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    • 21. 发明申请
    • USE OF COPOLYMERS CONTAINING SULFONIC ACID GROUPS, AS AN ADDITIVE IN DETERGENTS AND CLEANSERS
    • 含有硫酸组合物的共聚物作为添加剂在洗涤剂和清洁剂中的应用
    • US20080281053A1
    • 2008-11-13
    • US12181900
    • 2008-07-29
    • Pia BaumKathrin MichlFranz WeingartStephan NiedGregor Brodt
    • Pia BaumKathrin MichlFranz WeingartStephan NiedGregor Brodt
    • C08F228/02C08F230/04
    • C11D3/378
    • Use of copolymers containing sulfonic acid groups which comprise (a) 30 to 95 mol % of at least one monoethylenically unsaturated carboxylic acid, one monoethylenically unsaturated carboxylic ester or one water-soluble salt of a monoethylenically unsaturated carboxylic acid, (b) 3 to 35 mol % of at least one monomer containing sulfonic acid groups of the formula I in which the variables have the following meanings: R is hydrogen or methyl; X is a chemical bond or —COO—R1—; R1 is unbranched or branched C1-C4-alkylene; M is hydrogen, alkali metal or ammonium, and (c) 2 to 35 mol % of at least one nonionic monomer of the formula II in which the variables have the following meanings: R2 is hydrogen or methyl; R3 is a chemical bond or unbranched or branched C1-C6-alkylene; R4 are identical or different unbranched or branched C2-C4-alkylene radicals; R5 is unbranched or branched C1-C6-alkyl, C5-C8-cycloalkyl or aryl; n is 3 to 50, in random or block copolymerized form, as additive for detergents and cleaners.
    • 使用包含(a)30-95摩尔%至少一种单烯属不饱和羧酸,一种单烯属不饱和羧酸酯或一种单烯属不饱和羧酸的一种水溶性盐的磺酸基团的共聚物,(b)3-35 mol%的至少一种含有式I磺酸基的单体,其中变量具有以下含义:R是氢或甲基; X是化学键或-COO-R 1 - R 1是非支链或支链C 1 -C 4 - 亚烷基; M是氢,碱金属或铵,和(c)2-35mol%的至少一种式II的非离子单体,其中变量具有以下含义:R 2是氢或甲基 ; R 3是化学键或无支链或支链C 1 -C 6 - 亚烷基; R 4是相同或不同的未支链或支链C 2 -C 4 - 亚烷基; R 5是非支链或支链C 1 -C 6 - 烷基,C 5 -C 8 环烷基或芳基; n为3至50,以无规或嵌段共聚形式,作为洗涤剂和清洁剂的添加剂。
    • 27. 发明授权
    • Copolymers comprising N-heterocyclic groups, and use thereof as an additive in detergents
    • 包含N-杂环基团的共聚物及其作为洗涤剂中的添加剂的用途
    • US07728063B2
    • 2010-06-01
    • US11587584
    • 2005-04-26
    • Gregor BrodtPia BaumTanja SeebeckMarcus Guzmann
    • Gregor BrodtPia BaumTanja SeebeckMarcus Guzmann
    • A61K9/16C08F8/30C08F290/06C08F20/58C08F18/00C08F16/12C08F116/12
    • C11D3/3776C11D3/0021
    • The present invention relates to the use of a copolymer comprising, in polymerized form, (a) from 80 to 99.9 mol %, based on the total amount of the monomers polymerized to prepare the copolymer, of at least one monomer A which in each case comprises a heterocycle having at least 1 nitrogen atom and composed of from 3 to 10 ring members and a C2-C6-alkenyl group bonded to a carbon or nitrogen ring atom of the heterocycle; and (b) from 0.1 to 20 mol %, based on the total amount of the monomers polymerized to prepare the copolymer, of at least one monomer B copolymerizable with monomer A, said monomer B having a monoethylenically unsaturated double bond and also a linear or branched poly-C2-C4-alkylene oxide group having on average from 4 to 500 C2-C4-alkylene oxide units, in liquid and in solid detergent formulations. In addition, the invention relates to a process for preparing such a copolymer, and also to a liquid or solid detergent formulation comprising at least one such copolymer.
    • 本发明涉及共聚物的用途,所述共聚物以聚合形式包含(a)基于聚合制备共聚物的单体总量的80至99.9mol%的至少一种单体A,其在每种情况下 包括具有至少1个氮原子并由3至10个环成员组成的杂环和与该杂环的碳或氮环原子键合的C 2 -C 6 - 链烯基; 至少一种可与单体A共聚的单体B,所述单体B具有单烯键式不饱和双键,并且还包括直链或者直链或不饱和的双键,并且(b)0.1至20摩尔%,基于聚合以制备共聚物的单体的总量, 在液体和固体洗涤剂配方中平均具有4至500个C 2 -C 4 - 烯化氧单元的支链多C 2 -C 4 - 烯化氧基团。 此外,本发明涉及一种制备这种共聚物的方法,还涉及包含至少一种这样的共聚物的液体或固体洗涤剂制剂。