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21. 发明授权

US06596796B1 Stabilizers for emulsion crude rubbers, synthetic latex and natural rubber latex 失效
标题翻译：乳化乳胶，合成胶乳和天然橡胶胶乳的稳定剂
公开(公告)号：US06596796B1
公开(公告)日：2003-07-22
申请号：US09688417
申请日：2000-10-16
申请人： Hans-Rudolf Meier , Gerrit Knobloch , Paul Dubs , Samuel Evans
发明人： Hans-Rudolf Meier , Gerrit Knobloch , Paul Dubs , Samuel Evans
IPC分类号： C08K5134
CPC分类号： C08K5/134 , C08L21/02
摘要： There are described compositions comprising a) an emulsion crude rubber, synthetic latex or natural rubber latex subject to oxidative, thermal, dynamic and/or light-induced degradation, and b) as stabilizer at least one compound of formula I wherein R1 is C8-C20alkyl; and optionally c) as further stabilizer at least one compound of formula II wherein R2 is C8-C12alkyl, R3 is hydrogen, C1-C12alkyl, cyclohexyl, 1-methylcyclohexyl, benzyl, &agr;-methylbenzyl, &agr;,&agr;-dimethylbenzyl or —CH2—S—R2, R4 is C1-C12alkyl, benzyl, &agr;-methylbenzyl, 60 ,&agr;-dimethylbenzyl or —CH2—S—R2, and R5 is hydrogen or methyl.
摘要翻译：描述的组合物包括：a）经受氧化，热，动态和/或光诱导降解的乳液粗橡胶，合成胶乳或天然橡胶胶乳，和b）作为稳定剂的至少一种式I化合物，其中R1是C8-C20烷基;和任选地，c）作为其它稳定剂的至少一种式II化合物，其中R2是C8-C12烷基，R3是氢，C1-C12烷基，环己基，1-甲基环己基，苄基，α-甲基苄基，α，α-二甲基苄基或-CH2-S-R2 R 4是C 1 -C 12烷基，苄基，α-甲基苄基，60，α-二甲基苄基或-CH 2 -S-R 2，R 5是氢或甲基。

22. 发明授权

US5668206A Liquid antioxidants as stabilizers 失效
标题翻译：液体抗氧化剂作为稳定剂
公开(公告)号：US5668206A
公开(公告)日：1997-09-16
申请号：US466520
申请日：1995-06-06
申请人： Paul Dubs , Roger Martin , Samuel Evans
发明人： Paul Dubs , Roger Martin , Samuel Evans
IPC分类号： C07C69/28 , C07C67/62 , C07C69/30 , C07C69/732 , C07C215/08 , C07C323/12 , C08K5/00 , C08K5/134 , C08K5/3435 , C09K15/08 , C08K5/04 , C08K5/06 , C08K5/10
CPC分类号： C08K5/3435 , C07C215/08 , C07C323/12 , C07C67/62 , C07C69/732 , C08K5/005 , C08K5/134 , C09K15/08
摘要： Products are described which can be obtained by reacting components a), b) and c), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II and component c) is a compound of the formula III or a mixture of compounds of the formula III, ##STR1## in which the general symbols are as defined in claim 1, the compound of the formula I being, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,4-propanediol, diethylene glycol, triethylene glycol, diethanolamine or glycerol, the compound of the formula II being, for example, sunflower oil or coconut fat, and the compound of the formula III being, for example, methyl 3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate. The abovementioned products can be used as liquid antioxidants in polymers and lubricants.
摘要翻译：描述了通过使组分a），b）和c）反应得到的产物，其中组分a）是式I化合物或式I化合物的混合物，组分b）是式II化合物或式II化合物和组分c）的化合物的混合物是式III的化合物或式III化合物，X（Y）a，（I），（II）权利要求1中，式I化合物为例如季戊四醇，硫代二甘醇，1,4-丁二醇，1,4-丙二醇，二甘醇，三甘醇，二乙醇胺或甘油，式II化合物为例如向日葵油或椰子脂肪，式III化合物为例如3-（3'，5'-二叔丁基-4'-羟基苯基）丙酸甲酯。上述产品可用作聚合物和润滑剂中的液体抗氧化剂。

