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21. 发明授权

US4717451A Process for the preparation of anthraquinone dispersions and their use in alkaline wood digestion processes 失效
标题翻译：制备蒽醌分散体的方法及其在碱性木材消化过程中的应用
公开(公告)号：US4717451A
公开(公告)日：1988-01-05
申请号：US810405
申请日：1985-12-18
申请人： Michel Devic , Jean-Pierre Schirmann
发明人： Michel Devic , Jean-Pierre Schirmann
IPC分类号： C07C50/18 , C07C45/00 , C07C46/00 , C07C67/00 , D21C3/00 , D21C3/20
CPC分类号： C07C46/00
摘要： The process of making a wet or dry dispersion containing anthraquinone suitable for use in the alkaline digestion of wood comprising cyclizing ortho-benzoylbenzoic acid at a temperature of about 150.degree. to 180.degree. C. and at an absolute pressure between about 5 and 40 millibars in the presence of between about 0.05 to 2 parts by weight of sulfuric acid, having a concentration of at least about 95%, per part by weight of ortho-benzoylbenzoic acid to form a reaction mixture containing anthraquinone, bringing the reaction mixture to a pH of at least about 7 by addition thereto at a temperature between about ambient temperature and 100.degree. C. of an aqueous solution of sodium hydroxide or potassium hydroxide containing between about 10% to 40% hydroxide by weight, and then forming a dispersion thereof and using such dispersion in the alkaline digestion of wood.
摘要翻译：制备适合用于木材碱性消化的含有蒽醌的湿或干分散体的方法，包括在约150-180℃的温度和绝对压力为约5至40毫巴之间环化邻苯甲酰基苯甲酸，存在约0.05至2重量份的浓度为至少约95重量％的邻苯甲酰基苯甲酸的至少约95重量％的硫酸，以形成含有蒽醌的反应混合物，使反应混合物的pH为在大约环境温度和100℃之间的温度下加入至少约7的氢氧化钠或氢氧化钾水溶液，其含有约10重量％至40重量％的氢氧化物，然后形成其分散体，并使用它们分散在木材的碱性消化中。

22. 发明授权

US4159991A Acyloxy-N,N'-diacylmalonamides and methods for their preparation 失效
标题翻译：酰氧基-N，N {40-二酰基丙二酰胺及其制备方法
公开(公告)号：US4159991A
公开(公告)日：1979-07-03
申请号：US826478
申请日：1977-08-22
申请人： Bernard Dubreux , Serve Y. Delavarenne , Jean-Pierre Schirmann
发明人： Bernard Dubreux , Serve Y. Delavarenne , Jean-Pierre Schirmann
IPC分类号： C07C309/59 , C07C20060101 , C07C67/00 , C07C231/00 , C07C231/14 , C07C233/90 , C07C235/88 , C07C301/00 , C07C313/00 , C07C315/04 , C07C317/00 , C07C317/44 , C07D20060101 , C09F5/00 , C11D20060101 , C11D1/28 , C11D3/39 , C11D3/395 , C11D7/54 , C07C143/90
CPC分类号： C07C255/00
摘要： .alpha.-Acyloxy-N,N'-diacylmalonamides of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different and are hydrogen, straight chain or branched alkyl radicals having from one to eleven carbon atoms, or hydrocarbon radicals with six to twelve carbon atoms and comprising at least one aromatic ring, are novel compounds prepared by the action of a mixture of carboxylic acids R.sub.3 COOH and R.sub.4 COOH upon an .alpha.-acyloxymalononitrile, R.sub.1 COO--C(CN).sub.2 --R.sub.2, in the presence of an acid catalyst and are useful as intermediates in organic synthesis and low temperature activators in bleaching or scouring compositions.
摘要翻译：式中，R 1，R 2，R 3和R 4相同或不同，为氢，具有1至11个碳原子的直链或支链烷基，或碳原子数为1〜7的α-甲酰氧基-N，N'-二酰基丙二酰胺具有6至12个碳原子并且包含至少一个芳环的基团是通过羧酸R 3 COOH和R 4 COOH的混合物在α-酰氧基丙二腈，R 1 COO-C（CN）2 -R 2）的作用下制备的新化合物的酸催化剂，可用作漂白或冲洗组合物中有机合成和低温活化剂的中间体。

