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21. 发明授权

US07026390B2 Extended binder compositions 有权
标题翻译：延伸粘合剂组合物
公开(公告)号：US07026390B2
公开(公告)日：2006-04-11
申请号：US10325017
申请日：2002-12-19
申请人： Frank C. O'Brien-Bernini , Liang Chen , Yadollah Delaviz , Kathleen M. Bullock , William E. Downey
发明人： Frank C. O'Brien-Bernini , Liang Chen , Yadollah Delaviz , Kathleen M. Bullock , William E. Downey
IPC分类号： C08B30/00 , C08B37/00 , C08L89/00 , C08L97/00
CPC分类号： C09J133/04 , C08L97/005 , C08L2666/26 , D04H1/587 , D04H1/64
摘要： The present invention provides a variety of extended polyacrylic acid based binder compositions comprising a low molecular weight polyacrylic acid (typically hypophosphite or sulfite terminated), a crosslinking agent (such as triethanolamine or glycerol) and one or more water soluble materials, such as lignin, low molecular weight starch and soybean protein. The extended binder composition of the present invention provides a lower cost binder composition without degrading the performance and may be selected to alter one or more characteristics of the basic binder composition such binder wetting, emulsion compatibility, dust suppression and wash water flow properties.
摘要翻译：本发明提供了多种延伸的基于聚丙烯酸的粘合剂组合物，其包含低分子量聚丙烯酸（通常为次亚磷酸酯或亚硫酸酯封端的），交联剂（例如三乙醇胺或甘油）和一种或多种水溶性材料，例如木质素，低分子量淀粉和大豆蛋白。本发明的延伸的粘合剂组合物提供了较低成本的粘合剂组合物，而不会降低性能，并且可以选择以改变碱性粘合剂组合物的一种或多种特性，例如粘合剂润湿，乳液相容性，粉尘抑制和洗涤水流动性质。

22. 发明授权

US08754143B2 Polystyrene/polyethylene oxide copolymer for enhancing water vapor permeability in thermoplastic foam 有权
标题翻译：聚苯乙烯/聚环氧乙烷共聚物，用于提高热塑性泡沫塑料中的水蒸气渗透性
公开(公告)号：US08754143B2
公开(公告)日：2014-06-17
申请号：US13769647
申请日：2013-02-18
申请人： Yadollah Delaviz , Raymond M. Breindel , Mitchell Z. Weekley , John F. Budinscak, Jr.
发明人： Yadollah Delaviz , Raymond M. Breindel , Mitchell Z. Weekley , John F. Budinscak, Jr.
IPC分类号： B22C1/22 , C08J9/00
CPC分类号： C08J9/146 , C08J9/0061 , C08J9/0066 , C08J9/12 , C08J9/141 , C08J9/142 , C08J2205/052 , C08J2205/10 , C08J2325/06 , C08J2425/00
摘要： Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, a polystyrene/polyethylene oxide copolymer, and optionally, an infrared attenuating agent, are provided. In exemplary embodiments, the blowing agent includes at least one hydrofluorocarbon blowing agent. The maleic anhydride-styrene copolymer grafted with polyethylene oxide provides a water vapor permeability of 1.1 perm inch or greater in the extruded foam product without detrimentally affecting physical or thermal properties of the product. Additionally, the copolymer of maleic anhydride-styrene grafted with polyethylene oxide has a positive affect on the processability of the blowing agent(s) in the composition by both widening the process window and enhancing the solubility of the blowing agent in the polymer melt. Thus, the polystyrene/polyethylene oxide copolymer present in the inventive composition acts as a cell enlarger, a plasticizer, and a processing aid. A method of forming an extruded foam product is also provided.
摘要翻译：提供含有可发泡聚合物材料，至少一种发泡剂，聚苯乙烯/聚环氧乙烷共聚物和任选的红外衰减剂的聚合物泡沫和聚合泡沫产品。在示例性实施方案中，发泡剂包括至少一种氢氟烃发泡剂。用聚环氧乙烷接枝的马来酸酐 - 苯乙烯共聚物在挤出的泡沫产品中提供1.1 perm英寸或更大的水蒸汽透过率，而不会有害地影响产品的物理或热性能。此外，接枝聚环氧乙烷的马来酸酐 - 苯乙烯的共聚物通过加工工艺窗口和提高发泡剂在聚合物熔体中的溶解度而对组合物中的发泡剂的加工性具有积极的影响。因此，存在于本发明组合物中的聚苯乙烯/聚环氧乙烷共聚物用作电池放大器，增塑剂和加工助剂。还提供了一种形成挤出泡沫产品的方法。

