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1. 发明授权

US5523471A Process for the preparation of ether-sulphonates 失效
标题翻译：醚磺酸盐的制备方法
公开(公告)号：US5523471A
公开(公告)日：1996-06-04
申请号：US520712
申请日：1995-08-29
申请人： Klaus Delpy , Fritz Engelhardt , Ralf Zerrer , Dirk Buhring
发明人： Klaus Delpy , Fritz Engelhardt , Ralf Zerrer , Dirk Buhring
IPC分类号： B01J23/04 , C07B61/00 , C07C303/32 , C07C309/10 , C07C381/00
CPC分类号： C07C303/32
摘要： The present invention relates to a process for the preparation of ether-sulphonates of high purity, substantially free from extraneous salts, of the general formula IR.sup.1 --[O--(CR.sup.2 R.sup.2 R.sup.2' --CR.sup.5 R.sup.5' SO.sub.3 MIin whichR.sup.2 to R.sup.5, R.sup.2+ to R.sup.5', M, x and y are defined as given in claim 1 by reacting a compound of the general formula IIR.sup.1 --[O--(CR.sup.2 R.sup.2+ --CR.sup.3 R.sup.3').sub.x ].sub.y --OHIIwith a compound of the general formula IIIHO--CR.sup.4 R.sup.4' CR.sup.5 R.sup.5' --SO.sub.3 M IIIin the presence of a compound of the general formula IVMOH IVfollowed by neutralization of the compound of the general formula IV with an acid, characterized in that the acid employed is a compound of the general formula VR.sup.1 --[O--(CR.sup.2 R.sup.2' --CR.sup.3 R.sup.3').sub.x ].sub.y --OCR.sup.4 R.sup.4' CR.sup.5 R.sup.5' SO.sub.3 H V
摘要翻译：本发明涉及一种制备基本上不含外来盐的通式ⅠR1- [O-（CR2R2R2'-CR5R5'SO3MI）的高纯度醚 - 磺酸盐的方法，其中R2至R5，R2 +至R5 '，M，x和y定义如权利要求1中所述，通式II的化合物R1- [O-（CR2R2 + -CR3R3'）x] y-OHII与通式III的化合物HO-CR4R4 在通式IV MOHIV的化合物的存在下，用酸中和所述通式IV的化合物，其特征在于所用的酸是通式为R 1 - [O - （CR2R2'-CR3R3'）x] y-OCR4R4'CR5R5'SO3HV

2. 发明授权

US5530093A Polycondensates containing phosphinic and phosphonic acid groups 失效
标题翻译：含有次膦酸和膦酸基的缩聚物
公开(公告)号：US5530093A
公开(公告)日：1996-06-25
申请号：US380388
申请日：1995-01-30
申请人： Fritz Engelhardt , Willi Steckelberg , Karl-Heinz Keil , Ralf Zerrer
发明人： Fritz Engelhardt , Willi Steckelberg , Karl-Heinz Keil , Ralf Zerrer
IPC分类号： C08G63/692 , C08G79/02 , C08G79/04 , D06M15/507 , D06M15/667
CPC分类号： C08G63/6926 , D06M15/507 , D06M15/667
摘要： ##STR1## in which X denotes ##STR2## and the other variables are defined as indicated in claim 1, processes for their preparation and their use.
摘要翻译：（I）其中X表示，其他变量如权利要求1所述定义，其制备过程及其用途。

3. 发明授权

US5488123A Polycondensates containing polysiloxane groups 失效
标题翻译：含聚硅氧烷基团的缩聚物
公开(公告)号：US5488123A
公开(公告)日：1996-01-30
申请号：US384404
申请日：1995-02-06
申请人： Fritz Engelhardt , Jurgen Kuhlwein , Wilfried Schuler , Ralf Zerrer , Werner Antwerpen
发明人： Fritz Engelhardt , Jurgen Kuhlwein , Wilfried Schuler , Ralf Zerrer , Werner Antwerpen
IPC分类号： C08G63/68 , C08G63/695 , C08G77/42 , C08G77/445 , C07F7/08
CPC分类号： C08G77/445 , C08G63/6956 , Y10S8/01 , Y10S8/08
摘要： The present invention relates to polycondensates of the general formula I ##STR1## in which ##STR2## and the other variables are defined as indicated in claim 1, processes for their preparation and their use.
摘要翻译：本发明涉及通式I（I）的缩聚物，其中“IMAGE”和其它变量如权利要求1所述定义，其制备方法及其用途。

