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21. 发明授权

US5961945A Method of producing cyano compounds by ammoxidation 失效
标题翻译：通过氨氧化制备氰基化合物的方法
公开(公告)号：US5961945A
公开(公告)日：1999-10-05
申请号：US970765
申请日：1997-11-14
申请人： Lukas M. J. Von Hippel , Jorg Sauer , Rudiger Schutte , Manfred Sauer , Dietrich Arntz
发明人： Lukas M. J. Von Hippel , Jorg Sauer , Rudiger Schutte , Manfred Sauer , Dietrich Arntz
IPC分类号： C07D213/84 , B01J29/26 , C01C3/02 , C07B43/08 , C07B61/00 , C07C253/24 , C07C255/01 , C07D213/54
CPC分类号： C07D213/54 , C01C3/0212 , C07B43/08
摘要： An ammoxidizable compound is reacted with an ammonium salt, especially an inorganic ammonium salt, in the presence of a source of oxygen and an ammoxidation catalyst at 100 to 700.degree. C., preferably 200 to 700.degree. C., in order to produce cyano compounds of the formula R--CN, in which R is H or an organic group.
摘要翻译：在氧气和氨氧化催化剂的存在下，在100-700℃，优选200-700℃下，使氨基可化合物与铵盐，特别是无机铵盐反应，以产生氰基化合物式R-CN，其中R是H或有机基团。

22. 发明授权

US5741904A Method of producing .epsilon.-caprolactam, MFI zeolite catalysts on whose surface symmetrically arranged OH groups are present and to a method of producing them 失效
标题翻译：生产ε-己内酰胺的方法，其表面对称排列的OH基团的MFI沸石催化剂及其生产方法
公开(公告)号：US5741904A
公开(公告)日：1998-04-21
申请号：US647438
申请日：1996-05-06
申请人： Wolfgang Hoelderich , Joerg Roeseller , Dietrich Arntz
发明人： Wolfgang Hoelderich , Joerg Roeseller , Dietrich Arntz
IPC分类号： B01J29/40 , B01J29/86 , C07B61/00 , C07D201/04
CPC分类号： C07D201/04 , Y02P20/52
摘要： A method of producing .epsilon.-caprolactam from cyclohexanone in the gaseous phase using MFI catalysts on whose surface symmetrically arranged OH groups are present.
摘要翻译：使用在其表面对称排列的OH基团上的MFI催化剂在气相中从环己酮生产ε-己内酰胺的方法。

23. 发明授权

US5705706A Process for the production of 2-(alkoxymethyl)acrolein 失效
标题翻译：制备2-（烷氧基甲基）丙烯醛的方法
公开(公告)号：US5705706A
公开(公告)日：1998-01-06
申请号：US681509
申请日：1996-07-23
申请人： Mathias Hoepp , Klaus Koehler , Dietrich Arntz
发明人： Mathias Hoepp , Klaus Koehler , Dietrich Arntz
IPC分类号： B01J31/02 , C07B61/00 , C07C45/75 , C07C47/277 , C07C45/61
CPC分类号： C07C45/75
摘要： 2-(Alkoxymethyl)acrolein of the formula ##STR1## is produced from acrolein, an alcohol ROH and formaldehyde, in one step, with a good yield being obtained. The acrolein is reacted with a substantially equimolar quantity of a source of formaldehyde in the presence of at least an equimolar quantity of the alcohol ROH and a catalytic quantity of a catalyst system based on a secondary amine and a mineral acid at a pH value of the reaction mixture in the range of 1 to less than 7.
摘要翻译：式（IMAGE）的2-（烷氧基甲基）丙烯醛由丙烯醛，醇ROH和甲醛一步制备，得到良好的收率。在至少等摩尔量的ROH和催化量的基于仲胺和无机酸的催化剂体系的存在下，丙烯醛与基本上等摩尔量的甲醛源反应，pH值为反应混合物的范围为1至小于7。