23. 发明授权

US5616774A Inhibition of unsaturated monomers with 7-aryl quinone methides 失效
标题翻译：用7-芳基醌甲基化物抑制不饱和单体
公开(公告)号：US5616774A
公开(公告)日：1997-04-01
申请号：US422284
申请日：1995-04-14
申请人： Samuel Evans , Matthew E. Gande , Peter Nesvadba , Volker H. von Ahn , Roland A. E. Winter
发明人： Samuel Evans , Matthew E. Gande , Peter Nesvadba , Volker H. von Ahn , Roland A. E. Winter
IPC分类号： C07D333/22 , C07B63/04 , C07C7/20 , C07C49/683 , C07C49/747 , C07C49/753 , C07C67/62 , C07C205/45 , C07C225/22 , C07C255/56 , C07D207/333 , C07D211/94 , C07D307/46 , C07D401/04 , C07D401/14 , C08F2/38 , C08F4/00 , C07C69/00
CPC分类号： C07C255/56 , C07B63/04 , C07C205/45 , C07C225/22 , C07C49/683 , C07C49/747 , C07C49/753 , C07C67/62 , C07C7/20 , C07C2101/16
摘要： Ethylenically unsaturated monomers are protected from premature polymerization during manufacture and storage by the incorporation therein of an effective stabilizing amount of a 7-aryl quinone methide compound.
摘要翻译：乙烯基不饱和单体通过在其中加入有效稳定量的7-芳基醌甲基化合物在制备和储存过程中得到保护，防止过早聚合。

24. 发明授权

US5520848A Mixtures and compositions containing phenothiazines 失效
标题翻译：含有吩噻嗪的混合物和组合物
公开(公告)号：US5520848A
公开(公告)日：1996-05-28
申请号：US385020
申请日：1995-02-07
申请人： Samuel Evans
发明人： Samuel Evans
IPC分类号： B01J27/02 , B01J27/06 , C07B61/00 , C07C211/55 , C07D279/20 , C08K5/45 , C08K5/46 , C09K15/26 , C10M135/36 , C10N30/00 , C10N30/08 , C10N30/10 , C10N70/00
CPC分类号： C08K5/46
摘要： A mixture containing phenothiazines which is obtainable by reacting a mixture of diphenylamines comprising______________________________________ 1 to 5% by weight a) diphenylamine of 8 to 18% by b) 4-tert-butyldiphenylamine weight of 21 to 31% by c) one or more compounds selected from weight of i) 4-tert-octyldiphenylamine ii) 4,4'-di-tert-butyldiphenylamine iii) 2,4,4'-tris-tert-butyldiphenylamine 20 to 31% by d) one or more compounds selected from weight of i) 4-tert-butyl-4'-tert-octyldiphenylamine ii) 2,2'- or 2,4'-di-tert-octyldiphenylamine iii) 2,4-di-tert-butyl-4'-tert-octyldiphenylamine, and 15 to 29% by e) the compound weight of i) 4,4'-di-tert-octyldiphenylamine, or the compounds i) 4,4'-di-tert-octyldiphenylamine and ii) 2,4-di-tert-octyl-4'-tert-butyldiphenylamine, ______________________________________ with 1 to 200 mol % of elemental sulfur, in the presence of 0.25 to 5 mol % of a condensation catalyst selected from the group consisting of iodine, aluminum bromide, aluminum chloride, iron(III) chloride, antimony chloride, copper iodide or sulfur iodide, in the temperature range from 80.degree. to 250.degree. C.The mixture containing phenothiazines finds utility as antioxidant in organic materials which are subject to degradation induced by oxidation, heat or exposure to actinic light, especially in lubricants and hydraulic fluids.
摘要翻译：包含吩噻嗪的混合物，其可通过使包含-1至5重量％的二苯胺的混合物a）二苯胺-8至18重量％的b）4-叔丁基二苯胺重量为-21至31％的c）一种或多种选自i）4-叔辛基二苯胺的化合物 - ii）4,4'-二叔丁基二苯胺-ii）2,4,4'-三叔丁基二苯胺-20至31％ d）一种或多种选自i）4-叔丁基-4'-叔辛基二苯胺的化合物 - ii）2,2'-或2,4'-二叔辛基二苯胺-ii）2,4 - 叔丁基-4'-叔辛基二苯胺，和-15至29％e）i）4,4'-二叔辛基二苯胺的化合物 - 或 - 化合物 - i）4 ，4'-二叔辛基二苯胺和 - ii）2,4-二叔辛基-4'-叔丁基二苯胺， - 1至200摩尔％的元素硫，在0.25至5摩尔％的选自碘，溴化铝，氯化铝，氯化铁（III），氯化锑的缩合催化剂，碘化铜或碘化亚铜，在80-250℃的温度范围内。含吩噻嗪的混合物可用作有机材料中的抗氧化剂，这些有机物质经过氧化，加热或暴露于光化光，尤其是润滑剂和液压油。