23. 发明申请

US20110144221A1 Extruded Polystyrene Foam Containing Propylene Carbonate, Ethylene Carbonate or Butylene Carbonate as a Process Aids 审中-公开
标题翻译：包含碳酸丙烯酯，碳酸亚乙酯或碳酸亚丁酯作为加工助剂的挤出聚苯乙烯泡沫
公开(公告)号：US20110144221A1
公开(公告)日：2011-06-16
申请号：US12996032
申请日：2008-06-04
申请人： Yadollah Delaviz , Raymond Marshall Breindel , Mitchell Z. Weekley
发明人： Yadollah Delaviz , Raymond Marshall Breindel , Mitchell Z. Weekley
IPC分类号： C08J9/00 , B82Y30/00
CPC分类号： C08J9/0066 , C08J9/0014 , C08J9/0061 , C08J9/0071 , C08J9/12 , C08J2201/03 , C08J2203/142 , C08J2205/052 , C08J2325/04 , C08J2495/00
摘要： Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one hydrofluorocarbon (HFC) blowing agent, an infrared attenuating agent such as nanographite, and propylene carbonate, ethylene carbonate, or butylene carbonate as a process additive are provided. In one or more embodiments, the HFC blowing agent is 1,1-difluoroethane (HFC-152a), 1,1,1,2-tetrafluoroethane (HFC-134a), or a combination of 1,1-difluoroethane (HFC-152a) and 1,1,1,2-tetrafluoroethane (HFC-134a). The propylene carbonate, ethylene carbonate, or butylene carbonate acts as a cell enlarger to increase the average cell size of the foamed product, as a process aid, as a plasticizer, and lowers the die pressure. The inventive foam composition produces extruded foams that have insulation values (R-values) that are equal to or better than conventional extruded, closed cell foams produced with 1-chloro-1,1-difluoroethane (HCFC-142b). In exemplary embodiments, less than 4% of the cells are open cells. A method of forming an extruded foam product is also provided.
摘要翻译：提供含有可发泡聚合物材料，至少一种氢氟烃（HFC）发泡剂，红外衰减剂如纳米石墨和碳酸亚丙酯，碳酸亚乙酯或碳酸亚丁酯作为加工添加剂的聚合物泡沫和聚合物泡沫产品。在一个或多个实施方案中，HFC发泡剂是1,1-二氟乙烷（HFC-152a），1,1,1,2-四氟乙烷（HFC-134a）或1,1-二氟乙烷（HFC-152a ）和1,1,1,2-四氟乙烷（HFC-134a）。碳酸亚丙酯，碳酸亚乙酯或碳酸亚丁酯充当电池放大器，以增加发泡产品的平均泡孔尺寸作为加工助剂作为增塑剂，并降低模具压力。本发明的泡沫组合物产生具有等于或优于用1-氯-1,1-二氟乙烷（HCFC-142b）生产的常规挤出的闭孔泡沫的绝缘值（R值）的挤出泡沫。在示例性实施例中，小于4％的细胞是开放细胞。还提供了一种形成挤出泡沫产品的方法。

24. 发明授权

US5420225A Aramid compositions of improved solubility and flame retardancy 失效
标题翻译：芳族聚酰胺组合物具有改善的溶解性和阻燃性
公开(公告)号：US5420225A
公开(公告)日：1995-05-30
申请号：US736541
申请日：1991-07-26
申请人： Attila Gungor , James E. McGrath , Yadollah Delaviz , Harry W. Gibson
发明人： Attila Gungor , James E. McGrath , Yadollah Delaviz , Harry W. Gibson
IPC分类号： C08G69/32 , C08G69/42 , C08G79/02
CPC分类号： C08G69/32 , C08G69/42
摘要： Aramid polymers, e.g., those derived from p-phenylene diamine and terephthaloyl chloride, can have their solubility properties and flame retardancy enhanced by the incorporation therein of a moiety derived from a bis(aminophenoxyphenyl) phosphine oxide, e.g., bis(3-aminophenoxy-4'-phenyl) phenylphosphine oxide.
摘要翻译：芳族聚酰胺聚合物，例如衍生自对苯二胺和对苯二甲酰氯的聚酰胺聚合物，可以通过引入衍生自双（氨基苯氧基苯基）氧化膦的部分，例如双（3-氨基苯氧基 - 4'-苯基）苯基氧化膦。

