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1. 发明授权

US06281271B1 Radically polymerizable dental material 有权
标题翻译：可自由基聚合的牙科材料
公开(公告)号：US06281271B1
公开(公告)日：2001-08-28
申请号：US09296340
申请日：1999-04-22
申请人： André Rumphorst , Ulrich Salz , Alexandros Gianasmidis , Thomas Völkel , Volker Rheinberger , Norbert Moszner
发明人： André Rumphorst , Ulrich Salz , Alexandros Gianasmidis , Thomas Völkel , Volker Rheinberger , Norbert Moszner
IPC分类号： A61K6083
CPC分类号： A61K6/083 , A61K6/0023 , A61K6/005 , A61K6/0073 , C08L33/00
摘要： The invention relates to a dental material with at least one polymerizable binder and at least one filler containing a redox-initiator system for the radical polymerization, which comprises an initiator and an activator. The material is characterized in that the filler contains a homogeneous mixture of a first part of the filler, which is mixed with the initiator, a second part of the filler, which is mixed with the activator, and a third part of the filler, which does not contain a component of the initiator system. The materials are particularly suitable as cements and filling materials.
摘要翻译：本发明涉及具有至少一种可聚合粘合剂和至少一种含有用于自由基聚合的氧化还原引发剂体系的填料的牙科材料，其包含引发剂和活化剂。该材料的特征在于填料含有与引发剂混合的填料的第一部分，与活化剂混合的填料的第二部分和填料的第三部分的均匀混合物，其中不包含引发剂体系的组分。这些材料特别适合作为水泥和填充材料。

2. 发明授权

US06353039B1 Polymerizable composite material 有权
标题翻译：可聚合复合材料
公开(公告)号：US06353039B1
公开(公告)日：2002-03-05
申请号：US09209905
申请日：1998-12-11
申请人： Volker Rheinberger , Ulrich Salz , Wolfram Höland , André Rumphorst , Kurt Grabher , Urs Karl Fischer , Marcel Schweiger , Norbert Moszner
发明人： Volker Rheinberger , Ulrich Salz , Wolfram Höland , André Rumphorst , Kurt Grabher , Urs Karl Fischer , Marcel Schweiger , Norbert Moszner
IPC分类号： A61K6083
CPC分类号： A61K6/0276 , A61K6/083 , A61K6/09 , C08F2/44 , C08K3/40 , C08K9/08 , C08L33/00 , C08L75/16
摘要： A composite material is described which contains polymerizable monomers plus a special transparent glass having high release of calcium ions and fluorine ions and, because of this release property and in particular of its optical properties, can be used as a restoration material in dentistry.
摘要翻译：描述了一种复合材料，其包含可聚合单体加上具有高释放的钙离子和氟离子的特殊透明玻璃，并且由于该释放性质，特别是其光学性质，可用作牙科中的修复材料。

3. 发明授权

US06450717B1 Applicator and method of applying 有权
标题翻译：申请人和申请方法
公开(公告)号：US06450717B1
公开(公告)日：2002-09-17
申请号：US09695029
申请日：2000-10-24
申请人： Ulrich Salz , Andre Rumphorst , Alexandros Gianasmidis , Frank Muller , Volker Rheinberger
发明人： Ulrich Salz , Andre Rumphorst , Alexandros Gianasmidis , Frank Muller , Volker Rheinberger
IPC分类号： A46B1100
CPC分类号： A61C3/005 , A61C5/60 , A61J1/2031 , A61J1/2041 , A61J1/2093
摘要： An applicator kit, for dental purposes. has an application element with a grip area for handling, and also has a shaft, on a tip of which is disposed an application member, preferably in the form of a micro-brush that is provided with a reaction substance. A cup shaped sealing mechanism surrounds the shaft and the application member. The cup shaped sealing mechanism is slidably received within a housing which also receives a low velocity fluid initially spaced away from the cup-shaped sealing mechanism. The reaction substance on the application member is activated by pressing the sealing mechanism and application member into the fluid within the housing which causes the fluid to wet the application member.
摘要翻译：用于牙科用途的涂抹器套件。具有用于处理的抓握区域的应用元件，并且还具有轴，其尖端设置在施加构件上，优选地为具有反应物质的微型刷形式。杯形密封机构围绕轴和施加构件。杯形密封机构可滑动地容纳在壳体内，该壳体还容纳最初与杯状密封机构间隔开的低速流体。施加构件上的反应物质通过将密封机构和施加构件压入壳体内的流体而使流体润湿施加构件而被致动。