24. 发明授权

US5177220A Method for the asymmetric hydrogenation of .alpha.-ketocarbonyl compounds to optically active .alpha.-hydroxycarbonyl compounds 失效
标题翻译：（ALPHA） - 氯代羰基化合物对光学活性（ALPHA） - 羟基碳化物化合物的不对称加氢方法
公开(公告)号：US5177220A
公开(公告)日：1993-01-05
申请号：US639087
申请日：1991-01-09
申请人： Adolf Schafer , Dietrich Arntz
发明人： Adolf Schafer , Dietrich Arntz
IPC分类号： B01J31/02 , B01J31/18 , C07B61/00 , C07C51/367 , C07C59/01 , C07C67/31 , C07C67/317 , C07C69/675 , C07C231/12 , C07C235/06 , C07D307/33
CPC分类号： C07D307/33 , C07C67/31
摘要： Asymmetric hydrogenation of .alpha.-ketocarbonyl compounds, especially .alpha.-ketolactones, to the corresponding, optically active .alpha.-hydroxycarbonyl compounds in the presence of iridium diphosphine complexes as catalyst and dicarboxylic acid imides as co-catalyst.
摘要翻译：在作为催化剂的铱二膦配合物和二羧酸酰亚胺作为助催化剂的存在下，α-酮羰基化合物，特别是α-酮内酯不对称氢化成相应的光学活性的α-羟基羰基化合物。

25. 发明授权

US5171898A Method for the production of 1,3-propandiol 失效
标题翻译： 1,3-丙二醇的生产方法
公开(公告)号：US5171898A
公开(公告)日：1992-12-15
申请号：US798225
申请日：1991-11-27
申请人： Dietrich Arntz , Norbert Wiegand
发明人： Dietrich Arntz , Norbert Wiegand
IPC分类号： B01J31/08 , C07B61/00 , C07C29/04 , C07C29/14 , C07C29/141 , C07C31/20 , C07C45/64
CPC分类号： C07C29/141 , C07C45/64
摘要： The hydration of acrolein in the presence of a chelate-forming ion exchange resin based on polystyrene/divinyl benzene as catalyst and on the subsequent hydrogenation of the reaction mixture freed of the non-reacted acrolein and containing 3-hydroxypropionaldehyde is disclosed. As a result of using chelate-forming ion exchangers with anchor groups of the formula ##STR1## in which Z=H, C.sub.1 -C.sub.6 -alkyl, --CH.sub.2 --CH(CH.sub.3)--Y' or --(CH.sub.2).sub.o --Y' and Y and/or Y'=--COOH, --OH, pyridyl or --P(O)(CH.sub.2 OH)OH, the hydration occurs at lower temperatures with a greater space-time yield and especially a greater selectivity than when using previously known ion exchangers. Resins with methylene imino diacetic acid anchor groups in the H form or partially doped with alkali-, alkaline-earth or earth-metal ions are especially suitable.
摘要翻译：公开了在基于聚苯乙烯/二乙烯基苯作为催化剂的螯合形成离子交换树脂存在下丙烯醛的水合，然后在无反应的丙烯醛和含有3-羟基丙醛的反应混合物的随后氢化中进行水合。作为使用螯合形成离子交换剂，其结构式为“IMAGE”的锚定基团，其中Z = H，C 1 -C 6 - 烷基，-CH 2 -CH（CH 3）-Y'或 - （CH 2）o Y'和Y 和/或Y'= -COOH，-OH，吡啶基或-P（O）（CH 2 OH）OH时，水合在较低的温度下发生，具有比使用先前已知的离子交换剂更大的空时收率，特别是更大的选择性。具有H形式的亚甲基亚氨基二乙酸锚定基团或部分掺杂有碱金属，碱土金属或土金属离子的树脂是特别合适的。

