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21. 发明授权

US06713555B2 Hydrolyzable and polymerizable silanes based on methylene dithiepane 有权
标题翻译：基于亚甲基二硫杂环丁烷的可水解和可聚合硅烷
公开(公告)号：US06713555B2
公开(公告)日：2004-03-30
申请号：US10260069
申请日：2002-09-27
申请人： Norbert Moszner , Sabine Stein , Thomas Völkel , Volker Rheinberger
发明人： Norbert Moszner , Sabine Stein , Thomas Völkel , Volker Rheinberger
IPC分类号： C08L8308
CPC分类号： C07F7/1804
摘要： Methylene dithiepane silanes according to Formula I in which R1 is a saturated or unsaturated aliphatic or alicyclic hydrocarbon radical with 1 to 10 carbon atoms, which can be interrupted by one or more oxygen and/or sulphur atoms and can contain one or more ester, carbonyl, amide and/or urethane groups, or is an aromatic or heteroaromatic hydrocarbon radical with 6 to 18 carbon atoms, the hydrocarbon radicals being able to be substituted or unsubstituted; R2 has one of the meanings given for R1 or is absent; R3 has one of the meanings given for R1 or is absent; R4 is equal to —(CHR6)n—, —Y—CO—NH—(CHR6)n—, —Y—CO—NH—R5—, —(CHR6)n—S—R5—, —S—R5—, —CO—O—R5— or is absent, with n being equal to 1 to 4, R6 is hydrogen, C1 to C10 alkyl or C6 to C10 aryl, R5 has one of the meanings given for R1 and Y stands for an O or S atom or is absent; with R5 and R6 being able to be substituted or unsubstituted; X is a hydrolyzable group; a, b, c and x each independently of each other being 1, 2 or 3; and the sum of a+x=2 to 4. The silanes are particularly suitable for the preparation of dental materials.
摘要翻译：具有式Iin的亚甲基二噻吩烷硅烷，其中R 1是具有1至10个碳原子的饱和或不饱和脂族或脂环族烃基，其可被一个或多个氧和/或硫原子间隔并且可含有一个或多个酯，羰基，酰胺和/或氨基甲酸酯基团，或是具有6至18个碳原子的芳族或杂芳族烃基，所述烃基能够被取代或未取代; R 2具有R 1给出的含义之一或不存在; R 3具有R 1给出的含义之一或不存在; R 4等于 - （CHR 6）n - ， - O-CO-NH-（CHR 6）n-，-Y-CO-NH-R 5 - ， - （CHR < 6））nSR 5 - ， - SR 5 - ， - CO-OR 5 - 或不存在，n等于1至4，R 6是氢，C 1至C 10烷基或C 6 对于C 10芳基，R 5具有对R 1给出的含义之一，Y表示O或S原子或不存在; 其中R 5和R 6能够被取代或未取代; X是可水解基团; a，b，c和x各自独立地为1,2或3; 并且a + x = 2至4的总和。硅烷特别适用于制备牙科材料。

22. 发明授权

US06180688B2 Ion-releasing composite material 有权
标题翻译：离子释放复合材料
公开(公告)号：US06180688B2
公开(公告)日：2001-01-30
申请号：US09210510
申请日：1998-12-11
申请人： Volker Rheinberger , Ulrich Salz , Andr{acute over (e)} Rumphorst , Kurt Grabher , Urs Karl Fischer , Norbert Moszner
发明人： Volker Rheinberger , Ulrich Salz , Andr{acute over (e)} Rumphorst , Kurt Grabher , Urs Karl Fischer , Norbert Moszner
IPC分类号： A61K6083
CPC分类号： A61K6/083
摘要： The invention relates to ion-releasing composite materials on the basis of polymerizable monomers. The material is characterized in that it contains one or more non-acid, non-ionic, hydrophilic crosslinker monomers, one or more non-acid, non-ionic, hydrophilic dilution monomers having a viscosity of ≦1 Pas and at least one ion-releasing filler. The materials are suitable in particular for use as dental materials.
摘要翻译：本发明涉及基于可聚合单体的离子释放复合材料。该材料的特征在于其含有一种或多种非酸性，非离子型亲水性交联剂单体，一种或多种非酸性，非离子型亲水稀释单体，其粘度为≥1Pa·s和至少一种离子释放填料这些材料特别适合用作牙科材料。