4. 发明授权

US06394803B1 Mixing arrangement 有权
标题翻译：混合布置
公开(公告)号：US06394803B1
公开(公告)日：2002-05-28
申请号：US09695000
申请日：2000-10-24
申请人： Ulrich Salz , Andre Rumphorst , Alexandros Gianasmidis , Frank Muller , Volker Rheinberger
发明人： Ulrich Salz , Andre Rumphorst , Alexandros Gianasmidis , Frank Muller , Volker Rheinberger
IPC分类号： A61C114
CPC分类号： A61C19/005 , A61C5/60
摘要： A mixing arrangement and method for mixing a substance for the field of dentistry are provided, with the production of the substance requiring at least one base material and one reactant. A catalyst is applied to a base surface as reactant in a solid or semi-solid layer. The unit comprising catalyst and base is prefabricated, and the base material, particularly in liquid form, can be applied or introduced to the base surface that is provided with the catalyst prior to using the substance. The substance can be applied ready for use by means of an application element after the catalyst and base material have been mixed.
摘要翻译：提供了用于混合牙科领域的物质的混合装置和方法，其中所述物质的生产需要至少一种基础材料和一种反应物。将催化剂作为固体或半固体层中的反应物施加到基底表面。包含催化剂和碱的单元是预制的，并且特别是液体形式的基材可以在使用该物质之前施加或引入到设置有催化剂的基础表面。在催化剂和基材混合后，该物质可以通过应用元素使用即可使用。

5. 发明授权

US5889132A Dental material 失效
标题翻译：牙科材料
公开(公告)号：US5889132A
公开(公告)日：1999-03-30
申请号：US850161
申请日：1997-05-02
申请人： Volker Rheinberger , Norbert Moszner , Ulrich Salz , Herbert Wolter , Werner Storch , Helma Baeuerlein
发明人： Volker Rheinberger , Norbert Moszner , Ulrich Salz , Herbert Wolter , Werner Storch , Helma Baeuerlein
IPC分类号： A61K6/093 , C08F230/08
CPC分类号： A61K6/093
摘要： A dental material is described which is characterized by a content of silicic acid condensates of norbornene or mercapto silanes, and which, after thiol-ene polymerisation with suitable reactants, shows only slight polymerisation shrinkage and produces polymerisates with high mechanical strength.
摘要翻译：描述了一种牙科材料，其特征在于降冰片烯或巯基硅烷的硅酸缩合物的含量，并且在与合适的反应物硫醇聚合之后，仅显示轻微的聚合收缩并产生具有高机械强度的聚合物。

