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    • 23. 发明授权
    • Process for the electrolytic treatment of alkali halide
    • 碱卤化物电解处理方法
    • US4076604A
    • 1978-02-28
    • US732095
    • 1976-10-13
    • Naohiro MurayamaKenichi NakamuraMakoto FukudaTeruo SakagamiShirou Suzuki
    • Naohiro MurayamaKenichi NakamuraMakoto FukudaTeruo SakagamiShirou Suzuki
    • C25B1/46C25B1/16C25B1/26
    • C25B1/46
    • In an electrolytic treatment of alkali halide for the manufacture of alkali hydroxide, a three-chamber type reaction vessel assembly is used so as to provide an anodic chamber, an intermediate chamber and a cathodic chamber arranged in succession one after another and mutually separated by means of anodic (i.e., cationic selective) ion exchange membranes. From the intermediate chamber, low concentration caustic alkali solution is obtained, while from the cathodic chamber, high concentration caustic alkali solution is obtained. In this electrolytic process, the system is operated with the cathodic chamber supplied with no water or aqueous content. The high concentration caustic alkali solution is made from water and alkali metal ions conveyed from the intermediate chamber to the cathodic chamber and exclusively and osmotically passed through the anodic ion exchange membrane. The polymers or copolymers of the anodic ion exhange membrane include sulfonic acid, carboxylic acid and/or phenolic radicals. As the method for the introduction of these radicals, formation of corresponding copolymers may be utilized in the most recommended way. As an example, the membrane may comprise a fluorinated polymer having a cyclic ring structure unit and pendant type sulfonic acid radicals.
    • 在用于制造碱金属氢氧化物的碱金属卤化物的电解处理中,使用三室式反应容器组件,以便提供一个接一个地连续排列并相互分离的阳极室,中间室和阴极室 的阳极(即阳离子选择性)离子交换膜。 从中间室获得低浓度苛性碱溶液,而从阴极室获得高浓度苛性碱溶液。 在这种电解过程中,系统在没有水或含水量的阴极室运行。 高浓度苛性碱溶液由从中间室输送到阴极室的水和碱金属离子制成,并且渗透通过阳极离子交换膜。 阳离子离子膜的聚合物或共聚物包括磺酸,羧酸和/或酚基。 作为引入这些基团的方法,可以以最推荐的方式使用相应的共聚物的形成。 作为示例,膜可以包含具有环状结构单元和侧链型磺酸基团的氟化聚合物。
    • 24. 发明授权
    • Method of absorbing rays outside a visible region
    • 吸收可见区域外的光线的方法
    • US06180224B2
    • 2001-01-30
    • US09117001
    • 1998-07-21
    • Masuhiro ShoujiHiroki KatonoTakeo OgiharaTeruo SakagamiOsamu Tanegashima
    • Masuhiro ShoujiHiroki KatonoTakeo OgiharaTeruo SakagamiOsamu Tanegashima
    • B32B516
    • C04B35/453G02B5/208Y10T428/25Y10T428/31504
    • An absorber of rays outside the visible region. The absorber includes a base made of a transparent synthetic resin with electroconductive anhydrous zinc antimonate incorporated therein; or a base made of a transparent synthetic resin with a layer formed of a synthetic resin and electroconductive anhydrous zinc antimonate incorporated therein, for absorbing rays outside the visible region, being disposed on a surface of the base; or wherein the layer is formed by depositing electron conductive anhydrous zinc antimonate powder on a surface of the base made of a transparent synthetic resin. The electroconductive anhydrous zinc antimonate can be a powder having a molar ratio of ZnO to Sb2O5 of 0.8 to 1.2 and a primary particle size of 5 to 200 nm. The light transmittances of the absorber are high in the visible region and low in both the ultraviolet and infrared wavelength regions.
