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21. 发明申请

US20090264689A1 Tetrafluoropropene Production Processes 有权
标题翻译：四氟丙烯生产工艺
公开(公告)号：US20090264689A1
公开(公告)日：2009-10-22
申请号：US12301077
申请日：2007-06-22
申请人： Velliyur Nott Mallikarjuna Rao , Mario Joseph Nappa , Allen Capron Sievert
发明人： Velliyur Nott Mallikarjuna Rao , Mario Joseph Nappa , Allen Capron Sievert
IPC分类号： C07C17/23
CPC分类号： C07C21/18 , C07C17/25
摘要： A process is disclosed for producing 2,3,3,3-tetrafluoropropene and 1,3,3,3-tetrafluoropropene. The process involves pyrolyzing 1,1,1,2,3-pentafluoropropane.
摘要翻译：公开了一种制备2,3,3,3-四氟丙烯和1,3,3,3-四氟丙烯的方法。该方法包括热解1,1,1,2,3-五氟丙烷。

22. 发明申请

US20090127496A1 Tetrafluoropropene Production Processes 有权
标题翻译：四氟丙烯生产工艺
公开(公告)号：US20090127496A1
公开(公告)日：2009-05-21
申请号：US12301070
申请日：2007-06-22
申请人： Velliyur Nott Mallikarjuna Rao , Mario Joseph Nappa , Allen Capron Sievert
发明人： Velliyur Nott Mallikarjuna Rao , Mario Joseph Nappa , Allen Capron Sievert
IPC分类号： C09K5/00 , C07C17/25
CPC分类号： B01J37/26 , B01J21/04 , B01J27/125 , C07C17/25 , C07C17/386 , C07C21/18 , C07C19/08
摘要： A process is disclosed for the manufacture of CF3CF═CH2 and CF3CH═CHF. The process involves dehydrofluorinating CF3CHFCH2F in the presence of a dehydrofluorination catalyst to produce a product mixture comprising CF3CF═CH2 and CF3CH═CHF, and recovering said CF3CF═CH2 and CF3CH═CHF from the product mixture.The present invention also provides a composition comprising (a) the Z-isomer of CF3CH═CHF and (b) HF; wherein the HF is present in an effective amount to form an azeotropic combination with the Z—CF3CH═CHF.
摘要翻译：公开了用于制造CF 3 CF-CH 2和CF 3 CH-CHF的方法。该方法包括在脱氟化氢催化剂的存在下对CF 3 CHFCH 2 F进行脱氟化氢，以产生包含CF 3 CF-CH 2和CF 3 CH-CHF的产物混合物，并从产物混合物回收所述CF 3 CF-CH 2和CF 3 CH-CHF。本发明还提供一种组合物，其包含（a）CF 3 CH-CHF的Z-异构体和（b）HF; 其中HF以有效量存在以与Z-CF 3 CH-CHF形成共沸组合。