4. 发明授权

US5492995A Polycondensates containing phosphinic or phosphonic acid groups and siloxane groups 失效
标题翻译：含有次膦酸基或膦酸基和硅氧烷基的缩聚物
公开(公告)号：US5492995A
公开(公告)日：1996-02-20
申请号：US383833
申请日：1995-02-06
申请人： Fritz Engelhardt , Karl-Heinz Keil , Jurgen Kuhlwein , Wilfried Schuler , Willi Steckelberg , Ralf Zerrer , Werner Antwerpen
发明人： Fritz Engelhardt , Karl-Heinz Keil , Jurgen Kuhlwein , Wilfried Schuler , Willi Steckelberg , Ralf Zerrer , Werner Antwerpen
IPC分类号： C08G63/68 , C08G63/692 , C08G63/695 , C08G77/42 , C08G77/445 , C08G79/02 , C08G79/04 , C08G77/395
CPC分类号： C08G77/445 , C08G63/6926 , C08G63/6956 , C08G79/04 , Y10S8/01
摘要： The present invention relates to polycondensates of the general formula I ##STR1## in which X stands, at least once, for a group of the formula VII ##STR2## and, at least once, a group of the formula VIII ##STR3## and the other variables are defined as indicated in claim 1, processes for their preparation and their use.
摘要翻译：本发明涉及通式Ⅰ（I）的缩聚物，其中X表示至少一次式VII（VII）的基团，并且至少一次是式（VIII），其它变量如权利要求1所述定义，其制备方法及其用途。

5. 发明申请

US20090216043A1 Arylglycerine Ether 审中-公开
标题翻译：芳基甘油醚
公开(公告)号：US20090216043A1
公开(公告)日：2009-08-27
申请号：US11922855
申请日：2006-06-22
申请人： Joachim Hess , Ralf Zerrer , Franz-Xaver Scherl , Christian Sowa
发明人： Joachim Hess , Ralf Zerrer , Franz-Xaver Scherl , Christian Sowa
IPC分类号： C07C43/115 , C07C309/12
CPC分类号： B01F17/0021 , B01F17/0028 , B01F17/0042 , B01F17/005 , B01F17/0057 , B01F17/0064 , C07C43/1785 , C07C43/23
摘要： The invention relates to aromatically substituted glycerine ethers of formula (I), wherein at least one of the radicals R1, R2, or R3 is or contains an aromatic group. Said compounds can be used, preferably, as surface-active agents.
摘要翻译：本发明涉及式（I）的芳族取代的甘油醚，其中基团R 1，R 2或R 3中的至少一个是或含有芳族基团。所述化合物可优选用作表面活性剂。

6. 发明申请

US20060142162A1 Pesticide formulations containing alkoxylated amines 审中-公开
标题翻译：含有烷氧基化胺的农药制剂
公开(公告)号：US20060142162A1
公开(公告)日：2006-06-29
申请号：US10533474
申请日：2003-10-22
申请人： Franz Scherl , Joachim Hess , Ralf Zerrer
发明人： Franz Scherl , Joachim Hess , Ralf Zerrer
IPC分类号： A01N57/18 , A01N25/10
CPC分类号： A01N57/20 , A01N25/30
摘要： The invention relates in particular to compositions comprising one or more pesticides and one or more alkoxylated amines. The compositions have an improved effectiveness and are simultaneously economical, simple to handle and well tolerated by man and the environment.
摘要翻译：本发明特别涉及包含一种或多种农药和一种或多种烷氧基化胺的组合物。组合物具有改进的有效性并且同时经济，易于处理并且被人和环境良好耐受。

7. 发明申请

US20050085391A1 Aqueous plant-protection formulations 审中-公开
标题翻译：含水植物保护制剂
公开(公告)号：US20050085391A1
公开(公告)日：2005-04-21
申请号：US10500025
申请日：2002-12-17
申请人： Gerd Meyer , Ralf Zerrer , Roman Morschhaeuser
发明人： Gerd Meyer , Ralf Zerrer , Roman Morschhaeuser
IPC分类号： A01N25/02 , A01N57/20 , A01N25/10
CPC分类号： A01N25/02 , A01N57/20 , A01N25/30 , A01N25/10 , A01N2300/00
摘要： The invention relates to aqueous plant protection formulations comprising water-soluble pesticides, agrochemical salts and polymers based on acrylamidopropylmethylenesulfonic acid (AMPS) and “macromonomers”. The formulations show high solubility of the pesticides and of the agrochemical salts, and excellent stability on storage. The addition of the polymers improves the compatibility and solubility in water of the pesticides and agrochemical salts. Salting-out effects are suppressed or minimized. The formulations are preferably concentrated formulations, preferably soluble liquids (SL) and soluble concentrates.
摘要翻译：本发明涉及包含水溶性农药，农用化学盐和基于丙烯酰胺丙基甲基磺酸（AMPS）和“大分子单体”）的聚合物的含水植物保护制剂。制剂显示出高度的农药和农药盐的溶解度，并且在储存时具有优异的稳定性。聚合物的添加改善了农药和农药盐在水中的相容性和溶解度。盐析效应被抑制或最小化。制剂优选是浓缩制剂，优选可溶性液体（SL）和可溶性浓缩物。

