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21. 发明申请

US20120190117A1 CATALYST FORMULATION FOR HYDROGENATION 有权
标题翻译：催化剂用于氢化反应
公开(公告)号：US20120190117A1
公开(公告)日：2012-07-26
申请号：US13431964
申请日：2012-03-27
申请人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
发明人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
IPC分类号： G01N31/10 , B01J23/08 , B01J23/34 , B01J23/06 , B01J23/44
CPC分类号： B01J23/50 , B01J23/44 , B01J23/48 , B01J23/52 , B01J23/60 , B01J23/62 , B01J23/6562 , B01J23/66 , B01J35/002 , B01J37/0036 , B01J37/009 , B01J37/0205 , B01J37/18 , C10G45/34 , C10G45/40 , C10G2400/20
摘要： A method of screening catalysts for liquid-phase selective hydrogenation by preparing a test catalyst by adding a promoter to a reference catalyst; preparing a liquid reactant stream comprising C2H2 dissolved in n-methyl-2-pyrrolidone; testing the test and reference catalysts by contacting the reactant stream and gas mixture comprising hydrogen and carbon monoxide in continuous flow with the test catalyst and reference catalyst, respectively, at selective hydrogenation reaction conditions to produce a product stream, condensing substantially all of the n-methyl-2-pyrrolidone from the product stream; measuring the concentrations of products comprising C2H2, C2H4, and C2H6 in the product stream at steady state; determining performance parameters for the test catalyst and the reference catalyst comprising the respective C2H2 conversion Sc and C2H4 selectivity relative to C2H6 Ss; and comparing the test catalyst performance parameters to those for the reference catalyst.
摘要翻译：一种筛选用于液相选择性氢化的催化剂的方法，通过向参考催化剂中加入助催化剂制备试验催化剂; 制备包含溶解在正甲基-2-吡咯烷酮中的C2H2的液体反应物流; 通过在选择性氢化反应条件下分别使包含氢气和一氧化碳的反应物流和连续流动的气体混合物与测试催化剂和参考催化剂分别接触来测试测试和参考催化剂，以产生产物流，基本上将所有的n- 甲基-2-吡咯烷酮; 在稳定状态下测量产物流中包含C2H2，C2H4和C2H6的产物的浓度; 确定测试催化剂和参考催化剂的性能参数，其包含相对于C 2 H 6 S的相应的C 2 H 2转化率Sc和C 2 H 4选择性; 并将试验催化剂性能参数与参考催化剂的参数进行比较。

22. 发明授权

US07919431B2 Catalyst formulation for hydrogenation 有权
标题翻译：用于氢化的催化剂配方
公开(公告)号：US07919431B2
公开(公告)日：2011-04-05
申请号：US10727919
申请日：2003-12-04
申请人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
发明人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： B01J23/50 , B01J23/44 , B01J23/48 , B01J23/52 , B01J23/60 , B01J23/62 , B01J23/6562 , B01J23/66 , B01J35/002 , B01J37/0036 , B01J37/009 , B01J37/0205 , B01J37/18 , C10G45/34 , C10G45/40 , C10G2400/20
摘要： A composition and method for preparation of a catalyst for the liquid phase selective hydrogenation of alkynes to alkenes with high selectivity to alkenes relative to alkanes, high alkyne conversion, and sustained catalytic activity comprising a Group VIII metal and a Group IB, Group IIB, Group IIIA, and/or Group VIIB promoter on a particulate support.
摘要翻译：一种用于制备用于相对于烷烃对烯烃具有高选择性的炔烃至烯烃的液相选择性氢化的催化剂的组合物和方法，具有高炔烃转化率和持续催化活性的组合物和方法，其包含VIII族金属和IB族，IIB族， IIIA和/或VIIB族促进剂。

23. 发明授权

US07915463B2 Process for the conversion of natural gas to hydrocarbon liquids 有权
公开(公告)号：US07915463B2
公开(公告)日：2011-03-29
申请号：US12684373
申请日：2010-01-08
申请人： Sean C. Gattis , Edward R. Peterson
发明人： Sean C. Gattis , Edward R. Peterson
IPC分类号： C07C2/78
CPC分类号： C10G50/00 , Y10S585/943
摘要： A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.