25. 发明授权

US5503759A Mixtures of alkylated aromatic amines and phenothiazines 失效
标题翻译：烷基化芳香胺和吩噻嗪的混合物
公开(公告)号：US5503759A
公开(公告)日：1996-04-02
申请号：US359978
申请日：1994-12-20
申请人： Samuel Evans , Stephan Allenbach
发明人： Samuel Evans , Stephan Allenbach
IPC分类号： C07D279/36 , C07C211/54 , C07C211/55 , C07C211/58 , C07D279/20 , C08K5/1545 , C09K15/18 , C09K15/30 , C10M159/12 , C10N30/04 , C10N40/08 , C10N40/20 , C10M135/36 , C08K5/34
CPC分类号： C07C211/55 , C07C211/58 , C07D279/20
摘要： The invention relates to reaction products suitable as antioxidants which are substantially liquid at room temperature and which are obtained by the reaction of olefins with mixtures of diphenylamines and phenothiazines which may be alkylated. These products are obtainable by reacting an olefin of formulaR.sub.1 R.sub.2 C.dbd.CHR.sub.3 (I)with a mixture of compounds of formulae II and III ##STR1## in the presence of an acid catalyst, wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.25 alkyl or phenyl,R.sub.2 is C.sub.1 -C.sub.25 alkyl, benzyl or phenyl,R.sub.3 is hydrogen or C.sub.1 -C.sub.12 alkyl,R.sub.4, R*.sub.4, R.sub.5 and R*.sub.5 are each independently of one another hydrogen, C.sub.1 -C.sub.25 alkyl, C.sub.5 -C.sub.12 cycloalkyl, benzyl, .alpha.-methylbenzyl or .alpha.,.alpha.-dimethylbenzyl, and R.sub.6 and R*.sub.6 are each independently of the other hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.4 alkenyl, benzyl or a radical of formula --CH(R.sub.9)--CH(R.sub.10)--S--R.sub.11, andR.sub.7 and R.sub.8 are hydrogen, or together form a divalent group ##STR2## R.sub.9 and R.sub.10 are each independently of the other hydrogen, phenyl or C.sub.1 -C.sub.12 alkyl,R.sub.11 is C.sub.4 -C.sub.18 alkyl, phenyl or --(CH.sub.2).sub.a --CO--OR.sub.12,a is 1 or 2, andR.sub.12 is C.sub.1 -C.sub.18 alkyl.
摘要翻译：本发明涉及适合作为抗氧化剂的反应产物，其在室温下基本上是液体，并且是通过烯烃与可被烷基化的二苯胺和吩噻嗪的混合物反应获得的。这些产物可通过在酸催化剂存在下使式R 1 R 2 C = CHR 3（I）的烯烃与式II和III化合物（II）的混合物反应获得，其中R1是氢，C 1 -C 25烷基或苯基，R 2为C 1 -C 25烷基，苄基或苯基，R 3为氢或C 1 -C 12烷基，R 4，R * 4，R 5和R 5各自独立地为氢，C 1 -C 25烷基， C 1 -C 18烷基，苄基，α-甲基苄基或α，α-二甲基苄基，R 6和R 6各自独立地为另一个氢，C 1 -C 18烷基，C 1 -C 4链烯基，苄基或式-CH（R 9）-CH R 10）-S-R 11，并且R 7和R 8是氢或一起形成二价基团R 9和R 10各自独立地为氢，苯基或C 1 -C 12烷基，R 11为C 4 -C 18烷基，苯基或 - （ CH2）a-CO-OR12，a为1或2，R12为C1-C18烷基。

26. 发明授权

US5427701A Substituted phenols as stabilizers 失效
标题翻译：取代酚作为稳定剂
公开(公告)号：US5427701A
公开(公告)日：1995-06-27
申请号：US275689
申请日：1994-07-14
申请人： Hans R. Meier , Samuel Evans , Paul Dubs
发明人： Hans R. Meier , Samuel Evans , Paul Dubs
IPC分类号： C07C323/16 , C07C323/52 , C08K5/13 , C08K5/36 , C08K5/37 , C08K5/375 , C08L75/04 , C08L101/00 , C09K15/14 , C10M135/22 , C10M135/24 , C10M135/26 , C10M135/28 , C10N30/00 , C10N30/08 , C10N30/10 , C10N40/25 , C07C321/00
CPC分类号： C10M135/28 , C07C323/00 , C08K5/375 , C09K15/14 , C10M135/24 , C10M135/26 , C10M2219/084 , C10M2219/085 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： Novel compositions are described which comprises an elastomer or a lubricant and at least one compound of the formulae I or II ##STR1## The symbols R.sub.1, R.sub.2, R.sub.3, Z.sub.1 and Z.sub.2 are as defined in claim 1.The compounds of the formula II and some of the compounds of the formula I are novel, and they are used especially as antioxidants.
摘要翻译：描述了新的组合物，其包含弹性体或润滑剂和至少一种式I或II的化合物。（I）符号R1，R2，R3，Z1和Z2如权利要求中所定义。式II化合物和一些式I化合物是新颖的，它们特别用作抗氧化剂。