8. 发明申请

US20060264330A1 Agricultural agents containing copolymers 审中-公开
公开(公告)号：US20060264330A1
公开(公告)日：2006-11-23
申请号：US10546504
申请日：2004-02-13
申请人： Ralf Zerrer , Franz-Xaver Scherl
发明人： Ralf Zerrer , Franz-Xaver Scherl
IPC分类号： A01N25/10
CPC分类号： A01N25/30 , A01N2300/00
摘要： The present invention relates to agricultural compositions comprising: A) a pesticide or a plant growth regulator B) a copolymer made of a) a polyglycerol ether b) one or more dicarboxylic acid(s) and/or polycarboxylic acids, wherein the polyglycerol ethers being defined by the formula (I) wherein the radicals R1, R2 and R3 are independently identical or different and represent hydrogen; (C1-C30)-alkyl which is optionally substituted by 1 to 3 (C1-C4)-alkyl or (C1-C4)-alkoxy groups; (C2-C30)-alkenyl which is optionally sulfonated and optionally substituted by 1 to 3 (C1-C4)-alkyl or (C1-C4)-alkoxy groups; phenyl which is optionally substituted by 1 to 3 (C1-C4)-alkyl or (C1-C4)-alkoxy groups; naphthyl which is optionally substituted by 1 to 3 (C1-C4)-alkyl or (C1-C4)-alkoxy groups; groups of the formulae R4R5N—(CH2)y—; HO—(CH2)y—; -(AO)zH; —SO3H; —SO3−X+; —PO3H2; —PO32−X+; —CR2—COOR′; —CR2—COO−X+; —CO—R6—COOH; —CO—R6—COO−X+; —C(R)2C(R)2C(R)2—N(R)2; —C(R)2C(R)2C(R)2—N((AO)zH)2; —[CH2CH(O(AO)zH)CH2O]n—R1; where R represents H and/or C1-C4-alkyl; R′ represents H or (C1-C10)-alkyl, (C2-C30)-alkenyl, optionally sulfonated; R4 and R5, which can be identical or different, represent hydrogen, (C1-C10)-alkyl, (C2-C30)-alkenyl, optionally sulfonated, or a group of the formula -(AO)zH; R6 represents (C1-C10)-alkylene, (C2-C30)-alkenylene, optionally sulfonated; X+ represents Na+, K+, Ca2+ or N(R7)4+, where R7 represents H or (C1-C10)-alkyl, preferably (C1-C4)-alkyl; x represents a number from 0 to 15; y represents a number from 4 to 6; z represents a number from 0 to 30, preferably 1 to 5; A represents an alkylene group, preferably a group —C2H4—, —C3H6— or —C4H8—; n represents a number from 4 to 40, preferably 5 to 20, in particular 10 to 20; and the indices p1, q1, r1, p2, q2, r2, p3, q3 and r3 represent numbers from 0 to 500; with the proviso that the compounds of the formula (I) comprise free OH groups, and at least one of the radicals R1, R2 and R3 represents a hydrocarbon group, preferably (C1-C30)-alkyl.

9. 发明申请

US20060030486A1 Crystallization inhibitor for plant-protective formulations 审中-公开
标题翻译：用于植物保护制剂的结晶抑制剂
公开(公告)号：US20060030486A1
公开(公告)日：2006-02-09
申请号：US11242220
申请日：2005-10-03
申请人： Gerd Meyer , Ralf Zerrer , Roman Morschhaeuser
发明人： Gerd Meyer , Ralf Zerrer , Roman Morschhaeuser
IPC分类号： A01N63/00
CPC分类号： C08F291/00 , C08F265/00 , C08F265/10 , C08F290/06 , C08L51/00 , C08L2666/02
摘要： The invention relates to the use of polymers based on acrylamidopropylmethylenesulfonic acid (AMPS) and macromonomers as crystallization inhibitor for plant protection formulations. The polymers inhibit crystallization of the pesticidal active substances (herbicides, insecticides, fungicides, acaricides, bactericides, molluscicides, nematicides and rodenticides) present in the plant protection formulations. The use in the case of emulsifiable concentrates (EC) and suspension concentrates (SC) is particularly advantageous.
摘要翻译：本发明涉及使用基于丙烯酰胺丙基甲基磺酸（AMPS）和大分子单体的聚合物作为植物保护制剂的结晶抑制剂。聚合物抑制植物保护制剂中存在的杀虫活性物质（除草剂，杀虫剂，杀真菌剂，杀螨剂，杀菌剂，杀软体动物剂，杀线虫剂和杀鼠剂）的结晶。在可乳化浓缩物（EC）和悬浮浓缩物（SC）的情况下的用途是特别有利的。

10. 发明授权

US06391962B1 Copolymers and their use as drift control agents 有权
公开(公告)号：US06391962B1
公开(公告)日：2002-05-21
申请号：US09784536
申请日：2001-02-15
申请人： Ralf Zerrer , Rainer Kupfer
发明人： Ralf Zerrer , Rainer Kupfer
IPC分类号： C08K500
摘要： What is claimed are copolymers consisting essentially of from 1 to 90% by weight of the repetitive structural unit of the formula (1) in which R1 is hydrogen or methyl, Z is a C1-C4-alkylene group and X is hydrogen, an alkali metal or ammonium, from 10 to 99% by weight of a repetitive structural unit which is derived from olefinically unsaturated comonomers containing at least one oxygen, nitrogen, sulfur or phosphorus atom and from 0 to 20% by weight of crosslinking structures originating from monomers having at least two olefinic double bonds. These copolymers are suitable for use as drift control agents for crop protection compositions.

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