23. 发明授权

US07435700B2 Chromium oxide compositions containing zinc, their preparation and their use as catalysts and catalyst precursors 有权
标题翻译：含有锌的氧化铬组合物，它们的制备及其作为催化剂和催化剂前体的用途
公开(公告)号：US07435700B2
公开(公告)日：2008-10-14
申请号：US10572628
申请日：2004-10-13
申请人： Tammy Georgette Amos , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert , Shekhar Subramoney
发明人： Tammy Georgette Amos , Velliyur Nott Mallikarjuna Rao , Allen Capron Sievert , Shekhar Subramoney
IPC分类号： B01J21/00 , C07C17/00
CPC分类号： B01J23/86 , B01J23/002 , B01J23/26 , B01J35/0006 , B01J35/002 , B01J37/03 , B01J2523/00 , C07C17/25 , C07C17/37 , C07C21/18 , B01J2523/27 , B01J2523/67
摘要： A chromium-containing catalyst is disclosed which includes both ZnCr2O4 and crystalline α-chromium oxide. The ZnCr2O4 contains between about 10 atom percent and 67 atom percent of the chromium in the composition and at least about 70 atom percent of the zinc in the composition, and at least about 90 atom percent of the chromium present as chromium oxide in the composition is present as ZnCr2O4 or crystalline α-chromium oxide. Also disclosed are a method for preparing this composition comprising ZnCr2O4 and crystalline α-chromium oxide; and a chromium-containing catalyst composition prepared by treatment of the composition comprising ZnCr2O4 and crystalline α-chromium oxide with a fluorinating agent. Also disclosed is a process for changing the fluorine distribution in a halogenated hydrocarbon, or incorporating fluorine in a saturated or unsaturated hydrocarbon, in the presence of at least one composition selected from the group consisting of (i) the ZnCr2O4 and crystalline α-chromium oxide compositions and (ii) the ZnCr2O4 and crystalline α-chromium oxide compositions which have been treated with a fluorinating agent.
摘要翻译：公开了一种含铬催化剂，其包括ZnCr 2 O 4 O 4和结晶α-氧化铬。 ZnCr 2 O 4 4含有组合物中铬的约10原子％至67原子％，组合物中的锌的至少约70原子％，以及作为组合物中作为氧化铬存在的至少约90原子％的铬以ZnCr 2 O 4 O 4或结晶α-氧化铬存在。还公开了一种制备该组合物的方法，该组合物包含ZnCr 2 O 4 O 4和结晶α-氧化铬; 以及通过用氟化剂处理包含ZnCr 2 O 4 O 4和结晶α-氧化铬的组合物制备的含铬催化剂组合物。还公开了一种改变卤代烃中的氟分布或在饱和或不饱和烃中引入氟的方法，所述方法是在至少一种选自（i）ZnCr 2 SO 2 O 3和结晶α-氧化铬组合物和（ii）ZnCr 2 O 4 O 4和结晶α-氧化铬组合物，它们具有用氟化剂处理。

24. 发明授权

US07384572B2 Azeotrope-like compositions containing fluoroethane 失效
标题翻译：含有氟乙烷的类共沸组合物
公开(公告)号：US07384572B2
公开(公告)日：2008-06-10
申请号：US11585536
申请日：2006-10-24
申请人： Barbara Haviland Minor , Vinci Martinez Felix , Allen Capron Sievert
发明人： Barbara Haviland Minor , Vinci Martinez Felix , Allen Capron Sievert
IPC分类号： C09K5/04
CPC分类号： C07C19/08 , C08J9/146 , C08J9/149 , C08J2203/14 , C08J2203/142 , C08J2207/04 , C09K3/30 , C09K5/045 , C09K2205/11 , C09K2205/12 , C09K2205/22 , C09K2205/32
摘要： The present invention relates to the discovery of compositions which include fluoroethane, 2-fluoropropane or tert-butylfluoride. These compositions are useful as pure components or with at least one of tetrafluoroethane, difluoroethane, hexafluoropropane, a hydrocarbon or dimethylether.These compositions are useful as aerosol propellants, refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.
摘要翻译：本发明涉及发现包括氟乙烷，2-氟丙烷或叔丁基氟化物的组合物。这些组合物可用作纯组分或与四氟乙烷，二氟乙烷，六氟丙烷，烃或二甲醚中的至少一种有用。这些组合物可用作气溶胶推进剂，制冷剂，清洁剂，聚烯烃和聚氨酯的膨胀剂，制冷剂，传热介质，气体电介质，灭火剂，动力循环工作流体，聚合介质，颗粒去除流体，载体流体，抛光磨料代理和置换干燥剂。