6. 发明授权

US5780668A X-ray opaque dental materials 失效
标题翻译： X光透镜牙科材料
公开(公告)号：US5780668A
公开(公告)日：1998-07-14
申请号：US450812
申请日：1995-05-25
申请人： Volker Rheinberger , Norbert Moszner , Ulrich Salz
发明人： Volker Rheinberger , Norbert Moszner , Ulrich Salz
IPC分类号： A61K6/083 , C07C69/76 , C07C69/78 , C07C69/84 , C07C69/92 , C07C229/54 , C07C229/56 , C07C229/60 , C07C229/64 , C07C233/54 , C07C233/69 , C07C233/75 , C08F20/26 , C08F20/30 , C08F20/34 , C08F20/36 , C08F220/30 , C08F290/00 , C08F290/06 , C07C69/767 , A61C5/08 , C07C235/42 , C07C235/88
CPC分类号： A61K6/083 , C07C233/54 , C07C69/76 , C08F220/30
摘要： X-ray opaque esters or amides of iodosubstituted benzoic acid according to formula I and polymers and dental materials produced therefrom. ##STR1## R.sup.1 =hydrogen or C.sub.1 to C.sub.3 alkyl, preferably H or CH.sub.3 ; R.sup.2 =straight-chain or branched C.sub.1 to C.sub.6 alkylene, oxyalkylene or arylene, preferably C.sub.2 to C.sub.4 alkylene and particularly preferably --CH.sub.2 --CH.sub.2 -- and --CH.sub.2 CH(--)CH.sub.2 --; X=O or NH, preferably O; R.sup.3 -R.sup.7 =at least 3 iodine substituents, preferably in R.sup.3, R.sup.4 and R.sup.6 or R.sup.3, R.sup.5 and R.sup.7 position, the other groups are hydrogen, C.sub.1 to C.sub.6 alkyl, C.sub.1 to C.sub.6 alkoxy, --Cl, --Br, --OH, --NH.sub.2, --N(C.sub.1 to C.sub.6 alkyl).sub.2 or --NH--CO--(C.sub.1 to C.sub.6 alkyl), preferably R.sup.3, R.sup.4, and R.sup.6 are=I and R.sup.5 and R.sup.7 =H, or R.sup.3, R.sup.5 and R.sup.7 =I and R.sup.4 and R.sup.6 =--NH(COCH.sub.3); n=1, 2 or 3, preferably 1 or 2. The benzoic acid esters and amides according to the invention can be well polymerized radically or anionically, the polymers are well soluble in the usual dental monomers. Dental materials produced from the monomers or polymers are characterized in that the X-ray opaque component is bonded covalently into the polymeric matrix material and cannot therefore be washed out. Furthermore, excellent X-ray opacity can be achieved without using fillers.
摘要翻译：根据式I的碘取代苯甲酸的X-射线不透明酯或酰胺和由其制备的聚合物和牙科材料。式I R1 =氢或C1至C3烷基，优选H或CH3; R2 =直链或支链C1至C6亚烷基，氧化烯或亚芳基，优选C2至C4亚烷基，特别优选-CH2-CH2-和-CH2CH（ - ）CH2-; X = O或NH，优选O; R3-R7 =至少3个碘取代基，优选在R3，R4和R6或R3，R5和R7位置，其他基团是氢，C1至C6烷基，C1至C6烷氧基，-Cl，-Br，-OH， -NH 2，-N（C 1至C 6烷基）2或-NH-CO-（C 1至C 6烷基），优选R 3，R 4和R 6为= I且R 5和R 7 = H，或R 3，R 5和R 7 = 和R 4和R 6 = -NH（COCH 3）; n = 1,2或3，优选1或2.根据本发明的苯甲酸酯和酰胺可以完全聚合或阴离子聚合，这些聚合物在通常的牙科单体中很好地溶解。由单体或聚合物生产的牙科材料的特征在于，X射线不透明组分共价键合到聚合物基体材料中，因此不能被洗掉。此外，可以在不使用填料的情况下实现优异的X射线不透明度。

7. 发明授权

US09668946B2 Dental materials based on monomers having debonding-on-demand properties 有权
公开(公告)号：US09668946B2
公开(公告)日：2017-06-06
申请号：US14343297
申请日：2012-09-10
申请人： Norbert Moszner , Iris Lamparth , Thorsten Bock , Urs Karl Fischer , Ulrich Salz , Volker Rheinberger , Robert Liska
发明人： Norbert Moszner , Iris Lamparth , Thorsten Bock , Urs Karl Fischer , Ulrich Salz , Volker Rheinberger , Robert Liska
IPC分类号： A61K6/083 , A61K6/00 , C07D239/47 , C07F3/06 , C08F122/22
CPC分类号： A61K6/0835 , A61K6/0002 , A61K6/0023 , A61K6/083 , C07D239/47 , C07F3/06 , C08F122/22 , C08L33/00
摘要： The invention relates to a dental restorative material which comprises a thermolabile or photolabile polymerizable compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]l Formula I, in which T represents a thermolabile or photolabile group, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2═CR1—CO—O— and CH2═CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, wherein at least one Z1 or Z2 is a polymerizable group, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing or represent —O—, —S—, CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, R, R1, R2 and R3 in each case independently represent H or a C1-C7 alkyl radical and k, l, m and n in each case independently are 1, 2 or 3.