24. 发明申请

US20100167135A1 PROCESS FOR THE CONVERSION OF NATURAL GAS TO HYDROCARBON LIQUIDS 有权
标题翻译：将天然气转化为烃类液体的方法
公开(公告)号：US20100167135A1
公开(公告)日：2010-07-01
申请号：US12684221
申请日：2010-01-08
申请人： Sean C. Gattis , Edward R. Peterson
发明人： Sean C. Gattis , Edward R. Peterson
IPC分类号： H01M8/06 , C07C2/00 , C10G57/00 , F01D15/10 , F02C7/22 , F01K7/16
CPC分类号： C10G50/00 , Y10S585/943
摘要： A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.
摘要翻译：一种将天然气转化为液体烃的方法，包括将气体在选定的温度范围内加热足够的时间和/或在足够的温度和适当的条件下燃烧气体以使反应时间足以转化一部分气流反应性烃产物，主要是乙烯或乙炔。可以分离含乙炔的气体，使乙炔转化为乙烯。乙烯产物可以在酸性催化剂的存在下反应以产生液体，其中一部分主要是石脑油或汽油。在该过程中产生的一部分进入的天然气或氢气可用于将剩余的天然气加热到所选择的温度范围。反应性气体组分用于催化液化步骤和/或用于替代化学处理。

25. 发明申请

US20080300437A1 PROCESS FOR LIQUID PHASE HYDROGENATION 有权
标题翻译：液相加氢方法
公开(公告)号：US20080300437A1
公开(公告)日：2008-12-04
申请号：US12114088
申请日：2008-05-02
申请人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
发明人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
IPC分类号： C07C5/05 , B01J23/08 , B01J23/44 , B01J23/48 , B01J23/06 , B01J23/70 , B01J23/80 , B01J23/825 , B01J27/10 , B01J27/25 , B01J23/34
CPC分类号： B01J37/08 , B01J21/04 , B01J23/44 , B01J23/50 , B01J23/52 , B01J23/60 , B01J23/62 , B01J23/6562 , B01J23/66 , B01J35/008 , B01J35/08 , B01J37/18 , C07C7/167 , C07C2523/56 , C07C2523/60 , C07C2523/62 , C07C2523/64
摘要： A process and catalyst for the liquid phase selective hydrogenation of alkynes to alkenes with high selectivity to alkenes relative to alkanes, high alkyne conversion, and sustained catalytic activity comprising a reactant comprising an alkyne and a non-hydrocarbon solvent/absorbent, contacting the reactant stream with a hydrogen-containing stream in the presence of a supported, promoted, Group VIII catalyst, removing the solvent/absorbent, and recovering the alkene product.
摘要翻译：一种用于相对于烷烃对烯烃具有高选择性的烯烃至烯烃的液相选择性氢化的方法和催化剂，高炔转化率和持续的催化活性，其包含含有炔烃和非烃溶剂/吸收剂的反应物，使反应物流在含有载体的促进的VIII族催化剂的存在下，将含氢的物流除去溶剂/吸收剂，并回收烯烃产物。

26. 发明授权

US07183451B2 Process for the conversion of natural gas to hydrocarbon liquids 有权
标题翻译：将天然气转化为烃类液体的方法
公开(公告)号：US07183451B2
公开(公告)日：2007-02-27
申请号：US10844852
申请日：2004-05-13
申请人： Sean C. Gattis , Edward R. Peterson
发明人： Sean C. Gattis , Edward R. Peterson
IPC分类号： C07C2/78
CPC分类号： C10G50/00 , Y10S585/943
摘要： A process for converting natural gas to liquid hydrocarbons comprising heating the gas through a selected range of temperature for sufficient time and/or combustion of the gas at a sufficient temperature and under suitable conditions for a reaction time sufficient to convert a portion of the gas stream to reactive hydrocarbon products, primarily ethylene or acetylene. The gas containing acetylene may be separated such that acetylene is converted to ethylene. The ethylene product(s) may be reacted in the presence of an acidic catalyst to produce a liquid, a portion of which will be predominantly naphtha or gasoline. A portion of the incoming natural gas or hydrogen produced in the process may be used to heat the remainder of the natural gas to the selected range of temperature. Reactive gas components are used in a catalytic liquefaction step and/or for alternate chemical processing.
摘要翻译：一种将天然气转化为液体烃的方法，包括将气体在选定的温度范围内加热足够的时间和/或在足够的温度和适当的条件下燃烧气体以使反应时间足以转化一部分气流反应性烃产物，主要是乙烯或乙炔。可以分离含乙炔的气体，使乙炔转化为乙烯。乙烯产物可以在酸性催化剂的存在下反应以产生液体，其中一部分主要是石脑油或汽油。在该过程中产生的一部分进入的天然气或氢气可用于将剩余的天然气加热到所选择的温度范围。反应性气体组分用于催化液化步骤和/或用于替代化学处理。