25. 发明授权

US06376727B1 Processes for the manufacture of 1,1,1,3,3-pentafluoropropene, 2-chloro-pentafluoropropene and compositions comprising saturated derivatives thereof 失效
标题翻译：用于制造1,1,1,3,3-五氟丙烯，2-氯 - 五氟丙烯的方法和包含其饱和衍生物的组合物
公开(公告)号：US06376727B1
公开(公告)日：2002-04-23
申请号：US09367900
申请日：1999-08-19
申请人： V. N. Mallikarjuna Rao , Allen Capron Sievert
发明人： V. N. Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： C07C1700
CPC分类号： C07C19/08 , B01J23/868 , B01J27/12 , B01J27/132 , B01J37/0009 , B01J37/06 , C07C17/00 , C07C17/087 , C07C17/21 , C07C17/23 , C07C17/354 , C07C17/38 , C07C43/12 , Y02P20/582 , C07C21/18
摘要： Disclosed are azeotropic compositions comprising CF3CHFCF3 and HF. Also disclosed are compositions and a process for producing compositions comprising (c1) CF3CHFCF3, CF3CH2CF3, or CHF2CH2CF3, and (c2) at least one saturated halogenated hydrocarbon and or ether having the formula: CnH2n+2−a−bClaFbOc wherein n is an integer from 1-4, a is an integer from 0-2n+1, b is an integer from 1-2n+2a, and c is 0 or 1, provided that when c is 1 then n is an integer from 2-4, and provided that component (c2) does not include the selected component (c1) compound, wherein the molar ratio of component (c2) to component (c1) is between about 1:99 and a molar ratio of HF to component (c1) in an azeotrope or azeotrope-like composition of component (c1) with HF. The process involves (A) combining (1) the azeotropic composition with (ii) the fluorination precursor to component (c2); and (B) reacting a sufficient amount of the HF from the azeotrope or azeotrope-like composition (1) with the precursor component (ii) to provide a composition containing components (c1) and (c2) in the desired ratio. The compositions include at least two (c1) compounds, at least one of which is an ether.
摘要翻译：公开了包含CF 3 CHFCF 3和HF的共沸组合物。还公开了组合物和制备包含（c1）CF 3 CHFCF 3，CF 3 CH 2 CF 3或CHF 2 CH 2 CF 3的组合物和（c2）至少一种具有下式的饱和卤代烃和或醚的组合物和方法：C n H 2n + 2-a-b Cl a F b O c其中n是整数从1-4开始，a是0-2n + 1的整数，b是1-2n + 2a的整数，c是0或1，条件是当c为1时，n为2-4的整数，（c2）与成分（c1）的摩尔比为约1:99，HF与成分（c1）的摩尔比在下述式（c2）中，式（c2）组分（c1）与HF的共沸物或类共沸组合物。该方法包括（A）将（1）共沸组合物与（ii）氟化前体与组分（c2）组合; 和（B）使足够量的来自共沸物或类共沸组合物（1）的HF与前体组分（ii）反应，以提供含有所需比例的组分（c1）和（c2）的组合物。组合物包括至少两种（c1）化合物，其中至少一种是醚。

26. 发明授权

US06242658B1 Process for the manufacture of fluorine-substituted hydrocarbons 失效
标题翻译：氟取代烃的制造方法
公开(公告)号：US06242658B1
公开(公告)日：2001-06-05
申请号：US09155262
申请日：1999-08-06
申请人： Ralph Thomas Baker , Richard Paul Beatty , Allen Capron Sievert , Robert Lewis Wallace, Jr.
发明人： Ralph Thomas Baker , Richard Paul Beatty , Allen Capron Sievert , Robert Lewis Wallace, Jr.
IPC分类号： C07C1908
CPC分类号： C07F15/04 , C07B31/00 , C07B37/02 , C07C17/00 , C07C19/08
摘要： Processes involving certain nickel metallacycles with phosphite ligands are disclosed as useful for the manufacture of selected substituted hydrocarbons. Also disclosed are selected compounds including both nickel and phosphite ligands.
摘要翻译：涉及涉及某些具有亚磷酸酯配体的镍金属螯合物的方法被公开用于制备所选取代的烃。还公开了选择的化合物，包括镍和亚磷酸酯配体。