26. 发明授权

US4621072A Process for preparing abrasion-resistant coated catalysts 失效
标题翻译：制备耐磨涂层催化剂的方法
公开(公告)号：US4621072A
公开(公告)日：1986-11-04
申请号：US710078
申请日：1985-02-26
申请人： Dietrich Arntz , Gunter Prescher , Werner Burkhardt , Johannes Heilos , Reinhard Manner
发明人： Dietrich Arntz , Gunter Prescher , Werner Burkhardt , Johannes Heilos , Reinhard Manner
IPC分类号： C07C57/05 , B01J23/22 , B01J23/30 , B01J23/34 , B01J23/68 , B01J23/84 , B01J23/88 , B01J23/885 , B01J23/89 , B01J27/192 , B01J27/198 , B01J27/199 , B01J33/00 , B01J37/02 , C07B31/00 , C07B33/00 , C07B61/00 , C07C27/00 , C07C27/14 , C07C45/00 , C07C45/35 , C07C47/052 , C07C47/22 , C07C51/00 , C07C51/25 , C07C57/055 , C07C67/00 , C07C253/00 , C07C253/18 , C07C255/08 , C07D213/84 , B01J27/224 , B01J23/00 , B01J27/19
CPC分类号： C07D213/84 , B01J23/885 , B01J27/192 , B01J37/0223 , C07C45/35 , C07C51/252 , B01J2523/00
摘要： A process is disclosed for preparing coated catalysts, inter alia, for gas phase oxidations in organic chemistry, comprised of an inert support and a coating of catalyst material enclosing this support, wherein a suspension of the starting material for the coating is sprayed onto an agitated bed of the support, while the suspending medium is being partially removed by a gas stream, and the raw material is then dried and heat-treated. For this purpose, the support bed is mechanically agitated and loosened by a gas stream blown in from below. The catalyst precursor containing a binder and, if appropriate, a pore-former is sprayed in an increasing amount from above onto the bed, the ratio between suspending medium sprayed on and drawn off remaining about constant. The thermal expansion coefficient of the precursor as a dry powder must not deviate by more than 15% from that of the support. The applied coating is densified by continuing the mechanical and fluidizing mixing motion, the material is then dried in a continuing gas stream and heat-treated, if appropriate after decomposition of an added pore-former.
摘要翻译：公开了一种用于制备涂覆的催化剂的方法，特别是用于有机化学中的气相氧化，包括惰性载体和包围该载体的催化剂材料的涂层，其中用于涂层的起始材料的悬浮液被喷涂到搅拌的同时通过气流部分地除去悬浮介质，然后将原料干燥和热处理。为此，支撑床被从下方吹入的气流机械搅拌和松动。含有粘合剂的催化剂前体，如果合适的话，将成孔剂从上面以增加的量喷洒到床上，喷雾和吸出的悬浮介质之间的比例保持不变。作为干粉的前体的热膨胀系数不能偏离载体的热膨胀系数的15％以上。施加的涂层通过继续机械和流化混合运动致密化，然后将材料以连续的气流干燥，并在适当的情况下在加入的成孔剂分解后进行热处理。

27. 发明授权

US06294138B1 Reactor for performing endothermic catalytic reactions 失效
标题翻译：用于进行吸热催化反应的反应器
公开(公告)号：US06294138B1
公开(公告)日：2001-09-25
申请号：US09459977
申请日：1999-12-14
申请人： Lukas von Hippel , Dietrich Arntz , Bernd Kuttruf , Brigitta Walter
发明人： Lukas von Hippel , Dietrich Arntz , Bernd Kuttruf , Brigitta Walter
IPC分类号： F28D700
CPC分类号： F28F7/02 , B01J4/001 , B01J12/007 , B01J19/0013 , B01J19/2425 , B01J19/2485 , B01J35/04 , B01J2208/021 , B01J2219/00063 , B01J2219/00117 , C01C3/0233 , Y02P20/124
摘要： A reactor for performing endothermic catalytic reactions is disclosed formed of a monolithic counterflow reactor with parallel heating and reaction channels. The internal walls of the reaction channels are coated with a catalyst for the catalytic reaction to be performed, while the internal walls of the heating channels have a catalyst for the catalytic combustion of a fuel gas/air mixture.
摘要翻译：公开了一种用于进行吸热催化反应的反应器，其由具有平行加热和反应通道的单片逆流反应器形成。反应通道的内壁涂覆有用于进行催化反应的催化剂，而加热通道的内壁具有用于燃料气体/空气混合物的催化燃烧的催化剂。

28. 发明授权

US5977011A Catalyst, process for its preparation, and use for synthesis of methyl mercaptan 失效
标题翻译：催化剂，其制备方法和用于合成甲硫醇的用途
公开(公告)号：US5977011A
公开(公告)日：1999-11-02
申请号：US885042
申请日：1997-06-30
申请人： Joerg Sauer , Lukas von Hippel , Dietrich Arntz , Wolfgang Boeck
发明人： Joerg Sauer , Lukas von Hippel , Dietrich Arntz , Wolfgang Boeck
IPC分类号： B01J23/04 , B01J23/30 , B01J37/02 , C07B61/00 , C07C319/00 , C07C319/08 , C07C321/04 , B01J23/24
CPC分类号： B01J23/30 , C07C319/08
摘要： A catalyst for the synthesis of methyl mercaptan from hydrogen sulfide and methanol as well as a process for preparation of the catalyst. The catalyst is an active aluminum oxide onto which 5 to 25% by weight potassium tungstate is deposited as an activator. A two-stage impregnation with intermediate drying produces a catalyst which exhibits distinctly better selectivity for formation of methyl mercaptan than catalysts obtained by single-stage impregnation.
摘要翻译：用于从硫化氢和甲醇合成甲硫醇的催化剂以及催化剂的制备方法。该催化剂是一种活性氧化铝，5至25％（重量）的钨酸钾沉积为活化剂。使用中间干燥的两阶段浸渍产生催化剂，其比通过单阶段浸渍获得的催化剂显示出明显更好的形成甲硫醇的选择性。