27. 发明授权

US07045670B2 Process for liquid phase hydrogenation 有权
标题翻译：液相氢化方法
公开(公告)号：US07045670B2
公开(公告)日：2006-05-16
申请号：US10728310
申请日：2003-12-04
申请人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
发明人： Marvin M. Johnson , Edward R. Peterson , Sean C. Gattis
IPC分类号： C07C5/02 , C07C5/08
CPC分类号： B01J37/08 , B01J21/04 , B01J23/44 , B01J23/50 , B01J23/52 , B01J23/60 , B01J23/62 , B01J23/6562 , B01J23/66 , B01J35/008 , B01J35/08 , B01J37/18 , C07C7/167 , C07C2523/56 , C07C2523/60 , C07C2523/62 , C07C2523/64
摘要： A process for the liquid phase selective hydrogenation of alkynes to alkenes with high selectivity to alkenes relative to alkanes, high alkyne conversion, and sustained catalytic activity comprising a reactant comprising an alkyne and a non-hydrocarbon solvent/absorbent, contacting the reactant stream with a hydrogen-containing stream in the presence of a supported, promoted, Group VIII catalyst, removing the solvent/absorbent, and recovering the alkene product.
摘要翻译：将烯烃液相选择性氢化为烯烃的方法，其相对于烷烃具有对烯烃的高选择性，高炔转化率和持续的催化活性，其包括含有炔烃和非烃溶剂/吸收剂的反应物，使反应物流与在负载的，促进的VIII族催化剂存在下，含氢的物流，去除溶剂/吸收剂，并回收烯烃产物。

28. 发明授权

US09683703B2 Method of storing and transporting light gases 有权
公开(公告)号：US09683703B2
公开(公告)日：2017-06-20
申请号：US12704372
申请日：2010-02-11
申请人： Edward R. Peterson
发明人： Edward R. Peterson
IPC分类号： F17C11/00
CPC分类号： F17C11/007 , F17C11/00 , F17C2205/0323 , F17C2205/0341 , F17C2221/016 , F17C2221/03 , F17C2221/033 , F17C2223/0161 , F17C2223/0184 , F17C2223/033 , F17C2227/0135 , F17C2227/0185 , F17C2227/0341 , F17C2227/0365 , F17C2260/056 , F17C2265/012 , F17C2265/015 , F17C2265/025 , F17C2265/05 , F17C2270/0105
摘要： A method and system of storing and transporting gases comprising mixing the gases with liquid natural gas to form a mixture. The mixture is a liquid-liquid mixture or slurry, and is stored in vessel configured for maintaining the mixture at a first location. The mixture is transported to a second location for storage in vessel for maintaining the mixture. The mixture is removed from the second location storage vessel for separation and use in additional processes.

