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    • 23. 发明授权
    • Process for the preparation of ether-sulphonates
    • 醚磺酸盐的制备方法
    • US5523471A
    • 1996-06-04
    • US520712
    • 1995-08-29
    • Klaus DelpyFritz EngelhardtRalf ZerrerDirk Buhring
    • Klaus DelpyFritz EngelhardtRalf ZerrerDirk Buhring
    • B01J23/04C07B61/00C07C303/32C07C309/10C07C381/00
    • C07C303/32
    • The present invention relates to a process for the preparation of ether-sulphonates of high purity, substantially free from extraneous salts, of the general formula IR.sup.1 --[O--(CR.sup.2 R.sup.2 R.sup.2' --CR.sup.5 R.sup.5' SO.sub.3 MIin whichR.sup.2 to R.sup.5, R.sup.2+ to R.sup.5', M, x and y are defined as given in claim 1 by reacting a compound of the general formula IIR.sup.1 --[O--(CR.sup.2 R.sup.2+ --CR.sup.3 R.sup.3').sub.x ].sub.y --OHIIwith a compound of the general formula IIIHO--CR.sup.4 R.sup.4' CR.sup.5 R.sup.5' --SO.sub.3 M IIIin the presence of a compound of the general formula IVMOH IVfollowed by neutralization of the compound of the general formula IV with an acid, characterized in that the acid employed is a compound of the general formula VR.sup.1 --[O--(CR.sup.2 R.sup.2' --CR.sup.3 R.sup.3').sub.x ].sub.y --OCR.sup.4 R.sup.4' CR.sup.5 R.sup.5' SO.sub.3 H V
    • 本发明涉及一种制备基本上不含外来盐的通式ⅠR1- [O-(CR2R2R2'-CR5R5'SO3MI)的高纯度醚 - 磺酸盐的方法,其中R2至R5,R2 +至R5 ',M,x和y定义如权利要求1中所述,通式II的化合物R1- [O-(CR2R2 + -CR3R3')x] y-OHII与通式III的化合物HO-CR4R4 在通式IV MOHIV的化合物的存在下,用酸中和所述通式IV的化合物,其特征在于所用的酸是通式为R 1 - [O - (CR2R2'-CR3R3')x] y-OCR4R4'CR5R5'SO3HV