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21. 发明授权

US07320818B2 Multilayers of polyamides and fluorinated copolymers 有权
标题翻译：多层聚酰胺和氟化共聚物
公开(公告)号：US07320818B2
公开(公告)日：2008-01-22
申请号：US10086845
申请日：2002-03-04
申请人： Julio A. Abusleme , Claudia Manzoni
发明人： Julio A. Abusleme , Claudia Manzoni
IPC分类号： B32B27/02 , B32B27/08 , B32B27/18 , B32B27/30 , B32B27/34
CPC分类号： D01F8/06 , B32B27/28 , B32B27/34 , F16L11/04 , Y10T428/1393 , Y10T428/2929 , Y10T428/2938 , Y10T428/3154 , Y10T428/31725 , Y10T428/31855 , Y10T428/31931
摘要： Multilayer manufactured articles comprising at least one layer based on thermoprocessable copolymers of ethylene with chlorotrifluoroethylene and/or tetrafluroethylene and with acrylic monomers, and one layer based on polyamides.
摘要翻译：包含基于乙烯与氯三氟乙烯和/或四氟乙烯和丙烯酸单体的热可加工共聚物的至少一层的多层制品以及基于聚酰胺的一层。

22. 发明授权

US06878453B2 Multilayers of polyamides and CPVC 失效
标题翻译：聚酰胺和CPVC多层
公开(公告)号：US06878453B2
公开(公告)日：2005-04-12
申请号：US10157851
申请日：2002-05-31
申请人： Julio A. Abusleme , Claudia Manzoni , Giambattista Besana
发明人： Julio A. Abusleme , Claudia Manzoni , Giambattista Besana
IPC分类号： B32B27/30 , B32B27/34 , B32B27/00 , B32B27/08
CPC分类号： B32B27/08 , B32B27/30 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/322 , B32B27/34 , B32B2323/04 , B32B2327/18 , B32B2377/00 , Y10T428/31504 , Y10T428/3154 , Y10T428/31544 , Y10T428/31725 , Y10T428/31743 , Y10T428/3175
摘要： A multilayer comprising at least one layer A) of at least one thermoprocessable polymer containing at least 5% by weight of chlorinated polyvinyl chloride (CPVC) and one layer B) based on polyamides having an amount of —NH2 end groups in the range 20-300 μeq/g.
摘要翻译：包含至少一种含有至少5重量％氯化聚氯乙烯（CPVC）和一层B）的热可加工聚合物的至少一层A），其基于具有在20至20的范围内的-NH 2端基的量的聚酰胺， 300 mueq / g。

23. 发明授权

US06569946B2 Thermoplastic fluoropolymers 有权
标题翻译：热塑性氟聚合物
公开(公告)号：US06569946B2
公开(公告)日：2003-05-27
申请号：US09781210
申请日：2001-02-13
申请人： Julio A. Abusleme , Claudia Manzoni
发明人： Julio A. Abusleme , Claudia Manzoni
IPC分类号： C08F800
CPC分类号： C08F259/08 , C08F255/02 , C08L23/08 , C08L27/12 , C08F214/18 , C08L2666/04
摘要： Polymer composition comprising (A) (co)polymers based on chlorotrifluoroethylene (PCTFE) and (B) copolymers based on ethylene/chlorotrifluoroethylene (ECTFE) and/or ethylene/tetrafluoroethylene (ETFE).
摘要翻译：包含基于三氟氯乙烯（PCTFE）的（A）（共）聚合物和（B）基于乙烯/氯三氟乙烯（ECTFE）和/或乙烯/四氟乙烯（ETFE）的共聚物的聚合物组合物。

24. 发明授权

US06391975B1 Thermoplastic perhalogenated (CO)polymers of chlorotrifluoroethylene 有权
标题翻译：氯三氟乙烯的热塑性全卤化（CO）聚合物
公开(公告)号：US06391975B1
公开(公告)日：2002-05-21
申请号：US09612284
申请日：2000-07-07
申请人： Julio A. Abusleme , Claudia Manzoni
发明人： Julio A. Abusleme , Claudia Manzoni
IPC分类号： C08L2704
CPC分类号： C08F259/08 , C08F214/242 , C08F259/02 , C08L51/04 , C08L51/06
摘要： Chlorotrifluoroethylene (CTFE) thermoplastic perhalogenated polymers, formed by the following polymer components: (I) 10-90% by weight of a CTFE homopolymer and (II) 90-10% by weight of a CTFE copolymer modified with comonomer (a) selected from one or more perfluoroalkyl vinylethers having the formula: Rf—O—CF═CF2 wherein: Rf is a C2-C5 perfluoroalkyl group, resulting in the final polymer (I)+(II), the amount of (a) being from 0,2 to 5% by moles and the CTFE the remaining part to 100% by moles.
摘要翻译：由以下聚合物组分形成的三氟氯乙烯（CTFE）热塑性全卤代聚合物：（I）10-90重量％的CTFE均聚物和（II）90-10重量％的用共聚单体（a）改性的CTFE共聚物，一种或多种具有下式的全氟烷基乙烯基醚：其中：Rf是C2-C5全氟烷基，得到最终聚合物（I）+（II），（a）的量为0.2-5％（摩尔），和 CTFE其余部分为100％摩尔。