23. 发明授权

US3953480A Epoxidation of olefins by hydrogen peroxide 失效
标题翻译：用过氧化氢环氧化烯烃
公开(公告)号：US3953480A
公开(公告)日：1976-04-27
申请号：US510461
申请日：1974-09-30
申请人： Serge Delavarenne , Francis Weiss , Jean-Pierre Schirmann
发明人： Serge Delavarenne , Francis Weiss , Jean-Pierre Schirmann
IPC分类号： B01J21/00 , B01J23/00 , B01J31/00 , B01J31/20 , C07B61/00 , C07D301/12 , C07D303/04
CPC分类号： B01J31/122 , B01J31/20 , C07D301/12 , C07D303/04 , B01J2231/72 , B01J2531/44 , B01J2531/64 , B01J2531/66 , Y02P20/52
摘要： An oxirane compound is prepared by reacting an olefinically unsaturated compound with hydrogen peroxide in the presence both of (i) at least one lead compound, exemplarily triethyl lead hydroxide and also of (ii) at least one compound of a group IV-A, V-A or VI-A transition metal exemplarily tungsten hexacarbonyl. The epoxided products are useful in the manufacture of plastics, adhesives and the like.
摘要翻译：在（i）至少一种铅化合物，例如三乙基氢氧化铅和（ii）至少一种IV-A，VA的化合物的存在下，使烯属不饱和化合物与过氧化氢反应制备环氧乙烷化合物或VI-A过渡金属示例性地为六羰基钨。环氧化产品可用于制造塑料，粘合剂等。

24. 发明授权

US06881698B2 Ion liquids derived from Lewis acid based on titanium, niobium, tantalum, tin or antimony, and uses thereof 有权
标题翻译：衍生自基于钛，铌，钽，锡或锑的路易斯酸的离子液体及其用途
公开(公告)号：US06881698B2
公开(公告)日：2005-04-19
申请号：US10258481
申请日：2001-04-24
申请人： Phillippe Bonnet , Eric Lacroix , Jean-Pierre Schirmann
发明人： Phillippe Bonnet , Eric Lacroix , Jean-Pierre Schirmann
IPC分类号： C07D233/02 , B01J31/26 , B01J31/38 , C07B39/00 , C07B61/00 , C07C17/10 , C07C17/20 , C07C17/21 , C07C19/08 , C07C19/10 , C07C211/63 , C07C381/12 , C07D213/20 , C07D233/54 , C07D521/00 , C07F7/00 , C07F9/00 , C07F9/54 , C07F9/6568 , C07F9/90 , B01J31/00
CPC分类号： C07D213/20 , C07B39/00 , C07C17/206 , C07C17/21 , C07C381/12 , C07D231/12 , C07D233/56 , C07D249/08 , C07F7/003 , C07F9/005 , C07F9/54 , C07F9/65688 , C07F9/902
摘要： The ionic liquids according to the invention result from the reaction of a halogenated or oxyhalogenated Lewis acid based on titanium, niobium, tantalum, tin or antimony with an organic salt of formula X+A− in which A− is a halide anion and X+ a quaternary ammonium, quaternary phosphonium or ternary sulphonium cation. These liquids can be used in particular in the liquid-phase fluorination using HF of saturated or unsaturated compounds having C—Cl groups.
摘要翻译：根据本发明的离子液体是由基于钛，铌，钽，锡或锑的卤化或卤代卤代的路易斯酸与式XO的有机盐的反应而产生的， / SUP>其中A +为卤化物阴离子，X +为季铵，季鏻或三元锍阳离子。这些液体可以特别用于使用具有C-Cl基团的饱和或不饱和化合物的HF的液相氟化。

25. 发明授权

US06649560B2 Bulk catalysts based on chromium and on nickel for the gas-phase fluorination of halogenated hydrocarbons 有权
标题翻译：基于铬和镍的散装催化剂用于卤代烃的气相氟化
公开(公告)号：US06649560B2
公开(公告)日：2003-11-18
申请号：US10107242
申请日：2002-03-28
申请人： Eric Lacroix , Jean-Pierre Schirmann
发明人： Eric Lacroix , Jean-Pierre Schirmann
IPC分类号： B01J2706
CPC分类号： B01J23/866 , C07C17/206 , C07C17/21
摘要： Catalysts which are useful in the fluorination of halogenated hydrocarbons by HF in the gas phase are obtained by simple impregnation of a bulk chromium oxide with a solution of a nickel derivative, the chromium oxide used exhibiting a BET specific surface of greater than 150 m2/g and a pore volume of greater than 0.15 ml/g.
摘要翻译：可用于通过HF在气相中氟化卤代烃的催化剂通过用镍衍生物的溶液简单浸渍体积氧化铬而获得，所用的氧化铬显示BET比表面积大于150m 2 > g，孔体积大于0.15ml / g。

