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    • 22. 发明授权
    • Molecular devices activated by an electric field for electronic ink and other visual display
    • 通过电场激活的分子器件用于电子墨水等视觉显示
    • US06805817B2
    • 2004-10-19
    • US09932186
    • 2001-08-17
    • Xiao-An ZhangAlexandre BratkovskiYong ChenR. Stanley WilliamsKent D. Vincent
    • Xiao-An ZhangAlexandre BratkovskiYong ChenR. Stanley WilliamsKent D. Vincent
    • H01B112
    • G11C13/0014B82Y10/00C09D11/03C09D11/50C09K9/02G02B26/026G02F1/15G02F1/17G02F1/174G11C13/02G11C13/04G11C23/00G11C2213/14G11C2213/77
    • An electric field activated molecular system, preferably bi-stable, configured within an electric field generated by a pair of electrodes is provided for use, e.g., as electronic ink or other visual displays. The molecular system has an electric field induced band gap change that occurs via a change (reversible or irreversible) of the extent of the electron conjugation via chemical bonding change to change the band gap, wherein in a first state, there is substantial conjugation throughout the molecular system, resulting in a relatively smaller band gap, and wherein in a second state, the substantial conjugation is destroyed, resulting in a relatively larger band gap. The changing of substantial conjugation may be accomplished in one of the following ways: (1) charge separation or recombination accompanied by increasing or decreasing electron localization in the molecule; or (2) change of substantial conjugation via charge separation or recombination and&pgr;-bond breaking or making. A primary advantage of the molecular system is improved contrast. Because the colorant of the present invention is molecular and thus effectively monoplanar, there should be no backside reflection or excessive scattering from the colorant. A second advantage of the present invention is improved resolution. Finally, each molecule of the present invention will latch to stabilize one or the other of its color states.
    • 提供了在由一对电极产生的电场内配置的电场活化分子系统,优选双稳态,用于例如电子墨水或其它视觉显示器。 分子系统具有电场诱导的带隙变化,其通过经由化学键合改变的电子共轭程度的变化(可逆的或不可逆的)发生,以改变带隙,其中在第一状态下,在整个 分子系统,导致相对较小的带隙,并且其中在第二状态下,基本共轭被破坏,导致相对较大的带隙。 基本共轭的改变可以通过以下方式之一来实现:(1)伴随着分子中电子定位增加或减少的电荷分离或重组; 或(2)通过电荷分离或重组和断裂或制造改变基本共轭。 分子系统的主要优点是对比度提高。 因为本发明的着色剂是分子的,因此有效地是单面的,所以不应该有着色剂的背面反射或过度的散射。 本发明的第二个优点是分辨率提高。 最后,本发明的每个分子将锁定以稳定其一个或多个其颜色状态。
    • 24. 发明授权
    • Capacitive latched bi-stable molecular switch
    • 电容锁存双稳分子开关
    • US07580239B2
    • 2009-08-25
    • US11478278
    • 2006-06-29
    • Kent D. VincentXiao-An Zhang
    • Kent D. VincentXiao-An Zhang
    • H01G4/06G02F1/035H01L35/24H01L51/00
    • H01G7/023
    • A charge storage cell is made up of two electrodes spaced apart by a dielectric layer incorporating a molecular switch. A method of operating a bi-stable, molecular switch charge storage cell encompassing two electrodes spaced apart by a dielectric layer incorporating a molecular switch having an electric dipole is also disclosed. The method involves applying a voltage across said dielectric layer to induce opposing charges on said electrodes that create an electric field across said dielectric layer, wherein molecular dipoles within said dielectric layer align or change in response to said electric field, creating an opposing electric field and a change in state of said molecular switch from a first state to a second state; and applying a voltage of reverse polarity across said dielectric aver to change said state of said molecular switch from said second state to said first state.
    • 电荷存储单元由两个电极组成,两个电极由并入有分子开关的电介质层隔开。 还公开了一种操作双稳态分子开关电荷存储单元的方法,所述双稳态分子开关电荷存储单元包含由掺有具有电偶极子的分子开关的电介质层隔开的两个电极。 所述方法包括在所述电介质层上施加电压以在所述电极上产生相反的电荷,所述电荷在所述电介质层上产生电场,其中所述电介质层内的分子偶极子响应于所述电场对准或改变,产生相对的电场, 所述分子开关从第一状态到第二状态的状态变化; 并且在所述介电平均值上施加相反极性的电压以将所述分子开关的所述状态从所述第二状态改变到所述第一状态。
    • 30. 发明授权
    • Scanning, copying, and printing with rewritable media
    • 使用可重写介质进行扫描,复制和打印
    • US06806453B1
    • 2004-10-19
    • US10051669
    • 2002-01-17
    • Kent D. VincentXia-An ZhangR. Stanley WilliamsPhilip J. Kuekes
    • Kent D. VincentXia-An ZhangR. Stanley WilliamsPhilip J. Kuekes
    • H01L2700
    • B41J3/4076
    • A scan-print device is hand-held and is scanned over the surface of a paper-like rewritable sheet. The sheet has a colorant responsive to a linear array of pixel-sized electric fields written over the sheet by the scan-print device during each scan, producing a bistable pixel (e.g., black or white) in response to field polarity. The bi-stable, rewritable colorant is highly energy efficient, requiring energy only to change an image, not to hold or illuminate it. Once a series of scans sufficient to cover the entire sheet has been made, the printed image appears as if printed conventionally. The print remains stable until reprinted or intentionally erased. Combined with hand-held scanner-copier technology, a portable copier is also implemented.
    • 扫描打印设备是手持式的,并且被扫描在纸状可重写纸张的表面上。 片材具有响应于在每次扫描期间由扫描打印设备在片材上写入的像素尺寸的电场线性阵列的着色剂,响应于场极性产生双稳态像素(例如黑色或白色)。 双稳态可重写着色剂具有高能效,仅需要能量来改变图像,而不是保持或照亮图像。 一旦已经完成了足以覆盖整个片材的一系列扫描,印刷的图像看起来像传统上印刷一样。 打印保持稳定,直到转印或故意删除。 结合手持式扫描复印机技术,还实现了便携式复印机。