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    • 21. 发明申请
    • Photothermographic material
    • 光热成像材料
    • US20060110691A9
    • 2006-05-25
    • US10760496
    • 2004-01-21
    • Tomoyuki OhzekiHiroyuki MifuneKatsuyuki WatanabeEiichi Okutsu
    • Tomoyuki OhzekiHiroyuki MifuneKatsuyuki WatanabeEiichi Okutsu
    • G03C5/16
    • G03C1/49845G03C1/04G03C1/49818G03C1/49827G03C1/49863G03C1/49881G03C7/30541G03C2005/166G03C2200/36G03C2200/39
    • A photothermographic material including an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder on the same surface of a support, wherein the photothermographic material contains a compound having an adsorption group to silver halide and a reducing group, or a precursor of the compound, and satisfies one of the following conditions: 1) the photothermographic material contains a development accelerator; 2) the non-photosensitive organic silver contains silver behenate in an amount of not less than 80% by mole, and the binder has a glass transition temperature (Tg) of 45° C. or less; or 3) the photothermographic material contains at least one compound represented by the following formula (H); Q-(Y)n—C(Z1)(Z2)X wherein, in formula (H), Q represents an alkyl group, an aryl group or a heterocyclic group; Y represents a divalent linking group; n represents 0 or 1; Z1 and Z2 each independently represent a halogen atom; and X represents a hydrogen atom or an electron attracting group.
    • 一种光热敏成像材料,其包括在载体的同一表面上至少含有感光卤化银,非感光性有机银盐,还原剂和粘合剂的成像层,其中光热敏成像材料含有具有吸附基团的化合物 卤化银和还原基团或化合物的前体,并且满足以下条件之一:1)光热敏成像材料含有显影促进剂; 2)非感光性有机银含有不小于80摩尔%的山嵛酸银,并且粘合剂的玻璃化转变温度(Tg)为45℃以下; 或3)光热照相材料含有至少一种由下式(H)表示的化合物; <?in-line-formula description =“In-line Formulas”end =“lead”?> Q-(Y) -C(Z 1) 其中,在式(H)中,Q表示烷基,芳基或芳基, 杂环基; Y表示二价连接基团; n表示0或1; Z 1和Z 2各自独立地表示卤素原子; X表示氢原子或吸电子基团。
    • 25. 发明授权
    • Internal latent image type direct positive silver halide emulsions and
process for producing the same
    • 内部潜像型直接正卤化银乳剂及其制造方法
    • US4863845A
    • 1989-09-05
    • US82922
    • 1987-08-06
    • Ashita MuraiHiroyuki MifuneTatsuo Heki
    • Ashita MuraiHiroyuki MifuneTatsuo Heki
    • G03C1/005G03C1/485G03C8/06
    • G03C1/48576Y10S430/141Y10S430/144
    • In an internal latent image type direct positive silver halide emulsion containing core/shell type silver halide grains wherein at least light-sensitive sites of the silver halide internal core which has been subjected to doping with metal ions or chemical sensitization, or both, is covered with a silver halide outer shell, the improvement wherein a photographic additive which is adsorbed on silver halide in said emulsion or interacts with silver ion, said additive being a compound which functions to change the crystal form or particle size of the silver halide grains in the case of the formation thereof or acts as a sensitizer or a sensitizing assistant in the case of chemically sensitizing the core particles but has a harmful influence on photographic properties if it remains after use of it, is deactivated by a deactivator prior to completion of the formation of said core/shell type silver halide grains or completion of surface chemical ripening of said grains. A process for producing the above internal latent image type direct positive silver halide emulsion is also disclosed.
    • 在包含核/壳型卤化银颗粒的内部潜像型直接正卤化银乳剂中,其至少覆盖已经被金属离子掺杂或化学增感的卤化银内核的光敏部位或两者覆盖 具有卤化银外壳的改进,其中吸附在所述乳液中的卤化银上或与银离子相互作用的照相添加剂,所述添加剂是用于改变卤化银颗粒的结晶形式或粒度的化合物 形成的情况或作为敏化剂或敏化助剂,在对核心颗粒进行化学敏化的情况下,但如果在使用之后仍然对照相特性有影响,则在形成之前由钝化剂失活 的所述核/壳型卤化银颗粒或完成所述颗粒的表面化学成熟。 还公开了制备上述内部潜像型直接正卤化银乳剂的方法。
    • 30. 发明授权
    • Silver halide photographic light-sensitive element
    • 卤化银照相感光元件
    • US4334010A
    • 1982-06-08
    • US284164
    • 1981-07-17
    • Hiroyuki MifuneShoji IshiguroTadao ShishidoYoshiharu FuseyaTeruaki Tsujikawa
    • Hiroyuki MifuneShoji IshiguroTadao ShishidoYoshiharu FuseyaTeruaki Tsujikawa
    • C07C13/20C07D333/22C07D335/02G03C1/34
    • G03C1/34C07D333/22
    • A silver halide photographic light-sensitive element is described comprising a support having thereon at least one silver halide emulsion layer, wherein at least one compound represented by formula (I) is incorporated in the silver halide emulsion layer or in another hydrophilic colloid layer: ##STR1## wherein X represents a hydroxy group or a group represented by ##STR2## wherein R.sup.2 and R.sup.3 (which may be the same or different) each reprsents hydrogen, an alkyl group, or an aryl group; R.sup.1 represents a sulfur-containing saturated heterocyclic group or a group represented by -A-S-B, wherein A represents an alkylene group and B represents hydrogen, an alkyl group, or an aryl group; and Z represents an atomic group forming a 5-membered or 6-membered unsubstituted or substituted carbocyclic ring.In the silver halide photographic light-sensitive element, the so-called "latent image fading" phenomenon is prevented without accompanying degradation of other photograhic properties.
    • 描述了一种卤化银照相感光元件,其包括其上具有至少一个卤化银乳剂层的载体,其中至少一种由式(I)表示的化合物引入卤化银乳剂层或另一亲水胶体层中: 图像(I)其中X表示羟基或由其表示的基团,其中R2和R3(可以相同或不同)各自代表氢,烷基或芳基; R1表示含硫的饱和杂环基或由-A-S-B表示的基团,其中A表示亚烷基,B表示氢,烷基或芳基; Z表示形成5元或6元未取代或取代的碳环的原子团。 在卤化银摄影感光元件中,防止所谓的“潜像褪色”现象,而不伴随着其它光致变色性能的降低。