25. 发明授权

US06369130B2 Thermoplastic fluoropolymer compositions containing hydrogenated plasticizers 失效
标题翻译：含有氢化增塑剂的热塑性含氟聚合物组合物
公开(公告)号：US06369130B2
公开(公告)日：2002-04-09
申请号：US09164625
申请日：1998-10-01
申请人： Mikhail Zolotnitsky , Gary Stanitis , Julio A. Abusleme
发明人： Mikhail Zolotnitsky , Gary Stanitis , Julio A. Abusleme
IPC分类号： C08L2712
CPC分类号： C08K5/0016 , C08K3/01 , C08L27/12
摘要： Thermoplastic fluoropolymer compositions, flexible, without whitening, comprising: I) ETFE or ECTFE fluoropolymers modified with hydrogenated monomers; II) one or more hydrogenated plasticizers; III) one or more inorganic fire retardants; IV) optionally other ingredients such as fillers, smoke retarders, intumescent agents, pigments, lubricants, organic fire retardants and thermal stabilizers.
摘要翻译：热塑性含氟聚合物组合物，柔软的，不增白的，包括：I）用氢化单体改性的ETFE或ECTFE含氟聚合物; II）一种或多种氢化增塑剂; III）一种或多种无机阻燃剂; IV）任选的其他成分例如填料，防烟剂，膨胀剂，颜料，润滑剂，有机阻燃剂和热稳定剂。

26. 发明授权

US5688838A Process for preparing hydrogen-containing fluoropolymers by suspension (co)polymerization 失效
标题翻译：通过悬浮（共）聚合制备含氢含氟聚合物的方法
公开(公告)号：US5688838A
公开(公告)日：1997-11-18
申请号：US508926
申请日：1995-07-28
申请人： Julio A. Abusleme , Pier Antonio Guarda , Ralph De Pasquale
发明人： Julio A. Abusleme , Pier Antonio Guarda , Ralph De Pasquale
IPC分类号： C08F14/24 , C08F2/18 , C08F2/48 , C08F2/50 , C08F14/00 , C08F14/18 , C08F14/26 , C08F210/02 , C08F2/46
CPC分类号： C08F14/18 , C08F210/02
摘要： Process for preparing hydrogen-containing fluoropolymers, wherein the corresponding olefinic monomers are (co) polymerized in an organic suspending medium in the presence of a radical photoinitiator and of ultraviolet-visible radiation at a temperature of from -60.degree. C. to +30.degree. C. Hydrogen-containing fluoropolymers are thus obtained having high second melting temperature and high maximum operating temperature, using as initiators non-hazardous products, which can be easily handled and kept also at room temperature.
摘要翻译：制备含氢含氟聚合物的方法，其中相应的烯属单体在有机悬浮介质中在自由基光引发剂的存在下和在-60℃至+ 30℃的温度下进行紫外 - 可见辐射（共）聚合因此，使用具有高的第二熔解温度和高的最高工作温度的含氢的含氟聚合物作为引发剂非危险产品，其可以容易地在室温下处理和保存。

27. 发明授权

US5646223A Perfluorodioxoles, the preparation process thereof, and homopolymers and copolymers therefrom 失效
标题翻译：全氟二恶烷，其制备方法及其均聚物和共聚物
公开(公告)号：US5646223A
公开(公告)日：1997-07-08
申请号：US694509
申请日：1996-08-07
申请人： Walter Navarrini , Vito Tortelli , Pasqua Colaianna , Julio A. Abusleme
发明人： Walter Navarrini , Vito Tortelli , Pasqua Colaianna , Julio A. Abusleme
IPC分类号： C07D317/42 , C08F34/00 , C08F34/02 , C08F134/02 , C08F214/26 , C08F234/02 , C10M107/24 , C10N50/10 , C08F16/24
CPC分类号： C07D317/42 , C08F214/262 , C08F2438/01
摘要： The invention relates to new thermoprocessable copolymers of tetrafluoroethylene constituted by perfluoromethylvinylether (0.5-13% by weight), a fluorinated dioxole (0.05-3%) and tetrafluoroethylene (difference to 100%), particularly useful for coating electric cables by melt extrusion. It relates also to new perfluorodioxoles of formula ##STR1## wherein R.sub.F is a C.sub.1 -C.sub.5 perfluoroalkyl radical; X.sub.1 and X.sub.2 are, independently from each other, F or CF.sub.3 ; and their homopolymers and copolymers, in particular thermoprocessable copolymers as defined above.
摘要翻译：本发明涉及由全氟甲基乙烯基醚（0.5-13重量％），氟化二氧杂环戊烯（0.05-3％）和四氟乙烯（差异至100％）构成的四氟乙烯的新型热可加工共聚物，特别适用于通过熔融挤出涂覆电缆。它还涉及式为“IMAGE”的新的全氟二恶烷，其中RF是C1-C5全氟烷基; X 1和X 2彼此独立地为F或CF 3; 和它们的均聚物和共聚物，特别是如上定义的热可加工共聚物。