25. 发明申请

US20070299152A1 Cell size enlargers for polystyrene foams 有权
标题翻译：聚苯乙烯泡沫的泡孔尺寸放大器
公开(公告)号：US20070299152A1
公开(公告)日：2007-12-27
申请号：US11472772
申请日：2006-06-22
申请人： Bharat Patel , Yadollah Delaviz , Raymond M. Breindel , Mitchell Z. Weekley , Roland R. Loh , Manoj K. Choudhary
发明人： Bharat Patel , Yadollah Delaviz , Raymond M. Breindel , Mitchell Z. Weekley , Roland R. Loh , Manoj K. Choudhary
IPC分类号： C08J9/00
CPC分类号： C08J9/0061 , C08J9/0014 , C08J2325/06 , C08J2423/00 , C08J2471/00
摘要： Polymer extruded foams that contain cell size enlarging agents are provided. The inventive composition includes a foamable polymer material, at least one blowing agent, and at least one cell size enlarging agent. The blowing agent utilized in the inventive composition is preferably selected such that the composition has a zero ozone depletion and low global warming potential. Examples include any inorganic blowing agents and/or non-hydrogenated chlorofluorocarbons (non-HCFCs). The foamable polymer material is preferably polystyrene. The cell size enlarging agent may be chosen from ethylene vinyl acetate (EVA) and/or ethylene methyl acrylate (EMA). The cell size enlarging agent permits the formation of a foam with large cell sizes that are desirable to achieve a high insulation value and to optimize the physical properties of the foamed product. In addition, the cell size enlarging agent provides an increased cell size to the foamed product without detracting from the physical and thermal properties.
摘要翻译：提供了含有电池尺寸扩大剂的聚合物挤出泡沫体。本发明的组合物包括可发泡聚合物材料，至少一种发泡剂和至少一种细胞尺寸扩大剂。本发明组合物中使用的发泡剂优选地选择成使得组合物具有零臭氧消耗和低的全球变暖潜能。实例包括任何无机发泡剂和/或非氢化氯氟烃（非HCFC）。可发泡聚合物材料优选为聚苯乙烯。电池尺寸扩大剂可以选自乙烯乙酸乙烯酯（EVA）和/或乙烯丙烯酸甲酯（EMA）。电池尺寸扩大剂允许形成具有大电池尺寸的泡沫，这是希望达到高绝缘值并优化发泡产品的物理性能的泡沫。此外，电池尺寸扩大剂为发泡产品提供增加的电池尺寸，而不会降低物理和热性能。

26. 发明授权

US06706808B2 Binder compositions exhibiting reduced emissions 有权
标题翻译：粘合剂组合物表现出减少的排放
公开(公告)号：US06706808B2
公开(公告)日：2004-03-16
申请号：US09368056
申请日：1999-08-03
申请人： Yadollah Delaviz , Susan Muench , Kathleen Bullock
发明人： Yadollah Delaviz , Susan Muench , Kathleen Bullock
IPC分类号： C08J300
CPC分类号： C09J161/14 , C03C25/34 , C08G8/28 , C08G14/08 , C08K5/34922 , C08K5/42 , C08L61/14 , C08L61/34 , C08L61/00
摘要： The presently disclosed invention relates to a phenolic binder comprising a premix of a urea modified phenol-formaldehyde resole resin, a curing agent, and an additive selected from the group consisting of ammonium lignosulfonate, melamine and a melamine derivative. A method for reducing gaseous emissions in the manufacture of fibrous insulation materials is also disclosed.
摘要翻译：本公开的本发明涉及一种酚类粘合剂，其包含脲改性酚醛甲醛树脂预固化剂，固化剂和选自木素磺酸铵，三聚氰胺和三聚氰胺衍生物的添加剂。还公开了一种在制造纤维绝缘材料中减少气体排放的方法。

27. 发明授权

US06699945B1 Polycarboxylic acid based co-binder 有权
标题翻译：聚羧酸基共粘合剂
公开(公告)号：US06699945B1
公开(公告)日：2004-03-02
申请号：US10308427
申请日：2002-12-03
申请人： Liang Chen , Kathleen M. Bullock , William E. Downey , Michael T. Pellegrin , Yadollah Delaviz , Kevin Guigley , Harry B. Cline
发明人： Liang Chen , Kathleen M. Bullock , William E. Downey , Michael T. Pellegrin , Yadollah Delaviz , Kevin Guigley , Harry B. Cline
IPC分类号： C08F2000
CPC分类号： C08G63/12 , C03C25/285 , C03C25/323 , C03C25/328 , C08F8/14 , C08F2810/20 , C08F2810/30 , C08G63/16
摘要： A formaldehyde free co-binder solution formed by using a polyol to crosslink polycarboxylic acid and a polyacid monomer is provided. In forming the co-binder solution, the polyacid monomer and the polyol are mixed in any conventional device with heat and agitation for a period of time sufficient for the chemicals to react and form a reaction product. The resultant product is then admixed with polycarboxylic acid to form a co-binder solution. In a preferred embodiment, the polyacid is maleic anhydride and the polyol is triethanolamine.
摘要翻译：提供了通过使用多元醇交联多元羧酸和多元酸单体形成的不含甲醛的共粘合剂溶液。在形成共粘合剂溶液中，多酸单体和多元醇在任何常规装置中在热和搅拌下混合一段足以使化学品反应并形成反应产物的时间。然后将所得产物与多元羧酸混合以形成共粘合剂溶液。在优选的实施方案中，多酸是马来酸酐，多元醇是三乙醇胺。