26. 发明授权

US06605265B1 Continuous production of azines/hydrazine hydrate 失效
标题翻译：连续生产吖嗪/水合肼
公开(公告)号：US06605265B1
公开(公告)日：2003-08-12
申请号：US08217752
申请日：1994-03-25
申请人： Jean-Pierre Schirmann , Jean-Pierre Pleuvry , Pierre Tellier
发明人： Jean-Pierre Schirmann , Jean-Pierre Pleuvry , Pierre Tellier
IPC分类号： C01B2116
CPC分类号： C01B21/16 , C07C249/00 , C07C251/88 , Y02P20/582
摘要： Azines, e.g., ketazines, are continuously produced by (i) establishing a loop having an azine reaction medium circulating therein, such loop including an azine reaction zone, means for separating azine final product from the circulating reaction medium, means for heating the reaction medium and for purging water therefrom, and means for recycling heated and purged reaction medium to the azine reaction zone, (ii) introducing hydrogen peroxide, ammonia and a carbonyl compound into the circulating reaction medium in the azine reaction zone, (iii) withdrawing azine final product thus formed from the circulating reaction medium. downstream of the azine reaction zone, (iii) thereafter purging water from the circulating reaction medium to maintain the volume thereof essentially constant, (iv) heating the circulating reaction medium to a temperature of at least 130° C., (v) recycling thus heated reaction medium to the azine reaction zone, and (vi), at any point along the loop, introducing a reagent into the circulating reaction medium as to essentially maintain the equilibrium of the azine-forming reaction; the final product azines are conveniently hydrolyzed into hydrazine hydrate.
摘要翻译：通过（i）建立其中循环其中的吖嗪反应介质的环，包括吖嗪反应区的环路，用于从循环反应介质中分离吖嗪最终产物的装置，连续制备氮杂环丁烷，例如加入反应介质和用于从其中清洗水的装置，以及用于将加热和净化的反应介质再循环到吖嗪反应区的装置，（ii）在吖嗪反应区中将过氧化氢，氨和羰基化合物引入循环反应介质中，（iii）由循环反应介质形成的产物。（iii）然后从循环反应介质中清洗水以使其体积保持基本恒定，（iv）将循环反应介质加热到至少130℃的温度，（v）由此回收加热的反应介质到吖嗪反应区，和（vi）在沿着环的任何点，将试剂引入循环反应介质中，从而基本维持吖嗪形成反应的平衡; 最终产物吖嗪方便地水解成水合肼。

27. 发明授权

US6019870A Process for the preparation of delignified and bleached chemical paper pulps 失效
标题翻译：制备脱木素和漂白化学纸浆的方法
公开(公告)号：US6019870A
公开(公告)日：2000-02-01
申请号：US737684
申请日：1997-01-17
申请人： Michel Devic , Jean-Pierre Schirmann
发明人： Michel Devic , Jean-Pierre Schirmann
IPC分类号： D21C9/10 , D21C9/16 , D21C9/147
CPC分类号： D21C9/1026 , D21C9/1042 , D21C9/163
摘要： A process of dignifying lignocellulosic pulp with oxygen followed by treatment of the delignified pulp with a chelating agent, followed by washing, followed by treatment with hydrogen peroxide at an alkaline pH in the presence of an alkali metal silicate at a temperature greater than 100.degree. C. and a pressure greater than 1.5 times the saturated vapor pressure.
摘要翻译： PCT No.PCT / FR95 / 00494 Sec。 371日期1997年1月17日 102（e）日期1997年1月17日PCT提交1995年4月14日PCT公布。出版物WO95 / 31599 日期1995年11月23日一种使木质纤维素纸浆氧化的方法，然后用螯合剂处理脱木素纸浆，然后洗涤，随后在碱性pH下在碱金属硅酸盐存在下用过氧化氢处理温度大于100℃，压力大于饱和蒸汽压力的1.5倍。

28. 发明授权

US4996039A Production of hydrogen peroxide 失效
标题翻译：生产过氧化氢
公开(公告)号：US4996039A
公开(公告)日：1991-02-26
申请号：US420514
申请日：1989-10-12
申请人： Christian Pralus , Jean-Pierre Schirmann
发明人： Christian Pralus , Jean-Pierre Schirmann
IPC分类号： C01B15/029
CPC分类号： C01B15/029
摘要： Hydrogen peroxide is produced from hydrogen and oxygen by (a) intimately contacting gaseous hydrogen at superatmospheric pressure with an inorganic aqueous reaction medium which includes a catalytically effective amount of a platinum group metal catalyst, (b) next diminishing the amount of hydrogen in the gaseous phase to a value under the explosive/flammable limits of admixture thereof with the gaseous oxygen introduced in step (c), and (c) intimately contacting and reacting the aqueous reaction medium and diminished gaseous phase with a source of gaseous oxygen.
摘要翻译：氢过氧化氢是通过（a）在超大气压下将气态氢气与包含催化有效量的铂族金属催化剂的无机水性反应介质紧密接触而产生的，（b）接着减少气态氢气的量相到在与步骤（c）中引入的气态氧的混合物的爆炸/可燃极限值，和（c）使水性反应介质和减少的气相与气态氧气的紧密接触和反应。