27. 发明授权

US06224781B1 Compositions comprising hydrofluorocarbons and their manufacture 有权
标题翻译：包含氢氟碳化合物及其制备的组合物
公开(公告)号：US06224781B1
公开(公告)日：2001-05-01
申请号：US09137343
申请日：1998-08-20
申请人： Barry A. Mahler , V. N. Mallikarjuna Rao , Allen Capron Sievert , Munirpallam A. Subramanian , Edwin James Warwas
发明人： Barry A. Mahler , V. N. Mallikarjuna Rao , Allen Capron Sievert , Munirpallam A. Subramanian , Edwin James Warwas
IPC分类号： A62D100
CPC分类号： A62D1/0057 , A62D1/00
摘要： A process is disclosed for producing compositions including (a) a compound selected from the group consisting of CHF2CF3, CHF2CHF2, CH2FCF3, CH3CF3, CH3CHF2, CH2FCF2CHF2 and CHF2CF2CF2CHF2 and (b) at least one saturated halogenated hydrocarbon and/or ether having the formula: CnH2n+2−a−bClaFbOc wherein n is an integer from 1 to 4, a is an integer from 0 to 2n+1, b is an integer from 1 to 2n+2−a, and c is 0 or 1, provided that when c is 1 then n is an integer from 2 to 4, and provided that component (b) does not include the selected component (a) compound, wherein the molar ratio of component (b) to component (a) is between about 1:99 and a molar ratio of HF to component (a) in an azeotrope or azeotrope-like composition of component (a) with HF. This process involves (A) combining (i) the azeotrope or azeotrope-like composition with (ii) at least one fluorination precursor compound wherein the precursor component (ii) is the fluorination precursor to component (b); and (B) reacting a sufficient amount of the HF from the azeotrope or azeotrope-like composition (i) with precursor component (ii) to provide a composition containing components (a) and (b) in said ratio.
摘要翻译：公开了用于制备组合物的方法，其包括（a）选自CHF 2 CF 3，CHF 2 CHF 2，CH 2 FFC 3，CH 3 CF 3，CH 3 CHF 2，CH 2 F 2 CHF 2和CHF 2 CF 2 CF 2 CHF 2的化合物和（b）至少一种具有下式的饱和卤代烃和/或醚：其中n为1〜4的整数，a为0〜2n + 1的整数，b为1〜2n + 2-a的整数，c为0或1，条件是当c为1时，n为组分（b）与组分（a）的摩尔比为约1:99，摩尔比为2〜4的整数，并且组分（b）不包括所选择的组分（a）化合物，其中组分 HF与组分（a）在组分（a）的共沸物或类共沸组合物中与HF混合。该方法包括：（i）将共沸物或类共沸组合物与（ii）至少一种氟化前体化合物组合（其中前体组分（ii）为组分（b）的氟化前体）; 和（B）使来自共沸物或类共沸组合物（i）的足够量的HF与前体组分（ii）反应，以提供含有所述比例的组分（a）和（b）的组合物。

28. 发明授权

US06207869B1 Process for perhalofluorinated butanes and hexanes 失效
标题翻译：全氟化丁烷和己烷的方法
公开(公告)号：US06207869B1
公开(公告)日：2001-03-27
申请号：US09519791
申请日：2000-03-07
申请人： Mario Joseph Nappa , Allen Capron Sievert
发明人： Mario Joseph Nappa , Allen Capron Sievert
IPC分类号： C07C1908
CPC分类号： C07C19/14 , B01J27/125 , C07C17/23 , C07C17/278 , C07C19/08 , C07C19/10
摘要： The instant invention relates to producing perhalofluorobutanes and perhalofluorohexanes, more particularly it relates to their production by utilizing tetrafluoroethylene (hereinafter referred to as “TFE”) and chlorotrifluoro-ethylene (hereinafter referred to as “CTFE”) with selected perhalofluoroethanes containing 2 to 4 nonfluorine halogen and 2 to 4 fluorine substituents in the presence of a polyvalent metal halide such as an aluminum chloride or chlorofluoride as catalyst.
摘要翻译：本发明涉及生产全氟全氟代丁烷和全卤代己烷，更具体地说，涉及其使用四氟乙烯（以下称为“TFE”）和氯三氟乙烯（以下称为“CTFE”）的制备方法，该选择性全卤代乙烷含有2-4个非氟卤素和2至4个氟取代基在多价金属卤化物如氯化铝或氯氟化物作为催化剂存在下进行。