29. 发明授权

US5892129A Process for the preparation of 1,1,3-trialkoxypropane 失效
标题翻译：制备1,1,3-三烷氧基丙烷的方法
公开(公告)号：US5892129A
公开(公告)日：1999-04-06
申请号：US859845
申请日：1997-05-21
申请人： Mathias Hoepp , Dietrich Arntz , Hans-Peter Ohlinger , Willi Hofen
发明人： Mathias Hoepp , Dietrich Arntz , Hans-Peter Ohlinger , Willi Hofen
IPC分类号： B01J31/08 , C07B61/00 , C07C41/48 , C07C41/50 , C07C41/54 , C07C41/56 , C07C43/315 , C07C43/30
CPC分类号： C07C41/54 , C07C41/56
摘要： A process for the preparation of 1,1,3-trialkoxypropane by acid-catalyzed reaction of acrolein with a C.sub.1 to C.sub.6 alcohol, which can be carried out well on a large scale and leads to a higher selectivity. The process involves (a) the reaction, in the presence of a solid acid catalyst which is insoluble in the reaction mixture, (b) a partial neutralization of the reaction mixture, using an amine or basic ion exchanger, and (c) specific recovery by distillation of the reaction mixture and recirculation of fractions containing useful materials; aqueous fractions containing recyclable useful materials are largely dehydrated by pervaporation prior to being recirculated.
摘要翻译：通过丙烯醛与C1〜C6醇的酸催化反应制备1,1,3-三烷氧基丙烷的方法，其可以大规模良好地进行并导致更高的选择性。该方法包括（a）在不溶于反应混合物的固体酸催化剂存在下的反应，（b）使用胺或碱式离子交换剂部分中和反应混合物，和（c）特定回收通过蒸馏反应混合物和再循环含有有用材料的级分; 含有可回收有用物质的含水馏分在再循环之前通过渗透蒸发大部分脱水。

30. 发明授权

US5688973A Process for the production of 2-vinyl-1,3-dioxolane 失效
标题翻译： 2-乙烯基-1,3-二氧戊环的制备方法
公开(公告)号：US5688973A
公开(公告)日：1997-11-18
申请号：US523339
申请日：1995-09-05
申请人： Mathias Hoepp , Dietrich Arntz , Wolfgang Boeck , Andreas Bosse-Plois , Klaus Raible
发明人： Mathias Hoepp , Dietrich Arntz , Wolfgang Boeck , Andreas Bosse-Plois , Klaus Raible
IPC分类号： B01J31/10 , C07B61/00 , C07D317/12
CPC分类号： C07D317/12
摘要： Process for the production of 2-vinyl-1,3-dioxolane reacting acrolein with ethylene glycol in the presence of a solid, acidic catalyst and recovery of the reaction mixture. Selectivity may be increased in comparison with known prior art processes by performing the reaction in the presence of a solid acidic catalyst at a temperature of below 50.degree. C.; the reaction mixture, from which the catalyst has been removed, is treated by extraction using an organic solvent which substantially does not dissolve ethylene glycol and has a boiling point of above 130.degree. C.; the two phases obtained on extraction are treated for recovery by distillation and recovered educts and the organic solvent are recycled.
摘要翻译：在固体酸性催化剂存在下，用乙二醇生产2-乙烯基-1,3-二氧戊环的方法，回收反应混合物。与已知的现有技术方法相比，通过在低于50℃的温度下在固体酸性催化剂存在下进行反应可以增加选择性; 已经除去催化剂的反应混合物通过萃取使用基本上不溶解乙二醇并且沸点高于130℃的有机溶剂进行处理。萃取后得到的两相进行蒸馏回收处理，回收出去，并回收有机溶剂。

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