23. 发明授权

US6136887A Vinylcyclopropane-(meth)acrylates and their use 有权
标题翻译：乙烯基环丙烷 - （甲基）丙烯酸酯及其用途
公开(公告)号：US6136887A
公开(公告)日：2000-10-24
申请号：US266509
申请日：1999-03-11
申请人： Norbert Moszner , Volker Rheinberger , Thomas Voelkel , Urs Karl Fischer
发明人： Norbert Moszner , Volker Rheinberger , Thomas Voelkel , Urs Karl Fischer
IPC分类号： A61K6/00 , A61K6/083 , C07C69/743 , C08F22/10
CPC分类号： A61K6/0023 , A61K6/083 , C07C69/743 , C08F22/105
摘要： The invention relates to vinylcyclopropane derivatives according to the formula ##STR1## in which A is --[--Y--CO--C(.dbd.CH.sub.2)R.sup.4 ].sub.m or --C(.dbd.CH.sub.2)CO--O--C.sub.1-4 -alkyl, U and X, independently of each other, stand for CO, COO or CONH; Y and Z stand for O or NH or are absent, but Y and Z cannot be absent at the same time; n, m stand for a whole number from 0 to 4, but n and m are not 0 at the same time; R.sup.1 is H, CH.sub.3 or Cl; R.sup.2, R.sup.3 stand for H, a C.sub.1 - to C.sub.10 -alkyl or alkylene radical, which can be interrupted by O, S or NH, for a C.sub.6 - to C.sub.14 -aryl or arylene, C.sub.7 - to C.sub.14 -alkylaryl or alkylarylene or a C.sub.5 - to C.sub.8 -cycloalkyl or cycloalkylene radical; and R.sup.4 is H or a C.sub.1 - to C.sub.10 -alkyl radical, and to processes for their production. The compounds are suitable in particular for the production of adhesives, cements, composites and mouldings.
摘要翻译：本发明涉及下式的乙烯基环丙烷衍生物，其中A为 - [ - Y-CO-C（= CH2）R4] m或-C（= CH2）CO-O-C1-4烷基，U和X，独立于代表CO，COO或CONH; Y和Z代表O或NH或不存在，但Y和Z不能同时不存在; n，m表示从0到4的整数，但n和m不同时为0; R1是H，CH3或Cl; R2，R3代表H，C 1至C 10 - 烷基或亚烷基，其可被O，S或NH中断，用于C 6至C 14 - 芳基或亚芳基，C 7至C 14 - 烷基芳基或烷基亚芳基或 C5至C8-环烷基或环亚烷基; 并且R4是H或C1-至C10-烷基，并且用于其制备。该化合物特别适用于粘合剂，水泥，复合材料和模制品的生产。