29. 发明授权

US06143938A Process for perhalocycloalkane purification 失效
标题翻译：全卤烷烃纯化方法
公开(公告)号：US06143938A
公开(公告)日：2000-11-07
申请号：US429271
申请日：1999-10-29
申请人： Allen Capron Sievert , V. N. Mallikarjuna Rao
发明人： Allen Capron Sievert , V. N. Mallikarjuna Rao
IPC分类号： C07C17/04 , C07C17/20 , C07C17/395 , C07C19/08 , C07C17/38
CPC分类号： C07C19/08 , C07C17/04 , C07C17/206 , C07C17/395
摘要： A process is disclosed for recovering at least one perhalocycloalkane selected from the group consisting of octafluorocyclobutane, hexafluoro-bis(trifluoromethyl)cyclobutane (1,2 and 1,3; cis and trans), 1,2-dichloro-1,2,3,3,4,4-hexafluorocyclobutane (cis and trans), 1,1,2,2-tetrachloro-3,3,4,4-tetrafluorocyclobutane, 1-chloro-1,2,2,3,3,4-hexafluoro-4-(trifluoromethyl)-cyclobutane, heptafluoro(trifluoromethyl)cyclobutane and chloroheptafluoro-cyclobutane from a mixture comprising (a) the perhalocycloalkane, (b) olefinic impurity and optionally (c) saturated fluorine-containing impurity selected from the group consisting of hydrochlorofluorocarbons, hydrofluorocarbons and mixtures thereof. The process involves (1) contacting the mixture with chlorine under conditions suitable for chlorinating the olefinic impurity, thereby converting the olefinic impurity to a saturated impurity containing at least one chlorine substituent and reducing the hydrogen content of the saturated fluorine-containing impurity (if present), and (2) separating said at least one perhalocycloalkane from the products produced during the chlorination of (1).Also disclosed is a process for producing n-decafluorobutane. The process involves contacting a mixture comprising octafluorocyclobutane (i.e., C-318) and 1,1,1,2,3,4,4,4-octafluorobutene-2 (FC-1318my) with chlorine under conditions suitable for converting the FC-1318my to 2,3-dichloro-1,1,1,2,3,4,4,4-octa-fluorobutane (i.e., CFC-318mbb); separating the C-318 from the CFC-318mbb; and reacting the CFC-318mbb with HF.
摘要翻译：公开了一种用于回收至少一种选自八氟环丁烷，六氟 - 双（三氟甲基）环丁烷（1,2和1,3;顺式和反式）的全卤烷烃的方法，1,2-二氯-1,2,3 ，3,4,4-六氟环丁烷（顺式和反式），1,1,2,2-四氯-3,3,4,4-四氟环丁烷，1-氯-1,2,2,3,3,4-四氟环丁烷六氟代-4-（三氟甲基） - 环丁烷，七氟（三氟甲基）环丁烷和氯三氟环丁烷，其包含（a）全卤代环烷烃，（b）烯属杂质和任选的（c）饱和含氟杂质，氢氯氟烃，氢氟碳化合物及其混合物。该方法包括（1）在适于氯化烯烃杂质的条件下使混合物与氯接触，从而将烯烃杂质转化为含有至少一个氯取代基的饱和杂质并降低饱和含氟杂质的氢含量（如果存在）和（2）从（1）的氯化期间产生的产物中分离出所述至少一种全卤烷烃。还公开了制备正九氟丁烷的方法。该方法包括使包含八氟环丁烷（即C-318）和1,1,1,2,3,4,4,4-八氟丁烯-2（FC-1318my）的混合物与氯在适于转化FC- 1318my至2,3-二氯-1,1,1,2,3,4,4,4-八氟丁烷（即CFC-318mbb）; 将C-318与CFC-318mbb分离; 并使CFC-318mbb与HF反应。

