrick J. Kinlen
IPC分类号： A62D3/38 , C01B15/022 , C09K3/00
CPC分类号： B01J31/184 , A01N59/00 , A61L2/186 , A62D3/38 , A62D5/00 , A62D2101/02 , B01J31/006 , B01J31/0208 , B01J31/223 , B01J2231/70 , B01J2531/0272 , B01J2531/72 , B01J2531/842 , C01B15/023 , A01N25/08 , A01N2300/00
摘要： A composition including at least one peroxide-generating electrocatalyst, at least one peroxide-activation catalyst, and carbon.
摘要翻译：包含至少一种产生过氧化物的电催化剂，至少一种过氧化物活化催化剂和碳的组合物。

29. 发明申请

US20090036687A1 MULTINUCLEAR COMPLEX AND CONDENSATION PRODUCT THEREOF 审中-公开
标题翻译：多功能复合物和凝结产品
公开(公告)号：US20090036687A1
公开(公告)日：2009-02-05
申请号：US12278415
申请日：2007-02-08
申请人： Yoshiyuki Sugahara , Takeshi Ishiyama , Hideyuki Higashimura
发明人： Yoshiyuki Sugahara , Takeshi Ishiyama , Hideyuki Higashimura
IPC分类号： C07D403/14 , C07F7/10
CPC分类号： C07F15/025 , B01J31/183 , B01J31/2243 , B01J2231/62 , B01J2531/0216 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07F7/1804
摘要： A multinuclear complex comprising a plurality of metal atoms and a ligand L coordinating to the metal atoms, and satisfying the following conditions (i), (ii), (iii) and (iv):(i) The ligand L has a monovalent group represented by the following general formula (1) and/or a divalent group represented by the following general formula (2), (ii) The ligand L has at least 5 coordination atoms bonding to the metal atom, (iii) At least one of the coordination atoms bonds to two of the metal atoms, or the minimum number of covalent bonds between any two selected coordination atoms is 1-5, and (iv) The ligand L is soluble in the solvent.
摘要翻译：包含多个金属原子的多核络合物和与金属原子配位的配位体L，并满足下列条件（i），（ii），（iii）和（iv）：（i）配体L具有一价基团由下述通式（1）表示的化合物和/或由以下通式（2）表示的二价基团，（ii）配体L具有至少5个与金属原子键合的配位原子，（iii）至少一个配位原子与两个金属原子键合，或任意两个选定的配位原子之间的最小共价键数为1-5，和（ⅳ）配体L可溶于溶剂中。

30. 发明申请

US20090012330A1 METHOD FOR PRODUCING OPTICALLY ACTIVE ALCOHOL COMPOUND 失效
标题翻译：生产光学活性醇类化合物的方法
公开(公告)号：US20090012330A1
公开(公告)日：2009-01-08
申请号：US12161576
申请日：2007-01-31
申请人： Kazuaki Sasaki
发明人： Kazuaki Sasaki
IPC分类号： C07C41/03
CPC分类号： C07C41/03 , B01J31/0212 , B01J31/2243 , B01J2231/485 , B01J2531/0252 , B01J2531/48 , B01J2531/49 , B01J2531/62 , B01J2531/72 , B01J2531/845 , C07B53/00 , C07B2200/07 , C07C251/24 , C07C43/23 , C07C43/295
摘要： A method for producing an optically active alcohol compound comprising reacting a cyclic ether compound with a phenol compound in the presence of an asymmetric complex obtained by reacting an optically active metal complex represented by the formula (1): wherein R1, R2, R3, R4, R5, R6, R7 and R8 are the same or different and each independently represent a hydrogen atom, an alkyl group or the like; one of R9 and R10 is a hydrogen group and the other is a substituted or unsubstituted phenyl group or the like; Q represents a single bond, a C1-C4 alkylene group or the like; M represents a metal ion; and when an ionic valency of the metal ion is same as a coordination number of a ligand, A is nonexistent, and when the above-mentioned ionic valency is different from the coordination number, and A represents a counter ion or a ligand, with a zirconium alkoxide or a hafnium alkoxide.
摘要翻译：一种制备光学活性醇化合物的方法，包括使环醚化合物与酚化合物在通式（1）表示的光学活性金属络合物反应得到的不对称络合物的存在下反应：其中R1，R2，R3，R4 R5，R6，R7和R8相同或不同，各自独立地表示氢原子，烷基等; R9和R10中的一个是氢基团，另一个是取代或未取代的苯基基团等; Q表示单键，C1-C4亚烷基等; M表示金属离子; 当金属离子的离子价与配位体的配位数相同时，A不存在，当上述离子价与配位数不同时，A表示抗衡离子或配体，烷氧基锆或醇铪。

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