24. 发明授权

US5733968A Multi-component dental cement based on calcium hydroxide 失效
标题翻译：基于氢氧化钙的多组分牙科水泥
公开(公告)号：US5733968A
公开(公告)日：1998-03-31
申请号：US746157
申请日：1996-11-06
申请人： Norbert Moszner , Ulrich Salz , Volker Rheinberger
发明人： Norbert Moszner , Ulrich Salz , Volker Rheinberger
IPC分类号： A61K6/083 , C08J3/00 , C08F4/44 , C08K3/08 , C08L23/00
CPC分类号： A61K6/083
摘要： The invention relates to a multi-component dental cement which contains as a first component an ethylenically unsaturated polymerisable compound, as a second component calcium hydroxide, calcium oxide or a precursor thereof and also a polymerisation initiator, the constituents of which can be contained in one or more cement components, which is characterized in that the ethylenically unsaturated polymerisable compound has both at least one .beta.-dicarbonyl group and also at least one acrylic, alkacrylic or vinyl aromatic group. Also included are a process for the production of a multi-component dental cement and the use of the described polymerisable .beta.-dicarbonyl compounds in calcium hydroxide dental cements.
摘要翻译：本发明涉及一种多组分牙科粘固剂，其包含作为第一组分的烯属不饱和可聚合化合物，作为第二组分氢氧化钙，氧化钙或其前体，以及聚合引发剂，其组分可以包含在一种或更多的水泥组分，其特征在于烯属不饱和可聚合化合物具有至少一个β-二羰基和至少一个丙烯酸，丙烯酸或乙烯基芳族基团。还包括用于生产多组分牙科粘固剂的方法以及所述可聚合的β-二羰基化合物在氢氧化钙牙科用水泥中的用途。

25. 发明申请

US20140371341A1 DENTAL MATERIALS BASED ON COMPOUNDS HAVING DEBONDING-ON-DEMAND PROPERTIES 有权
公开(公告)号：US20140371341A1
公开(公告)日：2014-12-18
申请号：US14343300
申请日：2012-09-10
申请人： Norbert Moszner , Thomas Hirt , Kai Rist , Ulrich Salz , Christoph Weder , Gina Fiore , Christian Heinzmann , Volker Rheinberger
发明人： Norbert Moszner , Thomas Hirt , Kai Rist , Ulrich Salz , Christoph Weder , Gina Fiore , Christian Heinzmann , Volker Rheinberger
IPC分类号： A61K6/083 , C07D239/47 , C08F122/22 , C07F3/06
CPC分类号： A61K6/0835 , A61K6/0002 , A61K6/0023 , A61K6/083 , C07D239/47 , C07F3/06 , C08F122/22 , C08L33/00
摘要： The invention relates to a dental restorative material which comprises a thermolabile compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]l Formula I, in which T represents a thermolabile unit which contains at least one thermolabile group based on non-covalent interactions, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2═CR1—CO—O— and CH2═CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing or represent —O—, —S—, CO—O—, —O—CO—, —CO—NR3— or —NR3—CO—, R, R1, R2 and R3 in each case independently represent H or a C1-C7 alkyl radical, k and l in each case independently are 0, 1, 2 or 3 and m and n in each case independently are 1, 2 or 3.

26. 发明申请

US20060287458A1 Dental materials with unusual fluorine distribution 有权
公开(公告)号：US20060287458A1
公开(公告)日：2006-12-21
申请号：US11338034
申请日：2006-01-24
申请人： Norbert Moszner , Urs Fischer , Volker Rheinberger , Giancarlo Galli , Marina Ragnoli , Emo Chiellini
发明人： Norbert Moszner , Urs Fischer , Volker Rheinberger , Giancarlo Galli , Marina Ragnoli , Emo Chiellini
IPC分类号： C08F220/68
CPC分类号： A61K6/083 , A61K6/0017 , A61K6/0023 , C08L33/00 , C08L25/00
摘要： A composition comprising (A) at least one fluorinated vinylcyclopropane according to Formula (I) wherein R1 is H or —CO—O—(CH2CH2)p—R7; R2 is H or forms together with R6 a —CH2—C(R9) (R10)—CH2— residue; R3 is H; R4 is H or forms together with R5 a —CH2—C(R9) (R10)—CH2— residue; R5 is H, —CO—O—R8, —CO—O— (CH2CH2)p—R7 or forms together with R4 a —CH2—C (R9) (R10)—CH2— residue; R6 is H, —CO—O—R8, —CO—O— (CH2CH2)p—R7 or forms together with R2 a —CH2—C(R9) (R10)—CH2— residue; R7 is perfluorinated C2-C20 aliphatic or alicyclic group; R8 is H, phenyl, benzyl, or a linear or branched C1-C12 aliphatic or alicyclic group; R9 is a H, benzoyl, acetyl or a C1-C5-alkyl group; R10 H or a —CO—O—R8; p is 1, 2, 3, or 4, provided that the compound of Formula (I) comprises at least one —CO—O—(CH2CH2)p—R7 residue; (B) at least one non-fluorinated vinylcyclopropane derivative; (C) a bisphenol-A-ether di(meth)acrylate according to Formula (II) wherein R18 is H or CH3, R19 is CH3 or CF3, Y is a C2-C5-alkylen residue which can be substituted by an OH group or is preferably unsubstituted.