29. 发明授权

US08434505B2 Secondary reaction quench device and method of use 有权
标题翻译：二次反应淬火装置及其使用方法
公开(公告)号：US08434505B2
公开(公告)日：2013-05-07
申请号：US13397295
申请日：2012-02-15
申请人： Duane Morrow , Joel Cantrell , Edward R. Peterson
发明人： Duane Morrow , Joel Cantrell , Edward R. Peterson
IPC分类号： B08B3/00
CPC分类号： B08B9/093 , B01J19/0013 , B01J19/0026 , B01J19/26 , B01J2219/00123 , F28C3/06 , F28G1/16
摘要： In this disclosure, a reactor system is described. The reaction system comprises (a) a reaction vessel having an inner wall, wherein said reaction vessel is configured to receive reactants and export products and byproducts; (b) a primary quench device (PQD) configured to receive a coolant and disperse said coolant into said reaction vessel; and (c) a secondary quench device (SQD) configured to receive a coolant and disperse said coolant into said reaction vessel; wherein said PQD comprises an array of spray nozzles fixed on the inner wall of said reaction vessel at a first axial position; and wherein said SQD comprises (1) an axially movable pipe having a coolant entry end and a nozzle end, wherein said pipe is configured to be removably fixed inside said reaction vessel; and (2) a spray nozzle that is fluidly connected to said pipe at its nozzle end via a fluid tight seal connection.
摘要翻译：在本公开中，描述了反应器系统。反应体系包括（a）具有内壁的反应容器，其中所述反应容器构造成接收反应物并输出产物和副产物; （b）构造成接收冷却剂并将所述冷却剂分散到所述反应容器中的主骤冷装置（PQD）; 和（c）二次淬火装置（SQD），其构造成接收冷却剂并将所述冷却剂分散到所述反应容器中; 其中所述PQD包括在第一轴向位置处固定在所述反应容器的内壁上的喷嘴阵列; 并且其中所述SQD包括（1）具有冷却剂入口端和喷嘴端的可轴向移动的管，其中所述管构造成可移除地固定在所述反应容器内; 和（2）喷嘴，其通过流体密封连接在其喷嘴端处流体地连接到所述管。

30. 发明申请

US20120197053A1 SYSTEM AND METHOD FOR THE PRODUCTION OF LIQUID FUELS 审中-公开
标题翻译：液体燃料生产系统和方法
公开(公告)号：US20120197053A1
公开(公告)日：2012-08-02
申请号：US13192396
申请日：2011-07-27
申请人： Joel CANTRELL , Duane Morrow , Edward R. Peterson
发明人： Joel CANTRELL , Duane Morrow , Edward R. Peterson
IPC分类号： C07C2/08 , B01J19/00 , C07C7/00 , C07C5/03 , C07C5/09
CPC分类号： C10G50/00 , B01J21/04 , B01J21/18 , B01J23/72 , B01J23/883 , B01J29/46 , B01J35/0006 , C07C2/12 , C07C2529/46 , C10G3/46 , C10G3/47 , C10G3/49 , C10G3/50 , C10G69/126 , C10G2300/1088 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/22 , C10L1/04 , Y02P30/20 , C07C11/08
摘要： A method of producing liquid fuels by providing an olefin feed containing at least one C2-C20 olefin, oligomerizing a part of the feed in the presence of a first catalyst to form a first product comprising oligomers of the at least one olefin, and oligomerizing a portion of the first product in the presence of a second catalyst to produce a second product. A system of producing liquid hydrocarbons, the system including a first reactor configured to provide a first product by oligomerizing, in the presence of a first catalyst, at least a portion of an olefin feed comprising at least one olefin, a separator configured to provide an unreacted olefin-reduced first product by separating unreacted olefin from the first product, and a second reactor configured to provide a second product by oligomerizing, in the presence of a second catalyst, at least a portion of the unreacted olefin-reduced first product.
摘要翻译：一种通过提供含有至少一种C 2 -C 20烯烃的烯烃进料来生产液体燃料的方法，在一种第一种催化剂的存在下将部分原料低聚以形成包含至少一种烯烃的低聚物的第一产物，部分第一产物在第二催化剂的存在下产生第二产物。一种生产液体烃的系统，该系统包括第一反应器，其被配置成通过在第一催化剂存在下使至少一部分包含至少一种烯烃的烯烃进料进行低聚而提供第一产物，未反应的烯烃还原的第一产物通过从第一产物中分离未反应的烯烃，以及第二反应器构造成通过在第二催化剂的存在下使至少一部分未反应的烯烃还原的第一产物低聚来提供第二产物。

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