30. 发明授权

US6107267A Compositions comprising CF.sub.3 CF.sub.2 CHF.sub.2 and their manufacture 失效
标题翻译：包含CF 3 CF 2 CHF 2的组合物及其制备
公开(公告)号：US6107267A
公开(公告)日：2000-08-22
申请号：US137342
申请日：1998-08-20
申请人： V. N. Mallikarjuna Rao , Allen Capron Sievert , Munirpallam A. Subramanian
发明人： V. N. Mallikarjuna Rao , Allen Capron Sievert , Munirpallam A. Subramanian
IPC分类号： B01D3/36 , C11D7/30 , C11D7/50
CPC分类号： C11D7/5036 , B01D3/36 , C11D7/30
摘要： A process is disclosed for recovering HF from a product mixture including HF and CF.sub.3 CF.sub.2 CHF.sub.2. The process involves (1) distilling the product mixture to remove all products which have a lower boiling point than the lowest boiling azeotrope containing HF and CF.sub.3 CF.sub.2 CHF.sub.2 ; and (2) distilling the azeotrope to recover HF as an azeotropic composition containing HF and CF.sub.3 CF.sub.2 CHF.sub.2. Also disclosed are compositions of hydrogen fluoride in combination with an effective amount of CF.sub.3 CF.sub.2 CHF.sub.2 to form an azeotrope or azeotrope-like composition with hydrogen fluoride, (e.g., compositions containing from about 57.1 to 67.2 mole percent CF.sub.3 CF.sub.2 CHF.sub.2).A process for producing certain compositions comprising(a) CF.sub.3 CF.sub.2 CHF.sub.2 and (b) at least one saturated halogenated hydrocarbon and/or ether having the formula:C.sub.n H.sub.2n+2-a-b Cl.sub.a F.sub.b O.sub.cwherein n is an integer from 1 to 4, a is an integer from 0 to 2n+1, b is an integer from 1 to 2n+2-a, and c is 0 or 1, provided that when c is 1 then n is an integer from 2 to 4 (and provided that component (b) does not include CF.sub.3 CF.sub.2 CF.sub.2) is also disclosed. This process involves (A) combining (i) an azeotropic composition of CF.sub.3 CF.sub.2 CHF.sub.2 and HF with (ii) at least one fluorination precursor compound wherein the precursor component (ii) is the fluorination precursor to component (b); and (B) reacting a sufficient amount of the HF from the azeotropic composition (i) with precursor component (ii), to provide a composition containing components (a) and (b) in the desired ratio. In addition, certain compositions are disclosed which include (a) CF.sub.3 CF.sub.2 CHF.sub.2 and (b) at least two saturated halogenated hydrocarbons and/or ethers having the formula:C.sub.n H.sub.2n+2-a-b Cl.sub.a F.sub.b O.sub.cwherein the molar ratio of said at least one compound to HFC-227ca is between about 1:99 and about 43:57 and c is 1 for at least one of the component (b) compounds.
摘要翻译：公开了从包含HF和CF 3 CF 2 CHF 2的产物混合物中回收HF的方法。该方法包括（1）蒸馏产物混合物以除去所有具有比含有HF和CF 3 CF 2 CHF 2的最低沸点共沸物沸点低的产物; 和（2）蒸馏共沸物以回收HF作为含有HF和CF 3 CF 2 CHF 2的共沸组合物。还公开了氟化氢与有效量的CF 3 CF 2 CHF 2组合以与氟化氢形成共沸物或类共沸组合物的组合物（例如，含有约57.1至67.2摩尔％CF 3 CF 2 CHF 2的组合物）。一种制备某些组合物的方法，其包含（a）CF 3 CF 2 CHF 2和（b）至少一种具有下式的饱和卤代烃和/或醚：n为1至4的整数，a为从 0〜2n + 1，b为1〜2n + 2-a的整数，c为0或1，条件是当c为1时，n为2〜4的整数（（b）成分也不包括CF 3 CF 2 CF 2）。该方法包括：（i）将CF 3 CF 2 CHF 2和HF的共沸组合物与（ii）至少一种氟化前体化合物组合（其中前体组分（ii）是组分（b）的氟化前体）; 和（B）使足够量的来自共沸组合物（i）的HF与前体组分（ii）反应，从而以所需的比例提供含有组分（a）和（b）的组合物。此外，公开了某些组合物，其包括（a）CF 3 CF 2 CHF 2和（b）至少两种具有下式的饱和卤代烃和/或醚：CnH2n + 2-a-bClaFbOc，其中所述至少一种化合物与HFC- 对于至少一种组分（b）化合物，227ca为约1:99至约43:57，c为1。

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