8. 发明申请

US20140329929A1 DENTAL MATERIALS BASED ON MONOMERS HAVING DEBONDING-ON-DEMAND PROPERTIES 有权
公开(公告)号：US20140329929A1
公开(公告)日：2014-11-06
申请号：US14343297
申请日：2012-09-10
申请人： Norbert Moszner , Iris Lamparth , Thorsten Bock , Urs Karl Fischer , Ulrich Salz , Volker Rheinberger , Robert Liska
发明人： Norbert Moszner , Iris Lamparth , Thorsten Bock , Urs Karl Fischer , Ulrich Salz , Volker Rheinberger , Robert Liska
IPC分类号： A61K6/083
CPC分类号： A61K6/0835 , A61K6/0002 , A61K6/0023 , A61K6/083 , C07D239/47 , C07F3/06 , C08F122/22 , C08L33/00
摘要： The invention relates to a dental restorative material which comprises a thermolabile or photolabile polymerizable compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]1 Formula I, in which T represents a thermolabile or photolabile group, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2═CR1—CO—O— and CH2═CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, wherein at least one Z1 or Z2 is a polymerizable group, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing or represent —O—, —S—, CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, R, R1, R2 and R3 in each case independently represent H or a C1-C7 alkyl radical and k, l, m and n in each case independently are 1, 2 or 3.

9. 发明授权

US06939489B2 Desktop process for producing dental products by means of 3-dimensional plotting 有权
标题翻译：通过三维绘图生产牙科产品的桌面工艺
公开(公告)号：US06939489B2
公开(公告)日：2005-09-06
申请号：US10107526
申请日：2002-03-25
申请人： Norbert Moszner , Armin Burgath , Rolf Mulhaupt , Ulrich Salz , Volker Rheinberger , Rudiger Landers
发明人： Norbert Moszner , Armin Burgath , Rolf Mulhaupt , Ulrich Salz , Volker Rheinberger , Rudiger Landers
IPC分类号： A61C13/00 , A61C19/00 , A61K6/083 , B29C67/00 , A61C13/20 , B29C35/08 , B29C41/02 , B29C41/22
CPC分类号： A61K6/083 , A61C13/0004 , A61C13/0019 , A61C19/003 , B29C64/165 , B29L2031/7536 , B33Y80/00 , C08L33/00 , C08L25/04
摘要： A process for fabricating dental form pieces for dental restoration and replacement parts is provided and includes the step of applying a material, on a firm support or a fluid medium, by a three dimensional plotting technology in a layer by layer manner. The material has micro cords and/or micro drops which include at least one of a meltable, polymerizable, polycondensable, and polyaddable constituent element that is an unfilled monomer, a reinforced monomer, oligomer, polymer, or a ceramic element. The process also includes the step of hardening the applied material by cooling of the material, chemical reaction, polymerization with thermal handling, or polymerization by irradiation of the material with UV or visible light.
摘要翻译：提供了一种用于制造用于牙科修复和更换部件的牙形片的方法，并且包括通过三维绘图技术逐层施加材料在坚固的支撑物或流体介质上的步骤。所述材料具有微丝和/或微滴，其包括作为未填充单体，增强单体，低聚物，聚合物或陶瓷元素的可熔化，可聚合，可缩聚和可共聚的构成元素中的至少一种。该方法还包括通过材料的冷却，化学反应，热处理聚合或用UV或可见光照射材料进行聚合来硬化所施加的材料的步骤。

10. 发明授权

US6031015A Dental materials based on liquid crystalline monomers 失效
标题翻译：基于液晶单体的牙科材料
公开(公告)号：US6031015A
公开(公告)日：2000-02-29
申请号：US682327
申请日：1996-07-17
申请人： Helmut Ritter , Georg Draheim , Norbert Moszner , Ulrich Salz , Volker Rheinberger
发明人： Helmut Ritter , Georg Draheim , Norbert Moszner , Ulrich Salz , Volker Rheinberger
IPC分类号： A61C13/23 , A61K6/083 , C07C69/54 , C07C69/92 , C07J9/00 , C08F2/50 , C08F20/26 , C08F20/30 , C08G63/181 , C08G63/19 , C09J4/00 , C09J4/02 , C09K19/20 , C09K19/36 , C08K9/06 , C08L67/07
CPC分类号： A61K6/083 , C07C69/92 , C09K19/2007 , C09K19/36 , C09K2019/0448 , Y10S522/908
摘要： A dental material based on polymerizable monomers is described which contains at least one polymerizable monomer which has liquid crystalline properties. Compared with traditional materials, the dental material displays a lower decrease in volume upon polymerization and, because of its low viscosity, higher filler contents can be achieved.
摘要翻译：描述了基于可聚合单体的牙科材料，其含有至少一种具有液晶性质的可聚合单体。与传统材料相比，牙科材料在聚合时体积减小，粘度低，可以实现更高的填料含量。

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