27. 发明授权

US5273669A Lubricant composition 失效
标题翻译：润滑油组成
公开(公告)号：US5273669A
公开(公告)日：1993-12-28
申请号：US951377
申请日：1992-09-25
申请人： Rolf Schumacher , Samuel Evans , Paul Dubs
发明人： Rolf Schumacher , Samuel Evans , Paul Dubs
IPC分类号： C10M133/02 , C10M141/08 , C10M141/10 , C10M135/36 , C10M133/40
CPC分类号： C10M141/10 , C10M133/02 , C10M141/08 , C10M2207/023 , C10M2207/024 , C10M2207/026 , C10M2207/027 , C10M2207/287 , C10M2215/00 , C10M2215/06 , C10M2215/062 , C10M2215/064 , C10M2215/065 , C10M2215/066 , C10M2215/067 , C10M2215/068 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/12 , C10M2215/122 , C10M2215/18 , C10M2215/22 , C10M2215/221 , C10M2215/222 , C10M2215/225 , C10M2215/226 , C10M2215/28 , C10M2215/30 , C10M2217/00 , C10M2217/02 , C10M2217/028 , C10M2217/04 , C10M2217/042 , C10M2217/043 , C10M2217/044 , C10M2217/045 , C10M2217/06 , C10M2219/06 , C10M2219/083 , C10M2219/084 , C10M2219/085 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/106 , C10M2219/108 , C10M2223/04 , C10M2223/042 , C10M2223/065 , C10M2227/04 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： A lubricant based on a mineral or synthetic oil is stabilized against oxidative degradation by the addition of a mixture comprising at least one specified aromatic amine of the formula I or II ##STR1## and at least one sterically hindered amine. The lubricant may contain other antioxidants or other additives. It is preferably used as motor oil.
摘要翻译：基于矿物或合成油的润滑剂通过加入包含至少一种特定的式I或II芳香胺（I）（II）的芳族胺和至少一种空间位阻的混合物而稳定，防止氧化降解受阻胺。润滑剂可能含有其他抗氧化剂或其他添加剂。优选用作机油。

28. 发明授权

US5091099A Lubricating oil composition 失效
标题翻译：润滑油组成
公开(公告)号：US5091099A
公开(公告)日：1992-02-25
申请号：US360646
申请日：1989-06-01
申请人： Samuel Evans , Rolf Schumacher
发明人： Samuel Evans , Rolf Schumacher
IPC分类号： C09K15/08 , C09K15/14 , C10M141/06 , C10M141/08 , C10N30/04 , C10N30/10 , C10N40/25
CPC分类号： C10M141/06 , C10M141/08 , C10M2207/023 , C10M2207/026 , C10M2207/027 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/287 , C10M2207/288 , C10M2207/289 , C10M2215/06 , C10M2215/062 , C10M2215/064 , C10M2215/065 , C10M2215/066 , C10M2215/067 , C10M2215/068 , C10M2219/084 , C10M2219/085 , C10M2219/086 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： Phosphite-free lubricating oil composition which comprises a) a mineral oil or a synthetic oil or a mixture thereof, and b) a mixture containing at least one aromatic amine of the formula (I), ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.3 ' are as defined in claim 1, and at least one phenol of the formula ##STR2## in which R.sup.4, R.sup.5 and A are as defined in claim 1, and the compounds are present in the mixture in a ratio of 2 to 6 parts by weight of the aromatic amine(s) of the formula I to 1 part by weight of the phenol(s) of the formula II.The lubricating oil compositions are highly resistant to ageing and are effective in preventing black sludge formation.
摘要翻译：无亚磷酸盐的润滑油组合物，其包含a）矿物油或合成油或其混合物，和b）含有至少一种式（I）的芳族胺的混合物，其中R1， R2，R3和R3'如权利要求1中所定义，并且至少一种式（II）的酚，其中R 4，R 5和A如权利要求1所定义，并且化合物存在于混合物中 2至6重量份的式I的芳族胺与1重量份式II的苯酚的比例。润滑油组合物耐老化性高，有效防止黑色污泥的形成。