28. 发明授权

US5331098A Mono- and di(functionally-substituted phenylene) semi-rigid crowns and precursors thereof 失效
标题翻译：单 - 和二（功能取代的亚苯基）半刚性冠及其前体
公开(公告)号：US5331098A
公开(公告)日：1994-07-19
申请号：US902185
申请日：1992-06-22
申请人： Harry W. Gibson , Yadollah Delaviz
发明人： Harry W. Gibson , Yadollah Delaviz
IPC分类号： C07D323/00 , C08G18/32 , C08G18/77 , C08G63/185 , C08G63/193 , C08G69/26 , C08G71/02
CPC分类号： C07D323/00 , C08G18/3215 , C08G18/771 , C08G63/185 , C08G63/193 , C08G69/26 , C08G71/02
摘要： Bis(carboalkoxy-substituted m-phenylene)-32-crown-10 compounds, useful as polymerizable monomers, can be formed in one step by reacting a functionalized dihydroxy aromatic compound with a dihalopolyether. In the same reaction, carboalkoxy-substituted m-phenylene-16-crown-5 is formed. Other mono- and di-functionalized bis(phenylene) crown ethers can be made by one step as well as multistep synthesis from similar starting materials.
摘要翻译：可以通过使官能化的二羟基芳族化合物与二卤代聚醚反应，在一个步骤中形成可用作可聚合单体的双（烷氧基取代的间 - 亚苯基）-32-冠-10化合物。在相同的反应中，形成了烷氧基取代的亚苯基-16-冠-5。其他单 - 和二官能化双（亚苯基）冠醚可以通过一步制备，以及从相似起始原料进行多步合成。

29. 发明授权

US5302729A Dibenzo crown monomers and polymers formed therefrom 失效
标题翻译：二苯基冠单体和由其形成的聚合物
公开(公告)号：US5302729A
公开(公告)日：1994-04-12
申请号：US686087
申请日：1991-04-16
申请人： Harry W. Gibson , Yadollah Delaviz
发明人： Harry W. Gibson , Yadollah Delaviz
IPC分类号： C07D323/00 , C08G18/32 , C08G18/77 , C08G63/185 , C08G63/193 , C08G69/26 , C08G71/02
CPC分类号： C08G18/771 , C07D323/00 , C08G18/3215 , C08G63/185 , C08G63/193 , C08G69/26 , C08G71/02
摘要： Novel bis(extraannular functionally-substituted phenylene) crown compounds, useful as chelating agents or in the synthesis of condensation polymers containing large semi-rigid macrocycles in the polymer backbone, are described. A broad range of functional groups (preferably in the 5-position) can be used in the 1,3-phenylene varieties. Carboxy functional groups are used in certain novel 1,2-phenylene crowns.
摘要翻译：描述了可用作螯合剂或在聚合物主链中合成含有大的半刚性大环的缩合聚合物的新型双（全功能取代的亚苯基）冠化合物。可以在1,3-亚苯基品种中使用宽范围的官能团（优选在5位）。羧基官能团用于某些新型1,2-亚苯基冠。

30. 发明授权

US5142068A Mono- and Di(functionally-substituted phenylene) semi-rigid crowns and processes for making 失效
标题翻译：单功能和DI（功能取代的苯乙烯）半刚性冲击和制造工艺
公开(公告)号：US5142068A
公开(公告)日：1992-08-25
申请号：US574633
申请日：1990-08-29
申请人： Harry W. Gibson , Yadollah Delaviz
发明人： Harry W. Gibson , Yadollah Delaviz
IPC分类号： C07D323/00 , C08G18/32 , C08G18/77 , C08G63/185 , C08G63/193 , C08G69/26 , C08G71/02
CPC分类号： C07D323/00 , C08G18/3215 , C08G18/771 , C08G63/185 , C08G63/193 , C08G69/26 , C08G71/02
摘要： Bis(carboalkoxy-substituted m-phenylene)-32-crown-10 compounds, useful as polymerizable monomers, can be formed in one step by reacting a functionalized dihydroxy aromatic compound with a dihalopolyether. In the same reaction, carboalkoxy-substituted m-phenylene-16-crown-5 is formed. Other mono- and di-functionalized bis(phenylene) crown ethers can be made by one step as well as multistep synthesis from similar starting materials.
摘要翻译：可以通过使官能化的二羟基芳族化合物与二卤代聚醚反应，在一个步骤中形成可用作可聚合单体的双（烷氧基取代的间 - 亚苯基）-32-冠-10化合物。在相同的反应中，形成了烷氧基取代的亚苯基-16-冠-5。其他单 - 和二官能化双（亚苯基）冠醚可以通过一步制备，以及从相似起始原料进行多步合成。

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