29. 发明授权

US4128494A Activators for percompounds 失效
标题翻译：激活剂用于化合物
公开(公告)号：US4128494A
公开(公告)日：1978-12-05
申请号：US822145
申请日：1977-08-05
申请人： Jean-Pierre Schirmann , Bernard Dubreux , Michel Bakes , Serge-Yvon Delavarenne , Marie-Christine Daude-Lagrave
发明人： Jean-Pierre Schirmann , Bernard Dubreux , Michel Bakes , Serge-Yvon Delavarenne , Marie-Christine Daude-Lagrave
IPC分类号： A61K8/22 , A61K8/38 , A61K8/42 , A61Q5/08 , A61Q19/02 , C11D3/39 , C23C22/06 , C11D3/395 , C11D7/54 , D06L3/02
CPC分类号： A61Q19/02 , A61K8/22 , A61K8/38 , A61K8/42 , A61Q5/08 , C11D3/3917 , C23C22/06
摘要： Novel percompound activators having the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are the same or different and are hydrogen or certain substituted or unsubstituted straight or branched chain alkyl radicals, cycloalkyl radicals, or hydrocarbon radicals containing at least one aromatic ring, or R.sub.5 and/or R.sub.6 are COR.sub.7, where R.sub.7 is hydrogen or certain substituted or unsubstituted straight or branched chain alkyl radicals or hydrocarbon radicals containing at least one aromatic ring, the activators producing more rapid bleaching or oxidation at a given temperature or the same bleaching effect at a lower temperature and being useful for bleaching textile fibers, oils, fats, and waxes; hair and skin treatment; metal surface passivation; or purifying, sterilizing and disinfecting techniques.
摘要翻译：具有式“IMAGE”的新型全合成活化剂，其中R 1，R 2，R 3，R 4，R 5和R 6相同或不同，为氢或某些取代或未取代的直链或支链烷基，环烷基或含有至少一个芳环，或R 5和/或R 6为COR 7，其中R 7为氢或某些取代或未取代的直链或支链烷基或含有至少一个芳环的烃基，所述活化剂在给定的条件下产生更快的漂白或氧化温度或在较低温度下具有相同的漂白效果，并且可用于漂白纺织纤维，油，脂肪和蜡; 头发和皮肤治疗; 金属表面钝化; 或净化，消毒和消毒技术。

30. 发明授权

US3984451A Method for preparing hydrazo-bis-acetonitriles 失效
标题翻译：制备双氢 - 二乙腈的方法
公开(公告)号：US3984451A
公开(公告)日：1976-10-05
申请号：US579548
申请日：1975-05-21
申请人： Francis Weiss , Jean-Pierre Schirmann
发明人： Francis Weiss , Jean-Pierre Schirmann
IPC分类号： C07C255/66 , C07C120/00
CPC分类号： C07C251/88 , C07C255/00
摘要： This invention relates to a method for preparing hydrazo-bis-acetonitriles of the general formula: ##EQU1## wherein R.sub.1 and R.sub.2 have the same meaning hereinafter given, which comprises:A. i. reacting a carbonyl compound of the general formula: ##EQU2## wherein R.sub.1 and R.sub.2 have the same meaning hereinafter given, with ammonia and hydrogen peroxide in the presence of cyanogen or a nitrile of the formulaR.sub.3 (CN).sub.n (III)wherein n is an integer from 1 to 6 and R.sub.3 is an unsubstituted or substituted saturated aliphatic, acyclic or cyclic radical of from 1 to 12 carbon atoms or a benzenyl or pyridinyl radical, to form a symmetrical azine of the formula ##EQU3## ii. oxidizing a secondary alcohol of ##EQU4## wherein R.sub.1 and R.sub.2 have the same meaning hereinafter given, at a temperature and pressure which is sufficient to maintain the alcohol in the liquid phase and result in a liquid phase mixture containing the peroxidic products of the auto-oxidation of the alcohol [v] and reacting auto-oxidation products with ammonia and cyanogen or the nitrile R.sub.3 (CN).sub.n of formula (III) to form the symmetrical azine of formula (IV)b. eliminating unreacted ammonia from the medium resulting from (a);C. reacting the azine of formula (IV) contained in the ammonia-free medium resulting from (b) with at least two moles of hydrocyanic acid per mole of azine; andD. recovering the hydrazo-bis-acetonitrile of formula (I).
摘要翻译：本发明涉及通式为R1R1 || NC-C-NH-NH-C-CN（Ⅰ）| R2R2的双氢 - 二乙腈制备方法，其中R1和R2具有以下相同的含义，包含：

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