29. 发明授权

US5073278A Lubricant composition 失效
标题翻译：润滑剂组合物
公开(公告)号：US5073278A
公开(公告)日：1991-12-17
申请号：US380563
申请日：1989-07-13
申请人： Rolf Schumacher , Samuel Evans , Paul Dubs
发明人： Rolf Schumacher , Samuel Evans , Paul Dubs
IPC分类号： C10M129/10 , C10M133/00 , C10M133/02 , C10M133/04 , C10M133/06 , C10M133/12 , C10M133/14 , C10M133/40 , C10M135/22 , C10M137/02 , C10M137/04 , C10M141/08 , C10M141/10 , C10M141/12 , C10N30/10 , C10N40/25
CPC分类号： C10M133/02 , C10M141/08 , C10M141/10 , C10M2207/023 , C10M2207/024 , C10M2207/026 , C10M2207/027 , C10M2207/287 , C10M2215/00 , C10M2215/06 , C10M2215/062 , C10M2215/064 , C10M2215/065 , C10M2215/066 , C10M2215/067 , C10M2215/068 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/12 , C10M2215/122 , C10M2215/18 , C10M2215/22 , C10M2215/221 , C10M2215/222 , C10M2215/225 , C10M2215/226 , C10M2215/28 , C10M2215/30 , C10M2217/00 , C10M2217/02 , C10M2217/028 , C10M2217/04 , C10M2217/042 , C10M2217/043 , C10M2217/044 , C10M2217/045 , C10M2217/06 , C10M2219/06 , C10M2219/083 , C10M2219/084 , C10M2219/085 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/106 , C10M2219/108 , C10M2223/04 , C10M2223/042 , C10M2223/065 , C10M2227/04 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： A lubricant based on a mineral or synthetic oil is stabilized against oxidative degradation by the addition of a mixture comprising at least one specified aromatic amine of the formula I ##STR1## and at least one sterically hindered amine. The lubricant may contain other antioxidants or other additives. It is preferably used as motor oil.
摘要翻译：基于矿物或合成油的润滑剂通过加入包含至少一种具有式I（I）的特定芳族胺和至少一种空间位阻胺的混合物来稳定，防止氧化降解。润滑剂可能含有其他抗氧化剂或其他添加剂。优选用作机油。

30. 发明授权

US4963276A Lubricant composition 失效
标题翻译：润滑油组成
公开(公告)号：US4963276A
公开(公告)日：1990-10-16
申请号：US284568
申请日：1988-12-15
申请人： Samuel Evans
发明人： Samuel Evans
IPC分类号： C10M141/08 , C10N30/10 , C10N40/08
CPC分类号： C10M141/08 , C10M2215/06 , C10M2215/064 , C10M2215/065 , C10M2215/066 , C10M2215/067 , C10M2215/068 , C10M2219/08 , C10M2219/082 , C10M2219/084 , C10M2219/085 , C10M2219/086 , C10M2219/087 , C10M2219/088 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2219/108 , C10N2240/08
摘要： Composition containing at least one lubricant, for example based on mineral oils, synthetic oils or mixtures thereof or a hydraulic fluid and a mixture of one or more compounds from series (A) and one or more compounds from series (B), the compounds of series (A) having the general formula ##STR1## and the compounds of series (B) having the general formula ##STR2## in which the radicals R.sup.1 and R.sup.1 ' are, for example, --H or alkyl having 1 to 24 C atoms and n is 0, 1 or 2, R.sup.2 and R.sup.3 are, for example, --H, alkyl having 1 to 24 C atoms or phenyl or R.sup.2 and R.sup.3 together are an alkylene group, and R.sup.4 is, for example, an alkyl group having 4-18 C atoms or a radical ##STR3## in which R.sup.5 can be an alkyl group, and R.sup.4' is an alkylene group and Y is O or S. The mixture imparts a high stability towards oxidative degradation to lubricant compositions.
摘要翻译：含有至少一种润滑剂的组合物，例如基于矿物油，合成油或其混合物，或液压油和一种或多种来自（A）系列化合物和一种或多种来自（B）系列化合物的化合物的混合物，具有通式（I）的系列（A）和具有通式（IMAGE）（II）的化合物或其中基团R 1和R 1'为（IMA）例如-H或具有1至24个C原子且n为0,1或2的烷基，R 2和R 3为例如-H，具有1至24个碳原子的烷基或苯基或R 2和R 3一起为亚烷基 R4是例如具有4-18个碳原子的烷基或其中R5可以是烷基，R4'是亚烷基并且Y是O或S的基团“基团”。该混合物赋予对润滑剂组合物的氧化降解的高稳定性。

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