    • 可见光区外的光线吸收体。 该吸收体包括:由透明合成树脂制成的基底,其中引入有导电无水锑酸锌; 或由合成树脂形成的层和引入其中的导电无水锑酸锌的透明合成树脂制成的底座,用于吸收可见区域外的射线,设置在基底的表面上; 或者通过在由透明合成树脂制成的基材的表面上沉积导电的无水锑酸锌粉末来形成该层。 导电性无水锑酸锌可以是ZnO与Sb 2 O 5的摩尔比为0.8〜1.2,一次粒径为5〜200nm的粉末。 吸收体的透光率在可见光区域高,在紫外线和红外波长区域都较低。
    • 27. 发明授权
    • Infrared-blocking optical fiber
    • 红外阻挡光纤
    • US5691838A
    • 1997-11-25
    • US467545
    • 1995-06-06
    • Masuhiro ShoujiHiroki KatonoTakeo OgiharaTeruo Sakagami
    • Masuhiro ShoujiHiroki KatonoTakeo OgiharaTeruo Sakagami
    • G02B5/20F21V9/04C08F30/00G02B5/08
    • G02B5/208
    • Disclosed herein is an infrared-blocking optical filter having optical properties that the transmittance to rays in a visible region is excellent while rays in a near infrared region, particularly, in a wavelength range longer than 1200 nm are cut off or attenuated with high efficiency. The infrared-blocking optical filter includes a transparent substrate and either of the following infrared-blocking film (A) and (B) provided on a surface of the transparent substrate. Film (A): an infrared-blocking film formed on a synthetic resin in which fine powder of metal oxide material composed of indium oxide and/or tin oxide is dispersed; and Film (B): an infrared-blocking film formed of a deposit of a metal oxide material composed of indium oxide and/or tin oxide. The infrared-blocking film may be formed on a transparent support member to constitute an infrared-blocking composite film which is provided on a surface of the transparent substrate to form an infrared-blocking optical filter.
    • 本发明公开了一种具有光学特性的红外阻挡滤光器,其特征在于,在近红外区域,特别是在1200nm以上的波长范围内的光线以高效率被切断或衰减,可见光区域的透射率优异。 红外阻挡滤光器包括透明基板和设置在透明基板的表面上的以下红外阻挡膜(A)和(B)之一。 膜(A):分散在由氧化铟和/或氧化锡构成的金属氧化物材料的细粉末的合成树脂上形成的红外阻挡膜; 和膜(B):由氧化铟和/或氧化锡构成的金属氧化物材料的沉积物形成的红外阻挡膜。 红外线阻挡膜可以形成在透明支撑构件上,以构成设置在透明基板的表面上以形成红外阻挡滤光器的红外阻挡复合膜。
    • 30. 发明授权
    • Optical fiber
    • 光纤
    • US4775590A
    • 1988-10-04
    • US887208
    • 1986-07-21
    • Teruo SakagamiNaohiro Murayama
    • Teruo SakagamiNaohiro Murayama
    • B29C47/00G02B1/04D02G3/00
    • G02B1/046B29C47/0014B29C47/0026G02B6/02033B29C47/00Y10T428/2929Y10T428/2933Y10T428/2935Y10T428/2964Y10T428/2967
    • A resin-made optical fiber is composed of a core of a polymer or copolymer obtained from a polymerizable monomer, which contains at least 1 wt. % of a crosslinkable monomer, and a cladding of a polymer of copolymer having a refractive index smaller than the core. The optical fiber is fabricated by filling a polymerizable monomer into a hollow fiber like cladding material, which is adapted to form a cladding and is made of a polymer or copolymer, and then placing the resultant composite material under polymerizing conditions to polymerize the polymerizable monomer. The latter step may preferably be carried out by causing the composite material to travel continuously in the direction of its length into a polymerization zone where conditions for the polymerization of the polymerizable monomer are satisfied, whereby the polymerizable monomer is successively polymerized to form a core having a refractive index greater than the cladding.
    • 树脂制光纤由可聚合单体获得的聚合物或共聚物的芯构成,该聚合物或共聚物含有至少1重量% %的可交联单体和折射率小于芯的共聚物聚合物的包层。 通过将可聚合单体填充到中空纤维状包覆材料中来制造光纤,该覆层材料适于形成包层并由聚合物或共聚物制成,然后将所得复合材料放置在聚合条件下聚合可聚合单体。 后一步骤可以优选通过使复合材料在其长度方向上连续移动到满足可聚合单体的聚合条件的聚合区域中进行,由此可聚合单体连续聚合以形成具有 折射率大于包层。