27. 发明申请

US20050165129A1 Dental coating materials 有权
标题翻译：牙科涂料
公开(公告)号：US20050165129A1
公开(公告)日：2005-07-28
申请号：US10928540
申请日：2004-08-27
申请人： Norbert Moszner , Simone Klapdohr , Ulrich Salz , Jorg Zimmermann , Volker Rheinberger
发明人： Norbert Moszner , Simone Klapdohr , Ulrich Salz , Jorg Zimmermann , Volker Rheinberger
IPC分类号： A61K6/093 , C08F290/06 , C08G77/20 , C09D183/04 , A61K6/08
CPC分类号： C09D183/04 , A61K6/0017 , Y10S522/908 , C08L83/16
摘要： Polymerizable materials which contain (1) 1 to 80 wt.-% of at least one polysiloxane, (2) 0.1 to 5 wt.-% of one or more initiators for radical polymerization, (3) 0 to 60 wt.-% of radically polymerizable monomer and (4) 1 to 50 wt.-% of one or more radically polymerizable monomers which carry at least phosphonic acid group, sulphonic acid group and/or mono- or dihydrogen phosphoric acid ester group, the polysiloxane (1), the monomer (3) or both being substituted by fluorine. The materials are suitable in particular for the coating of natural or artificial teeth.
摘要翻译：含有（1）1至80重量％的至少一种聚硅氧烷的可聚合材料，（2）0.1至5重量％的一种或多种用于自由基聚合的引发剂，（3）0至60重量％可自由基聚合的单体和（4）1至50重量％的至少携带膦酸基，磺酸基和/或单或二氢磷酸酯基的一种或多种可自由基聚合的单体，聚硅氧烷（1），单体（3）或两者均被氟取代。这些材料特别适用于天然或人造牙齿的涂层。

28. 发明授权

US06833394B2 Polymerizable dental material based on chromophoric xerogels 有权
标题翻译：基于发色干凝胶的可聚合牙科材料
公开(公告)号：US06833394B2
公开(公告)日：2004-12-21
申请号：US10209590
申请日：2002-07-30
申请人： Stefan Spange , Norbert Moszner , Volker Rheinberger , Peter Burtscher
发明人： Stefan Spange , Norbert Moszner , Volker Rheinberger , Peter Burtscher
IPC分类号： A61K608
CPC分类号： A61K6/0061 , A61K6/083 , A61K6/093 , C07F7/1804 , C08L51/085
摘要： Dental materials based on polymerizable binders, which contain at least one chromophoric xerogel of the formula I: (SiO2)a(SiO1.5-Sp-X-CG)(MenOm)b (I) in which Me represents a main-group metal of the 2nd to 3rd main groups or a transition metal of the 4th sub-group of the periodic table of elements; n being equal to 1 or 2, m being equal to 1 or 2 if n is equal to 1 and m being equal to 3 if n is equal to 2; Sp is a C1 to C10 alkylene radical or C2 to C10 oxyalkylene radical with 1 to 4 oxygen atoms or is absent; X is a compound group, such as CO—O, O—CO, CO—NH, NH—CO, O—CO—NH, NH—CO—O, NR, O or S or is absent, R being hydrogen or a C1 to C5 alkyl radical; CG is a chromophore; a is an integer from 0 to 20 and b is an integer from 0 to 5.
摘要翻译：基于可聚合粘合剂的牙科材料，其含有至少一种式I的发色干燥剂：其中Me表示2至3个主要基团的主族金属或第4 < >元素周期表的子组; n等于1或2，如果n等于1，则m等于1或2，如果n等于2，则m等于3; Sp是C1至C10亚烷基或具有1至4个氧原子的C2至C10氧化亚烷基，或不存在; X是一种化合物，如CO-O，O-CO，CO-NH，NH-CO，O-CO-NH，NH-CO-O，NR，O或S或不存在，R是氢或 C1至C5烷基; CG是发色团; a为0〜20的整数，b为0〜5的整数。

