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    • 24. 发明授权
    • Process for producing unsaturated group-terminated isobutylene polymer
    • 制备不饱和基团的异丁烯聚合物的方法
    • US5811501A
    • 1998-09-22
    • US671198
    • 1996-06-27
    • Takeshi ChibaHiroshi FujisawaYoshimichi YamanakaYoshikuni DeguchiKazuya Yonezawa
    • Takeshi ChibaHiroshi FujisawaYoshimichi YamanakaYoshikuni DeguchiKazuya Yonezawa
    • C08F2/06C08F10/10
    • C08F10/10Y10S525/918
    • The present invention provides a novel halogen-free solvent system which can produce a good isobutylene polymer and can be easily reused. A novel process for the production of an isobutylene polymer is provided which comprises using a hydrocarbon solvent having a boiling point of not lower than 105.degree. C. and a melting point of not higher than -90.degree. C. Heretofore, a solvent system containing a halogenated hydrocarbon such as methylene chloride has been used for the production of an isobutylene polymer. However, such a solvent system has a great adverse effect on the environment. Therefore, a non-halogenated solvent is desirable. The present invention is characterized by the use of a hydrocarbon solvent as a reaction solvent. The resulting polymer has good properties. Further, compounds which are produced as by-products during the reaction can be easily removed, enabling the recycling of the solvent used. Thus, the production cost can be reduced.
    • 本发明提供了一种新型的无卤素溶剂体系,其可以产生良好的异丁烯聚合物并且可以容易地重复使用。 提供了一种生产异丁烯聚合物的新方法,其包括使用沸点不低于105℃,熔点不高于-90℃的烃溶剂。迄今为止,含有 卤代烃如二氯甲烷已被用于生产异丁烯聚合物。 然而,这种溶剂体系对环境有很大的不利影响。 因此,非卤化溶剂是理想的。 本发明的特征在于使用烃溶剂作为反应溶剂。 所得聚合物具有良好的性能。 此外,可以容易地除去在反应期间作为副产物生成的化合物,使得所用溶剂的再循环。 因此,可以降低生产成本。