28. 发明授权

US5434229A Radical (co)polymerization process of fluorinated olefinic monomers 失效
标题翻译：氟化烯烃单体的自由基（共）聚合方法
公开(公告)号：US5434229A
公开(公告)日：1995-07-18
申请号：US200224
申请日：1994-02-23
申请人： Julio A. Abusleme , Guglielmo Gregorio
发明人： Julio A. Abusleme , Guglielmo Gregorio
IPC分类号： C08F2/38 , C08F2/22 , C08F14/18 , C08F214/18 , C08F2/18
CPC分类号： C08F14/18
摘要： Branched aliphatic hydrocarbons, having from 6 to 25 carbon atoms and a ratio between the number of methyl groups and the number of carbon atoms higher than 0.5, are used in radical (co)polymerization processes of fluorinated olefinic monomers, optionally in association with non-fluorinated olefins, both in suspension and in aqueous emulsion. Such hydrocarbons are characterized, in the usual reaction conditions, by a chain transfer effect practically absent.
摘要翻译：具有6至25个碳原子的分支脂族烃和甲基数和高于0.5的碳原子数之间的比例用于氟化烯烃单体的自由基（共）聚合方法中，任选地与非 - 氟化烯烃，均为悬浮液和水性乳液。这些烃在通常的反应条件下通过实际上不存在的链转移效应来表征。

29. 发明授权

US09701766B2 Hydrophilic vinylidene fluoride polymers 有权
公开(公告)号：US09701766B2
公开(公告)日：2017-07-11
申请号：US13995454
申请日：2011-12-13
申请人： Julio A. Abusleme , Roberto Biancardi , Fabien Roblot , Anna Maria Bertasa , Giulio Brinati
发明人： Julio A. Abusleme , Roberto Biancardi , Fabien Roblot , Anna Maria Bertasa , Giulio Brinati
IPC分类号： C08F14/22 , B01D71/32 , B01D71/78 , C08F214/22 , C08F251/02 , C08F290/02 , C08F290/10 , C08F8/00
CPC分类号： C08F14/22 , B01D71/32 , B01D71/78 , B01D2323/38 , C08F8/00 , C08F214/225 , C08F251/02 , C08F290/02 , C08F290/10 , C08F214/22
摘要： The present invention pertains to a process for the manufacture of a grafted fluorinated polymer comprising at least one grafted side chain comprising one or more glycosidic recurring units [polymer (F)], said process comprising polymerizing: vinylidene fluoride (VDF), optionally, one or more other fluorinated monomers [monomers (F)], and optionally, one or more (meth)acrylic monomers [monomers (MA)], in the presence of at least one polysaccharide derivative [derivative (P)], said polysaccharide derivative having a dynamic viscosity of less than 15 mPa×s, as measured according to ASTM D445 at 20° C. in an aqueous solution at a concentration of 2% by weight, and by further providing novel polymers (F) as defined above.

30. 发明申请

US20140127434A1 FLUOROPOLYMER COMPOSITION FOR MULTILAYER ASSEMBLIES 审中-公开
标题翻译：多层组合物的氟聚合物组合物
公开(公告)号：US20140127434A1
公开(公告)日：2014-05-08
申请号：US14131747
申请日：2012-07-10
申请人： Stefano Mortara , Julio A. Abusleme
发明人： Stefano Mortara , Julio A. Abusleme
IPC分类号： C08K3/22 , B29C47/06 , C08K3/30
CPC分类号： C08K3/22 , B29C48/21 , C08K3/30 , Y10T29/49826 , Y10T428/1352 , Y10T428/1393 , Y10T428/31515 , Y10T428/3154
摘要： The invention pertains to a composition (C1) comprising: at least one (meth)acrylic modified VDF polymer [polymer (A)] comprising recurring units derived from comprising recurring units derived from vinylidene fluoride (VDF) monomer and at least one hydrophilic (meth)acrylic monomer (MA) of formula (I), wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group; at least one inorganic UV blocker compound in an amount not exceeding 5% wt, with respect to the weight of polymer (A), to multilayer assemblies comprising one layer made from said composition (C1), to a method for manufacturing said multilayer assemblies and to the use of the same in different field of use, including protection of PV modules.
摘要翻译：本发明涉及一种组合物（C1），其包含：至少一种（甲基）丙烯酸改性的VDF聚合物[聚合物（A）]，其包含衍生自衍生自偏二氟乙烯（VDF）单体的重复单元和至少一种亲水（甲基））式（I）的丙烯酸单体（MA），其中R1，R2，R3彼此相同或不同的各自独立地为氢原子或C1-C3烃基，ROH为氢或C1- C5烃部分包含至少一个羟基; 相对于聚合物（A）的重量，不超过5重量％的至少一种无机UV阻断剂化合物，包含由所述组合物（C1）制成的一层的多层组件，涉及制备所述多层组件的方法和使用不同的使用领域，包括保护光伏组件。

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