29. 发明授权

US06794520B1 Hydrolyzable and polymerizable silanes based on methylene dithiepane 有权
公开(公告)号：US06794520B1
公开(公告)日：2004-09-21
申请号：US09657343
申请日：2000-09-07
申请人： Norbert Moszner , Sabine Stein , Thomas Völkel , Volker Rheinberger
发明人： Norbert Moszner , Sabine Stein , Thomas Völkel , Volker Rheinberger
IPC分类号： C07D33900
CPC分类号： C07F7/1804
摘要： Methylene dithiepane silanes according to Formula I in which R1 is a saturated or unsaturated aliphatic or alicyclic hydrocarbon radical with 1 to 10 carbon atoms, which can be interrupted by one or more oxygen and/or sulphur atoms and can contain one or more ester, carbonyl, amide and/or urethane groups, or is an aromatic or heteroaromatic hydrocarbon radical with 6 to 18 carbon atoms, the hydrocarbon radicals being able to be substituted or unsubstituted; R2 has one of the meanings given for R1 or is absent; R3 has one of the meanings given for R1 or is absent; R4 is equal to —(CHR6)n—, —Y—CO—NH—(CHR6)n—, —Y—CO—NH—R5—, —(CHR6)n—S—R5—, —S—R5—, —CO—O—R5— or is absent, with n being equal to 1 to 4, R6 is hydrogen, C1 to C10 alkyl or C6 to C10 aryl, R5 has one of the meanings given for R1 and Y stands for an O or S atom or is absent; with R5 and R6 being able to be substituted or unsubstituted; X is a hydrolyzable group; a, b, c and x each independently of each other being 1, 2 or 3; and the sum of a+x=2 to 4. The silanes are particularly suitable for the preparation of dental materials.

30. 发明授权

US06281271B1 Radically polymerizable dental material 有权
标题翻译：可自由基聚合的牙科材料
公开(公告)号：US06281271B1
公开(公告)日：2001-08-28
申请号：US09296340
申请日：1999-04-22
申请人： André Rumphorst , Ulrich Salz , Alexandros Gianasmidis , Thomas Völkel , Volker Rheinberger , Norbert Moszner
发明人： André Rumphorst , Ulrich Salz , Alexandros Gianasmidis , Thomas Völkel , Volker Rheinberger , Norbert Moszner
IPC分类号： A61K6083
CPC分类号： A61K6/083 , A61K6/0023 , A61K6/005 , A61K6/0073 , C08L33/00
摘要： The invention relates to a dental material with at least one polymerizable binder and at least one filler containing a redox-initiator system for the radical polymerization, which comprises an initiator and an activator. The material is characterized in that the filler contains a homogeneous mixture of a first part of the filler, which is mixed with the initiator, a second part of the filler, which is mixed with the activator, and a third part of the filler, which does not contain a component of the initiator system. The materials are particularly suitable as cements and filling materials.
摘要翻译：本发明涉及具有至少一种可聚合粘合剂和至少一种含有用于自由基聚合的氧化还原引发剂体系的填料的牙科材料，其包含引发剂和活化剂。该材料的特征在于填料含有与引发剂混合的填料的第一部分，与活化剂混合的填料的第二部分和填料的第三部分的均匀混合物，其中不包含引发剂体系的组分。这些材料特别适合作为水泥和填充材料。

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